The Development of UMo/Al Dispersion Fuel

2011 ◽  
Vol 335-336 ◽  
pp. 1285-1292 ◽  
Author(s):  
Xiao Liu ◽  
Da Zhi Qian ◽  
Tie Cheng Lu
Keyword(s):  
High Performance ◽  
Aluminum Matrix ◽  
Dispersion Fuel ◽  
Existing Problems ◽  
Irradiation Test ◽  
Fuel Fabrication ◽  
The Matrix ◽  
Further Development ◽  
Performance Research ◽  
Irradiation Behavior

UMo/Al dispersion fuel is one of the prospective materials as a high uranium density fuel for high performance research reactors due to its excellent stability during irradiation. In this paper, An overview is provided of current development activities of UMo/Al dispersion fuel at abroad and home, including: the development reasons, this fuel fabrication technology, and the irradiation test. A comprehensive summary is given on the irradiation test, the existing problems and the solution recently obtained by the different countries. Early irradiation experiments with uranium alloys showed promise of acceptable irradiation behavior if these alloys could be maintained in their cubic γ-U crystal structure. The further development of this fuel was delayed due to an unacceptable volume expansion caused by UMo/Al interaction layer (IL) formation and a subsequent gross pore formation at the interface between UMo particles and matrix Al when severe irradiation conditions are reached. In order to alleviate or eliminate the swelling of UMo/Al dispersion fuel,several potential remedies are available to correct the swelling problems. These range from relatively minor changes to the fuel and matrix chemistry, to replacement of the aluminum matrix with another material, or to eliminate the matrix altogether. All of these variations are currently being investigated in the world.

Irradiation behavior of atomized U–10wt.% Mo alloy aluminum matrix dispersion fuel meat at low temperature

2002 ◽  
Vol 211 (2-3) ◽  
pp. 229-235 ◽  
Author(s):  
Ki-Hwan Kim ◽  
Jong-Man Park ◽  
Chang-Kyu Kim ◽  
Gerard L. Hofman ◽  
Mitch K. Meyer
Keyword(s):  
Low Temperature ◽  
Aluminum Matrix ◽  
Dispersion Fuel ◽  
Fuel Meat ◽  
Irradiation Behavior

Fabrication of Carbon Nanotube/ Aluminum Matrix Functionally Graded Materials Using Centrifugal Slurry Methods

2021 ◽  
Vol 878 ◽  
pp. 31-40
Author(s):  
Satoshi Namigata ◽  
Hideaki Tsukamoto
Keyword(s):  
Carbon Nanotube ◽  
Functionally Graded Materials ◽  
High Performance ◽  
Inorganic Salt ◽  
Aluminum Matrix ◽  
Functionally Graded ◽  
Graded Materials ◽  
Dispersing Agent ◽  
The Matrix ◽  
Al Matrix

Carbon nanotube (CNT) has received broad scientific and industrial attention due to their excellent mechanical and functional properties. However, CNT has not been effectively used for high performance composites because of degradation of mechanical properties due to insufficient dispersibility of CNT in the matrix. In this study, CNT/ aluminum (Al) matrix functionally graded materials (FGMs) have been focused on. The processes of dispersion of CNT have been carried out with the solvent of dimethylacetamide, and the dispersing agent of potassium carbonate, which is an inorganic salt, under ultrasonic sonication conditions. Centrifugal slurry methods have been applied to obtain gradient of content of CNT in CNT/ Al matrix FGMs. Tribological characteristics on CNT/ Al matrix FGMs have been investigated using a ball-on-disk tribometer. It has been demonstrated that CNT contributes to enhance wear resistances.

scholarly journals Architecture of high-strength aluminum–matrix composites processed by a novel microcasting technique

2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Chenwei Shao ◽  
Shuo Zhao ◽  
Xuegang Wang ◽  
Yankun Zhu ◽  
Zhefeng Zhang ◽  
...  
Keyword(s):  
Yield Strength ◽  
High Performance ◽  
Aluminum Matrix ◽  
High Strength Steels ◽  
High Strength ◽  
Material Design ◽  
Crack Arrest ◽  
Aluminum Matrix Composites ◽  
Cast Aluminum ◽  
The Matrix

AbstractAs important lightweight structural materials, cast aluminum alloys have been largely used in the transportation and aerospace industries. In general, Al–Si-based alloys comprise more than 90% of all castings due to their excellent castability and corrosion resistance. However, even though various reinforcements have been introduced, the strength of these alloys is not that high, which severely limits their use for certain high-performance applications. Here, we report on a new strategy and technology to reinforce Al–Si alloys to increase their yield strength into the ~400–660 MPa range, a level that is 29–113% higher than that of all current cast Al–Si alloys, laboratory or commercial, and comparable to that of many high-strength steels but with ~40% lower density. By introducing continuous Ti–6Al–4V reinforcements into the Al–Si matrix through a novel microcasting process, the yield strength of the resulting alloy can be enhanced to between 4 and 6 times higher than that of the pure Al–Si alloy. The extraordinary reinforcing effect originates from the occurrence of multiscale strengthening mechanisms, including macroscale compound strengthening (the rule of mixtures amended by crack arrest mechanism), mesoscale strain-gradient strengthening, and microscale interface-affected-zone and nanoparticle strengthening. The core principle of our material design is to make all components of the composite fully participate in plastic (compatible) deformation, and thus, continuous reinforcements, instead of discrete reinforced structures (e.g., particles, whiskers, and short fibers), were introduced into the Al–Si alloy. Combined with 3-D printing technology, the present microcasting process can realize strengthening at the designed position by architecting specific reinforcements in the matrix.

Status of the Low Enriched Uranium Fuel Development for High Performance Research Reactors

2014 ◽  
Vol 94 ◽  
pp. 43-54 ◽  
Author(s):  
Leo Sannen ◽  
Sven van den Berghe ◽  
Ann Leenaers
Keyword(s):  
High Performance ◽  
Alternative Fuels ◽  
Volume Density ◽  
Lessons Learned ◽  
Research Reactors ◽  
Dispersion Fuel ◽  
Uranium Fuel ◽  
Low Volume ◽  
Enriched Uranium ◽  
Performance Research

Historically, uranium enriched to >90% 235U has been used for many peaceful applications requiring high fission densities such as driver fuels for research reactors. However, the use of high-enriched uranium or HEU (all enrichments >20% 235U are considered HEU) for civil applications, is considered a proliferation concern. Since the 1970's, efforts are being devoted to the conversion of research reactors operating on HEU to alternative fuels using uranium with enrichment below 20% or LEU. These efforts imply the development of high-density LEU fuels to replace the low volume-density (mostly) UAlx based HEU fuels. The paper updates the present status of these developments focusing on the UMo dispersion fuel. It aims to provide an overview of the knowledge generated and the lessons learned in roughly 15 years of UMo dispersion fuel R&D in Europe through irradiation experiments and post-irradiation examinations (PIE).

Morphology of High-Performance Rigid-Rod Polymer Fibers and Molecular Composites

1989 ◽  
Vol 47 ◽  
pp. 338-339
Author(s):  
W.W. Adams ◽  
S. J. Krause
Keyword(s):  
Tensile Strength ◽  
High Performance ◽  
Liquid Crystalline ◽  
Molecular Level ◽  
Synergistic Effects ◽  
Tensile Modulus ◽  
Commercial Development ◽  
The Matrix ◽  
Molecular Composites ◽  
Rigid Rod

Rigid-rod polymers such as PBO, poly(paraphenylene benzobisoxazole), Figure 1a, are now in commercial development for use as high-performance fibers and for reinforcement at the molecular level in molecular composites. Spinning of liquid crystalline polyphosphoric acid solutions of PBO, followed by washing, drying, and tension heat treatment produces fibers which have the following properties: density of 1.59 g/cm3; tensile strength of 820 kpsi; tensile modulus of 52 Mpsi; compressive strength of 50 kpsi; they are electrically insulating; they do not absorb moisture; and they are insensitive to radiation, including ultraviolet. Since the chain modulus of PBO is estimated to be 730 GPa, the high stiffness also affords the opportunity to reinforce a flexible coil polymer at the molecular level, in analogy to a chopped fiber reinforced composite. The objectives of the molecular composite concept are to eliminate the thermal expansion coefficient mismatch between the fiber and the matrix, as occurs in conventional composites, to eliminate the interface between the fiber and the matrix, and, hopefully, to obtain synergistic effects from the exceptional stiffness of the rigid-rod molecule. These expectations have been confirmed in the case of blending rigid-rod PBZT, poly(paraphenylene benzobisthiazole), Figure 1b, with stiff-chain ABPBI, poly 2,5(6) benzimidazole, Fig. 1c A film with 30% PBZT/70% ABPBI had tensile strength 190 kpsi and tensile modulus of 13 Mpsi when solution spun from a 3% methane sulfonic acid solution into a film. The modulus, as predicted by rule of mixtures, for a film with this composition and with planar isotropic orientation, should be 16 Mpsi. The experimental value is 80% of the theoretical value indicating that the concept of a molecular composite is valid.

scholarly journals Simplified and Rapid Determination of Primaquine and 5,6-Orthoquinone Primaquine by UHPLC-MS/MS: Its Application to a Pharmacokinetic Study

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4357
Author(s):  
Waritda Pookmanee ◽  
Siriwan Thongthip ◽  
Jeeranut Tankanitlert ◽  
Mathirut Mungthin ◽  
Chonlaphat Sukasem ◽  
...  
Keyword(s):  
Pharmacokinetic Study ◽  
High Performance ◽  
Rapid Determination ◽  
Active Metabolites ◽  
Chromatography Tandem Mass Spectrometry ◽  
Accuracy And Precision ◽  
The Matrix ◽  
Liquid Chromatography Tandem Mass ◽  
Isocratic Mode

The method for the determination of primaquine (PQ) and 5,6-orthoquinone primaquine (5,6-PQ), the representative marker for PQ active metabolites, via CYP2D6 in human plasma and urine has been validated. All samples were extracted using acetonitrile for protein precipitation and analyzed using the ultra-high-performance liquid chromatography–tandem mass spectrometry (UHPLC-MS/MS) system. Chromatography separation was carried out using a Hypersil GOLDTM aQ C18 column (100 × 2.1 mm, particle size 1.9 μm) with a C18 guard column (4 × 3 mm) flowed with an isocratic mode of methanol, water, and acetonitrile in an optimal ratio at 0.4 mL/min. The retention times of 5,6-PQ and PQ in plasma and urine were 0.8 and 1.6 min, respectively. The method was validated according to the guideline. The linearity of the analytes was in the range of 25–1500 ng/mL. The matrix effect of PQ and 5,6-PQ ranged from 100% to 116% and from 87% to 104% for plasma, and from 87% to 89% and from 86% to 87% for urine, respectively. The recovery of PQ and 5,6-PQ ranged from 78% to 95% and form 80% to 98% for plasma, and from 102% to from 112% to 97% to 109% for urine, respectively. The accuracy and precision of PQ and 5,6-PQ in plasma and urine were within the acceptance criteria. The samples should be kept in the freezer (−80 °C) and analyzed within 7 days due to the metabolite stability. This validated UHPLC-MS/MS method was beneficial for a pharmacokinetic study in subjects receiving PQ.

scholarly journals Simultaneously Regulating Uniform Zn2+ Flux and Electron Conduction by MOF/rGO Interlayers for High-Performance Zn Anodes

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Ziqi Wang ◽  
Liubing Dong ◽  
Weiyuan Huang ◽  
Hao Jia ◽  
Qinghe Zhao ◽  
...  
Keyword(s):  
High Performance ◽  
Surface Passivation ◽  
Coulombic Efficiency ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Growth Surface ◽  
Electron Conduction ◽  
Reduced Graphene ◽  
Metal Organic ◽  
Further Development

AbstractOwing to the merits of low cost, high safety and environmental benignity, rechargeable aqueous Zn-based batteries (ZBs) have gained tremendous attention in recent years. Nevertheless, the poor reversibility of Zn anodes that originates from dendrite growth, surface passivation and corrosion, severely hinders the further development of ZBs. To tackle these issues, here we report a Janus separator based on a Zn-ion conductive metal–organic framework (MOF) and reduced graphene oxide (rGO), which is able to regulate uniform Zn2+ flux and electron conduction simultaneously during battery operation. Facilitated by the MOF/rGO bifunctional interlayers, the Zn anodes demonstrate stable plating/stripping behavior (over 500 h at 1 mA cm−2), high Coulombic efficiency (99.2% at 2 mA cm−2 after 100 cycles) and reduced redox barrier. Moreover, it is also found that the Zn corrosion can be effectively retarded through diminishing the potential discrepancy on Zn surface. Such a separator engineering also saliently promotes the overall performance of Zn|MnO2 full cells, which deliver nearly 100% capacity retention after 2000 cycles at 4 A g−1 and high power density over 10 kW kg−1. This work provides a feasible route to the high-performance Zn anodes for ZBs.

scholarly journals Nonvolatile Ternary Resistive Memory Performance of a Benzothiadiazole-Based Donor–Acceptor Material on ITO-Coated Glass

Coatings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 318
Author(s):  
Yang Li ◽  
Cheng Zhang ◽  
Zhiming Shi ◽  
Jingni Li ◽  
Qingyun Qian ◽  
...  
Keyword(s):  
Data Storage ◽  
High Performance ◽  
Memory Performance ◽  
Resistive Memory ◽  
Molecular Systems ◽  
Threshold Voltages ◽  
Donor Acceptor ◽  
Low Threshold ◽  
Multilevel Memory ◽  
Further Development

The explosive growth of data and information has increasingly motivated scientific and technological endeavors toward ultra-high-density data storage (UHDDS) applications. Herein, a donor−acceptor (D–A) type small conjugated molecule containing benzothiadiazole (BT) is prepared (NIBTCN), which demonstrates multilevel resistive memory behavior and holds considerable promise for implementing the target of UHDDS. The as-prepared device presents distinct current ratios of 105.2/103.2/1, low threshold voltages of −1.90 V and −3.85 V, and satisfactory reproducibility beyond 60%, which suggests reliable device performance. This work represents a favorable step toward further development of highly-efficient D−A molecular systems, which opens more opportunities for achieving high performance multilevel memory materials and devices.

scholarly journals Development and Validation of a Sensitive, Specific and Reproducible UPLC-MS/MS Method for the Quantification of OJT007, A Novel Anti-Leishmanial Agent: Application to a Pharmacokinetic Study

2021 ◽  
Vol 18 (9) ◽  
pp. 4624
Author(s):  
Maria Rincon Nigro ◽  
Jing Ma ◽  
Ololade Tosin Awosemo ◽  
Huan Xie ◽  
Omonike Arike Olaleye ◽  
...  
Keyword(s):  
Formic Acid ◽  
High Performance ◽  
Leishmania Major ◽  
Internal Standard ◽  
Gradient Elution ◽  
Rat Plasma ◽  
The Matrix ◽  
Liquid Chromatography Tandem Mass ◽  
Positive Mode ◽  
Acquity Uplc

OJT007 is a methionine aminopeptidase 1 (MetAP1) inhibitor with potent anti-proliferative effects against Leishmania Major. In order to study its pharmacokinetics as a part of the drug development process, a sensitive, specific, and reproducible ultra-high performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) method was developed and validated. Voriconazole was used as the internal standard to generate standard curves ranging from 5 to 1000 ng/mL. The separation was achieved using a UPLC system equipped with an Acquity UPLC BEH C18 column (2.1 × 50 mm, 1.7 μm) with 0.1% formic acid in acetonitrile and 0.1% formic acid in water as the mobile phase under gradient elution at a flow rate of 0.4 mL/min. The mass analysis was performed with a 4000 QTRAP® mass spectrometer using multiple-ion reaction monitoring (MRM) in the positive mode, with the transition of m/z 325 → m/z 205 for OJT007 and m/z 350 → m/z 101 for voriconazole. The intra- and inter-day precision and accuracy were within ±15%. The mean extraction recovery and the matrix effect were 95.1% and 7.96%, respectively, suggesting no significant matrix interfering with the quantification of the drug in rat plasma. This study was successfully used for the pharmacokinetic evaluation of OJT007 using the rat as an animal model.

scholarly journals Assessment of the Accuracy of Determining the Angular Position of the Unmanned Bathymetric Surveying Vehicle Based on the Sea Horizon Image

Sensors ◽  
2019 ◽  
Vol 19 (21) ◽  
pp. 4644 ◽  
Author(s):  
Naus ◽  
Marchel ◽  
Szymak ◽  
Nowak
Keyword(s):  
Angular Position ◽  
Complementary Metal Oxide Semiconductor ◽  
General Concept ◽  
Oxide Semiconductor ◽  
Position Measurement ◽  
The Matrix ◽  
Horizon Line ◽  
Aerial Vehicle ◽  
Line Slope ◽  
Further Development

The paper presents the results of research on assessing the accuracy of angular position measurement relative to the sea horizon using a camera mounted on an unmanned bathymetric surveying vehicle of the Unmanned Surface Vehicle (USV) or Unmanned Aerial Vehicle (UAV) type. The first part of the article presents the essence of the problem. The rules of taking the angular position of the vehicle into account in bathymetric surveys and the general concept of the two-camera tilt compensator were described. The second part presents a mathematical description of the meters characterizing a resolution and a mean error of measurements, made on the base of the horizon line image, recorded with an optical system with a Complementary Metal-Oxide Semiconductor (CMOS) matrix. The phenomenon of the horizon line curvature in the image projected onto the matrix that appears with the increase of the camera height has been characterized. The third part contains an example of a detailed analysis of selected cameras mounted on UAVs manufactured by DJI, carried out using the proposed meters. The obtained results including measurement resolutions of a single-pixel and mean errors of the horizon line slope measurement were presented in the form of many tables and charts with extensive comments. The final part presents the general conclusions from the performed research and a proposal of directions for their further development.

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