scholarly journals Impact of halogen chemistry on summertime air quality in coastal and continental Europe: application of the CMAQ model and implications for regulation

2019 ◽  
Vol 19 (24) ◽  
pp. 15321-15337 ◽  
Author(s):  
Qinyi Li ◽  
Rafael Borge ◽  
Golam Sarwar ◽  
David de la Paz ◽  
Brett Gantt ◽  
...  
Keyword(s):  
Air Quality ◽  
Spatial Scales ◽  
Control Policy ◽  
The European Union ◽  
Human Beings ◽  
Coastal Cities ◽  
Halogen Chemistry ◽  
Secondary Air ◽  
The Impact ◽  
Halogen Species

Abstract. Halogen (Cl, Br, and I) chemistry has been reported to influence the formation of secondary air pollutants. Previous studies mostly focused on the impact of chlorine species on air quality over large spatial scales. Very little attention has been paid to the effect of the combined halogen chemistry on air quality over Europe and its implications for control policy. In the present study, we apply a widely used regional model, the Community Multiscale Air Quality Modeling System (CMAQ), incorporated with the latest halogen sources and chemistry, to simulate the abundance of halogen species over Europe and to examine the role of halogens in the formation of secondary air pollution. The results suggest that the CMAQ model is able to reproduce the level of O3, NO2, and halogen species over Europe. Chlorine chemistry slightly increases the levels of OH, HO2, NO3, O3, and NO2 and substantially enhances the level of the Cl radical. Combined halogen chemistry induces complex effects on OH (ranging from −0.023 to 0.030 pptv) and HO2 (in the range of −3.7 to 0.73 pptv), significantly reduces the concentrations of NO3 (as much as 20 pptv) and O3 (as much as 10 ppbv), and decreases NO2 in highly polluted regions (as much as 1.7 ppbv); it increases NO2 (up to 0.20 ppbv) in other areas. The maximum effects of halogen chemistry occur over oceanic and coastal regions, but some noticeable impacts also occur over continental Europe. Halogen chemistry affects the number of days exceeding the European Union target threshold for the protection of human beings and vegetation from ambient O3. In light of the significant impact of halogen chemistry on air quality, we recommend that halogen chemistry be considered for inclusion in air quality policy assessments, particularly in coastal cities.

scholarly journals Impact of halogen chemistry on air quality in coastal and continental Europe: application of CMAQ model and implication for regulation

2019 ◽  
Author(s):  
Qinyi Li ◽  
Rafael Borge ◽  
Golam Sarwar ◽  
David de la Paz ◽  
Brett Gantt ◽  
...  
Keyword(s):  
Air Quality ◽  
Spatial Scales ◽  
Control Policy ◽  
The European Union ◽  
Coastal Cities ◽  
Halogen Chemistry ◽  
Secondary Air ◽  
The Impact ◽  
Halogen Species

Abstract. Halogen (Cl, Br, and I) chemistry has been reported to influence the formation of secondary air pollutants. Previous studies mostly focused on the impact of chlorine species on air quality over large spatial scales. Very little attention has been paid to the effect of the combined halogen chemistry on air quality over Europe and its implications for control policy. In the present study, we utilize a widely-used regional model, the Community Multiscale Air Quality Modeling System (CMAQ), incorporated with the latest halogen sources and chemistry, to simulate the abundance of halogen species over Europe and to examine the role of halogens in the formation of secondary air pollution. The results suggest that the CMAQ model is able to reproduce the level of O3, NO2, and halogen species over Europe. Chlorine chemistry slightly increases the levels of OH, HO2, NO3, O3, and NO2 and substantially enhances the level of Cl radical. Combined halogen chemistry reduces the HO2/OH ratio by decreasing the level of HO2 and increasing OH, significantly reduces the concentrations of NO3 and O3, and decreases NO2 in the highly polluted regions and increases NO2 in other areas. The maximum effects of halogen chemistry occur over oceanic and coastal regions, but some noticeable impacts also occur over continental Europe. Halogen chemistry affects the number of days exceeding the European Union target threshold for the protection of human being and vegetation from ambient O3. In light of the significant impact of halogen chemistry on air quality, we recommend that halogen chemistry be considered for inclusion in air quality policy assessments, particularly in coastal cities.

scholarly journals Gender Differences in Association between Air Pollution and Daily Mortality in the Capital of the Green Lungs of Poland–Population-Based Study with 2,953,000 Person-Years of Follow-Up

2020 ◽  
Vol 9 (8) ◽  
pp. 2351
Author(s):  
Łukasz Kuźma ◽  
Krzysztof Struniawski ◽  
Szymon Pogorzelski ◽  
Hanna Bachórzewska-Gajewska ◽  
Sławomir Dobrzycki
Keyword(s):  
Public Health ◽  
Gender Differences ◽  
Air Pollution ◽  
Air Quality ◽  
Air Pollutant ◽  
World Health ◽  
The European Union ◽  
Daily Mortality ◽  
Male Population ◽  
The Impact

(1) Introduction: air pollution is considered to be one of the main risk factors for public health. According to the European Environment Agency (EEA), air pollution contributes to the premature deaths of approximately 500,000 citizens of the European Union (EU), including almost 5000 inhabitants of Poland every year. (2) Purpose: to assess the gender differences in the impact of air pollution on the mortality in the population of the city of Bialystok—the capital of the Green Lungs of Poland. (3) Materials and Methods: based on the data from the Central Statistical Office, the number—and causes of death—of Białystok residents in the period 2008–2017 were analyzed. The study utilized the data recorded by the Provincial Inspectorate for Environmental Protection station and the Institute of Meteorology and Water Management during the analysis period. Time series regression with Poisson distribution was used in statistical analysis. (4) Results: A total of 34,005 deaths had been recorded, in which women accounted for 47.5%. The proportion of cardiovascular-related deaths was 48% (n = 16,370). An increase of SO2 concentration by 1-µg/m3 (relative risk (RR) 1.07, 95% confidence interval (CI) 1.02–1.12; p = 0.005) and a 10 °C decrease of temperature (RR 1.03, 95% CI 1.01–1.05; p = 0.005) were related to an increase in the number of daily deaths. No gender differences in the impact of air pollution on mortality were observed. In the analysis of the subgroup of cardiovascular deaths, the main pollutant that was found to have an effect on daily mortality was particulate matter with a diameter of 2.5 μm or less (PM2.5); the RR for 10-µg/m3 increase of PM2.5 was 1.07 (95% CI 1.02–1.12; p = 0.01), and this effect was noted only in the male population. (5) Conclusions: air quality and atmospheric conditions had an impact on the mortality of Bialystok residents. The main air pollutant that influenced the mortality rate was SO2, and there were no gender differences in the impact of this pollutant. In the male population, an increased exposure to PM2.5 concentration was associated with significantly higher cardiovascular mortality. These findings suggest that improving air quality, in particular, even with lower SO2 levels than currently allowed by the World Health Organization (WHO) guidelines, may benefit public health. Further studies on this topic are needed, but our results bring questions whether the recommendations concerning acceptable concentrations of air pollutants should be stricter, or is there a safe concentration of SO2 in the air at all.

scholarly journals The impact of local surface changes in Borneo on atmospheric composition at wider spatial scales: coastal processes, land-use change and air quality

2011 ◽  
Vol 366 (1582) ◽  
pp. 3210-3224 ◽  
Author(s):  
J. A. Pyle ◽  
N. J. Warwick ◽  
N. R. P. Harris ◽  
Mohd Radzi Abas ◽  
A. T. Archibald ◽  
...  
Keyword(s):  
Land Use ◽  
Air Quality ◽  
Land Use Change ◽  
Spatial Scales ◽  
Model Performance ◽  
Atmospheric Composition ◽  
Model Studies ◽  
Uncertainty Model ◽  
Emission Changes ◽  
The Impact

We present results from the OP3 campaign in Sabah during 2008 that allow us to study the impact of local emission changes over Borneo on atmospheric composition at the regional and wider scale. OP3 constituent data provide an important constraint on model performance. Treatment of boundary layer processes is highlighted as an important area of model uncertainty. Model studies of land-use change confirm earlier work, indicating that further changes to intensive oil palm agriculture in South East Asia, and the tropics in general, could have important impacts on air quality, with the biggest factor being the concomitant changes in NO x emissions. With the model scenarios used here, local increases in ozone of around 50 per cent could occur. We also report measurements of short-lived brominated compounds around Sabah suggesting that oceanic (and, especially, coastal) emission sources dominate locally. The concentration of bromine in short-lived halocarbons measured at the surface during OP3 amounted to about 7 ppt, setting an upper limit on the amount of these species that can reach the lower stratosphere.

scholarly journals Effects of halogens on European air-quality

2017 ◽  
Vol 200 ◽  
pp. 75-100 ◽  
Author(s):  
T. Sherwen ◽  
M. J. Evans ◽  
R. Sommariva ◽  
L. D. J. Hollis ◽  
S. M. Ball ◽  
...  
Keyword(s):  
Air Quality ◽  
Stratospheric Ozone ◽  
Mixing Ratios ◽  
The North ◽  
Halogen Chemistry ◽  
The North Sea ◽  
Regional Air Quality ◽  
The Uk ◽  
The Impact ◽  
Quality Policy

Halogens (Cl, Br) have a profound influence on stratospheric ozone (O3). They (Cl, Br and I) have recently also been shown to impact the troposphere, notably by reducing the mixing ratios of O3 and OH. Their potential for impacting regional air-quality is less well understood. We explore the impact of halogens on regional pollutants (focussing on O3) with the European grid of the GEOS-Chem model (0.25° × 0.3125°). It has recently been updated to include a representation of halogen chemistry. We focus on the summer of 2015 during the ICOZA campaign at the Weybourne Atmospheric Observatory on the North Sea coast of the UK. Comparisons between these observations together with those from the UK air-quality network show that the model has some skill in representing the mixing ratios/concentration of pollutants during this period. Although the model has some success in simulating the Weybourne ClNO2 observations, it significantly underestimates ClNO2 observations reported at inland locations. It also underestimates mixing ratios of IO, OIO, I2 and BrO, but this may reflect the coastal nature of these observations. Model simulations, with and without halogens, highlight the processes by which halogens can impact O3. Throughout the domain O3 mixing ratios are reduced by halogens. In northern Europe this is due to a change in the background O3 advected into the region, whereas in southern Europe this is due to local chemistry driven by Mediterranean emissions. The proportion of hourly O3 above 50 nmol mol−1 in Europe is reduced from 46% to 18% by halogens. ClNO2 from N2O5 uptake onto sea-salt leads to increases in O3 mixing ratio, but these are smaller than the decreases caused by the bromine and iodine. 12% of ethane and 16% of acetone within the boundary layer is oxidised by Cl. Aerosol response to halogens is complex with small (∼10%) reductions in PM2.5 in most locations. A lack of observational constraints coupled to large uncertainties in emissions and chemical processing of halogens make these conclusions tentative at best. However, the results here point to the potential for halogen chemistry to influence air quality policy in Europe and other parts of the world.

scholarly journals DETERMINING THE IMPACTS OF FREIGHT TRANSPORT MODE COMBINATIONS ON AIR POLLUTION USING ARTIFICIAL NEURAL NETWORKS

2021 ◽  
Vol 19 (3) ◽  
pp. 191
Author(s):  
Nikola Petrović ◽  
Vesna Jovanović ◽  
Marijana Petrović ◽  
Boban Nikolić
Keyword(s):  
Neural Networks ◽  
Air Quality ◽  
Negative Impact ◽  
Freight Transport ◽  
The European Union ◽  
Transport Mode ◽  
Eu Member States ◽  
Feed Forward Neural Networks ◽  
The Impact ◽  
The Eu

Transport is one of the largest emitters of harmful substances that affect air quality. Each combination of freight transport modes has a different volume and at the same time has a differentiated negative impact on air quality. That is why the European Union has been making special efforts for many years to create and implement strategies aimed at improving air quality. The main goal of this paper is to present a methodology that enables quantification and analysis of the impact of each freight transport mode combination on air quality using feed-forward neural networks. The developed model uses the parameters of the EU member states in the period from 2000 to 2014. In addition to the scientific and practical contribution, the development of the model provides a good basis for the universal platform formation in order to create and develop strategies, i.e. measures to improve air quality on a global level.

scholarly journals Improving Air Quality in the Po Valley, Italy: Some Results by the LIFE-IP-PREPAIR Project

Atmosphere ◽  
2020 ◽  
Vol 11 (4) ◽  
pp. 429 ◽  
Author(s):  
Katia Raffaelli ◽  
Marco Deserti ◽  
Michele Stortini ◽  
Roberta Amorati ◽  
Matteo Vasconi ◽  
...  
Keyword(s):  
Air Quality ◽  
Northern Italy ◽  
The European Union ◽  
Limit Values ◽  
Po Valley ◽  
Limit Value ◽  
Northern Regions ◽  
Environmental Agencies ◽  
The Impact ◽  
The Eu

The Po Valley (Northern Italy) represents an important exceedance zone of the air-quality limit values for PM (particulate matter), NO2 (nitrogen dioxide) and O3 (ozone). This area covers the territory of most Italian northern regions and includes several urban agglomerates, such as Milan, Turin, Venice and Bologna. The area is densely populated and heavily industrialized. The paper summarizes the assessment of the impact of the current (2013) and future (2025) emissions and of the meteorological conditions on the air quality of the Po Valley. This study is one of the first outcomes of the EU LIFE-IP Clean Air Program Po Regions Engaged to Policies of Air (PREPAIR) project. The project, involving administrations and environmental agencies of eight regions and three municipalities in Northern Italy and Slovenia, started in 2017 and will end in 2024. Future emission scenarios consider the emissions reduction due to the air-quality action plans of the regions involved, of the agreements between the national authorities and regional administrations and of the PREPAIR project itself, in the overall context of the application of the current legislation of the European Union. The combination of these measures will lead to the reduction of direct emissions of PM10 in the Po Valley and of the main precursors emitted in the area (NOx, nitrogen oxides and NH3, and ammonia) by 38% for PM10, 39% for NOx and 22% for NH3, respectively. This lowering corresponds to a reduction of about 30.000 tons of primary PM10, 150.000 tons of NOx, 54.000 tons of NH3 and 1700 tons of SO2. The results show that these expected reductions should allow us to achieve the EU PM10 limit value in the Po Valley by the year 2025.

scholarly journals The impact of COVID-19 pandemic on nitrogen dioxide levels in Nigeria

PeerJ ◽  
2021 ◽  
Vol 9 ◽  
pp. e11387
Author(s):  
Johnson Adedeji Olusola ◽  
Adebola Adekunle Shote ◽  
Rima J. Isaifan ◽  
Abdellah Ouigmane
Keyword(s):  
Air Quality ◽  
Nitrogen Dioxide ◽  
Anthropogenic Activities ◽  
Economic Status ◽  
Health Impacts ◽  
Human Beings ◽  
Time Intervals ◽  
Restrictive Measures ◽  
Short Time ◽  
The Impact

The Coronavirus disease (COVID-19) has been transmitted worldwide over a very short time after it originated in China in December 2019. In an attempt to control its spread and reduce its health impacts, several countries including those in the African continent imposed restrictive measures that was termed “lockdown”. The outcomes of this lockdown have been reported to be beneficial to air quality worldwide. The main objective of this study is to assess the impact of lockdown due to COVID-19 on nitrogen dioxide (NO2) levels over six major cities in Nigeria. Maps extracted from satellite (Sentinel-5P) were used to indicate the significant reduction in the level of NO2 in the selected cities in Nigeria during two time-intervals, pre-lockdown (December, 2019) and during lockdown (April, 2020). The results show a significant reduction in NO2 levels during the lockdown period compared with its levels during the pre-lockdown period in 2019. The reduction in NO2 concentration levels during lockdown is likely due to less traffic, social distancing and restrictions on business and human activities. There could be an element of uncertainty in the results due to seasonality, as the comparison is done with a different season. However, the magnitude of change due to lockdown is probably much higher than the seasonal variability. Although COVID-19 has negatively impacted the health and economic status of all regions worldwide, it has benefited some aspects of air quality in most countries including Nigeria. This indicates that anthropogenic activities may be managed to reduce air pollution and positively impact the health of human beings.

scholarly journals Port-Related Emissions, Environmental Impacts and Their Implication on Green Traffic Policy in Shanghai

2020 ◽  
Vol 12 (10) ◽  
pp. 4162 ◽  
Author(s):  
Yuyan Zhou ◽  
Yan Zhang ◽  
Dong Ma ◽  
Jun Lu ◽  
Wenbin Luo ◽  
...  
Keyword(s):  
Air Quality ◽  
Environmental Impacts ◽  
Rapid Development ◽  
Control Policy ◽  
Throughput Capacity ◽  
Diesel Fuels ◽  
Cargo Handling ◽  
Ambient Concentrations ◽  
Cargo Throughput ◽  
The Impact

The port of Shanghai, as the world’s largest container port, has been experiencing rapid development in recent years, with increasing cargo throughput capacity. The combustion of diesel fuels used by internal and external port-related container trucks and in-port machineries can release various pollutants, causing air pollution. The terminals are close to the residential area, and the emissions are concentrated, which is worth paying attention to. This study aims to synthetically assess the port-related emissions and their environmental impacts. We firstly constructed an emission inventory of air pollutants in the port of Shanghai and then used the WRF-CMAQ model to estimate the influence of port-related source emissions on air quality. The results show that the annual emissions of SO2, NOX, CO, VOCS, PM, PM10, PM2.5, CO2, BC and OC caused by cargo-handling equipment were 21.88 t, 1811.22 t, 1741.72 t, 222.76 t, 61.52 t, 61.42 t, 58.41 t, 141,805.40 t, 26.80 t and 10.07 t in 2015. The emissions of NOX, CO, VOCS, PM10 and PM2.5 caused by external port-related container trucks were 18,002.92 t, 5308.0 t, 1134.57 t, 711.12 t and 640.58 t. The exhaust of external port-related container trucks was much larger than that of cargo-handling equipment, so the impact on air quality was also higher than that of the machinery. The peak annual average concentrations of PM2.5 and NOX contributed by the port-related sources were 1.75 μg/m3 and 49.21 μg/m3, respectively, which accounted for 3.08% and 36.7%, respectively, of the simulated ambient concentrations by all the anthropogenic emissions in Shanghai. Our results imply that the emission control policy to reduce the combined port-related emissions, especially for the cargo-delivery transportation phase from port to city, is key for large coastal port cities such as Shanghai.

New Approach to Economic Convergence in the EU: A Multilevel Analysis from the Spatial Effects Perspective

2018 ◽  
Vol 42 (3-4) ◽  
pp. 335-367 ◽  
Author(s):  
Alberto Díaz Dapena ◽  
Fernando Rubiera-Morollon ◽  
Dusan Paredes
Keyword(s):  
Economic Crisis ◽  
Spatial Scales ◽  
Spillover Effects ◽  
Spatial Effects ◽  
The European Union ◽  
General Process ◽  
Spatial Level ◽  
The Impact ◽  
Level Of Analysis ◽  
The Eu

The β-convergence model is based on the neoclassical framework in which the spatial level of analysis is not relevant. These levels will result in decreasing returns. However, local processes of agglomeration, spillover effects, or other forces could operate differently depending on the level of spatial disaggregation. The primary objective of this article is to observe whether different local, regional, and national convergence behaviors are possible in the European Union (EU). To capture the differences among spatial scales, a multilevel and spatial effects extension of the Solow–Swan theoretical growth model is proposed. The estimations of this model are made using consistent information from Eurostat and Cambridge Econometrics for the period of 2000–2014. A multilevel spatial Durbin model estimator is applied to evaluate the spatial interactions of the regions. The results indicate that a general process of convergence in the EU coexists with intranational processes of divergence, highlighting the relevance of the spatial level of analysis. A final analysis of the impact of the economic crisis over the general behavior has been included verifying that the economic crisis strongly reinforce the weakness of the EU convergence.

scholarly journals Combining Satellite Data and Spatial Analysis to Assess the UHI Amplitude and Structure within Urban Areas: The Case of Moroccan Cities

Urban Science ◽  
2021 ◽  
Vol 5 (3) ◽  
pp. 67
Author(s):  
Laila El Ghazouani ◽  
Lahouari Bounoua ◽  
Joseph Nigro ◽  
Majid Mansour ◽  
Hassan Radoine ◽  
...  
Keyword(s):  
Land Cover ◽  
Urban Areas ◽  
Spatial Scales ◽  
European Space Agency ◽  
Landsat 8 ◽  
Local Climate ◽  
Coastal Cities ◽  
Space Agency ◽  
Urban Heat ◽  
The Impact

Landsat-8 surface temperature and the European Space Agency land cover are used to assess the impact of land cover on the Urban Heat Island (UHI) and Urban Heat Sink (UHS). We analyzed five Moroccan cities selected for their different local climate, size, and typology during summer at three different spatial scales. The results show multiple causes defining the different forms and amplitudes of the UHI, namely: the ambient climate, the proximity to the sea, the presence of landscaped areas, and the color of building roofs and walls. Contrary to what was expected, the vegetation was not systematically an island of coolness, either because of its typology or its irrigation status. In the coastal cities of Tangier and Casablanca, UHIs around 20 °C are observed on the seaside, whereas a UHS of up to 11 °C is observed between the city center and the southern periphery of Casablanca. A moderate amplitude UHI of 7 °C is formed in the mountainous city of Ifrane. For cities built in desert-like environments, well-defined UHSs between 9 °C and 12 °C are observed in Smara and Marrakech, respectively. At a finer scale, towns recorded lower temperatures than their immediate surroundings, which are attributed to evaporation from irrigated plants.

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