Obtaining and Characterization of Ni-Ti Alloys Processed through Powder Metallurgy

2017 ◽  
Vol 1143 ◽  
pp. 13-19
Author(s):  
Florentina Potecaşu ◽  
Octavian Potecaşu ◽  
Francisco Manuel Braz Fernandes ◽  
Petrică Alexandru ◽  
Alexandru Alexa
Keyword(s):  
Plastic Deformation ◽  
Powder Metallurgy ◽  
Severe Plastic Deformation ◽  
High Pressure Torsion ◽  
Niti Alloy ◽  
Ultrafine Grain ◽  
Mass Composition ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Fine Grain

This study presents the result of the researches regarding the obtaining of NiTi alloy through powder metallurgy (PM) as a possible alternative to present technologies (melting through induction in vacuum—MIV and re-melting with electric arch in vacuum—VAR). The researches made by the authors have aim at the obtaining of Ni-Ti materials with fine grain or ultrafine grain through powder metallurgy techniques, starting from ordinary metallic powders of Ti, Ni, Cu, with grain size less than 100 micrometers, and also using processing through severe plastic deformation (HPT — high pressure torsion). The fabrication through PM has an important advantage because a product requires low processing subsequent considering that it can get with sizes and shape very similar to the final ones, which is not negligible if one takes into account that the alloys Ni-Ti do not excel on cutting processability. Cylindrical samples were produced by cold uniaxial compression, at the specific pressure of 600 MPa, dosed in a proportion of 52.5 % Ni + 43.5 % Ti + 4.0 % Cu, mass composition. The compressed samples, after the sintering in vacuum and severe plastic deformation have been characterized by X-ray diffraction (XRD) , differential scanning calorimetry (DSC) and optical microscopy.

scholarly journals Crystallization Features of Amorphous Rapidly Quenched High Cu Content TiNiCu Alloys upon Severe Plastic Deformation

Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2670
Author(s):  
Alexander Glezer ◽  
Nikolay Sitnikov ◽  
Roman Sundeev ◽  
Alexander Shelyakov ◽  
Irina Khabibullina
Keyword(s):  
Plastic Deformation ◽  
Severe Plastic Deformation ◽  
Copper Content ◽  
Melt Spinning ◽  
High Pressure Torsion ◽  
Amorphous State ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Cu Content ◽  
Rapid Melt Quenching

In recent years, the methods of severe plastic deformation and rapid melt quenching have proven to be an effective tool for the formation of the unique properties of materials. The effect of high-pressure torsion (HPT) on the structure of the amorphous alloys of the quasi-binary TiNi–TiCu system with a copper content of more than 30 at.% produced by melt spinning technique has been analyzed using the methods of scanning electron microscopy, X-ray diffraction analysis, and differential scanning calorimetry (DSC). The structure examinations have shown that the HPT of the alloys with a Cu content ranging from 30 to 40 at.% leads to nanocrystallization from the amorphous state. An increase in the degree of deformation leads to a substantial change in the character of the crystallization reflected by the DSC curves of the alloys under study. The alloys containing less than 34 at.% Cu exhibit crystallization peak splitting, whereas the alloys containing more than 34 at.% Cu exhibit a third peak at lower temperatures. The latter effect suggests the formation of regions of possible low-temperature crystallization. It has been established that the HPT causes a significant decrease in the thermal effect of crystallization upon heating of the alloys with a high copper content relative to that of the initial amorphous melt quenched state.

scholarly journals Improved Tensile Ductility by Severe Plastic Deformation for Nano-Structured Metallic Glass

Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1611 ◽  
Author(s):  
Yue Dong ◽  
Suya Liu ◽  
Johannes Biskupek ◽  
Qingping Cao ◽  
Xiaodong Wang ◽  
...  
Keyword(s):  
Plastic Deformation ◽  
Plastic Strain ◽  
Severe Plastic Deformation ◽  
Volume Fraction ◽  
High Pressure Torsion ◽  
Homogeneous Material ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Strain Limit ◽  
Small Volume Fraction

The effect of severe plastic deformation by high-pressure torsion (HPT) on the structure and plastic tensile properties of two Zr-based bulk metallic glasses, Zr55.7Ni10Al7Cu19Co8.3 and Zr64Ni10Al7Cu19, was investigated. The compositions were chosen because, in TEM investigation, Zr55.7Ni10Al7Cu19Co8.3 exhibited nanoscale inhomogeneity, while Zr64Ni10Al7Cu19 appeared homogeneous on that length scale. The nanoscale inhomogeneity was expected to result in an increased plastic strain limit, as compared to the homogeneous material, which may be further increased by severe mechanical work. The as-cast materials exhibited 0.1% tensile plasticity for Zr64Ni10Al7Cu19 and Zr55.7Ni10Al7Cu19Co8.3. Following two rotations of HPT treatment, the tensile plastic strain was increased to 0.5% and 0.9%, respectively. Further testing was performed by X-ray diffraction and by differential scanning calorimetry. Following two rotations of HPT treatment, the initially fully amorphous Zr55.7Ni10Al7Cu19Co8.3 exhibited significantly increased free volume and a small volume fraction of nanocrystallites. A further increase in HPT rotation number did not result in an increase in plastic ductility of both alloys. Possible reasons for the different mechanical behavior of nanoscale heterogeneous Zr55.7Ni10Al7Cu19Co8.3 and homogeneous Zr64Ni10Al7Cu19 are presented.

New Type of Device for Achievement of Grain Refinement in Metal Strip

2015 ◽  
Vol 1127 ◽  
pp. 91-97 ◽  
Author(s):  
Stanislav Rusz ◽  
Lubomír Čížek ◽  
Vít Michenka ◽  
Jan Dutkiewicz ◽  
Michal Salajka ◽  
...  
Keyword(s):  
Plastic Deformation ◽  
Grain Size ◽  
Severe Plastic Deformation ◽  
Cross Section ◽  
Circular Cross Section ◽  
Ultrafine Grain ◽  
Metallic Materials ◽  
Forming Process ◽  
Fine Grain ◽  
Extrusion Technology

DRECE - Dual Rolls Equal Channel Extrusion" (dual rolls pressure combined with equal channel extrusion) method is used for production of metallic materials with very fine grain size (hereinafter referred to as UFG structure - Ultrafine Grain Size). During the actual forming process the principle of severe plastic deformation is used. The device is composed of the following main parts: “Nord” type gearbox, electric motor with frequency speed converter, multi-plate clutch, feed roller and pressure rollers with regulation of thrust, and of the forming tool itself – made of Dievar steel type. Metallic strip with dimensions 58×2×1000 mm (width x thickness x length) is inserted into the device. During the forming process the main cylinder in synergy with the pressure roller extrude the material through the forming tool without any change of cross section of the strip. In this way a significant refinement of grain is achieved by severe plastic deformation. This method is used for various types of metallic materials, non-ferrous metals and their alloys. Forming process is based on extrusion technology with zero reduction of thickness of the sheet metal with the ultimate aim - achieving a high degree of deformation in the formed material. The DRECE device is also being verified from the viewpoint of achievement of a UFG structure in a blank of circular cross-section (wire) with diameter of ø 8 mm × 1000 mm (length).

Processing of Aluminium Alloys by Severe Plastic Deformation

2006 ◽  
Vol 519-521 ◽  
pp. 45-54 ◽  
Author(s):  
Terence G. Langdon
Keyword(s):  
Plastic Deformation ◽  
High Pressure ◽  
Severe Plastic Deformation ◽  
Elevated Temperatures ◽  
High Pressure Torsion ◽  
Simple Procedure ◽  
Superplastic Forming ◽  
High Strength ◽  
Ultrafine Grain ◽  
Grain Sizes

Processing through the application of severe plastic deformation (SPD) has become important over the last decade because it is now recognized that it provides a simple procedure for producing fully-dense bulk metals with grain sizes lying typically in the submicrometer range. There are two major procedures for SPD processing. First, equal-channel angular pressing (ECAP) refers to the repetitive pressing of a metal bar or rod through a die where the sample is constrained within a channel bent through an abrupt angle at, or close to, 90 degrees. Second, high-pressure torsion (HPT) refers to the procedure in which the sample, generally in the form of a thin disk, is subjected to a very high pressure and concurrent torsional straining. Both of these processes are capable of producing metallic alloys with ultrafine grain sizes and with a reasonable degree of homogeneity. Furthermore, the samples produced in this way may exhibit exceptional mechanical properties including high strength at ambient temperature through the Hall-Petch relationship and a potential superplastic forming capability at elevated temperatures. This paper reviews these two procedures and gives examples of the properties of aluminum alloys after SPD processing.

scholarly journals Applications of Differential Scanning Calorimetry on Materials Subjected by Severe Plastic Deformation

2008 ◽  
Vol 584-586 ◽  
pp. 255-260 ◽  
Author(s):  
Nong Gao
Keyword(s):  
Differential Scanning Calorimetry ◽  
Plastic Deformation ◽  
Severe Plastic Deformation ◽  
High Pressure Torsion ◽  
Solid State Reactions ◽  
Scanning Calorimetry ◽  
Angular Pressing ◽  
Analysis Technique ◽  
Properties Of Materials ◽  
Solid Liquid

Differential Scanning Calorimetry (DSC) is a thermal analysis technique that measures the energy absorbed or released by a sample as a function of temperature or time. DSC has wide application for analysis of solid state reactions and solid-liquid reactions in many different materials. In recent years, DSC has been applied to analyze materials and alloys processed through Severe Plastic Deformation (SPD). The basic principle of SPD processing is that a very high strain is introduced into materials which achieve significant grain refinement and improve properties of materials. This review paper presents some recent examples of the applications of DSC for materials subjected to SPD, especially by Equal-Channel Angular Pressing and High-Pressure Torsion.

Influence of Deformation on Precipitation Kinetics in Mg-Tb Alloy

2012 ◽  
Vol 322 ◽  
pp. 151-162 ◽  
Author(s):  
Oksana Melikhova ◽  
Jakub Čížek ◽  
Petr Hruška ◽  
Marián Vlček ◽  
Ivan Procházka ◽  
...  
Keyword(s):  
Plastic Deformation ◽  
Severe Plastic Deformation ◽  
Grain Boundaries ◽  
Positron Annihilation ◽  
High Pressure Torsion ◽  
Coarse Grained ◽  
Scanning Calorimetry ◽  
Fine Grained ◽  
Β Phase ◽  
Lower Temperature

Precipitation effects in age-hardenable Mg-13wt.%Tb alloy were investigated in this work. The solution treated alloy was subjected to isochronal annealing and decomposition of the supersaturated solid solution was investigated by positron annihilation spectroscopy combined with transmission electron microscopy, electrical resistometry, differential scanning calorimetry and microhardness measurements. Peak hardening was observed at 200°C due to precipitation of finely dispersed particles of β phase with the D019structure. Vacancy-like defects associated with β phase particles were detected by positron annihilation. At higher temperatures precipitation of β and subsequently β phase takes place. Formation of these phases lead to some additional hardening and introduces open volume defects at precipitate/matrix interfaces. To elucidate the effect of plastic deformation on the precipitation sequence we studied also a Mg-13wt.%Tb alloy with ultra fine grained structure prepared by high pressure torsion. In the ultra fine grained alloy precipitation of the β phase occurs at lower temperature compared to the coarse grained material and the peak hardening is shifted to a lower temperature as well. This effect can be explained by enhanced diffusivity of Mg and Tb atoms due to a dense network of grain boundaries and high density of dislocations introduced by severe plastic deformation. Moreover, dislocations and grain boundaries serve also as nucleation sites for precipitates. Hence, precipitation effects are accelerated in the alloy subjected to severe plastic deformation.

scholarly journals Processing of Nanostructured Bulk Fe-Cr Alloys by Severe Plastic Deformation

2021 ◽  
Vol 1016 ◽  
pp. 1603-1610
Author(s):  
Lukas Weissitsch ◽  
Martin Stückler ◽  
Stefan Wurster ◽  
Richard Pippan ◽  
Andrea Bachmaier
Keyword(s):  
Electron Microscopy ◽  
Plastic Deformation ◽  
Severe Plastic Deformation ◽  
High Pressure Torsion ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Thermodynamical Equilibrium ◽  
X Ray ◽  
Σ Phase ◽  
Arc Melting

The processing of binary alloys consisting of ferromagnetic Fe and antiferromagnetic Cr by severe plastic deformation (SPD) with different chemical compositions has been investigated. Although the phase diagram exhibits a large gap in the thermodynamical equilibrium at lower temperatures, it is shown that techniques based on SPD help to overcome common processing limits. Different processing routes including initial ball milling (BM) and arc melting (AM) and a concatenation with annealing treatments prior to high-pressure torsion (HPT) deformation are compared in this work. Investigation of the deformed microstructures by electron microscopy and synchrotron X-ray diffraction reveal homogeneous, nanocrystalline microstructures for HPT deformed AM alloys. HPT deformation of powder blends and BM powders leads to an exorbitant increase in hardness or an unusual fast formation of a σ-phase and therefore impede successful processing.

Microstructure Development and Superplasticity in a Zn-22% Al Eutectoid Alloy Processed by Severe Plastic Deformation

2014 ◽  
Vol 783-786 ◽  
pp. 2647-2652 ◽  
Author(s):  
Megumi Kawasaki ◽  
Terence G. Langdon
Keyword(s):  
Plastic Deformation ◽  
Severe Plastic Deformation ◽  
High Pressure Torsion ◽  
Ultrafine Grain ◽  
Al Alloy ◽  
Grain Sizes ◽  
Angular Pressing ◽  
Flow Mechanisms ◽  
Superplastic Properties ◽  
Eutectoid Alloy

Severe plastic deformation (SPD) is an attractive processing method for refining microstructures to have ultrafine grain sizes within the submicrometer or even the nanometer levels. In SPD, the most promising techniques are equal-channel angular pressing (ECAP) and high-pressure torsion (HPT). A conventional superplastic Zn-22% Al eutectoid alloy was processed by ECAP and HPT. Experiments were conducted to demonstrate the evolution of hardness and microstructure and the enhancement of superplastic properties of the Zn-Al alloy after processing by the SPD techniques. In addition, flow mechanisms of the Zn-22% Al alloy are discussed by utilizing a deformation mechanism map.

Influence of Severe Plastic Deformation on Physicomechanical Properties of Ti-40 mas % Nb Alloy

2016 ◽  
Vol 685 ◽  
pp. 525-529
Author(s):  
Zhanna G. Kovalevskaya ◽  
Margarita A. Khimich ◽  
Andrey V. Belyakov ◽  
Ivan A. Shulepov
Keyword(s):  
Plastic Deformation ◽  
Severe Plastic Deformation ◽  
Cold Working ◽  
Young Modulus ◽  
Physicomechanical Properties ◽  
X Ray Diffraction ◽  
Refined Grains ◽  
X Ray ◽  
Initial Alloy ◽  
Composition Structure

The changes of the phase composition, structure and physicomechanical properties of Ti‑40 mas % Nb after severe plastic deformation are investigated in this paper. By the methods of microstructural, X-ray diffraction analysis and scanning electron microscopy it is determined that phase and structural transformations occur simultaneously in the alloy after severe plastic deformation. The martensitic structure formed after tempering disappears. The inverse α'' → β transformation occurs. The structure consisting of oriented refined grains is formed. The alloy is hardened due to the cold working. The Young modulus is equal to 79 GPa and it is less than that of initial alloy and close to the value obtained after tempering. It is possible that Young modulus is reduced by additional annealing.

MULTI-SCALE FINITE ELEMENT SIMULATION OF SEVERE PLASTIC DEFORMATION

2009 ◽  
Vol 23 (06n07) ◽  
pp. 1621-1626
Author(s):  
HYOUNG SEOP KIM
Keyword(s):  
Plastic Deformation ◽  
Finite Element ◽  
Severe Plastic Deformation ◽  
Constitutive Model ◽  
Dislocation Cell ◽  
Ultrafine Grain ◽  
Angular Pressing ◽  
Element Simulation ◽  
Ultrafine Grain Size ◽  
Ultrafine Grained

The technique of severe plastic deformation (SPD) enables one to produce metals and alloys with an ultrafine grain size of about 100 nm and less. As the mechanical properties of such ultrafine grained materials are governed by the plastic deformation during the SPD process, the understanding of the stress and strain development in a workpiece is very important for optimizing the SPD process design and for microstructural control. The objectives of this work is to present a constitutive model based on the dislocation density and dislocation cell evolution for large plastic strains as applied to equal channel angular pressing (ECAP). This paper briefly introduces the constitutive model and presents the results obtained with this model for ECAP by the finite element method.

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