Simultaneous Use of Two Catalytic Wastes to Cement in Sustainable Construction Materials

2014 ◽  
Vol 634 ◽  
pp. 121-130 ◽  
Author(s):  
Maura Berger Maltez Melchert ◽  
Marcelo Mendes Viana ◽  
Jo Dweck
Keyword(s):  
Compressive Strength ◽  
Construction Materials ◽  
Sustainable Construction ◽  
Environmental Legislation ◽  
Mass Ratio ◽  
X Ray Diffraction ◽  
X Ray ◽  
Strength Tests ◽  
Sustainable Materials ◽  
Simultaneous Use

This paper presents the study of the simultaneous use of two residual catalysts (RAl and RNi) with type II Portland cement, in order to avoid environmental impacts and to use of the solidified products as structural sustainable materials. The solidification/stabilization (S/S) was evaluated by thermogravimetric analysis, X ray diffraction, leaching and compressive strength tests. Mortars with water/cement mass ratio equal to 0.5 were prepared, into which, different percentual masses of each waste were added. The main phases formed due to the retarding and accelerating actions of each waste were evaluated by thermogravimetry and X ray diffraction after 28 days of hydration. The leaching tests done with the solidified mortars presented values of Ni and Al contents below maximum accepted limits, indicating that they attend to environmental legislation, as well as eliminate the original environmental impact of the original wastes. Mortars evaluated after 28 days by compressive strength tests, presented acceptable results for their possible use as construction materials.

Effect of Curing Age on the Compressive Strength of Petrovege Blocks

2014 ◽  
Vol 980 ◽  
pp. 91-96
Author(s):  
O.A. Johnson ◽  
Napiah Madzlan ◽  
Ibrahim B. Kamaruddin
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Construction Industry ◽  
Construction Materials ◽  
Sustainable Construction ◽  
Liquid Content ◽  
Minimum Requirements ◽  
Sustainable Materials ◽  
Crude Oil Sludge ◽  
Curing Age

In the recent years there has been an intensification of policies on sustainable construction materials in the construction industry. This environmental policy has brought about development of various sustainable materials in which Petrovege blocks is one of the outstanding products. This paper investigates the effect of curing age on the compressive strength of the product. Block samples were prepared by adding 8%, 9%, 10%, 11%, 12%, and 13% liquid content of the mixture of vegetable oil and crude oil sludge as a binder after the optimum liquid content has been established. The specimens were cured at different period of time of 48hrs, 72hrs, 96hrs, and 120hrs. Mechanical properties of the products were evaluated. Compressive strength of Petrovege samples varies from 5.31 N/mm2to 18.88 N/mm2indicating that the compressive strength increases with increase in curing age, while decrease in porosity leads to increased compressive strength for the stipulated curing ages. All samples satisfied the minimum requirements in terms of compressive strength, in accordance with all available standards.

scholarly journals Application of sewage sludge for the production of construction

2019 ◽  
Vol 252 ◽  
pp. 05025
Author(s):  
Aneta Czechowska-Kosacka
Keyword(s):  
Electron Microscope ◽  
Fly Ash ◽  
Chemical Composition ◽  
Sewage Sludge ◽  
Construction Materials ◽  
X Ray Diffraction ◽  
Sewage Sludges ◽  
X Ray ◽  
Strength Tests ◽  
Scanning Electron

The paper presents the studies pertaining to sewage sludges and their mixtures with fly ash to be used as an additive for the manufacturing of construction materials. The studies were carried out using X-ray diffraction. The form and morphology of samples as well as the chemical composition in the micro-area were determined using a scanning electron microscope. The obtained results indicate the possibility of using sewage sludges for construction purposes. In the produced mixtures, an increase in the content of anhydrite and rock-forming calcite was noted in relation to the sludge. Production of the construction materials should be preceded with additional strength tests of the obtained product in order to determined the percentage of waste material addition.

Effect of SiC on Microstructures and Properties of Clay Foam Ceramics

2010 ◽  
Vol 105-106 ◽  
pp. 620-622
Author(s):  
Jian Guang Bai ◽  
Guang Liang Liu ◽  
Jian Feng Yang
Keyword(s):  
Compressive Strength ◽  
Bulk Density ◽  
Moisture Absorption ◽  
Raw Materials ◽  
Sintering Behavior ◽  
Powder Size ◽  
Mass Ratio ◽  
X Ray Diffraction ◽  
X Ray ◽  
Foam Ceramic

A foam ceramic was prepared using clay, SiC, Fe2O3, feldspar and other raw materials as main starting material in a furnace at 1140~1170oC for 15~25min. Effects of silicon carbide’s content and powder size on the bulk density, moisture absorption rate and compressive strength were studied, and the fracture surface morphology was observed and analyzed using Scanning Electron Microscope (SEM) and X-ray diffraction analysis (XRD). The results show that SiC powder reacted with Fe2O3, Fe3O4, CO2, iron, SiO2 and form foam. The sintering behavior and properties of the foam ceramics are influenced by the content and particle size of SiC, when the content of SiC is as high as 8%, and the mass ratio of grain size is 1:1, the foam ceramics with the rate of moisture absorption is 0.05%, the bulk density is 0.32g/cm3, and compressive strength is than 2.2MPa.

scholarly journals Machine Learning Approaches for Prediction of the Compressive Strength of Alkali Activated Termite Mound Soil

2021 ◽  
Vol 11 (11) ◽  
pp. 4754
Author(s):  
Assia Aboubakar Mahamat ◽  
Moussa Mahamat Boukar ◽  
Nurudeen Mahmud Ibrahim ◽  
Tido Tiwa Stanislas ◽  
Numfor Linda Bih ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Construction Materials ◽  
Curing Temperature ◽  
Sustainable Construction ◽  
Support Vector ◽  
Learning Approaches ◽  
Artificial Neural Network Ann ◽  
Curing Regime ◽  
Alkali Activated

Earth-based materials have shown promise in the development of ecofriendly and sustainable construction materials. However, their unconventional usage in the construction field makes the estimation of their properties difficult and inaccurate. Often, the determination of their properties is conducted based on a conventional materials procedure. Hence, there is inaccuracy in understanding the properties of the unconventional materials. To obtain more accurate properties, a support vector machine (SVM), artificial neural network (ANN) and linear regression (LR) were used to predict the compressive strength of the alkali-activated termite soil. In this study, factors such as activator concentration, Si/Al, initial curing temperature, water absorption, weight and curing regime were used as input parameters due to their significant effect in the compressive strength. The experimental results depict that SVM outperforms ANN and LR in terms of R2 score and root mean square error (RMSE).

Effect of P2O5 on the Properties of Alite-Calcium Strontium Sulphoaluminate Cement

2011 ◽  
Vol 306-307 ◽  
pp. 961-965
Author(s):  
Chao Nan Yin ◽  
Ling Chao Lu ◽  
Shou De Wang
Keyword(s):  
Compressive Strength ◽  
Electron Microscope ◽  
Heat Evolution ◽  
Petrographic Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sulphoaluminate Cement ◽  
Suitable Amount ◽  
Acceleration Period ◽  
Scanning Electron

The influence of P2O5on the properties of alite-calcium strontium sulphoaluminate cement was researched by means of X-ray diffraction, scanning electron microscope-energy dispersive spectroscopy (SEM-EDS) and petrographic analysis. The results show that the optimal content of P2O5is 0.3% and the compressive strength of the cement at 1, 3, 28d are 27.0, 59.1, 110.9MPa when the calcining temperature is 1350°C. P2O5mainly exists in the belite and a suitable amount of P2O5can promote the formation of C1.5Sr2.5A3and alite. When the content of P2O5is higher than 0.3%, the formation of C1.5Sr2.5A3and alite can be hindered. P2O5can enhance the hydration heat evolution rate in the acceleration period and the hydrate heat of cement containing P2O5increases slightly.

scholarly journals Thermal Stability and Kinetics of Formation of Magnesium Oxychloride Phase 3Mg(OH)2∙MgCl2∙8H2O

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 767 ◽  
Author(s):  
Michal Lojka ◽  
Ondřej Jankovský ◽  
Adéla Jiříčková ◽  
Anna-Marie Lauermannová ◽  
Filip Antončík ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Construction Materials ◽  
Simultaneous Thermal Analysis ◽  
Rietveld Analysis ◽  
X Ray Diffraction ◽  
Sustainable Building ◽  
X Ray ◽  
Kinetics Of Formation ◽  
Magnesium Oxychloride ◽  
Kinetics Of

In this paper, magnesium oxychloride cement with stoichiometry 3Mg(OH)2∙MgCl2∙8H2O (MOC 3-1-8) was prepared and characterized. The phase composition and kinetics of formation were studied by X-ray diffraction (XRD) and Rietveld analysis of obtained diffractograms. The chemical composition was analyzed using X-ray fluorescence (XRF) and energy dispersive spectroscopy (EDS). Furthermore, scanning electron microscopy (SEM) was used to study morphology, and Fourier Transform Infrared (FT-IR) spectroscopy was also used for the analysis of the prepared sample. In addition, thermal stability was tested using simultaneous thermal analysis (STA) combined with mass spectroscopy (MS). The obtained data gave evidence of the fast formation of MOC 3-1-8, which started to precipitate rapidly. As the length of the time of ripening increased, the amount of MgO decreased, while the amount of MOC 3-1-8 increased. The fast formation of the MOC 3-1-8 phase at an ambient temperature is important for its application in the production of low-energy construction materials, which corresponds with the challenges of a sustainable building industry.

scholarly journals Effect of Locally Available Wheat Straw Ash in Developing High Strength Concrete

2021 ◽  
pp. 19-28
Author(s):  
Muhammad Armaghan Siffat ◽  
Muhammad Ishfaq ◽  
Afaq Ahmad ◽  
Khalil Ur Rehman ◽  
Fawad Ahmad
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Wheat Straw ◽  
High Strength Concrete ◽  
High Strength ◽  
Optimum Temperature ◽  
X Ray Diffraction ◽  
X Ray ◽  
Strength Concrete ◽  
Straw Ash

This study is supervised to assess the characteristics of the locally available wheat straw ash (WSA) to consume as a substitute to the cement and support in enhancing the mechanical properties of concrete. Initially, after incineration at optimum temperature of 800°C for 0.5, the ash of wheat straw was made up to the desirable level of fineness by passing through it to the several grinding cycles. Subsequently, the X-ray fluorescence (XRF) along with X-ray diffraction (XRD) testing conducted on ash of wheat straw for the evaluation its pozzolanic potential. Finally, the specimens of concrete were made by consuming 10% and 20% percentages of wheat straw ash as a replacement in concrete to conclude its impact on the compressive strength of high strength concrete. The cylinders of steel of dimensions 10cm diameter x 20cm depth were acquired to evaluate the compressive strength of high strength concrete. The relative outcomes of cylinders made of wheat straw ash substitution presented the slight increase in strength values of the concrete. Ultimately, the C-100 blends and WSA aided cement blends were inspected for the rheology of WSA through FTIR spectroscopy along with Thermogravimetric technique. The conclusions authenticate the WSA potential to replace cement in the manufacturing of the high strength concrete.

scholarly journals Study on High Energy Propellant Waste in the Processing of Fired Clay Bricks

2020 ◽  
Vol 70 (6) ◽  
pp. 596-602
Author(s):  
P.K. Mehta ◽  
A. Kumaraswamy ◽  
V. K. Saraswat ◽  
Praveen Kumar B.
Keyword(s):  
Compressive Strength ◽  
Water Absorption ◽  
Pore Formation ◽  
High Energy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Clay Bricks ◽  
Baking Process ◽  
Fired Bricks ◽  
Xrd Studies

Utilisation of propellant waste in fabrication of bricks is not only used as efficient waste disposal method but also to get better functional properties. In the present study, high energy propellant (HEP) waste additive mixed with soil and fly ash in different proportions during manufacturing of bricks has been investigated experimentally. X-ray diffraction (XRD) studies were carried out to confirm the brick formation and the effect of HEP waste. Ceramic bricks were fabricated with HEP waste additive in proper proportions i.e. 0.5 wt %, 1.0 wt %, 1.5 wt %, 2.0 wt %, 2.5 wt %, 3 wt %, 3.5 wt %, and 4 wt % and then evaluated for water absorption capability and compressive strength. Compressive strength of 6.7 N/mm2, and Water absorption of 22 % have been observed from modified fired bricks impregnated with HEM waste additive. Scanning electron microscopy (SEM) studies were carried out to analyze the effect of HEP waste additive on pore formation and distribution in the bricks. Further, the heat resulting from decomposition of propellants can cause a decrease in the energy required of baking process. The process of manufacturing of bricks with HEP waste additive is first of its kind till date.

UTILIZATION OF FLY ASH AND CONCRETE RESIDUE IN THE PRODUCTION OF GEOPOLYMER BRICKS

2017 ◽  
Vol 12 (1) ◽  
pp. 63-77 ◽  
Author(s):  
Siriporn Sirikingkaew ◽  
Nuta Supakata
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Compressive Strength ◽  
Phase Composition ◽  
Fly Ash ◽  
Industrial Waste ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

This study presents the development of geopolymer bricks synthetized from industrial waste, including fly ash mixed with concrete residue containing aluminosilicate compound. The above two ingredients are mixed according to five ratios: 100:0, 95:5, 90:10, 85:15, and 80:20. The mixture's physico-mechanical properties, in terms of water absorption and the compressive strength of the geopolymer bricks, are investigated according to the TIS 168-2546 standard. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses are used to investigate the microstructure and the elemental and phase composition of the brick specimens. The results indicate that the combination of fly ash and concrete residue represents a suitable approach to brick production, as required by the TIS 168–2546 standard.

Optimization of Structure of Soft Block for Design of Adaptive Polyurethanes

2020 ◽  
Vol 869 ◽  
pp. 273-279
Author(s):  
Marina A. Gorbunova ◽  
Denis V. Anokhin ◽  
Valentina A. Lesnichaya ◽  
Alexander A. Grishchuk ◽  
Elmira R. Badamshina
Keyword(s):  
Mutual Influence ◽  
Glycol Adipate ◽  
Mass Ratio ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Crystallization Conditions ◽  
Crystalline Domains ◽  
Kinetics Of

A synthesis of new di-and triblock polyurethane thermoplastic copolymers containing different mass ratio of two crystallizing blocks - poly (1,4-butylene glycol) adipate and poly-ε-caprolactone diols was developed. Using combination of danamometric analysis, IR-spectroscopy, differential scanning calorimetry and X-ray diffraction, the effect of the soft block composition and crystallization conditions on crystal structure and thermal behavior of the obtained polymers have been studied. For the triblock copolymers we have shown a possibility of control the kinetics of material hardening and final mechanical characteristics due to the mutual influence of polydiols during crystallization. In the result, the second crystallizing component allows to control amount, structure and quality of crystalline domains in polyurethanes by variation of crystallization conditions.

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