A New PvT Device for the Thermoplastics Characterization in Extreme Thermal Conditions

2013 ◽  
Vol 554-557 ◽  
pp. 1619-1627 ◽  
Author(s):  
Xavier Tardif ◽  
Nicolas Boyard ◽  
Vincent Sobotka ◽  
Nicolas Lefèvre ◽  
Didier Delaunay

In this work, we present an apparatus associated to a methodology that is able to determine simultaneously and according to temperature (up to 400°C) the specific volume (up to 200MPa), the thermal conductivity and the temperature function of the crystallization kinetics. The PvT-XT is a home-built device that is able to impose and quantify 1D heat transfer through the radius of a sample. This apparatus controls the applied pressure on the sample while measuring its volume variations. The associated moving boundary model takes into account the temperature and crystallinity gradients. Specific volume is determined from direct measurement whereas inverse methods are used to estimate the thermal conductivity and the crystallization kinetics (with cooling rates up to 200K/min). Specific volume measurements are compared with literature results and exhibit a very good agreement. Thermal conductivity identified in the present paper is also very close to literatures values. Finally identification of kinetic function values is consistent with previous studies.

2012 ◽  
Vol 31 (6) ◽  
pp. 819-827 ◽  
Author(s):  
Xavier Tardif ◽  
Alban Agazzi ◽  
Vincent Sobotka ◽  
Nicolas Boyard ◽  
Yvon Jarny ◽  
...  

2004 ◽  
Vol 97-98 ◽  
pp. 125-132 ◽  
Author(s):  
George Varghese ◽  
Jacob George

Periodic precipitation pattern formation in reaction diffusion systems is interpreted as a moving boundary problem. All the existing laws are reexamined on the basis of the moving boundary assumption. Experimental observations were found to be in good agreement with the new equations suggested.


2014 ◽  
Vol 18 (4) ◽  
pp. 1413-1423 ◽  
Author(s):  
Dragan Ruzic ◽  
Sinisa Bikic

The aim of the research described in this paper, is to make a virtual thermal manikin that would be simple, but also robust and reliable. The virtual thermal manikin was made in order to investigate thermal conditions inside vehicle cabins. The main parameters of the presented numerical model that were investigated in this paper are mesh characteristics and turbulence models. Heat fluxes on the manikin's body segments obtained from the simulations were compared with published results, from three different experiments done on physical thermal manikins. The presented virtual thermal manikin, meshed with surface elements of 0.035 m in nominal size (around 13,600 surface elements) and in conjunction with the two-layer RANS Realizable k-? turbulence model, had generally good agreement with experimental data in both forced and natural flow conditions.


2015 ◽  
Vol 738-739 ◽  
pp. 986-990
Author(s):  
Zhi Gang Wang ◽  
Jia Guang Cheng ◽  
Yan Wang ◽  
Qiang Shen

Organic Rankine Cycle (ORC) is one of the most promising technologies for low-temperature energy conversion. In recent years, it has gotten more attention due to the energy crisis and environmental problems caused by the combustion of fossil fuels. In this paper, a moving boundary model is introduced to describe the transient phenomena of evaporator and condenser, which are the important components of ORC. The simulation results are given to illustrate the efficiency and feasibility of the proposed control strategy.


2014 ◽  
Vol 918 ◽  
pp. 21-26
Author(s):  
Chen Kang Huang ◽  
Yun Ching Leong

In this study, the transport theorem of phonons and electrons is utilized to create a model to predict the thermal conductivity of composite materials. By observing or assuming the dopant displacement in the matrix, a physical model between dopant and matrix can be built, and the composite material can be divided into several regions. In each region, the phonon or electron scattering caused by boundaries, impurities, or U-processes was taken into account to calculate the thermal conductivity. The model is then used to predict the composite thermal conductivity for several composite materials. It shows a pretty good agreement with previous studies in literatures. Based on the model, some discussions about dopant size and volume fraction are also made.


2010 ◽  
Vol 14 (1) ◽  
pp. 91-98 ◽  
Author(s):  
D. Jougnot ◽  
A. Revil

Abstract. The parameters used to describe the electrical conductivity of a porous material can be used to describe also its thermal conductivity. A new relationship is developed to connect the thermal conductivity of an unsaturated porous material to the thermal conductivity of the different phases of the composite, and two electrical parameters called the first and second Archie's exponents. A good agreement is obtained between the new model and thermal conductivity measurements performed using packs of glass beads and core samples of the Callovo-Oxfordian clay-rocks at different saturations of the water phase. We showed that the three model parameters optimised to fit the new model against experimental data (namely the thermal conductivity of the solid phase and the two Archie's exponents) are consistent with independent estimates. We also observed that the anisotropy of the effective thermal conductivity of the Callovo-Oxfordian clay-rock was mainly due to the anisotropy of the thermal conductivity of the solid phase.


2016 ◽  
Vol 30 (30) ◽  
pp. 1650373 ◽  
Author(s):  
Li Xue ◽  
Yi-Ming Ren ◽  
Zheng-Long Hu

[Formula: see text] is a promising thermoelectric (TE) material for high temperature TE applications. This work systematically investigated the structural, elastic and thermodynamic properties of [Formula: see text] ([Formula: see text] = 0, 0.25, 0.5, 0.75 and 1) by density functional theory. The calculated lattice volume is expanded with the increase of Ag content, but this expansion is anisotropic. The lattice parameter along [Formula: see text]-axis is linear expansion, and along [Formula: see text]-axis is parabolic expansion, which is in good agreement with available experimental data. The phase stability of [Formula: see text] alloy is studied by analyzing the formation energy, cohesive energy and elastic constants. Shear modulus, Young’s modulus, sound velocities, Debye temperature and the minimum thermal conductivity are obtained from the calculated elastic constants. The results show that Ag substitution could reduce the lattice thermal conductivity, which is helpful for improving the TE properties of [Formula: see text].


Author(s):  
Claudia Giovagnoli-Vicuña ◽  
Nelson O. Moraga ◽  
Vilbett Briones-Labarca ◽  
Pablo Pacheco-Pérez

Abstract The influence of drying on the color, porosity, shrinkage and moisture of persimmon fruit during convective drying was determined by computer vision. The experiments were performed with persimmon fruit that were cut into slab 20 × 20 mm, which were arranged into a bigger slab, 60 × 60 mm. Drying process was carried out at 60 °C. Noticeable changes in quality parameters (color, porosity and shrinkage) could be observed during the drying process, where the central region of the sample evidenced less changes. Persimmon’s physical properties were experimentally obtained as the temperature function and heat and mass convective coefficients were adjusted as a time function. A numerical simulation using the Finite Volume Method allowed to describe the evolution of temperature and moisture content distributions during drying. The numerical and experimental results of temperature and moisture during persimmon drying were found to be in a good agreement.


2021 ◽  
Vol 15 ◽  
pp. 12-21
Author(s):  
Jonatas Motta Quirino ◽  
Eduardo Dias Correa ◽  
Rodolfo do Lago Sobral

- The present work describes the thermal profile of a single dissipation fin, where their surfaces reject heat to the environment. The problem happens in steady state, which is, all the analysis occurs after the thermal distribution reach heat balance considering that the fin dissipates heat by conduction, convection and thermal radiation. Neumann and Dirichlet boundary conditions are established, characterizing that heat dissipation occurs only on the fin faces, in addition to predicting that the ambient temperature is homogeneous. Heat transfer analysis is performed by computational simulations using appropriate numerical methods. The most of solutions in the literature consider some simplifications as constant thermal conductivity and linear boundary conditions, this work addresses this subject. The method applied is the Kirchhoff Transformation, that uses the thermal conductivity variation to define the temperatures values, once the thermal conductivity variate as a temperature function. For the real situation approximation, this work appropriated the silicon as the fin material to consider the temperature function at each point, which makes the equation that governs the non-linear problem. Finally, the comparison of the results obtained with typical results proves that the assumptions of variable thermal conductivity and heat dissipation by thermal radiation are crucial to obtain results that are closer to reality.


Author(s):  
Kevin Irick ◽  
Nima Fathi

Abstract The complexity of conductive heat transfer in a structure increases with heterogeneity (e.g., multi-component solid-phase systems with a source of internal thermal heat generation). Any discontinuity of material property — especially thermal conductivity — would warrant a thorough analysis to evaluate the thermal behavior of the system of interest. Heterogeneous thermal conditions are crucial to heat transfer in nuclear fuel assemblies, because the thermal behavior within the assemblies is governed significantly by the heterogeneous thermal conditions at both the system and component levels. A variety of materials have been used as nuclear fuels, the most conventional of which is uranium dioxide, UO2. UO2 has satisfactory chemical and irradiation tolerances in thermal reactors, whereas the low thermal conductivity of porous UO2 can prove challenging. Therefore, the feasibility of enhancing the thermal conductivity of oxide fuels by adding a high-conductivity secondary solid component is still an important ongoing topic of investigation. Undoubtedly, long-term, stable development of clean nuclear energy would depend on research and development of innovative reactor designs and fuel systems. Having a better understanding of the thermal response of the unit cell of a composite that represents a fuel matrix cell would help to develop the next generation of nuclear fuel and understand potential performance enhancements. The aim of this article is to provide an assessment of a high-fidelity computational model response of heterogeneous materials with heat generation in circular fillers. Two-dimensional, steady-state systems were defined with a circular, heat-generating filler centered in a unit-cell domain. A Fortran-based finite element method (FEM) code was used to solve the heat equation on an unstructured triangular mesh of the systems. This paper presents a study on the effects of a heat-generating filler material’s relative size and thermal conductivity on effective thermal conductance, Geff, within a heterogenous material. Code verification using the method of manufactured solution (MMS) was employed, showing a second-order accurate numerical implementation. Solution verification was performed using a global deviation grid convergence index (GCI) method to assess solution convergence and estimate solution numerical uncertainty, Unum. Trend results are presented, showing variable response in Geff to filler size and thermal conductivity.


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