Preparation and Properties of Wood Flour/HDPE Composites Using C5-g-MAH as Compatilizer

2013 ◽  
Vol 779-780 ◽  
pp. 170-173
Author(s):  
Lan Cen ◽  
Fu Lin Chen ◽  
You Ming Cao ◽  
Hui Xue Chen
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
High Density Polyethylene ◽  
Wood Flour ◽  
Bend Strength ◽  
Grafting Ratio ◽  
Melt Grafting ◽  
Compatibilizing Effect ◽  
Morphology And Mechanical Properties ◽  
Properties Of Composites

Maleic anhydride grafted C5 petroleum resin (C5-g-MAH) was prepared using peroxide as an initiator by melt grafting process, and was incorporated as a compatibilizer into Wood Flour/High Density Polyethylene (WF/HDPE) composites. The effect of second monomers and C5-g-MAHs on the morphology and mechanical properties of composites was investigated. Results showed that the presence of a second monomer, Triallyl isocyanurate (TAI), Butyl acrylate (BA) or Trimethylol proane trimethacrylate (TMPTMA), in the grafting system gave rise to higher grafting ratio of C5-g-MAHs compared to that without a second monomer. The highest grafting ratio was obtained as TMPTMA content being 0.20~0.35wt% based on C5. The addition of C5-g-MAHs into WF/HDPE resulted in improved mechanical properties. Meanwhile the composite containing C5-g-MAH with 0.30wt% TMPTMA exhibits the most significant improvement in all mechanical properties with tensile strength and bend strength increasing up to 18% and 20% respectively, which is concomitant with the finer morphology structure observed by SEM, suggesting the remarkable compatibilizing effect of C5-g-MAH with TMPTMA for WF/HDPE composites.

Study on Application of Modified Polyethylene in Preparation of Wood-Plastic Composites

2010 ◽  
Vol 150-151 ◽  
pp. 379-385
Author(s):  
Qun Lü ◽  
Qing Feng Zhang ◽  
Hai Ke Feng ◽  
Guo Qiao Lai
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
High Density Polyethylene ◽  
Wood Flour ◽  
Wood Plastic Composites ◽  
Plastic Composites ◽  
The Matrix ◽  
The Impact

The wood-plastic composites (WPC) were prepared via compress molding by using the blends of high density polyethylene (HDPE) and modified polyethylene (MAPE) as the matrix and wood flour (WF) as filler. The effect of MAPE content in the matrix on the mechanical properties of the matrix and WPC was investigated. It was shown that the change of MAPE content in the matrix had no influence on the tensile strength of the matrix, but markedly reduced the impact strength of the matrix. Additionally, it had significant influence on the strength of WPC. When the content of wood flour and the content of the matrix remained fixed, with increasing the content of MAPE in the matrix, the tensile strength and the flexural strength of WPC tended to increase rapidly initially and then become steady. Moreover, with the increasing of MAPE concentration, the impact strength of WPC decreased when the low content of wood flour (30%) was filled, but increased at high wood flour loading (70%).

Green composites based on high density polyethylene and recycled coffee gunny: Morphology, thermal, and mechanical properties

2020 ◽  
Vol 34 (07n09) ◽  
pp. 2040008
Author(s):  
Yeng-Fong Shih ◽  
Venkata Krishna Kotharangannagari ◽  
Ruo-Mei Chen
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
High Density Polyethylene ◽  
High Density ◽  
Mechanical And Thermal Properties ◽  
Reinforced Composites ◽  
Green Composites ◽  
Thermal And Mechanical Properties ◽  
Heat Deflection Temperature ◽  
Properties Of Composites

In this study, recycled coffee gunny (RCG) was used to reinforce high density polyethylene (HDPE). Maleic anhydride grafted polyethylene (MAPE) was added as a compatibilizer. Moreover, the RCG was chemically treated to enhance the compatibility between fiber and HDPE matrix. A series of RCG reinforced composites were prepared and the effects of MAPE and chemical modification of RCG on the mechanical and thermal properties of HDPE were investigated. The results of thermal and mechanical properties of composites revealed that the increments of heat deflection temperature, tensile strength, and impact strength of HDPE were 16[Formula: see text]C, 19.64% and 43.63% by the addition of modified coffee gunny, respectively. It reveals that the HDPE was reinforced with the coffee gunny, and thus can effectively reuse the discarded resources.

scholarly journals Composites from Thermoplastic Natural Rubber Reinforced Rubberwood Sawdust: Effects of Sawdust Size and Content on Thermal, Physical, and Mechanical Properties

2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Chatree Homkhiew ◽  
Surasit Rawangwong ◽  
Worapong Boonchouytan ◽  
Wiriya Thongruang ◽  
Thanate Ratanawilai
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Natural Rubber ◽  
High Density Polyethylene ◽  
High Performance ◽  
Physical And Mechanical Properties ◽  
Modulus Of Rupture ◽  
Shore Hardness ◽  
Thermoplastic Natural Rubber ◽  
Plastic Content

The aim of this work is to investigate the effects of rubberwood sawdust (RWS) size and content as well as the ratio of natural rubber (NR)/high-density polyethylene (HDPE) blend on properties of RWS reinforced thermoplastic natural rubber (TPNR) composites. The addition of RWS about 30–50 wt% improved the modulus of the rupture and tensile strength of TPNR composites blending with NR/HDPE ratios of 60/40 and 50/50. TPNR composites reinforced with RWS 80 mesh yielded better tensile strength and modulus of rupture than the composites with RWS 40 mesh. The TPNR/RWS composites with larger HDPE content gave higher tensile, flexural, and Shore hardness properties and thermal stability as well as lower water absorption. The TPNR/RWS composites with larger plastic content were therefore suggested for applications requiring high performance of thermal, physical, and mechanical properties.

scholarly journals Preparation and properties of silicone rubber materials with foam/solid alternating multilayered structures

2021 ◽  
Author(s):  
Wenhuan Zhang ◽  
Zhaoping Deng ◽  
Hongwei Yuan ◽  
Shikai Luo ◽  
Huayin Wen ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Silicone Rubber ◽  
Cellular Structure ◽  
Cellular Structures ◽  
Compressive Property ◽  
Solid Layer ◽  
Multilayered Structures ◽  
Element Analysis ◽  
Morphology And Mechanical Properties

AbstractIn this paper, silicone rubber materials with foam/solid alternating multilayered structures were successfully constructed by combining the two methods of multilayered hot-pressing and supercritical carbon dioxide (SCCO2) foaming. The cellular morphology and mechanical properties of the foam/solid alternating multilayered silicone rubber materials were systematically studied. The results show that the growth of the cell was restrained by the solid layer, resulting in a decrease in the cell size. In addition, the introduction of the solid layer effectively improved the mechanical properties of the microcellular silicone rubber foam. The tensile strength and compressive strength of the foam/solid alternating multilayered silicone rubber materials reached 5.39 and 1.08 MPa, which are 46.1% and 237.5% of the pure silicone rubber foam, respectively. Finite element analysis (FEA) was applied and the results indicate that the strength and proportion of the solid layer played important roles in the tensile strength of the foam/solid alternating multilayered silicone rubber materials. Moreover, the small cellular structures in silicone rubber foam can provided a high supporting counterforce during compression, meaning that the microcellular structure of silicone rubber foam improved the compressive property compared to that for the large cellular structure of silicone rubber foam.

Effect of Wood Filler Concentration on Physical and Mechanical Properties of PLA-Based Composites

2021 ◽  
Vol 887 ◽  
pp. 110-115
Author(s):  
G.A. Sabirova ◽  
R.R. Safin ◽  
N.R. Galyavetdinov
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Elastic Modulus ◽  
Composite Materials ◽  
Impact Strength ◽  
Wood Flour ◽  
Experimental Studies ◽  
Physical And Mechanical Properties ◽  
Filler Concentration ◽  
High Concentration

This paper presents the findings of experimental studies of the physical and mechanical properties of wood-filled composites based on polylactide (PLA) and vegetable filler in the form of wood flour (WF) thermally modified at 200-240 °C. It also reveals the dependence of the tensile strength, impact strength, bending elastic modulus, and density of composites on the amount of wood filler and the temperature of its thermal pre-modification. We established that an increase in the concentration of the introduced filler and the degree of its heat treatment results in a decrease of the tensile strength, impact strength and density of composite materials, while with a lower binder content, thermal modification at 200 °C has a positive effect on bending elastic modulus. We also found that 40 % content of a wood filler heated to 200 °C is sufficient to maintain relatively high physical and mechanical properties of composite materials. With a higher content of a wood filler, the cost can be reduced but the quality of products made of this material may significantly deteriorate. However, depending on the application and the life cycle of this product, it is possible to develop a formulation that includes a high concentration of filler.

Preparation and characterizations of ternary biodegradable blends composed of polylactide, poly(ε-caprolactone), and wood flour

2012 ◽  
Vol 32 (6-7) ◽  
pp. 435-444 ◽  
Author(s):  
Hsin-Tzu Liao ◽  
Chin-San Wu
Keyword(s):  
Mechanical Properties ◽  
Weight Loss ◽  
Tensile Strength ◽  
Fourier Transform ◽  
Wood Flour ◽  
High Price ◽  
Infrared Analysis ◽  
Melt Blending ◽  
Ternary Blends ◽  
Elongation At Break

Abstract Melt blending of polylactide (PLA), poly(ε-caprolactone) (PCL), and wood flour (WF) was performed in an effort to overcome the major drawbacks (brittleness and high price) of PLA. In addition, the acrylic acid (AA)-grafted PLA70PCL30 (PLA70PCL30-g-AA) was used as the alternative for the preparation of ternary blends to improve the compatibility and the dispersability of WF within the PLA70PCL30 matrix. As expected, PCL improved the elongation at break and the toughness of PLA but decreased the tensile strength and modulus. Because the hydrophilic WF is dispersed physically in the hydrophobic PLA70PCL30 matrix, as the result of Fourier transform infrared analysis, the mechanical properties of PLA70PCL30 became noticeably worse when it was blended with WF. This problem was successfully conquered by using PLA70PCL30-g-AA to replace PLA70PCL30 due to the formation of an ester carbonyl group between PLA70PCL30-g-AA and WF. Furthermore, the PLA70PCL30-g-AA/WF blend provided a plateau tensile strength at break when the WF content was up to 50 wt%. PLA70PCL30/WF exhibited a tensile strength at break of approximately 3–25 MPa more than PLA70PCL30-g-AA/WF. By using p-cresol and tyrosinase, the enzymatic biodegradable test showed that PLA70PCL30-g-AA is somewhat more biodegradable than PLA70PCL30 because the former has better water absorption. After 16 weeks, the weight loss of the PLA70PCL30/WF (50 wt%) composite was >80%. PLA70PCL30-g-AA/WF exhibited a weight loss of approximately 1–12 wt% more than PLA70PCL30-g-AA/WF. It was also found that the addition of WF to PLA70PCL30 or PLA70PCL30-g-AA decreased the crystallinity of PLA and PCL in PLA70PCL30 or PLA70PCL30-g-AA and then increased their biodegradable property.

Enhancement of mechanical properties of composites made of calcium carbonate modified bamboo fibers and polypropylene

Holzforschung ◽  
2015 ◽  
Vol 69 (2) ◽  
pp. 215-221 ◽  
Author(s):  
Haitao Cheng ◽  
Jie Gao ◽  
Ge Wang ◽  
Sheldon Q. Shi ◽  
Shuangbao Zhang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Aqueous Solution ◽  
Tensile Strength ◽  
Tensile Modulus ◽  
Inorganic Materials ◽  
Polypropylene Composites ◽  
Fiber Treatment ◽  
Bamboo Fibers ◽  
Properties Of Composites

Abstract The work aimed at the improvement of the mechanical properties of bamboo fiber-polypropylene composites (BaFPPC) by treatment of the fibers with CaCO3 at various concentrations of the solution (0.05, 0.1, 0.2, and 0.3 mol l-1). CaCO3 particles were successfully deposited in situ to bamboo fibers by means of ionic reaction of Na2 CO3 and CaCl2 aqueous solution at various temperatures. Then BaFPPC were produced, and various tests on single fibers and the composites were performed. The compatibility between BaF and PP matrix was improved by the treatments. The crystallinity of inorganic materials was significantly affected by the reagent’s concentration. A 10.4% increase in tensile strength and a 16.7% increase in tensile modulus were observed after fiber treatment with CaCO3 at a concentration of 0.2 mol l-1.

Physic-Mechanical Properties of Composites Based on Secondary Polypropylene and Dispersed of Plant Waste

2020 ◽  
Vol 1006 ◽  
pp. 227-232
Author(s):  
Yuliya Danchenko ◽  
Artem Kariev ◽  
Vladimir Lebedev ◽  
Elena Barabash ◽  
Tatyana Obizhenko
Keyword(s):  
Mechanical Properties ◽  
Bending Strength ◽  
Wood Flour ◽  
Chemical Properties ◽  
Uniform Structure ◽  
Internal Stresses ◽  
Agricultural Plants ◽  
Oat Husk ◽  
Filled Composite ◽  
Properties Of Composites

The physic-mechanical properties of filled composites based on secondary polypropylene are investigated. As fillers the dispersed wastes of processing of agricultural plants - buckwheat and oat husk, as well as needles flour and wood flour were used. Water absorption, abrasion, impact strength and bending strength of composites were investigated. It has been proven that oat and buckwheat husks can be effectively used in composites based on secondary polypropylene and replace traditional wood fillers. It has been shown that the physic-chemical properties of the filled composites depend on the structure and physicochemical interactions on the phase separation surface, as well as on the surface properties of the filler particles. It is established that for the production of filled composites with improved physic-mechanical characteristics it is necessary to use fillers with small specific surface and concentration of surface functional groups, and the acid-base characteristic of the surface should be closer to neutral. It is shown that these conditions provide for the formation of a uniform structure of the filled composite with less internal stresses.

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