Degradation of Organophosphorus Pesticide in a Packed-Bed Plasma Reactor: Effects of Operating Parameters and Kinetics Study

2013 ◽  
Vol 781-784 ◽  
pp. 1637-1645 ◽  
Author(s):  
Ting Jun Ma ◽  
Yi Qing Xu

The degradation effectiveness and reaction kinetics of representative organophosphorus (OP) pesticide in a packed-bed plasma reactor have been studied. Important parameters, including peak voltage, pulse frequency, gas-flow rate, initial concentration, diameter of catalyst particles, and thickness of catalyst bed which influences the removal efficiency, were investigated. Experimental results indicated that rogor removal efficiency as high as 80% can be achieved at 35 kV with the gas flow rate of 800 mL/min and initial concentration of 11.2 mg/m3.The removal efficiency increased with the increase of pulsed high voltage, and pulse frequency, the decrease of the diameter of catalyst particles and the thickness of catalyst bed. Finally, a model was established to predict the degradation of the rogor, which generally can simulate the experimental measurements to some degree.

2021 ◽  
Vol 19 (1) ◽  
pp. 288-298
Author(s):  
Lien Thi Tran ◽  
Tuan Minh Le ◽  
Tuan Minh Nguyen ◽  
Quoc Toan Tran ◽  
Xuan Duy Le ◽  
...  

Abstract This study explores the possibility of applying high-gravity rotating packed bed (HGRPB) in removing H2S and CO2 from biogas. Ca(OH)2 aqueous solution was used as the absorbent in this study. Different experimental conditions including solution pH, rotating speed (R S) of HGRPB, gas flow rate (Q G), and liquid flow rate (Q L) were investigated with respect to the removal efficiency (E) of H2S and CO2. The experimental and simulated results show that the optimal removal efficiency of H2S and CO2 using HGRPB achieved nearly the same as 99.38 and 99.56% for removal efficiency of H2S and 77.28 and 77.86% for removal efficiency of CO2, respectively. Such efficiencies corresponded with the following optimal conditions: a solution pH of 12.26, HGRPB reactor with the rotating speed of 1,200 rpm, the gas flow rate of 2.46 (L/min), and the liquid flow rate of 0.134 (L/min).


2019 ◽  
Vol 960 ◽  
pp. 115-121
Author(s):  
Zhan Guo Li ◽  
Hong Jie Zhao

The removal of trichloroethylene (TCE) by corona discharge plasma was investigated. The influences of initial concentration, gas flow rate, injection of water vapor and ozone (O3) on removal efficiency were discussed. The results show that removal efficiency reduces with the initial concentration and gas flow rate increasing. A proper quantity of water vapor injection can improve the removal efficiency, but which is not always increased, due to the electronegative characteristic of water molecule. The maximum removal efficiency of 90.7% can be obtained in wet air flow with relative humidity of 70.6%. The removal efficiency increases obviously with O3 injection. The decomposition products are 2,2-Dichloroacetyl chloride (CHCl2COCl), carbonyl chloride (COCl2), hydrogen chloride (HCl) and carbon dioxide (CO2), based on which the decomposition mechanism is discussed. The oxygen chain reaction is the primary decomposition mechanism, and high energy electrons and active oxygen species play a leading role in the decomposition process. Therefore, removal efficiency of TCE can be improved greatly when water vapor and O3 is injected.


2012 ◽  
Vol 573-574 ◽  
pp. 538-541
Author(s):  
Yan Ping Duan ◽  
Sven Geissen ◽  
Ling Chen

Ozonation of clofibric acid (CA) in aqueous solution was carried out under continuous operation in a cascade bubble column. The influence of operation parameters including initial CA concentration, gas flow rate, liquid flow rate and pH on the removal of CA and TOC was investigated. The results indicated that ozonation could be used to effectively remove CA from water. Increasing the initial CA concentration resulted in a decrease of the CA and TOC removal efficiency. A comparison of CA removal efficiency and ozone utilization between cascade and conventional bubble column indicated that cascade bubble column was an effective way for increasing the solubility ozone in the reactor.


Catalysts ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1169
Author(s):  
Feng Chen ◽  
Dezheng Yang ◽  
Feng Yu ◽  
Yang Kun ◽  
Ying Song

In this work, the azoxystrobin removal in water by using a micro-size discharge array was investigated, and the removal efficiency can reach as high as 98.1% after 9 min plasma treatment as well as the energy utilization being only 0.73 g/(kW·h). Based on the relationship between the generation of gas bubbles and parameters of gas-liquid discharge, it was found that the variation of applied voltage, gas flow rate and initial solution temperature could cause particle number change, mass transfer rate change and the mass transfer time change, which significantly affected the practical applications at last. The experimental results indicated that when gas flow rate was 0.7 SLM (Standard Liter per Minute) and the initial solution temperature was 297 K with the applied voltage of 8 kV and discharge frequency of 6 kHz, the removal efficiency of azoxystrobin achieved maximum. Based on the analysis results of liquid mass spectrometry, the removal pathways of azoxystrobin were supposed by the decomposed by-products. Toxicity tests indicated that the decomposed products were safe and non-toxic. So, this study may reveal an azoxystrobin degradation mechanism and provide a safe, reliable and effective way for azoxystrobin degradation.


2016 ◽  
Vol 78 (8) ◽  
Author(s):  
Nor Faraliana Shazwani Nor Azmi ◽  
Abdullahi Mohammed Evuti ◽  
Mohd Ariffin Abu Hassan ◽  
R. K. Raja Ibrahim

Non Thermal Plasma (NTP) is an emerging method used for the decomposition of volatile organic compounds (VOCs). This research focuses on the optimization of NTP reactor performance for decomposition of xylene from wastewater using response surface methodology (RSM) by operating the NTP reactor at applied voltage of 12-15 kV, discharge gap of 2.0-3.0 cm and gas flow rate of 2.0-5.0 L/min. An optimum xylene removal efficiency of 81.98% was obtained at applied voltage 15kV, discharge gap 2.09cm and gas flow rate at 2.36 L/min. The experimental removal efficiencies and model predictions were in close agreement with an error of 0.63%. 


Author(s):  
Ramakrishna Koganti ◽  
Armando Joaquin ◽  
Matthew Zaluzec ◽  
Chris Karas

The development of lightweight vehicles, in particular aluminum intensive vehicles, require significant manufacturing process development for joining and assembling aluminum structures. Currently, 5xxx and 6xxx aluminum alloys are being used in various structural applications in a number of lightweight vehicles worldwide. Various joining methods, such as GMAW (it is also referred as Metal Inert Gas Welding), Laser and adhesive bonding have been investigated as technology enablers for high volume joining of 5xxx, and 6xxx series alloys. In this study, GMA welding was used to join 5754 non-heat-treatable alloy sheet and 6063-T6 heat treatable extrusion products. The objective of this study was to develop optimum weld process parameters for non-heat-treatable 5754 aluminum and heat treatble 6063-T6 alloys. For both the alloys, the lap joint configuration was used. The GMA welding equipment used in this study was an OTC/Daihen CPD-350 welding systems and DR-4000 pulse power supply. In the first phase of the experiments for 5754 aluminum alloy, the factors selected for the experiment were power input (torch speed, voltage, current, wire feed), pulse frequency, gas flow rate and surface condition. A full factorial design of experiment (DOE) was conducted (DOE #1) to understand the main and interaction effects on lap joint failure and weld penetration. Based on the results from phase 1 results, surface condition was eliminated in the phase 2 experiments. In phase 2 experiments for heat treatable alloys 6063 T6, the factors selected were power input (torch speed, voltage, current, wire feed), pulse frequency, gas flow rate, torch angle, and arc intensity. A partial factorial DOE was conducted (DOE # 2) primarily to understand the main effects and some two level interaction effects. For both phase 1 (non-heat treatable alloy 5754) and phase 2 (heat treatable alloy 6063-T6) experiments, the factors influence on the mechanical properties of the lap joint, metallurgy (weld penetration) and micro hardness were evaluated. Post weld analysis indicates for non heat treatable alloy 5754, power input and gas flow rate are the two signficant factors (statistically) based on lap shear load to failure and weld penentration data. For heat treatable alloy 6063, power input was the significant factor on joint load to failure, however, for weld penetration, power input, pulse frequency and gas flow rate were the significant factors. Based on the joint strength and weld penetration, optimum weld process factors were determined for both non-heat treatable alloy 5754 and heat treatble alloy 6063 T6.


2015 ◽  
Vol 737 ◽  
pp. 561-564
Author(s):  
Jing Xin Li ◽  
Bao Hui Li ◽  
Zhi Yong Li

The toluene being removed by dielectric barrier discharge (DBD) combined with modified photocatalyst was studied in the paper. Transition metal manganese was doped into crystal lattice of TiO2 in order to improve the activity of photocatalyst, and the optimal doping ratio was confirmed in the study. As one of main factors, the influence on toluene removal efficiency of gas flow rate, initial concentration and electric field intensity was analyzed in the study. Furthermore, the energy efficiency was another important index which had been compared amongγ-Al2O3, TiO2/γ-Al2O3 and Mn-TiO2/γ-Al2O3. The result of study showed that DBD combined with Mn-TiO2/γ-Al2O3 had the best buffer action against increasing of gas flow rate and initial concentration, the energy efficiency had the tendency as Mn-TiO2/γ-Al2O3 > TiO2/γ-Al2O3>γ-Al2O3, and the optimal doping ratio of manganese was 0.01.


2014 ◽  
Vol 884-885 ◽  
pp. 261-265
Author(s):  
Bao Lin Li ◽  
Ming Yu Li ◽  
Hai Hao Liu ◽  
Gang Cao ◽  
Gang Ren ◽  
...  

This paper presented a new method of absorption-oxidation-reduction which used ferrous sulfate solution as absorbent, oxygen as oxidizer and urea as reducer to remove NOX from flue gas based on the properties of Fe2+, NO, [Fe (NO)]2+ and urea. These properties included that Fe2+ and NO could produce [Fe (NO)]2+, furthermore [Fe (NO)]2+ was easy to be oxidized by O2, as well as urea can reduce HNO2 and HNO3 in the absorption liquid. This research was to discuss its absorption and removal mechanism with the influence of the initial urea concentration, pH value, initial NOX concentration and gas flow rate on the NOX removal efficiency. The results showed that the removal efficiency of NOX would increase when the initial concentration of urea and NOX increased, while the pH value and gas flow rate decreased.


2006 ◽  
Vol 515 (4) ◽  
pp. 1970-1975 ◽  
Author(s):  
W. Chen ◽  
X. Lu ◽  
Q. Yang ◽  
C. Xiao ◽  
R. Sammynaiken ◽  
...  

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