Low-Temperature Aluminosilicate Nanostructured Binder - Characteristics and Applicability

2019 ◽  
Vol 945 ◽  
pp. 193-198 ◽  
Author(s):  
Igor V. Zhernovsky ◽  
Alla V. Cherevatova ◽  
Natalia Ivanovna Kozhukhova ◽  
Maya Sergeevna Osadchaya ◽  
D.A. Ksenofontov
Keyword(s):  
Low Temperature ◽  
Building Materials ◽  
Construction Material ◽  
Thermal Exposure ◽  
Green Technology ◽  
Unit Cell ◽  
Current Trends ◽  
Mineral Phases ◽  
Wide Range ◽  
Cell Volumes

Current trends in the field of construction material is focused on enhancement of sustainability of building materials and constructions urging on development of new types of inorganic binders and composites in order to meet the modern requirements of service performance and special properties. This research studied and demonstrated the opportunity to develop zero-cement heat-resisting granite-based nanostructured binder (GNB) using «green» technology production. XRD and DTA analyses demonstrated that the thermal exposure of GNB to wide range of temperatures of 20–1000 °C leads to such phase transformations in the binder as α-quartz to β-quartz transformation; amorphous alkali-aluminosilicate (gel) to crystal phase of Са-albite. The calculation of cell volumes characteristics for low-temperature (before thermal exposure) and high-temperature (after thermal exposure) phases was performed using following equation: where is concentration (by wt. %) of mineral phases;Viis unit cell volume of mineral phases, Å. The calculated ratios of unit cell volumes were close to 1 which ensures a structural stability of the GNB under thermal exposure and confirms its heat-resistant performance.

The Development of Composite Nanostructured Gypsum Binder with Enhanced Heat Resistance Performance

2019 ◽  
Vol 945 ◽  
pp. 293-298 ◽  
Author(s):  
Alla V. Cherevatova ◽  
Igor V. Zhernovsky ◽  
M.I. Kozhukhova ◽  
D.A. Alehin
Keyword(s):  
High Temperature ◽  
Heat Resistance ◽  
Crystallization Process ◽  
Thermal Exposure ◽  
Reactive Component ◽  
Wide Range ◽  
The Subject ◽  
Temperature Exposure ◽  
Resistance Performance ◽  
Cell Volumes

The subject of this study was an experimental confirmation of stability of composite nanostructured gypsum silicate binder (CNGSB) system under high-temperature exposure (up to 1000 °C). The hypothesis of the heat-resistance performance of gypsum-based binder was crystallization process in CNGSB system involving a silicate constituent as a reactive component in NB. XRD and DTA analyses demonstrated that thermal exposure of CNGSB to wide range of temperatures of 20–1000 °C leads to α-quartz to β-quartz phase transformation in the binder; amorphous alkali-aluminosilicate (gel) changes to crystal phase of Са-albite. The calculation of cell volumes characteristics for low-temperature (before thermal exposure) and high-temperature (after thermal exposure) phases was performed. The calculated ratios of unit cell volumes were close to 1 which ensures a structural stability of the GNB under thermal exposure and confirms its heat-resistant performance.

Recycling and Reuse in the Roman Economy

2020 ◽  
Keyword(s):  
Building Materials ◽  
Computational Modelling ◽  
Late Antique ◽  
Roman Economy ◽  
Wide Range ◽  
The Status ◽  
Recent Developments ◽  
Methodological Approaches ◽  
First Time ◽  
Site Types

The recycling and reuse of materials and objects were extensive in the past, but have rarely been embedded into models of the economy; even more rarely has any attempt been made to assess the scale of these practices. Recent developments, including the use of large datasets, computational modelling, and high-resolution analytical chemistry, are increasingly offering the means to reconstruct recycling and reuse, and even to approach the thorny matter of quantification. Growing scholarly interest in the topic has also led to an increasing recognition of these practices from those employing more traditional methodological approaches, which are sometimes coupled with innovative archaeological theory. Thanks to these efforts, it has been possible for the first time in this volume to draw together archaeological case studies on the recycling and reuse of a wide range of materials, from papyri and textiles, to amphorae, metals and glass, building materials and statuary. Recycling and reuse occur at a range of site types, and often in contexts which cross-cut material categories, or move from one object category to another. The volume focuses principally on the Roman Imperial and late antique world, over a broad geographical span ranging from Britain to North Africa and the East Mediterranean. Last, but not least, the volume is unique in focusing upon these activities as a part of the status quo, and not just as a response to crisis.

scholarly journals RELaTED Project: New Developments on Ultra-Low Temperature District Heating Networks

Proceedings ◽  
2020 ◽  
Vol 65 (1) ◽  
pp. 25
Author(s):  
Antonio Garrido Marijuan ◽  
Roberto Garay ◽  
Mikel Lumbreras ◽  
Víctor Sánchez ◽  
Olga Macias ◽  
...  
Keyword(s):  
Low Temperature ◽  
High Performance ◽  
Waste Heat ◽  
District Heating ◽  
Hot Water ◽  
Thermal Systems ◽  
Heating Source ◽  
Wide Range ◽  
Thermal Sources ◽  
Heating Networks

District heating networks deliver around 13% of the heating energy in the EU, being considered as a key element of the progressive decarbonization of Europe. The H2020 REnewable Low TEmperature District project (RELaTED) seeks to contribute to the energy decarbonization of these infrastructures through the development and demonstration of the following concepts: reduction in network temperature down to 50 °C, integration of renewable energies and waste heat sources with a novel substation concept, and improvement on building-integrated solar thermal systems. The coupling of renewable thermal sources with ultra-low temperature district heating (DH) allows for a bidirectional energy flow, using the DH as both thermal storage in periods of production surplus and a back-up heating source during consumption peaks. The ultra-low temperature enables the integration of a wide range of energy sources such as waste heat from industry. Furthermore, RELaTED also develops concepts concerning district heating-connected reversible heat pump systems that allow to reach adequate thermal levels for domestic hot water as well as the use of the network for district cooling with high performance. These developments will be demonstrated in four locations: Estonia, Serbia, Denmark, and Spain.

scholarly journals Crushed Bricks: Demolition Waste as a Sustainable Raw Material for Geopolymers

2021 ◽  
Vol 13 (14) ◽  
pp. 7572
Author(s):  
Gigliola D’Angelo ◽  
Marina Fumo ◽  
Mercedes del Rio Merino ◽  
Ilaria Capasso ◽  
Assunta Campanile ◽  
...  
Keyword(s):  
Energy Consumption ◽  
Building Materials ◽  
Mechanical Performance ◽  
Raw Materials ◽  
Construction Material ◽  
Raw Material ◽  
The European Union ◽  
Total Energy Consumption ◽  
Demolition Waste ◽  
Crushed Brick

Demolition activity plays an important role in the total energy consumption of the construction industry in the European Union. The indiscriminate use of non-renewable raw materials, energy consumption, and unsustainable design has led to a redefinition of the criteria to ensure environmental protection. This article introduces an experimental plan that determines the viability of a new type of construction material, obtained from crushed brick waste, to be introduced into the construction market. The potential of crushed brick waste as a raw material in the production of building precast products, obtained by curing a geopolymeric blend at 60 °C for 3 days, has been exploited. Geopolymers represent an important alternative in reducing emissions and energy consumption, whilst, at the same time, achieving a considerable mechanical performance. The results obtained from this study show that the geopolymers produced from crushed brick were characterized by good properties in terms of open porosity, water absorption, mechanical strength, and surface resistance values when compared to building materials produced using traditional technologies.

scholarly journals Recent Attempts in the Design of Efficient PVC Plasticizers with Reduced Migration

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 844
Author(s):  
Joanna Czogała ◽  
Ewa Pankalla ◽  
Roman Turczyn
Keyword(s):  
Mechanical Properties ◽  
Partial Replacement ◽  
Total Replacement ◽  
Current Trends ◽  
Poly Vinyl Chloride ◽  
Wide Range ◽  
Migration Resistance ◽  
Secondary Plasticizer ◽  
New Compounds ◽  
Ethylhexyl Phthalate

This paper reviews the current trends in replacing commonly used plasticizers in poly(vinyl chloride), PVC, formulations by new compounds with reduced migration, leading to the enhancement in mechanical properties and better plasticizing efficiency. Novel plasticizers have been divided into three groups depending on the replacement strategy, i.e., total replacement, partial replacement, and internal plasticizers. Chemical and physical properties of PVC formulations containing a wide range of plasticizers have been compared, allowing observance of the improvements in polymer performance in comparison to PVC plasticized with conventionally applied bis(2-ethylhexyl) phthalate, di-n-octyl phthalate, bis(2-ethylhexyl) terephthalate and di-n-octyl terephthalate. Among a variety of newly developed plasticizers, we have indicated those presenting excellent migration resistance and advantageous mechanical properties, as well as those derived from natural sources. A separate chapter has been dedicated to the description of a synergistic effect of a mixture of two plasticizers, primary and secondary, that benefits in migration suppression when secondary plasticizer is added to PVC blend.

scholarly journals Characterization of a Novel CaCO3-Forming Alkali-Tolerant Rhodococcus erythreus S26 as a Filling Agent for Repairing Concrete Cracks

Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2967
Author(s):  
Seunghoon Choi ◽  
Sungjin Park ◽  
Minjoo Park ◽  
Yerin Kim ◽  
Kwang Min Lee ◽  
...  
Keyword(s):  
Building Materials ◽  
Culture Fluid ◽  
Natural Phenomenon ◽  
Environment Friendly ◽  
Wide Range ◽  
Filling Agent ◽  
Calcium Source ◽  
Alkali Tolerance ◽  
High Alkali

Biomineralization, a well-known natural phenomenon associated with various microbial species, is being studied to protect and strengthen building materials such as concrete. We characterized Rhodococcus erythreus S26, a novel urease-producing bacterium exhibiting CaCO3-forming activity, and investigated its ability in repairing concrete cracks for the development of environment-friendly sealants. Strain S26 grown in solid medium formed spherical and polygonal CaCO3 crystals. The S26 cells grown in a urea-containing liquid medium caused culture fluid alkalinization and increased CaCO3 levels, indicating that ureolysis was responsible for CaCO3 formation. Urease activity and CaCO3 formation increased with incubation time, reaching a maximum of 2054 U/min/mL and 3.83 g/L, respectively, at day four. The maximum CaCO3 formation was achieved when calcium lactate was used as the calcium source, followed by calcium gluconate. Although cell growth was observed after the induction period at pH 10.5, strain S26 could grow at a wide range of pH 4–10.5, showing its high alkali tolerance. FESEM showed rhombohedral crystals of 20–60 µm in size. EDX analysis indicated the presence of calcium, carbon, and oxygen in the crystals. XRD confirmed these crystals as CaCO3 containing calcite and vaterite. Furthermore, R. erythreus S26 successfully repaired the artificially induced large cracks of 0.4–0.6 mm width.

scholarly journals 6-Axis Stress Tensor Sensor Using Multifaceted Silicon Piezoresistors

Micromachines ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 279
Author(s):  
Kentaro Noda ◽  
Jian Sun ◽  
Isao Shimoyama
Keyword(s):  
Stress Tensor ◽  
Elastic Body ◽  
Building Materials ◽  
Sensor Response ◽  
Stress Change ◽  
Sensor Chip ◽  
Naked Eye ◽  
Highly Sensitive ◽  
Wide Range

A tensor sensor can be used to measure deformations in an object that are not visible to the naked eye by detecting the stress change inside the object. Such sensors have a wide range of application. For example, a tensor sensor can be used to predict fatigue in building materials by detecting the stress change inside the materials, thereby preventing accidents. In this case, a sensor of small size that can measure all nine components of the tensor is required. In this study, a tensor sensor consisting of highly sensitive piezoresistive beams and a cantilever to measure all of the tensor components was developed using MEMS processes. The designed sensor had dimensions of 2.0 mm by 2.0 mm by 0.3 mm (length by width by thickness). The sensor chip was embedded in a 15 mm3 cubic polydimethylsiloxane (PDMS) (polydimethylsiloxane) elastic body and then calibrated to verify the sensor response to the stress tensor. We demonstrated that 6-axis normal and shear Cauchy stresses with 5 kPa in magnitudes can be measured by using the fabricated sensor.

scholarly journals Fabrication and Compressive Behavior of a Micro-Lattice Composite by High Resolution DLP Stereolithography

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 785
Author(s):  
Chow Shing Shin ◽  
Yu Chia Chang
Keyword(s):  
High Resolution ◽  
Lattice Structure ◽  
Low Cost ◽  
Hierarchical Structures ◽  
Dip Coating ◽  
Unit Cell ◽  
Digital Light Processing ◽  
Unit Cell Size ◽  
Wide Range ◽  
And Performance

Lattice structures are superior to stochastic foams in mechanical properties and are finding increasing applications. Their properties can be tailored in a wide range through adjusting the design and dimensions of the unit cell, changing the constituent materials as well as forming into hierarchical structures. In order to achieve more levels of hierarchy, the dimensions of the fundamental lattice have to be small enough. Although lattice size of several microns can be fabricated using the two-photon polymerization technique, sophisticated and costly equipment is required. To balance cost and performance, a low-cost high resolution micro-stereolithographic system has been developed in this work based on a commercial digital light processing (DLP) projector. Unit cell lengths as small as 100 μm have been successfully fabricated. Decreasing the unit cell size from 150 to 100 μm increased the compressive stiffness by 26%. Different pretreatments to facilitate the electroless plating of nickel on the lattice structure have been attempted. A pretreatment of dip coating in a graphene suspension is the most successful and increased the strength and stiffness by 5.3 and 3.6 times, respectively. Even a very light and incomplete nickel plating in the interior has increase the structural stiffness and strength by more than twofold.

Developing Alternative Building Materials from Mining Waste

2014 ◽  
Vol 976 ◽  
pp. 202-206 ◽  
Author(s):  
Javier Flores Badillo ◽  
Juan Hernández Ávila ◽  
Francisco Patiño Cardona ◽  
Norma Yacelit Trápala Pineda ◽  
José Abacú Ostos Santos
Keyword(s):  
Compressive Strength ◽  
Building Materials ◽  
Subsequent Treatment ◽  
Mining Waste ◽  
Mineralogical Characterization ◽  
Green Strength ◽  
Mineral Phases ◽  
Heavy Clay ◽  
Industrial Materials ◽  
Strength And Plasticity

In this paper we present the production of alternative industrial materials from the mining waste in the form of tailings, this study was made with the tailings of Dos Carlos, establishing 4 sampling zones, dividing them into three strata in the bottom, middle and top. The sampling method used is quartering, to homogenize the material and anticipate the possible use of it as a building material, having for this purpose 12 ceramic mixtures for subsequent treatment. Chemical composition was determined as 70.43% SiO2, 7.032% Al2O3, 2.69% Fe2O3, 0.46% MnO2, 3.98% K2O, 3.34% CaO, 2.50% Na2O, 56 grams per tonne of Ag y 0.6 grams per tonne of Au. In the mineralogical characterization the tailings presents silica, albite, berlinite, orthoclase and potassium jarosite as the main mineral phases, among other mineral phases in lesser concentration such as gypsum, calcite, anorthoclase, pyrite, sphalerite and galena. The determinations of the tailing material granulometry in the range of 60% in a size less than 270 mesh (53 μm). Afterwards, the alternative industrial materials were produced by using the tailings and heavy clay in order to give the composite a good green strength and plasticity during development, but above all to give it a compressive strength similar or higher than that of products derived from conventional processes. Keywords: Tailings, green strength, compressive strength, plasticity, heavy clays, alternative industrial materials.

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