scholarly journals SPATIAL DISTRIBUTION OF HEAVY METAL CONTAMINATION IN GROUNDWATER OF ONITSHA URBAN, SOUTHEAST NIGERIA

Author(s):  
E.I Okoyeh ◽  
V.C Ahaneku ◽  
A Utom ◽  
I.E Udegbunam ◽  
G.E Egwuonwu

The investigation of the degree of trace heavy metals contamination in groundwater wells in Onitsha Southeast Nigeria, was carried out based on 20 preselected sample locations. The result of the analysis revealed water of relatively high acidity with pH ranging from 4.93 t0 6.94. The EC values for the analysed water samples ranged from 10.80 to 60.90u while TDS ranges from 20.00 to 410.00.Heavy metals in the form of Arsenic (As), Cadmium (Cd), Chromium (Cr), Iron (Fe), Nickel (Ni), Zinc (Zn), Vanadium (V) and Copper (Cu) were analyzed for their concentration in the water samples of the area. The study revealed that the mean value of Fe (0.832000 ± 1.0626228ppm) and Cd (0.043750 ± 0.0181713ppm) exceeded the permissible limit for NSDWQ water quality standard as indicated by the high concentrations of Fe and Cd values observed in water samples of the study area. The concentrations of the heavy metals except Fe and Cd range from Ni (0.000 – 0.750),(Cu 0.00 - 0.105), (Zn 0.00 – 1.798), (Cr 0.002 – 0.046), (As 0.000 – 0.056) and (Va 0.000 - 0.008). The spatial distribution of the heavy metals in the area shows that the eastern part of the study area has relative high concentration of the heavy metals which is attributed to anthropogenic impacts.

2018 ◽  
Vol 73 ◽  
pp. 06009
Author(s):  
Wardhani Eka ◽  
Notodarmojo Suprihanto ◽  
Roosmini Dwina

Saguling reservoir in West Java Province is becoming increasingly polluted by heavy metals. The purpose of this study was to determine the level of four heavy metals such as Cd, Cr, Cu, and Pb concentration at Saguling Reservoir at ’2 sampling location. Water samples were collected during rainy and summer 2008-2017 to determine the spatial distribution seasonal and temporal variation of different heavy metal contents. Mean metals concentrations in summer seasons were Cd, Cr, Cu, and Pb higher than rainy season. Mean concentration of Cd, Cu, Cr, and Pb in water samples were accordance water quality standard in both season. Heavy metal pollution that occurs in the Saguling reservoir must be monitored because this reservoir is planned to be a source of raw water for Bandung City.


2020 ◽  
Vol 18 (2) ◽  
pp. 373-384
Author(s):  
Tran Thi Ngat ◽  
Truong Xuan Lam ◽  
Hoang Gia Minh ◽  
Nguyen Thi Phuong Lien

Contamination of heavy metals (As, Cd, Hg, Pb and Sn) in honeybee products (Apis cerana) from Northern Vietnam is determined. The study was carried out in two main harvesting seasons of beekeeper farms (April and October), over two years (2018-2019). A total of 72 samples from 24 honeybee hives from 8 provinces and one city were collected. The results showed that the quality of three products in nearly all research sites were met the standards in accordance with the national technical regulation on the limits of heavy metal contamination in food of the Vietnamese Health Ministry, except for the pollen and beeswax from HY2 site. The concentration of Pb was most notably value in this study, which was determined at fairly high levels in pollen (3,767 mg/kg) and beeswax (5,840 mg/kg) from HY2 site. This can be a warning for this metal significant contamination in the habitat. Specially, Hg was not detected in most samples or only recorded without significant. For the environmental types, the mean value of As and Sn in all honeybee’s product types in semi-rural area were higher than that in rural area. Thus, the detection of the heavy metals proves that honeybee’s products could be good indicators to detect the environmental contaminants and monitor the habitat quality of a particular area


Atmosphere ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 62
Author(s):  
Robert Cichowicz ◽  
Maciej Dobrzański

Spatial analysis of the distribution of particulate matter PM10, PM2.5, PM1.0, and hydrogen sulfide (H2S) gas pollution was performed in the area around a university library building. The reasons for the subject matter were reports related to the perceptible odor characteristic of hydrogen sulfide and a general poor assessment of air quality by employees and students. Due to the area of analysis, it was decided to perform measurements at two heights, 10 m and 20 m above ground level, using measuring equipment attached to a DJI Matrice 600 unmanned aerial vehicle (UAV). The aim of the measurements was air quality assessment and investigate the convergence of the theory of air flow around the building with the spatial distribution of air pollutants. Considerable differences of up to 63% were observed in the concentrations of pollutants measured around the building, especially between opposite sides, depending on the direction of the wind. To explain these differences, the theory of aerodynamics was applied to visualize the probable airflow in the direction of the wind. A strong convergence was observed between the aerodynamic model and the spatial distribution of pollutants. This was evidenced by the high concentrations of dust in the areas of strong turbulence at the edges of the building and on the leeward side. The accumulation of pollutants was also clearly noticeable in these locations. A high concentration of H2S was recorded around the library building on the side of the car park. On the other hand, the air turbulence around the building dispersed the gas pollution, causing the concentration of H2S to drop on the leeward side. It was confirmed that in some analyzed areas the permissible concentration of H2S was exceeded.


2021 ◽  
Vol 11 (14) ◽  
pp. 6592
Author(s):  
Ana Moldovan ◽  
Maria-Alexandra Hoaghia ◽  
Anamaria Iulia Török ◽  
Marius Roman ◽  
Ionut Cornel Mirea ◽  
...  

This study aims to investigate the quality and vulnerability of surface water (Aries River catchment) in order to identify the impact of past mining activities. For this purpose, the pollution and water quality indices, Piper and Durov plots, as well vulnerability modeling maps were used. The obtained results indicate that the water samples were contaminated with As, Fe, Mn, Pb and have relatively high concentrations of SO42−, HCO3−, TDS, Ca, K, Mg and high values for the electrical conductivity. Possible sources of the high content of chemicals could be the natural processes or the inputs of the mine drainage. Generally, according to the pollution indices, which were correlated to high concentrations of heavy metals, especially with Pb, Fe and Mn, the water samples were characterized by heavy metals pollution. The water quality index classified the studied water samples into five different classes of quality, namely: unsuitable for drinking, poor, medium, good and excellent quality. Similarly, medium, high and very high vulnerability classes were observed. The Durov and Piper plots classified the waters into Mg-HCO3− and Ca-Cl− types. The past and present mining activities clearly change the water chemistry and alter the quality of the Aries River, with the water requiring specific treatments before use.


2021 ◽  
Vol 45 (1) ◽  
Author(s):  
Elijah Abakpa Adegbe ◽  
Oluwaseyi Oluwabukola Babajide ◽  
Lois Riyo Maina ◽  
Shola Elijah Adeniji

Abstract Background Heavy metal accumulation in the ecosystem constitutes a potential toxic effect which is hazardous to human health. Increasing environmental pollution has necessitated the use of cattle egrets to evaluate the levels of heavy metal contamination, to establish their use in biomonitoring of heavy metals and to provide data for monitoring pollution in the environment. Results The present study assessed the utilization of Bubulcus ibis in monitoring pollution in five abattoirs, namely Agege, Bariga, Kara, Itire and Idi-Araba, all situated in Lagos State. The concentration of five (5) heavy metals, cadmium (Cd), copper (Cu), nickel (Ni), lead (Pb) and zinc (Zn) was determined in the liver, muscle and feather of Bubulcus ibis using the atomic absorption spectrophotometer. The trend of metal accumulation was in the order: Zn > Cu > Pb > Cd > Ni for all the sampled tissues. The mean tissue concentrations of the metals were significantly different (p < 0.05) among the sites. The highest levels of metal concentration were reported in the liver in all the locations. Mean concentration of Cd in Kara (0.003 ± 0.00058) was significantly (p < 0.05) higher than those found at Agege (0.0013 ± 0.00058) and Idi-Araba (0.001 ± 0.001). A significant difference (p < 0.05) was also observed between the mean concentrations of Cu in Bariga (0.01 ± 0.001) and Idi-Araba (0.003 ± 0.001). Conclusion All the studied heavy metals were present in the liver, muscle and feathers of the cattle egrets. The contamination levels were ascertained from the study which indicated that cattle egrets are useful in biomonitoring studies and the generated data will serve as baseline data which could be compared with data from other locations for monitoring heavy metal pollution.


2021 ◽  
Vol 11 (5) ◽  
Author(s):  
Saheed Adekunle Ganiyu ◽  
Abimbola Temitope Oyadeyi ◽  
Azeem Adedeji Adeyemi

AbstractThis study has been conducted to appraise the concentrations of selected heavy metals and total dissolved solids (TDSs) in the drinking water from shallow wells in parts of Ibadan metropolis, southwest Nigeria. Fifteen (15) water samples were collected from three representative residential locations [traditional core area (TCA), peri-urban area (PUA), and urban area (UA)] for geochemical analysis. Heavy metals and TDS were analyzed with the aid of atomic absorption spectrophotometer and calibrated meter, respectively. The mean concentration (mg/L) of Zn, Pb Mn, Fe, and Cd has been 3.930, 0.658, 0.0304, 1.698, and 0.501, respectively, and as a consequence, the order of abundance of studied metals was Zn > Fe > Pb > Cd > Mn. Concentrations of Zn, Fe, Pb, and Cd were higher than recommended standards in 60%, 86.7%, 100%, and 100% of groundwater samples, respectively. However, at all points tested, the mean concentrations of Mn and TDS in water samples lie within the safe limits set by World Health Organization. The evaluation of geoaccumulation index (Igeo), enrichment factor (EF), and contamination factor suggests that representative water samples were low-to-moderate contamination. The potential ecological risk index advocates low-to-moderate ecological risk in TCA and PUA, while it demonstrated exclusive “moderate” risk in UA. Further, the range of pollution load index (PLI) (0.55–1.32) in both TCA and PUA shows nil-to-moderate pollution status, while PLI values > 1 in UA indicate moderate contaminated state. The degree of contamination in groundwater showed the following trends: UA > TCA > PUA in the study area. Moreover, the results of EF and quantification of contamination of analyzed metals in water samples indicate geogenic and anthropogenic inputs. The contribution of studied metals to the incidence of non-cancer risk via oral intake within the residential sites follows the order: cadmium > lead > zinc > iron > manganese. The hazard index as a result of ingested heavy metals for the three population classes surpasses the acceptable range in the order of infant < child < adult. Cadmium and lead made considerable impact to the estimation of cancer risk in the study area for the three human population categories. Factor analysis extracted only one component that explained 94.64% of the entire variance, while cluster analysis identified three distinct groups based on similar water quality characteristics. Based on the findings of the study, awareness programs toward protecting the shallow groundwater sources should be launched, encouraged, and sustained. Moreover, the study suggests better hygienic practices and pre-treatment of contaminated water before consumption.


2021 ◽  
Vol 25 (5) ◽  
pp. 841-845
Author(s):  
C.A.E. Ibhadode ◽  
I.R. Ilaboya

Groundwater pollution by heavy metals such as lead, copper, nickel and iron is one of the major environmental issues of concern which has developed into a widely studied area. In this study, attempt was made to investigate the level of heavy metals in selected boreholes around the vicinity of cemeteries in Benin City. Seventy-two (72) samples of groundwater were taken from boreholes in 9 stations around the three cemeteries in Benin City on monthly basis. The samples were analysed for 7 heavy metals, in accordance with standard procedures. The heavy metals include; Zinc, Lead Iron, Copper, Cadmium, Nickel and Mercury. From the results of the study, a variation in the mean concentration of zinc was observed. The mean concentration of zinc in site 1 was 0.450mg/l, for site 2, it was 0.140mg/l and for site 3, it was 1.0533mg/l. For iron, mean concentration was 0.072mg/l in site 1. For site 2, mean concentration of iron was 2.140mg/l and for site 3, mean concentration of iron was 0.560mg/l. It was further revealed based on the results that mean value of heavy metals in groundwater around cemeteries in Benin City were generally lower during dry season compared to wet season. In addition, result of computed pollution index (Pi) revealed that the heavy metal with the highest potential to pollute groundwater is Cadmium, with Pi of 0.5333 and 0.400 representing dry season and wet season respectively.


2021 ◽  
Author(s):  
Akhtar Jahan ◽  
Mohd Usman Khan ◽  
Nachiketa Rai ◽  
Abhayanand Singh Maurya ◽  
Sudhir Kumar

&lt;p&gt;Stable isotope analysis of hydrogen and oxygen is one of the important methods used to model the hydrological cycle. Oxygen and hydrogen isotopic investigation of river water, its tributaries, and groundwater of its catchment from the Satluj basin was undertaken to estimate the contributions of the main sources comprising discharge during major periods throughout a hydrologic year.&lt;/p&gt;&lt;p&gt;Estimation of the snow/glaciers melt contribution is also very important for tracing the sources and processes regulating the flow from the provenance and reservoirs in the context of global warming, for estimating flood flow, and for other water resource development activities in large parts of the Indian subcontinent. Water samples were collected during the non-monsoon season at increasing altitudes. In this work, in addition to stable isotopes, we also assessed the water quality using various physicochemical parameters and geochemistry of the water.&lt;/p&gt;&lt;p&gt;From isotopic analyses of river water samples, the mean value of the &amp;#948;&lt;sup&gt;18&lt;/sup&gt;O was found to be ~ -13&amp;#8240;, and the mean value of &amp;#948;D was found to be~ -85&amp;#8240;. For the samples from Satluj tributaries, the mean value of the &amp;#948;&lt;sup&gt;18&lt;/sup&gt;O was ~ -11&amp;#8240;, and the mean value of &amp;#948;D was ~ -69&amp;#8240;. A mean value of -8.4&amp;#8240;, was found based on the &amp;#948;&lt;sup&gt;18&lt;/sup&gt;O measurements of the groundwater samples, while the average &amp;#948;D value was found to be ~ -55&amp;#8240;.&lt;/p&gt;&lt;p&gt;For the mainstream and tributary, LWL, y = 8.2604x +20.208, and range of d-excess (&gt;10&amp;#8240;) and y = 8.2079x + 22.182 and d-excess &gt; 10&amp;#8240; indicates a system recharged by sources of recycled moisture derived from continental sources in addition to monsoonal climates. For the groundwater data, the slope is 6.7, and d-excess ranges from 7&amp;#8240; to 17&amp;#8240;. These observations are suggestive of the monsoonal source of Indian Ocean precipitation that has experienced significant evaporation during the non-monsoon season.&lt;/p&gt;&lt;p&gt;Our new data clearly shows that the surface water whether mainstream, tributary, and groundwater isotopes are homogenized from regional trends in precipitation, modified by evaporation, and are thus greatly influenced by latitude, elevation, and patterns of climate.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;


2019 ◽  
Vol 17 (2) ◽  
pp. 256
Author(s):  
Rosye H.R. Tanjung ◽  
Suwito Suwito ◽  
Vita Purnamasari ◽  
Suharno Suharno

Kebutuhan bahan pangan sangat tergantung pada ketersediaanya di lingungan. Bahan pangan yang diperlukan untuk memenuhi kebutuhan sehari-hari harus sehat dan bebas dari bahan pencemar, termasuk logam berat. Ikan kakap putih (Lates calcarifer) sering dijumpai pada kawasan muara sungai di hampir seluruh wilayah Indonesia, bahkan di Papua. Tujuan penelitian ini adalah untuk mengkaji kandungan logam berat Pb, Cd, Cu, Fe, As, dan Hg pada ikan kakap putih (L. calcarifer) yang hidup di perairan estuari Mimika Papua. Perairan estuari di Mimika diketahui sebagai salah satu daerah pengendapan pasir sisa tambang (tailing). Metode yang digunakan adalah survei dan analisis laboratorium kandungan logam berat pada tubuh ikan. Analisis Pb, Cd, Cu, Fe, As, dan Hg ditentukan dengan spektroskopi serapan atom (AAS, Atomic Absorpsion Spectroscopy). Penentuan tingkat pencemaran logam berat dilakukan dengan Metode Standar APHA 3113 Cetac Technologies SPR IDA. Analisis data dilakukan dengan membandingkan kandungan logam berat dalam air dengan baku mutu air laut menurut SK MNLH No. 51 tahun 2004. Untuk kandungan logam berat pada organ tubuh ikan dibandingkan dengan kandungan maksimum logam berat berdasarkan SNI 7387: 2009 tentang batas maksimum cemaran logam berat bahan pangan. Kandungan logam berat pada ikan kakap putih masih tergolong aman dikonsumsi karena mengandung logam berat di bawah ambang batas baku mutu. Kondisi ini didukung oleh hasil analisis logam berat pada air yang menunjukkan masih dalam kondisi baik.   Kata kunci: L. calcarifer, logam berat, Sungai Kamora, Sungai Ajkwa, Mimika.   The need for food depends on the availability in the environment. Foods needed to meet daily needs should be healthy and free of pollutants, including heavy metals. White snapper (Lates calcarifer) is often found in the estuary of the river in almost all parts of Indonesia, even in Papua. The purpose of this research is to study the heavy metal content of Pb, Cd, Cu, Fe, As, and Hg on white snapper (L. calcarifer) which live in Mimika Papua estuary waters. The estuary waters of Mimika are known as one of the deposition areas of tailings sand. The method used is survey and laboratory analysis of heavy metal content in fish body. Analysis of Pb, Cd, Cu, Fe, and Hg was determined by Atomic Absorption Spectroscopy (AAS). Determination of the level of heavy metal contamination was done by Standard Method of APHA 3113 Cetac Technologies SPR IDA. Data analysis was done by comparing the heavy metal content in water with sea water quality standard according to SK MNLH No. 51 year 2004. For heavy metal content in fish body organs compared with maximum content of heavy metals based on SNI 7387: 2009 on the maximum limit of heavy metal food contamination. The content of heavy metals in white snapper is still considered safe for consumption because its below the quality standard threshold. This condition is supported by the results of heavy metal analysis on the water which shows still in good condition. Key words: L. calcarifer, heavy metal, Kamora River, Ajkwa River, Mimika.


1984 ◽  
Vol 39 (9-10) ◽  
pp. 863-866 ◽  
Author(s):  
T. Stijve

Abstract A total of 138 samples of higher fungi, representing 35 species (15 belonging to the genus Amanita), were analysed for the trace element bromine using spectrophotometric and gas chromatographic methods. High concentrations of bromine, up to 100 mg/kg on dry weight, were encountered in Amanitaceae, especially in members of the subsections Phalloideae and Eu-Amanita, whereas in other fungi the mean value for this element was only 3,3 m g/kg. Some bromine-accumulating Amanitas also contained unusually high chlorine levels. Am axi­mum concentration of 3 percent on dry weight was measured in A. phalloides. It could be demonstrated that most, if not all of bromine and chlorine was present in the fungi as ionisable inorganic salts. Two organochlorine metabolites, previously reported in some mushrooms, were absent in A. phalloides and A. muscaria.


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