Evaluation of Photoinitiator and Fluorescent Pigments Impact on Color Stability in Pigmented UV-Curable Coatings

2021 ◽  
Vol 320 ◽  
pp. 77-82
Author(s):  
Zane Grigale-Soročina ◽  
Ingmārs Birks ◽  
Elina Vindedze
Keyword(s):  
Color Change ◽  
Uv Light ◽  
Light Exposure ◽  
Color Stability ◽  
Quality Parameter ◽  
Urethane Acrylate ◽  
Uv Curable ◽  
Complex Process ◽  
Coating Color ◽  
Pigmented Coatings

The testing of thin colored coatings based on urethane acrylate composition is a technologically advanced, highly specialized and complex process. For decorative pigmented coatings color stability is crucial quality parameter. The photo chemically curable polymer films were prepared by addition of 3 different radical initiators (KTO, TPO, TPO-L) to aliphatic urethane acrylate composition with various pigments (solid and fluorescent). Coating color change were evaluated in UV chamber (with luminous intensity 130 mw spectrum λmax = 405 nm) after 1 h, 48 h and 72 h. Color measurements were performed according to the CIEL*a*b* color standard to evaluate their stability over time. It was found that pigmented coatings have higher risk of yellowness than clear coatings. Also fluorescent pigments containing red has tendency to yellow after UV light exposure. The influence of the photoinitiator on the color stability were inconsiderable.

Surface Sealant Effect on the Color Stability of a Composite Resin Following Ultraviolet Light Artificial Aging

2019 ◽  
Vol 44 (3) ◽  
pp. 322-330
Author(s):  
A Brooksbank ◽  
BM Owens ◽  
JG Phebus ◽  
BJ Blen ◽  
W Wasson
Keyword(s):  
Artificial Aging ◽  
Composite Resin ◽  
Color Change ◽  
Uv Light ◽  
Light Exposure ◽  
Color Stability ◽  
Acceptable Range ◽  
Color Measurements ◽  
Intergroup Comparison ◽  
Surface Sealant

SUMMARY Objective: To examine how exposure to accelerated artificial aging (AAA) stimuli (ultraviolet [UV] light) affects the color stability of a composite resin following surface sealant (SS) application. Methods and Materials: A total of 30 cylindrical composite resin (Esthet-X) discs were prepared using Teflon-coated rings. The treatment groups, defined by different SS (Seal-N-Sine, PermaSeal, OptiGuard, Biscover LV, and DuraFinish) use, were divided into five groups of six discs each. The discs were subjected to baseline color measurements followed by measurements after surface sealant application (specular included component [SCI] and specular excluded component [SCE]) using a spectrophotometer. Three measurements (SCI and SCE) were performed for a total of 18 readings (test surface) per specimen group. All specimens were then exposed to a UV light source for a total of 382 hours. Color readings of the specimens were again recorded for each group. Quantitative color measurements were executed using Commission Internationale de l'Eclairage L*a*b* calculations. Results: Baseline color measurements of the composite resin discs, following the AAA exposure protocol, revealed no significant differences. A comparison of the composite resin discs before and after SS application (without UV light exposure) showed statistically significant differences using both SCI and SCE measurement criteria. Although significant differences were encountered between the ΔL*, Δa*, Δb*, and ΔE parameters, all specimens (groups) were within the clinically acceptable range (1.0<ΔE≤ 3.3). Again, statistically significant differences were noted (ΔL*, Δa*, Δb*, and ΔE parameters) for all specimen groups receiving SS application, utilizing both SCI and SCE measurements, following exposure to UV light. All groups were within the clinically acceptable range (1.0<ΔE≤ 3.3), except the Durafinish group. The Durafinish SS group experienced significantly greater (p<0.001) overall color change (SCI and SCE) following UV light exposure. An intergroup comparison following UV exposure revealed that the Permaseal, OptiGuard, and Seal-n-Shine SS groups displayed the least amount of color change statistically but not necessarily always perceptibly significant, while the Durafinish group exhibited the greatest color change statistically and perceptibly. Conclusions: The color stability of a composite resin, including the addition of most SSs, was not affected perceptibly by UV light exposure.

Photostabilizers performance on the surface analysis of green composites

2020 ◽  
Vol 29 (1) ◽  
pp. 57-64
Author(s):  
Hasret Ece Sönmez ◽  
Mehmet Safa Bodur ◽  
Alper Adrian Baysan ◽  
Mustafa Bakkal ◽  
Ersin Serhatli
Keyword(s):  
Surface Analysis ◽  
Color Change ◽  
Uv Light ◽  
Light Exposure ◽  
Accelerated Weathering ◽  
Reinforced Composites ◽  
Color Changes ◽  
Photodegradation Mechanism ◽  
Ldpe Composites

In this work, various stabilizers have been introduced to prevent or delay degradation due to ultraviolet (UV) light exposure to prolong the service life of cotton fiber-reinforced composites. The effect of various additives like hindered amine light stabilizer, UV absorber (UVA), and antioxidant as photostabilizers of CF/low-density polyethylene (CF/LDPE) composites was compared. We showed how they influence to delay or eliminate the photodegradation of CF/LDPE subjected accelerated weathering. Surface analysis was performed by Fourier transform infrared spectroscopy and color measurements. The results showed us the insight of the photodegradation mechanism of weathered CF/LDPE composites undergoing photooxidative reactions which causes a loss surface quality such as micro-cracking and color change. Among the stabilizers, UVA was found to be the most effective to delay some color changes in long term.

Removal of UV Cured Resin Using Hybrid Cleaning Method

2012 ◽  
Vol 195 ◽  
pp. 30-33 ◽  
Author(s):  
Min Su Kim ◽  
Bong Kyun Kang ◽  
Jae Kwan Kim ◽  
Byung Kyu Lee ◽  
Jin Goo Park
Keyword(s):  
Hydrogen Peroxide ◽  
Nanoimprint Lithography ◽  
Uv Light ◽  
Light Exposure ◽  
Quartz Substrate ◽  
Ammonium Hydroxide ◽  
Manufacturing Cost ◽  
Uv Curable ◽  
3 Dimensional ◽  
Haze Formation

Ultraviolet based nanoimprint lithography (UV-NIL) technology is widely used in nanosized fine pattern transfer. NIL, which uses low pressure and low temperature, makes it possible to fabricate 3-dimensional pattern [. So, UV-NIL is one of the techniques with great potential as a new manufacturing process. But, UV-NIL process uses an expensive quartz substrate for transmission of UV light. Therefore, quartz substrate needs to be recycled to reduce the manufacturing cost. Usually, UV-NIL uses UV curable resins, whose chemical bonding and structure could be altered during UV light exposure which would result in crosslinking between the polymers. This UV cured resin with cross-linked structure is very hard to remove from the quartz substrate [. Conventionally, UV cured resin is removed by treating with sulfuric acid-hydrogen peroxide mixture (SPM) followed by ammonium hydroxide-hydrogen peroxide mixture (APM). One of the major drawbacks in using SPM-based treatment is the chemical haze formation and particle contamination on the quartz substrate [. Thus, an alternative cleaning composition will be of interest.

Depletion of coating color components in the blade coating process circulation

TAPPI Journal ◽  
2011 ◽  
Vol 10 (9) ◽  
pp. 17-23 ◽  
Author(s):  
ANNE RUTANEN ◽  
MARTTI TOIVAKKA
Keyword(s):  
Fine Particles ◽  
Particle Density ◽  
Stable Process ◽  
Size Fraction ◽  
Color Stability ◽  
Strong Interactions ◽  
Coating Process ◽  
Size Segregation ◽  
Coating Color ◽  
Average Size

Coating color stability, as defined by changes in its solid particle fraction, is important for runnability, quality, and costs of a paper coating operation. This study sought to determine whether the size or density of particles is important in size segregation in a pigment coating process. We used a laboratory coater to study changes in coating color composition during coating operations. The results suggest that size segregation occurs for high and low density particles. Regardless of the particle density, the fine particle size fraction (<0.2 μm) was the most prone for depletion, causing an increase in the average size of the particles. Strong interactions between the fine particles and other components also were associated with a low depletion tendency of fine particles. A stable process and improved efficiency of fine particles and binders can be achieved by controlling the depletion of fine particles.

Assessment of Color Stability of Treated Leathers with Silicone Oil and Polyethylene Glycol

2014 ◽  
Vol 1 (1) ◽  
pp. 24-34
Author(s):  
Alireza K. ◽  
Hossein Ahmadi ◽  
Mohsen Mohammadi
Keyword(s):  
Ascorbic Acid ◽  
Polyethylene Glycol ◽  
Treatment Process ◽  
Color Change ◽  
Silicone Oil ◽  
Accelerated Aging ◽  
Color Stability ◽  
Antioxidant Additive ◽  
Before And After ◽  
Aesthetic Values

Lubricants and leather dressings are the most common treatments of dry and water logged historical leathers. Color change has a great importance during the time and treatment process, due to visual and aesthetic values of historic leather relics. Polyethylene glycol (PEG) and silicone oil (SiO) are frequently used leather dressings in the conservation procedures. Therefore, color stability of treated leathers with PEG and SiO were investigated before and after heat accelerated aging. Moreover, application of ascorbic acid was evaluated as an antioxidant additive for PEG (PEG+AA).Color change after treatment and aging were studied by colorimetry technique in the CIE *L*a*b system. Results indicated to severe color alteration in PEG treated and aged leathers with or without ascorbic acid. Whereas, SiO treated samples showed better stability and minimum color shift after aging. Silicone oil was characterized as the best dressing for historical leathers with compared to PEG and PEG+AA, due to its high stability and aesthetical properties.

scholarly journals Deposition of Zinc Oxide Coatings on Wood Surfaces Using the Solution Precursor Plasma Spraying Process

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 183
Author(s):  
Ghiath Jnido ◽  
Gisela Ohms ◽  
Wolfgang Viöl
Keyword(s):  
Zinc Oxide ◽  
Ftir Spectroscopy ◽  
Photoelectron Spectroscopy ◽  
Color Change ◽  
Uv Light ◽  
Beech Wood ◽  
Nitrate Solution ◽  
Ftir Spectra ◽  
Solution Precursor ◽  
Wood Surfaces

In the present work, the solution precursor plasma spray (SPPS) process was used to deposit zinc oxide (ZnO) coatings on wood surfaces using zinc nitrate solution as precursor to improve the hydrophobicity and the color stability of European beech wood under exposure to ultraviolet (UV) light. The surface morphology and topography of the wood samples and the coatings were characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The formation of ZnO was detected with the help of X-ray photoelectron spectroscopy (XPS) and by Fourier transform infrared (FTIR) spectroscopy. The FTIR spectra of the coated samples showed the typical Zn–O band at 445 cm−1. According to the XPS analysis, the coatings consist of two different Zn-containing species: ZnO and Zn(OH)2. Variation of the deposition parameters showed that the most significant parameters affecting the microstructure of the coating were the solution concentration, the deposition scan speed, and carrier gas flow rate. The wettability behaviors of the coated wood were evaluated by measuring the water contact angle (WCA). The coatings that completely covered the wood substrates showed hydrophobic behaviors. UV-protection of wood surfaces after an artificial UV light irradiation was evaluated by color measurements and FTIR spectroscopy. The ZnO-coated wood surfaces were more resistant to color change during UV radiation exposure. The total color change decreased up to 60%. Additionally, the FTIR spectra showed that the wood surfaces coated with ZnO had more stability. The carbonyl groups formation and C=C-bonds consumption were significantly lower.

scholarly journals Stability and ocular biodistribution of topically administered PLGA nanoparticles

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Sean Swetledge ◽  
Renee Carter ◽  
Rhett Stout ◽  
Carlos E. Astete ◽  
Jangwook P. Jung ◽  
...  
Keyword(s):  
Uv Light ◽  
Light Exposure ◽  
Polymeric Nanoparticles ◽  
Plga Nanoparticles ◽  
Eye Disease ◽  
Control Group ◽  
Eye Tissues ◽  
Nanoparticle Morphology ◽  
The Stability

AbstractPolymeric nanoparticles have been investigated as potential delivery systems for therapeutic compounds to address many ailments including eye disease. The stability and spatiotemporal distribution of polymeric nanoparticles in the eye are important regarding the practical applicability and efficacy of the delivery system in treating eye disease. We selected poly(lactic-co-glycolic acid) (PLGA) nanoparticles loaded with lutein, a carotenoid antioxidant associated with eye health, as our model ophthalmic nanodelivery system and evaluated its stability when suspended in various conditions involving temperature and light exposure. We also assessed the ocular biodistribution of the fluorescently labeled nanoparticle vehicle when administered topically. Lutein-loaded nanoparticles were stable in suspension when stored at 4 °C with only 26% lutein release and no significant lutein decay or changes in nanoparticle morphology. When stored at 25 °C and 37 °C, these NPs showed signs of bulk degradation, had significant lutein decay compared to 4 °C, and released over 40% lutein after 5 weeks in suspension. Lutein-loaded nanoparticles were also more resistant to photodegradation compared to free lutein when exposed to ultraviolet (UV) light, decaying approximately 5 times slower. When applied topically in vivo, Cy5-labled nanoparticles showed high uptake in exterior eye tissues including the cornea, episcleral tissue, and sclera. The choroid was the only inner eye tissue that was significantly higher than the control group. Decreased fluorescence in all exterior eye tissues and the choroid at 1 h compared to 30 min indicated rapid elimination of nanoparticles from the eye.

scholarly journals Fast Fabrication of Nanostructured Films Using Nanocolloid Lithography and UV Soft Mold Roller Embossing: Effects of Processing Parameters

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 405
Author(s):  
Demei Lee ◽  
Ya-Ling Tang ◽  
Shih-Jung Liu
Keyword(s):  
Uv Light ◽  
Processing Parameters ◽  
Polymeric Films ◽  
Step Motor ◽  
Silicon Substrates ◽  
Casting Method ◽  
Uv Curable ◽  
Soft Mold ◽  
Uv Curable Resin ◽  
Spin Coater

We report the fabrication of nanofeatured polymeric films using nanosphere lithography and ultraviolet (UV) soft-mold roller embossing and show an illuminative example of their application to solar cells. To prepare the nanofeatured template, polystyrene nanocolloids of two distinct sizes (900 and 300 nm) were overlaid on silicon substrates using a spin coater. A lab-made soft-mold roller embossing device equipped with a UV light source was adopted. A casting method was employed to replicate the nanofeatured template onto polydimethylsiloxane, which was used as the soft mold. During the embossing procedure, the roller was driven by a step motor and compressed the UV-curable resin against the glass substrate to form the nanofeatured layer, which was subsequently cured by UV radiation. Polymer films with nanoscaled features were thus obtained. The influence of distinct processing variables on the reproducibility of the nanofeatured films was explored. The empirical outcomes demonstrate that UV soft-mold roller embossing offers a simple yet potent way of producing nanofeatured films.

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