Rheological Behaviors of Alumina Aqueous Suspensions

2007 ◽  
Vol 280-283 ◽  
pp. 1039-1040
Author(s):  
Tie Chao Wang ◽  
Jin Long Yang ◽  
Li Guo Ma ◽  
Yong Huang

Rheological behaviors of alumina aqueous suspension were investigated, and some methods to modify the rheological behaviors of the suspensions were studied. It was found that there is a critical solid volume fraction for alumina aqueous suspensions. When the volume fraction reaches or exceeds the critical value the suspensions show shear thinning behaviors all along, while above which the rheological behaviors of alumina suspensions change from shear thinning to shear thickening.

2018 ◽  
Vol 852 ◽  
pp. 329-357 ◽  
Author(s):  
Dhiya Alghalibi ◽  
Iman Lashgari ◽  
Luca Brandt ◽  
Sarah Hormozi

We present a numerical study of non-colloidal spherical and rigid particles suspended in Newtonian, shear thinning and shear thickening fluids employing an immersed boundary method. We consider a linear Couette configuration to explore a wide range of solid volume fractions ($0.1\leqslant \unicode[STIX]{x1D6F7}\leqslant 0.4$) and particle Reynolds numbers ($0.1\leqslant Re_{p}\leqslant 10$). We report the distribution of solid and fluid phase velocity and solid volume fraction and show that close to the boundaries inertial effects result in a significant slip velocity between the solid and fluid phase. The local solid volume fraction profiles indicate particle layering close to the walls, which increases with the nominal $\unicode[STIX]{x1D6F7}$. This feature is associated with the confinement effects. We calculate the probability density function of local strain rates and compare the latter’s mean value with the values estimated from the homogenisation theory of Chateau et al. (J. Rheol., vol. 52, 2008, pp. 489–506), indicating a reasonable agreement in the Stokesian regime. Both the mean value and standard deviation of the local strain rates increase primarily with the solid volume fraction and secondarily with the $Re_{p}$. The wide spectrum of the local shear rate and its dependency on $\unicode[STIX]{x1D6F7}$ and $Re_{p}$ point to the deficiencies of the mean value of the local shear rates in estimating the rheology of these non-colloidal complex suspensions. Finally, we show that in the presence of inertia, the effective viscosity of these non-colloidal suspensions deviates from that of Stokesian suspensions. We discuss how inertia affects the microstructure and provide a scaling argument to give a closure for the suspension shear stress for both Newtonian and power-law suspending fluids. The stress closure is valid for moderate particle Reynolds numbers, $O(Re_{p})\sim 10$.


2007 ◽  
Vol 280-283 ◽  
pp. 1041-1044
Author(s):  
Yong Huang ◽  
Li Ming Zhang ◽  
Hai Feng Li ◽  
Tian Ma

The effects of solid volume fraction (SVF) on the gelation of alumina suspensions for gelcasting, debonding and sintering of the green body were studied. It was found that with SVF rising, the gelation of alumina suspension delayed; and the strength of green body decreased. On the other hand, high SVF resulted in that polymerized acrylamide split at a relative low temperature. These phenomena manifest that the fast polymerization of monomers in high SVF alumina suspension was inhibited, and the flexibility of the gelcasting was improved. However, Excessive solid volume fraction was prone to a bad rheological behavior of alumina suspension, and deteriorated the microstructure and properties of sintered body.


2010 ◽  
Vol 105-106 ◽  
pp. 833-836
Author(s):  
Xiang Yang Lu ◽  
Li Ming Zhang ◽  
Yong Huang

The rheological behavior of alumina suspension stabilized with Tri-ammonia citrate (TAC) was studied. It was thought that there would form some particle clusters due to the collisions between particles caused by their relative motion in the suspension, and such particle clusters are classified as thermodynamic clusters and hydrodynamic clusters by their origin. Shear thinning is the result of decomposition of the thermodynamic clusters, while shear thickening is the result of formation of the hydrodynamic clusters. From the view of cluster-forming potential barrier, it was deemed that the viscosities of alumina suspensions at low and high shear rates are respectively determined by zeta potential and Stern potential on the particle surface, and shear thickening behavior can be suppressed with some excessive TAC.


2017 ◽  
Vol 826 ◽  
pp. 918-941 ◽  
Author(s):  
A. Bougouin ◽  
L. Lacaze ◽  
T. Bonometti

Experiments on the collapse of non-colloidal and neutrally buoyant particles suspended in a Newtonian fluid column are presented, in which the initial volume fraction of the suspension $\unicode[STIX]{x1D719}$, the viscosity of the interstitial fluid $\unicode[STIX]{x1D707}_{f}$, the diameter of the particles $d$ and the mixing protocol, i.e. the initial preparation of the suspension, are varied. The temporal evolution of the slumping current highlights two main regimes: (i) an inertial-dominated regime followed by (ii) a viscous-dominated regime. The inertial regime is characterized by a constant-speed slumping which is shown to scale as in the case of a classical inertial dam-break. The viscous-dominated regime is observed as a decreasing-speed phase of the front evolution. Lubrication models for Newtonian and power-law fluids describe most of situations encountered in this regime, which strongly depends on the suspension parameters. The temporal evolution of the propagating front is used to extract the rheological parameters of the fluid models. At the early stages of the viscous-dominated regime, a constant effective shear viscosity, referred to as an apparent Newtonian viscous regime, is found to depend only on $\unicode[STIX]{x1D719}$ and $\unicode[STIX]{x1D707}_{f}$ for each mixing protocol. The obtained values are shown to be well fitted by the Krieger–Dougherty model whose parameters involved, say a critical volume fraction $\unicode[STIX]{x1D719}_{m}$ and the exponent of divergence, depend on the mixing protocol, i.e. the microscale interaction between particles. On a longer time scale which depends on $\unicode[STIX]{x1D719}$, the front evolution is shown to slightly deviate from the apparent Newtonian model. In this apparent non-Newtonian viscous regime, the power-law model, indicating both shear-thinning and shear-thickening behaviours, is shown to be more appropriate to describe the front evolution. The present experiments indicate that the mixing protocol plays a crucial role in the selection of a shear-thinning or shear-thickening type of collapse, while the particle diameter $d$ and volume fraction $\unicode[STIX]{x1D719}$ play a significant role in the shear-thickening case. In all cases, the normalized effective consistency of the power-law fluid model is found to be a unique function of $\unicode[STIX]{x1D719}$. Finally, an apparent viscoplastic regime, characterized by a finite length spreading reached at finite time, is observed at high $\unicode[STIX]{x1D719}$. This regime is mostly observed for volume fractions larger than $\unicode[STIX]{x1D719}_{m}$ and up to a volume fraction $\unicode[STIX]{x1D719}_{M}$ close to the random close packing fraction at which the initial column remains undeformed on opening the gate.


2021 ◽  
Author(s):  
Patrick Wilms ◽  
Jörg Hinrichs ◽  
Reinhard Kohlus

AbstractModelling the macroscopic rheology of non-Brownian suspensions is complicated by the non-linear behaviour that originates from the interaction between solid particles and the liquid phase. In this contribution, a model is presented that describes suspension rheology as a function of solid volume fraction and shear rate dependency of both the liquid phase, as well as the suspension as a whole. It is experimentally validated using rotational rheometry ($$\varphi$$ φ ≤ 0.40) and capillary rheometry (0.55 ≤ $$\varphi$$ φ  ≤ 0.60) at shear rates > 50 s−1. A modified Krieger-Dougherty relation was used to describe the influence of solid volume fraction on the consistency coefficient, $$K$$ K , and was fitted to suspensions with a shear thinning liquid phase, i.e. having a flow index, $$n$$ n , of 0.50. With the calculated fit parameters, it was possible to predict the consistency coefficients of suspensions with a large variation in the shear rate dependency of the liquid phase ($$n$$ n = 0.20–1.00). With increasing solid volume fraction, the flow indices of the suspensions were found to decrease for Newtonian and mildly shear thinning liquid phases ($$n$$ n ≥0.50), whereas they were found to increase for strongly shear thinning liquid phases ($$n$$ n ≤0.27). It is hypothesized that this is related to interparticle friction and the relative contribution of friction forces to the viscosity of the suspension. The proposed model is a step towards the prediction of the flow curves of concentrated suspensions with non-Newtonian liquid phases at high shear rates.


2011 ◽  
Vol 236-238 ◽  
pp. 1563-1567
Author(s):  
Ou Sheng Zhang ◽  
Chao Can Zhang ◽  
Li Li Wu ◽  
Wen Bing Sun ◽  
Liang Hu

By varying the feed ratios of comonomers, butyl acrylate (BA), acrylic acid (AA), and methyl methacrylate (MMA), four acrylate macromolecular modifiers (AC730, AC532, AC235, and AC037) were synthesized by free radical copolymeration in ethnol. The effect of these modifiers on rheological behaviors of ultrafine CaCO3 aqueous suspensions was investigated on the basis of a series of rheological measurements. The results showed that comonomer compositions and amounts of modifiers have obvious effect on rheological behaviors of CaCO3 aqueous suspensions. In the case of AC730 and 0.2-0.4 parts of AC532, suspensions were pseudoplastic fluids, exhibiting shear thinning behavior; while in the case of AC235, AC037 and 0.6-1.4 parts of AC532, suspensions were dilatant fluids, exhibiting shear thickening behavior. Except the suspensions modified by 1.2 and 1.4 parts of AC730, the rheological data of other suspending systems could be well correlated with Herschel-Bulkley model. Optimum amounts of different modifiers were determined on the basis of rheological analysis, 0.8 parts for AC730, 0.6 parts for AC532 or AC235, and 0.4 parts for AC037.


2007 ◽  
Vol 280-283 ◽  
pp. 987-990
Author(s):  
Li Ming Zhang ◽  
Tian Ma ◽  
Hai Feng Li ◽  
Yong Huang

Zirconia suspensions with coarse particles were prepared and the rheogical behavior and sediment stability of such suspensions with different dispersants were studied. It was found that ZrO2 suspension stabilized with TAC (tri-ammonium citrate) has an obvious shear-thinning behavior and rapid settlement; In contrast, the suspension stabilized with arabic gum shows a shear-thickening behavior and hardly any settlement. Considering both fluidity and settlement stability, APA (ammonium-polyacrylate) was chosen as the dispersant to increase the solid volume fraction of ZrO2 suspension. Utilizing the above suspension, a kind of refractory nozzle for precision casting of a Cu-Cr alloy was prepared by gelcasting. Such nozzle has a very good resistance to thermal shock and flux scouring.


2019 ◽  
Vol 880 ◽  
pp. 1070-1094 ◽  
Author(s):  
Adolfo Vázquez-Quesada ◽  
Pep Español ◽  
Roger I. Tanner ◽  
Marco Ellero

We study the rheology of a non-colloidal suspension of rigid spherical particles interacting with a viscoelastic matrix. Three-dimensional numerical simulations under shear flow are performed using the smoothed particle hydrodynamics method and compared with experimental data available in the literature using different constant-viscosity elastic Boger fluids. The rheological properties of the Boger matrices are matched in simulation under viscometric flow conditions. Suspension rheology under dilute to semi-concentrated conditions (i.e. up to solid volume fraction $\unicode[STIX]{x1D719}=0.3$) is explored. It is found that at small Deborah numbers $De$ (based on the macroscopic imposed shear rate), relative suspension viscosities $\unicode[STIX]{x1D702}_{r}$ exhibit a plateau at every concentration investigated. By increasing $De$, shear thickening is observed, which is related to the extensional thickening of the underlying viscoelastic matrix. Under dilute conditions ($\unicode[STIX]{x1D719}=0.05$), numerical results for $\unicode[STIX]{x1D702}_{r}$ agree quantitatively with experimental data in both the $De$ and $\unicode[STIX]{x1D719}$ dependences. Even under dilute conditions, simulations of full many-particle systems with no a priori specification of their spatial distribution need to be considered to recover precisely experimental values. By increasing the solid volume fraction towards $\unicode[STIX]{x1D719}=0.3$, despite the fact that the trend is well captured, the agreement remains qualitative with discrepancies arising in the absolute values of $\unicode[STIX]{x1D702}_{r}$ obtained from simulations and experiments but also with large deviations existing among different experiments. With regard to the specific mechanism of elastic thickening, the microstructural analysis shows that elastic thickening correlates well with the average viscoelastic dissipation function $\unicode[STIX]{x1D703}^{elast}$, requiring a scaling as $\langle \unicode[STIX]{x1D703}^{elast}\rangle \sim De^{\unicode[STIX]{x1D6FC}}$ with $\unicode[STIX]{x1D6FC}\geqslant 2$ to take place. Locally, despite the fact that regions of large polymer stretching (and viscoelastic dissipation) can occur everywhere in the domain, flow regions uniquely responsible for the elastic thickening are well correlated to areas with significant extensional component.


2020 ◽  
Vol 16 ◽  
Author(s):  
Adel Alblawi ◽  
Saba Keyani ◽  
S. Nadeem ◽  
Alibek Issakhov ◽  
Ibrahim M. Alarifi

Objective: In this paper, we consider a model that describes the ciliary beating in the form of metachronal waves along with the effects of Magnetohydrodynamic fluid over a curved channel with slip effects. This work aims at evaluating the effect of Magnetohydrodynamic (MHD) on the steady two dimensional (2-D) mixed convection flow induced in carbon nanotubes. The work is done for both the single wall nanotube and multiple wall nanotube. The right wall and the left wall possess a metachronal wave that is travelling along the outer boundary of the channel. Methods: The wavelength is considered as very large for cilia induced MHD flow. The governing linear coupled equations are simplified by considering the approximations of long wavelength and small Reynolds number. Exact solutions are obtained for temperature and velocity profile. The analytical expressions for the pressure gradient and wall shear stresses are obtained. Term for pressure rise is obtained by applying Numerical integration method. Results: Numerical results of velocity profile are mentioned in a table form, for various values of solid volume fraction, curvature, Hartmann number [M] and Casson fluid parameter [ζ]. Final section of this paper is devoted to discussing the graphical results of temperature, pressure gradient, pressure rise, shear stresses and stream functions. Conclusion: Velocity profile near the right wall of the channel decreases when we add nanoparticles into our base fluid, whereas an opposite behaviour is depicted near the left wall due to ciliated tips whereas the temperature is an increasing function of B and ߛ and decreasing function of ߶.


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