Research of Influence of Plasticizers on the Low-Temperature and Mechanical Properties of Rubbers

2019 ◽  
Vol 945 ◽  
pp. 459-464 ◽  
Author(s):  
M.D. Sokolova ◽  
A.F. Fedorova ◽  
V.V. Pavlova
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Frost Resistance ◽  
Nitrile Rubber ◽  
Butadiene Nitrile Rubber

In this paper, influence of new plasticizers on the mechanical and low-temperature properties of rubbers is studied. The subjects of the research are rubbers based on BNKS-18 butadiene-nitrile rubber and Hydrin T-6000 epichlorohydrin rubber (ECHR). As used plasticizers: DINP (diisononylphthalate), TOTM (trioctyltrimellitate), DOA (dioctyladipate), Alphaplast (complex plasticizer based on esters of organic alcohols and acids). For identification the efficiency, rubbers with the studied plasticizers compared with standard rubber, in which plasticizers have not introduced, as well as with rubber in which a widely used industrial plasticizer DOF (dioktilphthalate) was added. Research of the mechanical properties of rubbers based on BNKS-18 showed that the introduction of plasticizers leads to an increase in elasticity and a slight decrease in the strength of rubbers and on the contrary for rubbers based on ECHR. Low-temperature properties of rubbers with all studied plasticizers have an increased level in comparison with standard rubber. In rubber based on BNKS-18, the highest values of the coefficient of frost resistance at-45°C are observed with the introduction of plasticizers Alphaplast and DOA, an increase in the index compared to standard rubber is more than 50%. The same plasticizers have shown the greatest contribution to the increase in frost resistance of rubbers based on ECHR.

scholarly journals Influence of the Content and Nature of the Plasticizer on the Properties of Butadiene-Nitrile Rubber

2021 ◽  
pp. 222-232
Author(s):  
Valeriya V. Pavlova ◽  
Marina D. Sokolova ◽  
Aytalina F. Fedorova
Keyword(s):  
Low Temperature ◽  
Frost Resistance ◽  
Environmentally Friendly ◽  
Dioctyl Phthalate ◽  
Nitrile Rubber ◽  
Corrosive Media ◽  
Research Results ◽  
Noticeable Improvement ◽  
Butadiene Nitrile Rubber

In this article investigates the effect of the content of plasticizers on the properties of rubbers based on rubber BNKS-18 AMN. The traditional, widely used dioctyl phthalate (DOP), as well as the more modern, environmentally friendly dioctyl terephthalate (DOTP), were used as plasticizers. It has been established that the introduction of plasticizers contributes to the production of rubbers with an improved complex of operational properties, such as elasticity, frost resistance, resistance to the corrosive media SZhR-3. At the same time, according to the research results, it was revealed that the introduction of plasticizers in an amount of 20 phr leads to the most noticeable improvement in these properties. In terms of physicomechanical and low temperature properties, the samples containing DOTP significantly exceed those of the samples containing DOP. Thus, our data showed that the use of DOTP is promising as an alternative to the widely used DOP

Study on Application of the Blends of Nitrile Rubber with Acrylate Rubber in the Coat-Metal Sealing Gasket

2011 ◽  
Vol 393-395 ◽  
pp. 1438-1442 ◽  
Author(s):  
Zu Min Qiu ◽  
Chao Yan Qin ◽  
Jun Ming Qiu
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Heat Resistance ◽  
Nitrile Rubber ◽  
Temperature Resistance ◽  
Oil Resistance ◽  
Comprehensive Properties ◽  
The Cost ◽  
Low Temperature Resistance

This paper discussed the effect of different blending ratio with BNR and ACM on the mechanical properties, heat resistance, low temperature resistance and oil resistance of coat-metal sealing gasket. The result showed that the comprehensive properties of the NBR/ACM blends at the ratio of 85/15 were preferable to the NBR and ACM, the low temperature resistance and oil resistance of NBR are taken into account. The cost of the blends were lower than the ACM. The blends can be used for coat-metal sealing gasket instead of NBR.

Effect of Epoxy Resin Concentration on Some Mechanical Properties of Carbon Fabric/ Nitrile Rubber Reinforced Composites

2019 ◽  
Vol 9 (1) ◽  
pp. 1-15
Author(s):  
Sawsan Fakhry Halim ◽  
Said Sayed Gad El Kholy ◽  
HalaFikry Naguib ◽  
Riham Samir Hegazy ◽  
Nermen Mohamed Baheg
Keyword(s):  
Mechanical Properties ◽  
Epoxy Resin ◽  
Nitrile Rubber ◽  
Reinforced Composites ◽  
Carbon Fabric

scholarly journals Low-Temperature Mechanical Properties of High-Density and Low-Density Polyethylene and Their Blends

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1821
Author(s):  
Ildar I. Salakhov ◽  
Nadim M. Shaidullin ◽  
Anatoly E. Chalykh ◽  
Mikhail A. Matsko ◽  
Alexey V. Shapagin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Impact Strength ◽  
Relative Elongation ◽  
High Density ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Subzero Temperatures ◽  
Izod Impact

Low-temperature properties of high-density polyethylene (HDPE), low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), and their blends were studied. The analyzed low-temperature mechanical properties involve the deformation resistance and impact strength characteristics. HDPE is a bimodal ethylene/1-hexene copolymer; LDPE is a branched ethylene homopolymer containing short-chain branches of different length; LLDPE is a binary ethylene/1-butene copolymer and an ethylene/1-butene/1-hexene terpolymer. The samples of copolymers and their blends were studied by gel permeation chromatography (GPC), differential scanning calorimetry (DSC), 13С NMR spectroscopy, and dynamic mechanical analysis (DMA) using testing machines equipped with a cryochamber. It is proposed that such parameters as “relative elongation at break at −45 °C” and “Izod impact strength at −40 °C” are used instead of the ductile-to-brittle transition temperature to assess frost resistance properties because these parameters are more sensitive to deformation and impact at subzero temperatures for HDPE. LLDPE is shown to exhibit higher relative elongation at break at −45 °C and Izod impact strength at −20 ÷ 60 °C compared to those of LDPE. LLDPE terpolymer added to HDPE (at a content ≥ 25 wt.%) simultaneously increases flow properties and improves tensile properties of the blend at −45 °C. Changes in low-temperature properties as a function of molecular weight, MWD, crystallinity, and branch content were determined for HDPE, LLDPE, and their blends. The DMA data prove the resulting dependences. The reported findings allow one to understand and predict mechanical properties in the HDPE–LLDPE systems at subzero temperatures.

scholarly journals Effects of equal channel angular pressing and heat treatments on the microstructures and mechanical properties of selective laser melted and cast AlSi10Mg alloys

2021 ◽  
Vol 21 (3) ◽  
Author(s):  
Przemysław Snopiński ◽  
Mariusz Król ◽  
Marek Pagáč ◽  
Jana Petrů ◽  
Jiří Hajnyš ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Equal Channel Angular Pressing ◽  
Heat Treatments ◽  
Electron Backscattered Diffraction ◽  
Angular Pressing ◽  
Low Temperature Annealing ◽  
Transmission Electron ◽  
Before And After ◽  
The Impact

AbstractThis study investigated the impact of the equal channel angular pressing (ECAP) combined with heat treatments on the microstructure and mechanical properties of AlSi10Mg alloys fabricated via selective laser melting (SLM) and gravity casting. Special attention was directed towards determining the effect of post-fabrication heat treatments on the microstructural evolution of AlSi10Mg alloy fabricated using two different routes. Three initial alloy conditions were considered prior to ECAP deformation: (1) as-cast in solution treated (T4) condition, (2) SLM in T4 condition, (3) SLM subjected to low-temperature annealing. Light microscopy, transmission electron microscopy, X-ray diffraction line broadening analysis, and electron backscattered diffraction analysis were used to characterize the microstructures before and after ECAP. The results indicated that SLM followed by low-temperature annealing led to superior mechanical properties, relative to the two other conditions. Microscopic analyses revealed that the partial-cellular structure contributed to strong work hardening. This behavior enhanced the material’s strength because of the enhanced accumulation of geometrically necessary dislocations during ECAP deformation.

scholarly journals Analysis of Mechanical Properties and Mechanism of Natural Rubber Waterstop after Aging in Low-Temperature Environment

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2119
Author(s):  
Lin Yu ◽  
Shiman Liu ◽  
Weiwei Yang ◽  
Mengying Liu
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Energy Dispersive Spectrometry ◽  
Permanent Deformation ◽  
Test Chamber ◽  
Accelerate Aging ◽  
Aging Mechanism ◽  
Temperature Environment ◽  
Freezing Test ◽  
Temperature Water

In order to elucidate the aging performance and aging mechanism of a rubber waterstop in low-temperature environments, the rubber waterstops were placed in the freezing test chamber to accelerate aging, and then we tested its tensile strength, elongation, tear strength, compression permanent deformation and hardness at different times. Additionally, the damaged specimens were tested by scanning electron microscope, Fourier transform infrared spectroscopy and energy dispersive spectrometry. The results showed that with the growth of aging time, the mechanical properties of the rubber waterstop are reduced. At the same time, many protrusions appeared on the surface of the rubber waterstop, the C element gradually decreased, and the O element gradually increased. During the period of 72–90 days, the content of the C element in the low-temperature air environment significantly decreased compared with that in low-temperature water, while the content of O element increased significantly.

scholarly journals Interfacial Reactions and Mechanical Properties of Sn–58Bi Solder Joints with Ag Nanoparticles Prepared Using Ultra-Fast Laser Bonding

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 335
Author(s):  
Gyuwon Jeong ◽  
Dong-Yurl Yu ◽  
Seongju Baek ◽  
Junghwan Bang ◽  
Tae-Ik Lee ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Printed Circuit Boards ◽  
Solder Joints ◽  
Interfacial Reactions ◽  
Circuit Boards ◽  
Ag Nps ◽  
Laser Bonding ◽  
Laser Soldering ◽  
Low Temperature Bonding

The effects of Ag nanoparticle (Ag NP) addition on interfacial reaction and mechanical properties of Sn–58Bi solder joints using ultra-fast laser soldering were investigated. Laser-assisted low-temperature bonding was used to solder Sn–58Bi based pastes, with different Ag NP contents, onto organic surface preservative-finished Cu pads of printed circuit boards. The solder joints after laser bonding were examined to determine the effects of Ag NPs on interfacial reactions and intermetallic compounds (IMCs) and high-temperature storage tests performed to investigate its effects on the long-term reliabilities of solder joints. Their mechanical properties were also assessed using shear tests. Although the bonding time of the laser process was shorter than that of a conventional reflow process, Cu–Sn IMCs, such as Cu6Sn5 and Cu3Sn, were well formed at the interface of the solder joint. The addition of Ag NPs also improved the mechanical properties of the solder joints by reducing brittle fracture and suppressing IMC growth. However, excessive addition of Ag NPs degraded the mechanical properties due to coarsened Ag3Sn IMCs. Thus, this research predicts that the laser bonding process can be applied to low-temperature bonding to reduce thermal damage and improve the mechanical properties of Sn–58Bi solders, whose microstructure and related mechanical properties can be improved by adding optimal amounts of Ag NPs.

Research changes in the properties of butadiene-nitrile rubber under various aging conditions

2021 ◽  
pp. 009524432110290
Author(s):  
Mariya L Davydova ◽  
Aytalina F Fedorova
Keyword(s):  
Accelerated Aging ◽  
Physical And Mechanical Properties ◽  
Exposure Period ◽  
Climatic Conditions ◽  
Nitrile Rubber ◽  
Sterically Hindered Phenols ◽  
Loading Mode ◽  
Hindered Phenols ◽  
The Republic ◽  
Butadiene Nitrile Rubber

This article represents the results of a study of changes in the properties of vulcanizates based on BNR-18 butadiene-nitrile rubber containing as stabilizers the experimental spatially hindered phenols Stafen, CO3, CO4, and industrial antioxidant 6PPD, after accelerated aging (100°C 96 h) and aging under full-scale exposure in extreme climatic conditions of the Republic of Sakha (Yakutia) during 2 years. In winter, the air temperature reached—48°C, in summer—+36.1°C. It is shown that the experimental sterically hindered phenols more effectively under natural exposure conditions. They are characterized by the most stability in terms of strength throughout the entire exposure period. Under conditions of accelerated aging, the vulcanizate containing the industrial antioxidant 6PPD is characterized by the greatest stability of physical and mechanical properties. According to the viscoelastic characteristics obtained in the dynamic loading mode, the contribution of the presented stabilizers in maintaining resistance to temperature and deformation effects compared with unstabilized rubber is confirmed.

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