Peritectic Reactions and Phase Transformations of Sn-30wt%Cu for High Temperature Pb-Free Soldering Applications

2016 ◽  
Vol 857 ◽  
pp. 58-62 ◽  
Author(s):  
Selena Smith ◽  
Guang Zeng ◽  
Jonathan Read ◽  
Stuart D. McDonald ◽  
Kazuhiro Nogita
Keyword(s):  
Phase Diagram ◽  
High Temperature ◽  
Binary Phase Diagram ◽  
Volume Fraction ◽  
Dendritic Structure ◽  
Primary Phase ◽  
Crack Plane ◽  
Negative Effects ◽  
Cu Content ◽  
Cu Alloy

Extending the use of the Sn-Cu system to high-temperature solders poses additional challenges as the necessary high Cu content is in a region of the binary phase diagram which is dominated by the peritectic reaction and has the intermetallic compound (IMC) Cu3Sn as the primary phase, which is known to have negative effects on soldering properties. Minor additions of nickel (Ni) have been reported to suppress the formation of Cu3Sn in low Cu content Sn-Cu solder alloys though higher Cu content alloys have not been investigated. As such, the objective of this paper was to investigate the effect of more significant concentrations of Ni on the microstructure of a Sn-30wt%Cu alloy. An initial addition of 2wt%Ni greatly reduced the volume fractions of Cu3Sn and the amount of eutectic present whilst significantly increasing the volume fraction of Cu6Sn5; however, further additions of Ni had a less pronounced affect. The Sn-30wt%Cu morphology was changed from a plate-like structure to a dendritic structure by adding Ni, which would improve solder performance by decreasing the possible crack plane length.

scholarly journals Influence of Si, Cu, B, and Trace Alloying Elements on the Conductivity of the Al-Si-Cu Alloy

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 426
Author(s):  
Zhao Yang ◽  
Xiaolong He ◽  
Bin Li ◽  
Andrej Atrens ◽  
Xuyue Yang ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Element Concentration ◽  
Volume Fraction ◽  
Transition Element ◽  
Absolute Temperature ◽  
Alloying Elements ◽  
Cu Content ◽  
Cu Alloy ◽  
Die Cast ◽  
Thermal Conductivity Λ

The influence of Si, Cu, B, and trace alloying elements on the conductivity of aluminum die cast 12 (ADC12) alloy was investigated. The conductivity decreased linearly with increasing volume fraction of the Si phase attributed to a linear decrease of the volume of the more conductive Al phase through a rule of mixtures. The conductivity also decreased with increasing Cu content, between 0~3%. The conductivity increased with increasing B content, reached the peak at 0.02% B and thereafter decreased somewhat. The mechanism was that B reacted with the transition element in the Al phase to form boride, decreasing the transition element concentration in the Al lattice, and decreasing the lattice constant. The thermal conductivity, λ, was related to the electrical conductivity, σ, by means of λ=LTσ+λg, where L is the apparent Lorentz constant, 1.86 × 10−8; T is the absolute temperature, 293 K; λg is the lattice conductivity, 42.3 W/(m·K).

Relationship between Microstructure and Mechanical Strength of Dental Semiprecious Alloys Subjected to Solution Treatment

2018 ◽  
Vol 941 ◽  
pp. 1105-1110
Author(s):  
Toshikazu Akahori ◽  
Tusbasa Mizuno ◽  
Mitsuo Niinomi ◽  
Hisao Fukui
Keyword(s):  
High Temperature ◽  
Mechanical Strength ◽  
Corrosion Potential ◽  
Volume Fraction ◽  
Solution Treatment ◽  
Silver Alloy ◽  
Hardening Mechanism ◽  
Cu Content ◽  
Β Phase ◽  
The Relationship

Silver alloy is one of semi-precious alloys for dental prosthesis, which has been applied remarkably in Japanese dental field. Ag-20Pd-17.7Cu-12Au alloy (G12), which was newly developed for commercial dental silver alloy, shows the unique hardening mechanism after a simple solution treatment (ST) at relatively high temperature. However, the relationship between ST at various temperature and the mechanical strength of G12 has not been investigated fully. Therefore, the relationship between ST and mechanical properties of G12 after ST at various temperatures was investigated systematically in this study. G12 subjected to ST at relatively high temperature of 1173 K is composed of three kinds of phases with Ag-rich α2 phase, Cu-rich α1 phase and β phase of Pd-Cu intermetallic compound. Although nominal melting point of G12 was around 1233 K, the high Cu concentration area like α1 phase was partially dissolved and then the α1, α2 and partial β phases re-precipitated during cooling. On the other hand, the microstructure of G12 aged at 673 K after ST at 1023 K (STA) was mainly composed of two kinds of phases with α2 and α1 phases with a small amount of β phase, which was a typical microstructure of STA. The Vickers hardness of G12 subjected to ST at 1173 K was identical to that of the same alloy subjected to STA although the tensile strength, fatigue limit and ductility deteriorated to some degrees. The corrosion potential of G12 changed drastically with the temperature of ST. The potential may have been increased by the decrease in the volume fraction of the α1 phase with relatively high Cu content.

Microstructural characterization of a rapidly solidified Al-Fe-V-Si alloy for elevated temperature applications

1988 ◽  
Vol 46 ◽  
pp. 550-551
Author(s):  
R. E. Franck ◽  
J. A. Hawk ◽  
G. J. Shiflet
Keyword(s):  
High Temperature ◽  
Elevated Temperature ◽  
Grain Growth ◽  
Volume Fraction ◽  
Microstructural Characterization ◽  
Second Phase ◽  
Microstructural Stability ◽  
Elevated Temperature Strength ◽  
Temperature Applications

Rapid solidification processing (RSP) is one method of producing high strength aluminum alloys for elevated temperature applications. Allied-Signal, Inc. has produced an Al-12.4 Fe-1.2 V-2.3 Si (composition in wt pct) alloy which possesses good microstructural stability up to 425°C. This alloy contains a high volume fraction (37 v/o) of fine nearly spherical, α-Al12(Fe, V)3Si dispersoids. The improved elevated temperature strength and stability of this alloy is due to the slower dispersoid coarsening rate of the silicide particles. Additionally, the high v/o of second phase particles should inhibit recrystallization and grain growth, and thus reduce any loss in strength due to long term, high temperature annealing.The focus of this research is to investigate microstructural changes induced by long term, high temperature static annealing heat-treatments. Annealing treatments for up to 1000 hours were carried out on this alloy at 500°C, 550°C and 600°C. Particle coarsening and/or recrystallization and grain growth would be accelerated in these temperature regimes.

MAGNETIC PROPERTIES OF PSEUDO-BINARY Mn1−xFexSn2 ALLOYS

1993 ◽  
Vol 07 (01n03) ◽  
pp. 867-870 ◽  
Author(s):  
H. SHIRAISHI ◽  
T. HORI ◽  
Y. YAMAGUCHI ◽  
S. FUNAHASHI ◽  
K. KANEMATSU
Keyword(s):  
Field Theory ◽  
Phase Diagram ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
High Temperature ◽  
Magnetic Structure ◽  
Magnetic Phase ◽  
Magnetic Phase Diagram ◽  
Molecular Field ◽  
Magnetic Phases

The magnetic susceptibility measurements have been made on antiferromagnetic compounds Mn1–xFexSn2 and the magnetic phase diagram was illustrated. The high temperature magnetic phases I and III, major phases, were analyzed on the basis of molecular field theory and explained the change of magnetic structure I⇌III occured at x≈0.8.

High Temperature Mechanical Properties of Ni-Al-Cr Based Alloys with Refractory Alloying Elements

2006 ◽  
Vol 510-511 ◽  
pp. 358-361
Author(s):  
Won Yong Kim ◽  
Han Sol Kim ◽  
In Dong Yeo ◽  
Mok Soon Kim
Keyword(s):  
High Temperature ◽  
Volume Fraction ◽  
Lattice Parameter ◽  
Alloying Elements ◽  
Solid Solution Hardening ◽  
High Temperature Strength ◽  
High Temperature Mechanical Properties ◽  
Die Materials ◽  
The Matrix ◽  
Effective Role

We report on advanced Ni3Al based high temperature structural alloys with refractory alloying elements such as Zr and Mo to be apllied in the fields of die-casting and high temperature press forming as die materials. The duplex microstructure consisting of L12 structured Ni3Al phase and Ni5Zr intermetallic dispersoids was observed to display the microstructural feature for the present alloys investigated. Depending on alloying elements, the volume fraction of 2nd phase was measured to be different, indicating a difference in solid solubility of alloying elements in the matrix γ’ phase. Lattice parameter of matrix phase increased with increasing content of alloying elements. In the higher temperature region more than 973K, the present alloys appeared to show their higher strength compared to those obtained in conventional superalloys. On the basis of experimental results obtained, it is suggested that refractory alloying elements have an effective role to improve the high temperature strength in terms of enhanced thermal stability and solid solution hardening.

Synthesis of high-temperature thermally expandable microcapsules and their effects on foaming quality and surface quality of foamed ABS materials

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 519-527
Author(s):  
Wei Gong ◽  
Xianglin Pei ◽  
Xiaogang Yin ◽  
Daming Ban ◽  
Hai Fu ◽  
...  
Keyword(s):  
High Temperature ◽  
Surface Quality ◽  
Volume Fraction ◽  
Crosslinking Agent ◽  
Acrylonitrile Butadiene Styrene ◽  
Foaming Agent ◽  
Blowing Agent ◽  
Good Surface ◽  
Butadiene Styrene

AbstractIn this paper, acrylonitrile and hydroxypropyl acrylate are used as the binary polymerization monomers, and isooctane is used as the foaming agent to prepare high-temperature thermally expandable microcapsules. Analysis of the effect of blowing agent and crosslinking agent on the expansion properties of high-temperature thermally expandable microcapsules, the effects of foaming agent azodicarbonamide (ADCA) and micro-expansion capsule on the surface quality and foaming quality of foamed acrylonitrile–butadiene–styrene (ABS) products were investigated. The foamed product prepared by the high-temperature microcapsule has a good surface quality, the gloss is 52.3, the cell is not easily deformed, and the volume fraction is 4%; the foamed ABS/ADCA material has poor cell uniformity, the cell is easily deformed, the volume fraction is 6.5%, the surface quality is poor, and the gloss is only 8.7.

The activation energy U(T,B) in high temperature superconductor

2020 ◽  
Vol 92 (2) ◽  
pp. 20601
Author(s):  
Abdelaziz Labrag ◽  
Mustapha Bghour ◽  
Ahmed Abou El Hassan ◽  
Habiba El Hamidi ◽  
Ahmed Taoufik ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Activation Energy ◽  
Phase Diagram ◽  
High Temperature ◽  
Apparent Activation Energy ◽  
High Temperature Superconductor ◽  
Flux Flow ◽  
Resistivity Measurements ◽  
Vortex Phase ◽  
The Magnetic Field

It is reported in this paper on the thermally assisted flux flow in epitaxial YBa2Cu3O7-δ deposited by Laser ablation method on the SrTiO3 substrate. The resistivity measurements ρ (T, B) of the sample under various values of the magnetic field up to 14T in directions B∥ab-plane and B∥c-axis with a dc weak transport current density were investigated in order to determine the activation energy and then understand the vortex dynamic phenomena and therefore deduce the vortex phase diagram of this material. The apparent activation energy U0 (B) calculated using an Arrhenius relation. The measured results of the resistivity were then adjusted to the modified thermally assisted flux flow model in order to account for the temperature-field dependence of the activation energy U (T, B). The obtained values from the thermally assisted activation energy, exhibit a behavior similar to the one showed with the Arrhenius model, albeit larger than the apparent activation energy with ∼1.5 order on magnitude for both cases of the magnetic field directions. The vortex glass model was also used to obtain the vortex-glass transition temperature from the linear fitting of [d ln ρ/dT ] −1 plots. In the course of this work thanks to the resistivity measurements the upper critical magnetic field Hc2 (T), the irreversibility line Hirr (T) and the crossover field HCrossOver (T) were located. These three parameters allowed us to establish a phase diagram of the studied material where limits of each vortex phase are sketched in order to optimize its applicability as a practical high temperature superconductor used for diverse purposes.

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