The Effect of Trivalent Chromium Process on Al-Zn-In Pigments in Epoxy Primer on the Corrosion Protection of AA2024-T3

CORROSION ◽  
10.5006/3393 ◽  
2020 ◽  
Vol 76 (1) ◽  
pp. 103-113 ◽  
Author(s):  
Xi Wang ◽  
G.S. Frankel
Keyword(s):  
Aluminum Alloy ◽  
Corrosion Rate ◽  
Potentiodynamic Polarization ◽  
Treatment Time ◽  
Trivalent Chromium ◽  
Accelerated Corrosion ◽  
Epoxy Primer ◽  
Active Aluminum ◽  
Order Of Magnitude ◽  
The One

Active metal pigments in metal-rich coatings are oxidized preferentially and provide sacrificial protection to more-noble metallic substrates. Al-rich primer (AlRP), which contains pigment particles made from an active aluminum alloy (Al-5Zn-0.02In), uses this mechanism to provide a chromate-free epoxy primer system. To address the high self-corrosion rate of active aluminum pigments, the active aluminum pigment particles are pretreated using trivalent chromium process (TCP). In this study, the effects of different TCP treatment times were evaluated, and coating protection properties were studied. Potentiodynamic polarization tests were performed in aerated 0.1 M NaCl solution for a TCP-treated bulk active aluminum alloy and for AA2024-T3. The potentiodynamic polarization curves show that the corrosion potential of the bulk active aluminum alloy is about 500 mV lower than that of AA2024-T3. Therefore, bulk active aluminum alloy is a candidate alloy for cathodic protection of AA2024-T3. In addition, the TCP treatment reduces the corrosion rate of the bulk active aluminum alloy by one order of magnitude. AlRP-coated AA2024-T3 panel samples were scribed and exposed in corrosion chambers, and the cross section of each coating was evaluated by scanning electron microscopy and energy dispersive x-ray spectroscopy mapping. The accelerated corrosion exposure results show that AlRP coatings containing TCP-treated particles provided better protection to the scribe than the one with bare pigment particles. The adhesion of the AlRPs based on pull-off adhesion tests was similar regardless of the TCP treatment time of the pigments, but the adhesion of AlRP was reduced in comparison to a neat epoxy coating.

EFFECT OF BORATES AND SILICATES ON WEARING PROPERTIES OF MAO COATINGS

2016 ◽  
Vol 24 (05) ◽  
pp. 1750061
Author(s):  
Yu ZHANG ◽  
YAN-WEI ZHAO ◽  
NAN XIANG ◽  
REN-GUO SONG
Keyword(s):  
Mechanical Properties ◽  
Aluminum Alloy ◽  
Treatment Time ◽  
Microarc Oxidation ◽  
Smooth Structure ◽  
Electrolytic Bath ◽  
Optimum Treatment ◽  
The One ◽  
Wear Tests

In the present study, microarc oxidation (MAO) coatings were formed on ZL101A aluminum alloy in an electrolytic bath containing 3[Formula: see text]g/L KOH [Formula: see text] 2[Formula: see text]g/L Na2WO[Formula: see text] 4[Formula: see text]g/L KF. The morphology and wearing behavior were investigated. In both electrolytes, the additives were borates (Na2B4O718[Formula: see text]g/L) and silicates (Na2SiO3 18[Formula: see text]g/L), respectively. It was found that the coating formed in borates-containing electrolyte was of compact and smooth structure than that of the one formed in silicates-containing electrolyte at the optimum treatment time. It was found that all the coatings were composed of á-Al2O3 and ã-Al2O3. The microhardness and wear tests proved that the coating formed in borates-containing electrolyte was having better mechanical properties than those of the coating formed in silicates-containing electrolyte.

Bayesian Inference Method for Failure Probability of Wall Thinning Pipe in Corrosion Rate Fluctuation Model

2008 ◽  
Author(s):  
Satoshi Okajima ◽  
Satoshi Izumi ◽  
Shinsuke Sakai
Keyword(s):  
Corrosion Rate ◽  
Failure Probability ◽  
Error Term ◽  
Correction Term ◽  
Operational Environment ◽  
Bayes Method ◽  
Wall Thinning ◽  
Rate Fluctuation ◽  
The One ◽  
Linear Bayes

To rationalize the inspection interval for the wall-thinning piping element, the linear-Bayes method was proposed in the previous paper. To derive the simple formula, the linear-Bayes method ignores the corrosion rate change against time. However, this change may be caused by the one of the operational environment. Therefore, without the sufficient monitoring of the environment, the linear-Bayes method may underestimate the failure probability. In this paper, the linear-Bayes method is extended for the wall-thinning model with the corrosion rate fluctuation, which imitates the unexpected change of the corrosion rate. The extension is carried out through following two approaches: the “correction-term” and the “error-term” approaches. The correction-term approach can evaluate the change of corrosion rate, however, it requires sufficient number of inspections. The error-term approach evaluates the failure probability conservatively.

Theoretical studies on the one- and two-photon absorption of tetrabenzoporphyrins and phthalocyanines

2004 ◽  
Vol 82 (1) ◽  
pp. 19-26 ◽  
Author(s):  
Xin Zhou ◽  
Ai-Min Ren ◽  
Ji-Kang Feng ◽  
Xiao-Juan Liu
Keyword(s):  
Dipole Moment ◽  
Cross Sections ◽  
Density Functional ◽  
Transition Dipole Moment ◽  
Photon Absorption ◽  
Transition Dipole ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Order Of Magnitude ◽  
The One

The one-photon absorption (OPA) properties of tetrabenzoporphyrins (TBPs) and phthalocyanines (Pcs) were studied using the semiempirical ZINDO method and time-dependent density functional theory (TDDFT), respectively. The compared results confirmed that the semiempirical ZINDO method was reasonably reliable when calculating the OPA of tetrabenzoporphyrins and phthalocyanines. On the basis of the OPA properties obtained from the ZINDO method, two-photon absorption (TPA) properties of two series of molecules were investigated, using ZINDO and sum-over-states (SOS) methods. The results showed that the TPA cross-sections of all molecules were in the range of 220.6 × 10–50 – 345.9 × 10–50 cm4·s·photon–1, which were in the same order of magnitude as the values reported in the literature. The relatively larger δ(ω) value for Pcs with respect to that for corresponding TBPs originates from larger intramolecular charge transfer, which can be characterized by the difference of dipole moment between S0 and S1 and the transition dipole moment between S1 and S5.Key words: two-photon absorption, ZINDO, sum-over-states, tetrabenzoporphyrin, phthalocyanines.

Study on Corrosion Damage Rule for Two Type of Aluminum Alloy

2014 ◽  
Vol 599-601 ◽  
pp. 111-113
Author(s):  
Dan Feng Zhang ◽  
Xiao Ming Tan ◽  
Dan Gui Zhang ◽  
Fang Zhang ◽  
Wei Zhang
Keyword(s):  
Aluminum Alloy ◽  
Statistical Analysis ◽  
Marine Environment ◽  
Corrosion Test ◽  
Corrosion Damage ◽  
Aircraft Structure ◽  
Accelerated Corrosion ◽  
Damage Repair ◽  
Accelerated Corrosion Test ◽  
Damage Rule

Corrosion exists everywhere. It’s very widespread that the aluminum alloy aircraft structure suffers the corrosion damage under the marine environment particularly. The equivalent accelerated corrosion test of the new aluminum alloy 2B06 and 7B04 was carried out.Corrosion damage was inspected and measured through microscope. The rule of the corrosion damage can be obtained by statistical analysis. And which can supply the reference basis for the corrosion damage repair and evaluating the calendar life.

Discussion of Oxygen Threshold Level for Corrosion Management in Seawater Injection Systems

2021 ◽  
Author(s):  
Jean Vicente Ferrari
Keyword(s):  
Corrosion Rate ◽  
Oxygen Reduction ◽  
Water Injection ◽  
Steel Corrosion ◽  
Threshold Level ◽  
International Standards ◽  
Limiting Current ◽  
Order Of Magnitude ◽  
The Impact ◽  
Oxygen Concentrations

Abstract Generally, in water injection systems, oxygen levels starting from around eight ppm are deoxygenated to below 50 ppm, following international standards' guidelines. This work aims to discuss the impact of such a magnitude value of oxygen contamination on steel corrosion in seawater injection systems by analysing theoretical polarisation curves and results from published works with different approaches. Corrosion models consider mass-transfer controlled diffusion of oxygen to predict the maximum steel corrosion rate, which depends on the oxygen limiting current, which in turn is strongly influenced by flow velocity. The effect of free chlorine on corrosion in seawater injection systems has also been considered and included in an oxygen equivalent parameter. In such systems, where oxygen reduction is the key cathodic reaction, the corrosion process may be under cathodic activation control, independent of flow at higher velocities or when erosion-corrosion begins. In this work, theoretical polarisation curves were constructed by using published oxygen and chlorine cathodic limiting currents (iLc) on carbon steel and a noble metal electrode, respectively. Aerated (200 ppb and 9000 ppb of oxygen) and deaerated conditions (50 ppb of oxygen) and the presence of 300 ppb of chlorine were applied to the assumed exchange current densities (io). Neutral (pH 7) and acid (pH 4) conditions (considering the presence of CO2) were also assumed to be at room temperature and pressure. Since the corrosion rate in lower oxygen concentrations (ppb order of magnitude) may result in corrosion rates of the same order of magnitude than in higher oxygen concentrations (ppm order of magnitude) when comparing and analysing results from experimental, semi-empirical or mechanistic approaches, it is necessary to weigh up the effects of both steel surface (bare or scaled/corrosion products) and flow. At oxygen concentrations below 200 ppb and under acid conditions, the contribution of H+ reduction on corrosion rate starts to be higher than oxygen reduction, mainly in the absence of chlorine.

scholarly journals Effects of tungsten, chromium and zirconium on the corrosion behavior of ternary amorphous W–Cr–Zr alloys in 1 M NaOh solution

1970 ◽  
Vol 9 (9) ◽  
pp. 39-43
Author(s):  
Basu Ram Aryal ◽  
Jagadeesh Bhattarai
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Open Circuit Potential ◽  
Open Circuit ◽  
Corrosion Rates ◽  
Corrosion Resistance Property ◽  
Naoh Solution ◽  
Order Of Magnitude ◽  
Sputter Deposited ◽  
Zr Alloys

Simultaneous additions of tungsten, chromium and zirconium in the chromium- and zirconium-enriched sputter-deposited binary W-xCr and W-yZr are effective to improve the corrosion resistance property of the ternary amorphous W- xCr-yZr alloys after immersion for 240 h in 1 M NaOH solution open to air at 25°C. The corrosion rates of all the examined sputter-deposited (10-57)W-(18-42)Cr-(25-73)Zr alloys is higher than those of alloy-constituting elements (that is, tungsten, chromium and zirconium) in aggressive 1 M NaOH solution open to air at 25°C. The corrosion rates of all the examined sputter−deposited W–xCr–yZr alloys containing 10-57 at% tungsten, 18-42 at% chromium and 25-73 at% zirconium were in the range of 1.5-2.5 × 10−3 mm/y or lower which are more than two orders of magnitude lower than that of sputter-deposited tungsten and even about one order of magnitude lower than those of the sputter-deposited zirconium in 1 M NaOH solution. Keywords: Ternary W–Cr–Zr alloys; Amorphous; Corrosion rate; Open circuit potential; 1 M NaOH. DOI: http://dx.doi.org/10.3126/sw.v9i9.5516 SW 2011; 9(9): 39-43

scholarly journals Accelerated Short-Term Techniques to Evaluate Corrosion in TiC Reinforced AA6063 Composites

2017 ◽  
Vol 13 (10) ◽  
pp. 5905-5913
Author(s):  
S. Saravanan ◽  
P.Senthil Kumar ◽  
T. Palanisamy ◽  
M. Ravichandran ◽  
V. Anandakrishnan ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Room Temperature ◽  
Stir Casting ◽  
Short Term ◽  
Accelerated Corrosion ◽  
Weight Percentage ◽  
The Poor ◽  
Accelerated Corrosion Tests

AA6063-TiC composites have several weight percentages up to 9 wt. % were fabricated by using stir casting route method. The effects of the weight percentage of TiC particles on the microstructures and corrosion behavior of AA6063-TiC composites were studied. The results revealed that the AA6063-TiC composites exhibited higher density than the AA6063 matrix. The accelerated corrosion tests of AA6063-TiC composites in 3.5 wt. % NaCl aqueous solution at room temperature, the AA6063-TiC composites have better corrosion resistance than the AA6063 matrix. Increasing the weight percentage of the TiC particles to reduces the corrosion rate of the AA6063-TiC composites. In this process corrosion rate of 0.4402 mm/year for AA6063 matrix, 0.3891 mm/year for 3 wt. % , 0.3568 mm/year for 6 wt. % and 0.3062 mm/year for 9 wt. % of TiC particles respectively. The poor corrosion resistance of the composites can be attributed to the galvanic effects between the AA6063 matrix and TiC reinforcement.

scholarly journals Effect of Heat Treatment and Sulfuric Acid Anodization on Corrosion Resistance of Aluminum Alloy (AA7075)

2021 ◽  
Vol 40 (1) ◽  
pp. 56-62
Author(s):  
M. Abdullahi ◽  
L.S. Kuburi ◽  
P.T. Zubairu ◽  
U. Jabo ◽  
A.A. Yahaya ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Sulfuric Acid ◽  
Corrosion Rate ◽  
Polarization Resistance ◽  
Testing Machine ◽  
Palm Kernel ◽  
Engine Oil ◽  
Micro Hardness

This paper, studied the effect of heat treatment and anodization on corrosion resistance of aluminum alloy 7075 (AA7075), with a view to improving its corrosion resistance. Microstructure and micro hardness of the anodic film of the samples were studied with the aid of optical metallurgical microscope and automated micro hardness testing machine. Linear polarization methods were used to assess the corrosion behaviour of the alloy in 0.5M HCl. The microstructure of the annealed sample showed formation of dendrites while precipitation hardened samples in palm kernel oil and SAE 40 engine oil showed precipitates of MgZn2. The SEMS result showed pores and micro cracks on the surfaces of the anodized samples, with the as cast and anodized sample in sulfuric acid exhibiting most compact with few pores. The as cast and sulfuric acid anodized sample shows highest micro hardness value of 205.33 HV, while the least value of 150.67 HV was recorded in sample precipitation hardened in SAE 40 engine oil and anodized in sulfuric acid. Analysis of the potentiodynamic polarization data and curves showed a linear relationship (decrease in icorr, decreases the corrosion rate) between current density and the corrosion rate in all the samples. Higher polarization resistance of 15.093 Ω/cm2 was recorded by the as cast and Sulfuric acid (SA) anodized sample while the precipitation treated in SAE 40 engine oil plus SA anodized sample recorded lowest polarization resistance of 5.2311 Ω/cm2. Heat treatment alone improves corrosion resistance of AA 7075 in 0.5 M HCl solution but heat treatment plus SA anodization does not improve corrosion resistance in the same environment.

scholarly journals Corrosion Rate of Aluminum Alloy in Moving Sodium Chloride Solution

1998 ◽  
Vol 47 (4) ◽  
pp. 254-259 ◽  
Author(s):  
Yasuyuki Takatani ◽  
Tsuyoshi Masugata ◽  
Kazuo Fujiwara ◽  
Koichi Shinkai ◽  
Koichi Hayashi
Keyword(s):  
Aluminum Alloy ◽  
Sodium Chloride ◽  
Corrosion Rate ◽  
Chloride Solution ◽  
Sodium Chloride Solution

Research on the Influence of Salt Fog Corrosion Behavior of 6005A Aluminum Alloy Welded Joints by Environment Humidity

2013 ◽  
Vol 662 ◽  
pp. 251-257
Author(s):  
Ning Xia ◽  
Zhi Min Zhu ◽  
Hui Chen
Keyword(s):  
Weight Loss ◽  
Tensile Strength ◽  
Aluminum Alloy ◽  
Aluminum Alloys ◽  
Relative Humidity ◽  
Corrosion Rate ◽  
Environmental Humidity ◽  
Welding Joints ◽  
Salt Fog Corrosion ◽  
Salt Fog

6005A aluminum alloys were welded at different relative humidity conditions. The effects of relative humidity on the salt fog corrosion of the welding joints were researched. The results showed that the weight loss of the joints after 14 days corrosion was higher than that corroded after 7days, but the corrosion rate was lower. The corrosion rate first increased then declined with the increase of environmental humidity for the joints corroded for 7days. However, when the environmental humidity was 80%, corrosion rate achieved the maximum, when environment humidity was 70%, corrosion rate was the lowest. After corroded for 14 days, corrosion rate was the maximum when the environmental humidity was 50%, and it was the lowest when the environmental humidity was 90%. The tensile strength declined obviously after corrosion.

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