scholarly journals Ferrate (VI) as efficient oxidant for elimination of sulfamethazine in aqueous wastes: Real matrix implications

2021 ◽  
Vol 27 (5) ◽  
pp. 210256-0
Author(s):  
Lalhmunsiama ◽  
Levia Lalthazuala ◽  
Diwakar Tiwari
Keyword(s):  
Wastewater Treatment Plants ◽  
Ph Value ◽  
Batch Reactor ◽  
Molar Ratio ◽  
Resistant Bacteria ◽  
Aquatic Environments ◽  
Real Matrix ◽  
The Real ◽  
Water Matrix ◽  
Drug Resistant Bacteria

The presence of antibiotics in aquatic environments has become a serious concern since they develop the antibiotic/multi-drug-resistant bacteria which further affect to living beings. The study intended to assess the freshly synthesized ferrate (VI) in the degradation of an important emerging micro-pollutant i.e., sulfamethazine (SMZ). Moreover, the real matrix implications are extensively conducted for implication of ferrate (VI) technology as safer and viable options. Batch reactor studies enabled the molar ratio of ferrate (VI) to sulfamethazine is 2:1 with overall rate constant 6,128 mM-2.min-1. Percentage elimination of sulfamethazine was observed Ca. 80% at initial sulfamethazine concentration 0.02 mM and ferrate (VI) dose 0.1 mM. Presence of several co-ions NaCl, Na2HPO4, NaNO3, oxalic acid and NaNO2 showed insignificant effect on elimination of sulfamethazine; whereas the efficiency of ferrate (VI) was lowered due to glycine and EDTA. Mineralization of sulfamethazine is significantly increased at lower pH value (pH 5.0). Further, the removal of sulfamethazine in the real water matrix showed that the elimination efficiency of sulfamethazine is almost unaffected as compared to the distilled water treatment. This implied that ferrate (VI) is a viable and greener option for treatment of emerging water pollutants to enhance the efficiency of existing wastewater treatment plants.

scholarly journals Oxidation of Citalopram with Sodium Hypochlorite and Chlorine Dioxide: Influencing Factors and NDMA Formation Kinetics

Molecules ◽  
2019 ◽  
Vol 24 (17) ◽  
pp. 3065
Author(s):  
Juan Lv ◽  
Yan Wang ◽  
Na Li
Keyword(s):  
Sodium Hypochlorite ◽  
Chlorine Dioxide ◽  
Wastewater Treatment Plants ◽  
Ph Value ◽  
High Reactivity ◽  
Secondary Effluent ◽  
Water Matrix ◽  
Formation Kinetics ◽  
Operational Variables ◽  
Two Stages

The highly prescribed antidepressant, citalopram, as one of newly emerging pollutants, has been frequently detected in the aquatic environment. Citalopram oxidation was examined during sodium hypochlorite (NaOCl) and chlorine dioxide (ClO2) chlorination processes since conventional wastewater treatment plants cannot remove citalopram effectively. Citalopram has been demonstrated to form N-nitrosodimethylamine (NDMA) during chlorination in our previous study. Further investigation on NDMA formation kinetics was conducted in the present study. Influences of operational variables (disinfectant dose, pH value) and water matrix on citalopram degradation, as well as NDMA generation, were evaluated. The results indicated high reactivity of citalopram with NaOCl and ClO2. NDMA formation included two stages during CIT oxidation, which were linear related with reaction time. NaOCl was more beneficial to remove CIT, but it caused more NDMA formation. Increasing disinfectant dosage promoted citalopram removal and NDMA formation. However, no consistent correlation was found between citalopram removal and pH. Contrary to the situation of citalopram removal, NDMA generation was enhanced when citalopram was present in actual water matrices, especially in secondary effluent. DMA, as an intermediate of citalopram chlorination, contributed to NDMA formation, but not the only way.

scholarly journals Multidrug-Resistant Bacteria Isolated from Different Aquatic Environments in the North of Spain and South of France

2020 ◽  
Vol 8 (9) ◽  
pp. 1425
Author(s):  
Lara Pérez-Etayo ◽  
David González ◽  
José Leiva ◽  
Ana Isabel Vitas
Keyword(s):  
Wastewater Treatment Plants ◽  
Multidrug Resistant ◽  
World Health ◽  
Resistant Bacteria ◽  
Aquatic Environments ◽  
Multidrug Resistant Bacteria ◽  
Antibiotic Resistant ◽  
The North ◽  
New Antibiotics ◽  
Health Organization

Due to the global progress of antimicrobial resistance, the World Health Organization (WHO) published the list of the antibiotic-resistant “priority pathogens” in order to promote research and development of new antibiotics to the families of bacteria that cause severe and often deadly infections. In the framework of the One Health approach, the surveillance of these pathogens in different environments should be implemented in order to analyze their spread and the potential risk of transmission of antibiotic resistances by food and water. Therefore, the objective of this work was to determine the presence of high and critical priority pathogens included in the aforementioned list in different aquatic environments in the POCTEFA area (North Spain–South France). In addition to these pathogens, detection of colistin-resistant Enterobacteriaceae was included due its relevance as being the antibiotic of choice to treat infections caused by multidrug resistant bacteria (MDR). From the total of 80 analyzed samples, 100% of the wastewater treatment plants (WWTPs) and collectors (from hospitals and slaughterhouses) and 96.4% of the rivers, carried antibiotic resistant bacteria (ARB) against the tested antibiotics. Fifty-five (17.7%) of the isolates were identified as target microorganisms (high and critical priority pathogens of WHO list) and 58.2% (n = 32) of them came from WWTPs and collectors. Phenotypic and genotypic characterization showed that 96.4% were MDR and resistance to penicillins/cephalosporins was the most widespread. The presence of bla genes, KPC-type carbapenemases, mcr-1 and vanB genes has been confirmed. In summary, the presence of clinically relevant MDR bacteria in the studied aquatic environments demonstrates the need to improve surveillance and treatments of wastewaters from slaughterhouses, hospitals and WWTPs, in order to minimize the dispersion of resistance through the effluents of these areas.

scholarly journals The microbiome and resistome of hospital sewage during passage through the community sewer system

2017 ◽  
Author(s):  
Elena Buelow ◽  
Jumamurat R. Bayjanov ◽  
Rob J.L. Willems ◽  
Marc J.M. Bonten ◽  
Heike Schmitt ◽  
...  
Keyword(s):  
Wastewater Treatment Plants ◽  
Point Sources ◽  
Resistant Bacteria ◽  
Sewer System ◽  
Sewerage System ◽  
Drug Resistant Bacteria ◽  
Wwtp Effluent ◽  
Antimicrobial Resistance Genes ◽  
Culture Independent ◽  
Hospital Sewage

AbstractEffluents from wastewater treatment plants (WWTPs) have been proposed to act as point sources of antibiotic-resistant bacteria (ARB) and antimicrobial resistance genes (ARGs) in the environment. Hospital sewage may contribute to the spread of ARB and ARGs as it contains the feces and urine of hospitalized patients, who are more frequently colonized with multi-drug resistant bacteria than the general population. However, whether hospital sewage noticeably contributes to the quantity and diversity of ARGs in the general sewerage system has not yet been determined.Here, we employed culture-independent techniques, namely 16S rRNA and nanolitre-scale quantitative PCRs, to describe the role of hospital effluent as a point source of ARGs in the sewer system, through comparing microbiota composition and levels of ARGs in hospital sewage with WWTP influent, WWTP effluent and the surface water in which the effluent is released.Compared to other sample sites, hospital sewage was richest in human-associated bacteria and contained the highest relative levels of ARGs. Yet, the abundance of ARGs was comparable in WWTPs with and without hospital wastewater, suggesting that hospitals do not contribute to the spread of ARGs in countries with a functioning sewerage system.

Occurrence of levofloxacin, clarithromycin and azithromycin in wastewater treatment plant in Japan

2006 ◽  
Vol 53 (11) ◽  
pp. 227-233 ◽  
Author(s):  
M. Yasojima ◽  
N. Nakada ◽  
K. Komori ◽  
Y. Suzuki ◽  
H. Tanaka
Keyword(s):  
Wastewater Treatment ◽  
Activated Sludge ◽  
Wastewater Treatment Plants ◽  
Solid Phase ◽  
Treatment Plant ◽  
Pharmaceutical Products ◽  
The Body ◽  
Resistant Bacteria ◽  
Drug Resistant Bacteria ◽  
Liquid Chromatography Tandem Mass

Residual pharmaceutical products in sewage and other water environments have recently become a serious social problem in advanced countries. Among these pharmaceutical products, antibiotics have attracted special attention due to their serious impact on the ecosystem and connections to the emergence of drug-resistant bacteria. Our research intended to develop a new method to analyse the three antibiotics estimated to be released out of the body in large amounts in Japan; levofloxacin (LVFX), clarithromycin (CAM) and azithromycin (AZM), and survey the state of pollution in the sewerage. The concentrations of the water-phase antibiotics LVFX, CAM and AZM were measured in each process of activated sludge process in six wastewater treatment plants. Liquid chromatography tandem mass spectrometry (LC/MS/MS) was used to analyse solutions of the antibiotics after pretreatment with a solid phase extraction. The limits of quantification and the average recoveries for these antibiotics in the influent were 1.2 to 29 ng/L and 46 to 93%, respectively. In the influent, LVFX, CAM and AZM were detected at concentrations of 552, 647 and 260 ng/L, respectively, while their removal efficiencies were 42, 43 and 49%, respectively. Although the CAM and AZM concentrations decreased as the treatment progressed, it was shown that the LVFX concentration increased in activated sludge reactors in some cases. Despite differences in octanol-water partition coefficients among LVFX, CAM and AZM, their removal efficiency showed no major difference. This indicates that this removal phenomenon cannot be explained by simple adsorption by the activated sludge.

Novel Antibiotics from Marine Sources

2011 ◽  
Vol 4 (3) ◽  
pp. 1446-1461 ◽  
Author(s):  
E.A. Martis ◽  
G M Doshi ◽  
G V Aggarwal ◽  
P P Shanbhag
Keyword(s):  
Pharmaceutical Industry ◽  
Resistant Bacteria ◽  
Drug Resistant ◽  
Drug Resistant Bacteria ◽  
Terrestrial Life ◽  
New Antibiotics ◽  
Antibiotic Compounds ◽  
New Generation ◽  
Novel Antibiotics ◽  
Untapped Resource

With the emergence of newer diseases, resistant forms of infectious diseases and multi-drug resistant bacteria, it has become essential to develop novel and more effective antibiotics. Current antibiotics are obtained from terrestrial life or made synthetically from intermediates. The ocean represents virtually untapped resource from which novel antibiotic compounds can be discovered. It is the marine world that will provide the pharmaceutical industry with the next generation of antibiotics. Marine antibiotics are antibiotics obtained from marine organisms. Scientists have reported the discovery of various antibiotics from marine bacteria (aplasmomycin, himalomycins, and pelagiomycins), sponges (Ara C, variabillin, strobilin, ircinin-1, aeroplysin, 3,5-dibromo-4-hydroxyphenylacetamide), coelenterates (asperidol and eunicin), mollusks (laurinterol and pachydictyol), tunicates (geranylhydroquinone and cystadytins), algae (cycloeudesmol, aeroplysinin-1(+), prepacifenol and tetrabromoheptanone), worms (tholepin and 3,5-dibromo-4-hydroxybezaldehyde), and actinomycetes (marinomycins C and D). This indicates that the marine environment, representing approximately half of the global diversity, is an enormous resource for new antibiotics and this source needs to be explored for the discovery of new generation antibiotics. The present article provides an overview of various antibiotics obtained from marine sources.

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