scholarly journals Total OH reactivity over the Amazon rainforest: variability with temperature, wind, rain, altitude, time of day, season, and an overall budget closure

2020 ◽  
Author(s):  
Eva Y. Pfannerstill ◽  
Nina G. Reijrink ◽  
Achim Edtbauer ◽  
Akima Ringsdorf ◽  
Nora Zannoni ◽  
...  

Abstract. The tropical forests are Earth’s largest source of biogenic volatile organic compounds (BVOCs) and thus also the largest atmospheric sink region for the hydroxyl radical (OH). However, the OH sink above tropical forests is poorly understood, as past studies revealed large unattributed fractions of total OH reactivity. We present the first total OH reactivity and VOC measurements made at the Amazon Tall Tower Observatory (ATTO) at 80, 150, and 320 m above ground level, covering two dry seasons, one wet and one transition season in 2018–2019. By considering a wide range of previously unaccounted for VOCs, which we identified by PTR-ToF-MS, the unattributed fraction was with an overall average of 19 % within the measurement uncertainty of ~ 35 %. In terms of seasonal average OH reactivity, isoprene accounted for 23–43 % of the total, oxygenated VOCs (OVOCs) for 22–40 %, while monoterpenes, sesquiterpenes, and green leaf volatiles combined were responsible for 9–14 %. These findings show that OVOCs were until now an underestimated contributor to the OH sink above the Amazon forest. By day, total OH reactivity decreased towards higher altitudes with strongest vertical gradients observed around noon during the dry season (−0.026 s−1 m−1), while the gradient was inverted at night. Seasonal differences in total OH reactivity were observed, with the lowest daytime average and standard deviation of 19.9 ± 6.2 s−1 during a wet–dry transition season with frequent precipitation, 23.7 ± 6.5 s−1 during the wet season, and the highest average OH reactivities during two dry season observation periods with 28.1 ± 7.9 s−1 and 29.1 ± 10.8 s−1, respectively. The effects of different environmental parameters on the OH sink were investigated, and quantified, where possible. Precipitation caused short-term spikes in total OH reactivity, which were followed by below-normal OH reactivity for several hours. Biomass burning increased total OH reactivity by 2.7 s−1 to 9.5 s−1. We present a temperature-dependent parameterization of OH reactivity that could be applied in future models of the OH sink to further reduce our knowledge gaps in tropical forest OH chemistry.

2021 ◽  
Vol 21 (8) ◽  
pp. 6231-6256
Author(s):  
Eva Y. Pfannerstill ◽  
Nina G. Reijrink ◽  
Achim Edtbauer ◽  
Akima Ringsdorf ◽  
Nora Zannoni ◽  
...  

Abstract. The tropical forests are Earth's largest source of biogenic volatile organic compounds (BVOCs) and thus also the largest atmospheric sink region for the hydroxyl radical (OH). However, the OH sink above tropical forests is poorly understood, as past studies have revealed large unattributed fractions of total OH reactivity. We present the first total OH reactivity and volatile organic compound (VOC) measurements made at the Amazon Tall Tower Observatory (ATTO) at 80, 150, and 320 m above ground level, covering two dry seasons, one wet season, and one transition season in 2018–2019. By considering a wide range of previously unaccounted for VOCs, which we identified by proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS), the unattributed fraction was with an overall average of 19 % within the measurement uncertainty of ∼ 35 %. In terms of seasonal average OH reactivity, isoprene accounted for 23 %–43 % of the total and oxygenated VOCs (OVOCs) for 22 %–40 %, while monoterpenes, sesquiterpenes, and green leaf volatiles combined were responsible for 9 %–14 %. These findings show that OVOCs were until now an underestimated contributor to the OH sink above the Amazon forest. By day, total OH reactivity decreased towards higher altitudes with strongest vertical gradients observed around noon during the dry season (−0.026 s−1 m−1), while the gradient was inverted at night. Seasonal differences in total OH reactivity were observed, with the lowest daytime average and standard deviation of 19.9 ± 6.2 s−1 during a wet–dry transition season with frequent precipitation; 23.7 ± 6.5 s−1 during the wet season; and the highest average OH reactivities during two dry-season observation periods with 28.1 ± 7.9 s−1 and 29.1 ± 10.8 s−1, respectively. The effects of different environmental parameters on the OH sink were investigated, and quantified, where possible. Precipitation caused short-term spikes in total OH reactivity, which were followed by below-normal OH reactivity for several hours. Biomass burning increased total OH reactivity by 2.7 to 9.5 s−1. We present a temperature-dependent parameterization of OH reactivity that could be applied in future models of the OH sink to further reduce our knowledge gaps in tropical-forest OH chemistry.


2008 ◽  
Vol 25 (1) ◽  
pp. 32-39 ◽  
Author(s):  
Carlos Henrique de Freitas ◽  
Eleonore Z. F. Setz ◽  
Alba R. B. Araújo ◽  
Nivar Gobbi

Capuchin monkeys occupy a wide range of habitats where they feed on fruits, arthropods, and vertebrates. Their large home ranges (80-900 ha) suggest that living in forest fragments may challenge their adaptability. We identified and quantified the main food items of Cebus libidinosus Spix, 1823 in forests fragments (100 ha) in southeastern Brazil. We recorded the feeding activities of two groups using scan sampling over a 13-month period. The diet was composed of fruits, crops, animal prey, seeds, plant matter and undetermined. Fruit was eaten more in the wet season than in the dry season, and maize and sugar cane consumption peaked in the early dry season. The proportion of fruit in the diet was positively correlated with fruiting intensity of zoochorous trees. The plant diet included 54 species, with maize, Rhamnidium elaeocarpus, Acrocomia aculeata, Guazuma ulmifolia and Cariniana, being most important. Although dietary composition and diversity were similar to capuchins in larger forest fragments, feeding on crops attained higher percentages at times when zoochorous fruit production was low in fragments.


2017 ◽  
Vol 15 (2) ◽  
pp. 105
Author(s):  
Dharmadi Dharmadi ◽  
Endi Setiadi Kartamihardja ◽  
Agus Djoko Utomo ◽  
Dian Oktaviani

Tujuan penelitian ini adalah untuk mengetahui komposisi dan fluktuasi hasil tangkapan tuguk pada periode berbeda yang dioperasikan di Sungai Lempuing, Sumatera Selatan. Kegiatan penelitian dilaksanakan dengan metode survei pada periode musim peralihan penghujan sampai dengan kemarau (bulan April), musim kemarau (bulan Juni) dan musim penghujan (bulan Desember) tahun 2007. Komposisi jenis ikan dan hasil tangkapan diperoleh berdasarkan pada data pengambilan contoh pada saat ke lapangan dan data harian hasil tangkapan tuguk yang dicatat oleh 3 orang enumerator. Data dianalisis secara deskriptif. Hasil penelitian menunjukkan bahwa hasil tangkapan tuguk berbeda menurut periode waktu. Hasil tangkapan terdiri atas 11 jenis ikan untuk musim peralihan dan kemarau masing-masing berkisar 400-450 kg per unit per hari (rata-rata 411,2+14,1 kg per unit per hari) dan 250-300 kg per unit per hari (rata-rata 263,3+13,4 kg per unit per hari) dan 13 jenis ikan pada musim penghujan (bulan Desember) berkisar 700-750 kg per unit per hari (rata-rata 724,8+17,7 kg per unit per hari). Hasil tangkapan didominansi oleh jenis ikan lele (Clarias melanoderma) dan baung (Mystus nemurus). Selama penelitian, kandungan oksigen terlarut di perairan relatif rendah, berkisar 2-4 mg per l, namun dapat ditolelir oleh kelompok jenis ikan rawa (black fish). This research proposed to observed a catch composition and fluctuation of filtering device in different periods operated in the Lempuing River, South Sumatera. The research was conducted using survey method at a respective month of April (transition season), June (dry season) and December 07 (wet season). Fish composition and catch of tuguk were noted during survey and based on recording 3 enumerators. Descriptive analysis was used in this study. The results show that the catch of filtering device differed on diferent season periodes. A number of 11 fish species was caught at a respective season of transition season (April) of 400-450 kg per unit per day (average=411.2+14,1 kg per unit per day), dry season (June) of 250 300 kg per unit per day (average = 263,3+13,4 kg per unit per day), whilst at rainy season (December), fish catch composed of 13 fish species, ranging 700-750 kg per unit per day or (average = 724.8+17.7 kg per unit per day). Clarias melanoderma and Mystus nemurus were dominantly caught in the Lempuing River waters. During observation, dissolved oxygen content was relatively low (2-4 mg per l), that but could be tolerated by black fish.


2020 ◽  
Author(s):  
Heike Konow ◽  
Marcus Klingebiel ◽  
Felix Ament

<p><span>Trade wind cumulus clouds are the predominant cloud type over the tropical Atlantic east of the island of Barbados. Parameters describing their macroscopic shape can help characterizing and comparing general features of clouds. This characterizing will indirectly help to constrain estimates of climate sensitivity, because models with different structures of trade wind cumuli feature different response to increased CO2 contents.</span></p><p><span>Two aircraft campaigns with the HALO (High Altitude LOng range) aircraft took place in the recent past in this region: NARVAL-South (Next-generation Aircraft Remote-Sensing for VALidation studies) in December 2013, during the dry season, and NARVAL2 in August 2016, during the wet season. During these two campaigns, a wide range of cloud regimes from shallow to deep convection were sampled. This past observations are now extended with observations from this year’s measurement campaign EUREC<sup>4</sup>A, again during the dry season. EUREC<sup>4</sup>A is endorsed as WCRP capstone experiment and the synergy of four research aircraft, four research vessels and numerous additional observations will provide comprehensive characterizations of trade wind clouds and their environment.</span></p><p><span>Part of the NARVAL payload on HALO is a 35 GHz cloud radar, which has been deployed on HALO on several missions since 2013. These cloud radar measurements are used to segment individual clouds entities by applying connected component analysis to the radar cloud mask. From these segmented individual clouds, macrophysical parameters are derived to characterize each individual cloud. </span></p><p><span>This presentation will give an overview of the cloud macrophysics observed from HALO during EUREC<sup>4</sup>A. Typical macrophysical parameters, i.e. cloud depth, cloud length, cloud fraction, are analyzed. We will relate these to observations from past campaigns and assess the representativeness of EUREC<sup>4</sup>A. As special focus of the EUREC<sup>4</sup>A campaign, measurements will be performed during different times of the day to detect diurnal cycles. Macrophysical parameters can be used to characterize changes over the day and cloud scenes of similar clouds types can be identified.</span></p>


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Tewodros Kumssa ◽  
Afework Bekele

A study of the population status, habitat preference, and activity pattern of nonbreeding flamingos was carried out in Lakes Abijata, Shalla, and Chitu, part of the Great Rift Valley, Ethiopia, from 2011 to 2013. The current population status and habitat preference of flamingos in the area are still poorly known. Likewise, data on diurnal and seasonal activity pattern of the species are scarce and this leads to the misunderstanding of how Flamingos use local wetlands throughout the different seasons. Data regarding population size and activity pattern were gathered during the wet and dry seasons. Point-count method was used to estimate the population size. Behaviors were recorded using scan sampling techniques. A total of 53671 individuals representing two species of flamingo were counted during both wet and dry seasons from the three lakes. There were more flamingos during the dry season than the wet season in Lake Abijata contrary to Lakes Shalla and Chitu during the wet season. Lesser flamingos (Phoeniconaias minor) were the most abundant species comprising 95.39%, while Greater Flamingos (Phoenicopterus roseus) accounted for 4.61% of the total population. Lake Abijata is the major stronghold of Lesser Flamingos in the area. There was significant variation in the mean number of both species during the wet and dry season in the different study sites of the lake, respectively. The species were known to use varied habitats within the lakes. The Lesser Flamingo mainly preferred the shoreline and mudflat areas of the lakes. However, Greater Flamingo on several occasions showed preference to offshore area of the lakes. Seasonal average flock sizes were not similar between the species. There was a strong relationship between time allocated to each activity and time of day. Feeding activity varied among daylight hours and was higher in the evening (76.5%) and late morning (74.56%) and least during midday (54%). Some variations in activity breakdown were observed between time blocks and season. Conservation efforts in the park should include the wild flora and fauna not only of the land but also of the aquatic systems. The information in this study will be very useful for the future management of the species in the area.


PeerJ ◽  
2020 ◽  
Vol 8 ◽  
pp. e9636
Author(s):  
Irving Saenz-Pedroza ◽  
Richard Feldman ◽  
Casandra Reyes-García ◽  
Jorge A. Meave ◽  
Luz Maria Calvo-Irabien ◽  
...  

Tropical forests are globally important for biodiversity conservation and climate change mitigation but are being converted to other land uses. Conversion of seasonally dry tropical forests (SDTF) is particularly high while their protection is low. Secondary succession allows forests to recover their structure, diversity and composition after conversion and subsequent abandonment and is influenced by demographic rates of the constituent species. However, how these rates vary between seasons for different plant sizes at different successional stages in SDTF is not known. The effect of seasonal drought may be more severe early in succession, when temperature and radiation are high, while competition and density-dependent processes may be more important at later stages, when vegetation is tall and dense. Besides, the effects of seasonality and successional stage may vary with plant size. Large plants can better compete with small plants for limiting resources and may also have a greater capacity to withstand stress. We asked how size-dependent density, species density, recruitment and mortality varied between seasons and successional stages in a SDTF. We monitored a chronosequence in Yucatan, Mexico, over six years in three 0.1 ha plots in each of three successional stages: early (3–5 years-old), intermediate (18–20 years-old) and advanced (>50 years-old). Recruitment, mortality and species gain and loss rates were calculated from wet and dry season censuses separately for large (diameter > 5 cm) and small (1–5 cm in diameter) plants. We used linear mixed-effects models to assess the effects of successional stage, seasonality and their changes through time on demographic rates and on plant and species density. Seasonality affected demographic rates and density of large plants, which exhibited high wet-season recruitment and species gain rates at the early stage and high wet-season mortality at the intermediate stage, resulting in an increase in plant and species density early in succession followed by a subsequent stabilization. Small plant density decreased steadily after only 5 years of land abandonment, whereas species density increased with successional stage. A decline in species dominance may be responsible for these contrasting patterns. Seasonality, successional stage and their changes through time had a stronger influence on large plants, likely because of large among-plot variation of small plants. Notwithstanding the short duration of our study, our results suggest that climate-change driven decreases in rainy season precipitation may have an influence on successional dynamics in our study forest as strong as, or even stronger than, prolonged or severe droughts during the dry season.


2009 ◽  
Vol 4 (3) ◽  
pp. 1934578X0900400 ◽  
Author(s):  
Niko Radulović ◽  
Polina Blagojević ◽  
Radosav Palić

Chemical composition of the essential oil hydrodistilled from aerial parts of Sonchus arvensis subsp. uliginosus is reported for the first time. GC and GC-MS analyses of the oil enabled the identification of 114 components that represented 97.4% of the total oil. Main identified constituents were heneicosane (28.4%), ( Z)-3-hexen-1-ol (19.0%), ( E)-2-hexen-1-ol (11.6%), 1-eicosanol (7.5%) and tricosane (5.3%). Fatty acid derived compounds (“green leaf” volatiles, alkanes, n-alkenes, n-aldehydes and n-alcohols) were by far predominant (89.4%). A much lower percentage of shikimate metabolites (5.0%), carotenoid-derived compounds (1.7%) and terpenoids (0.9%) has also been detected in the oil. Compositions of the essential oils of S. arvensis subsp. uliginosus and other 18 randomly chosen species, characterized by a wide range of essential oil yields, belonging to different plant genera, were compared using multivariate statistical analysis. The results strongly suggest that the main volatiles of essential oil poor species (yields less then 0.1%) are fatty acid- and carotenoid derived compounds, while essential oil rich taxa (essential oil yields much higher then 0.1%) are generally characterized by the specific production of mono- and sesquiterpenoids, and/or phenylpropanoids.


1993 ◽  
Vol 29 (3) ◽  
pp. 323-339 ◽  
Author(s):  
William Stephens ◽  
M. K. V. Carr

SUMMARYRates of shoot extension and development (the unfolding of leaves) were recorded in an irrigation × fertilizer experiment on Clone 6/8 at Ngwazi Tea Research Unit in southern Tanzania. The wide range of mean temperatures (from 15–20°C) meant that the duration of the shoot replacement cycle (the time taken for an axillary bud released from apical dominance to develop three leaves and a terminal bud), in fully irrigated tea receiving 450 kg N ha-l, varied from 65 d in the warm wet season to 95 d in the cool dry season, compared with 75 to 180 d for unirrigated and unfertilized tea. Regression analysis indicated that the base temperature for extension, for Clone 6/8 in high-input plots, was about 10°C, some 2–3°C more than that for development. As a result of these differences in base temperature, the length of shoots with three leaves and a bud varied considerably between treatments and seasons, ranging from 15 mm in the unirrigated plots (at the end of the dry season) to 130 mm in the high-input plots at the start of the rains. Shoots from well fertilized tea were always longer (at a given stage of development) than those from unfertilized tea. The results are discussed in terms of the possible mechanisms responsible for the observed responses (changes in partitioning between roots and shoots), commercial harvesting practices and yield modelling.Extensión y desarrollo de broies en el té


1998 ◽  
Vol 14 (3) ◽  
pp. 309-321 ◽  
Author(s):  
JOHN A. BARONE

New leaf production in seasonal tropical forests may result from changes in water or light availability. In this study, the relationship between leaf flushing, photosynthetically active radiation (PAR) and rainfall was examined for understorey saplings in a moist tropical forest over one year. During the wet season, weeks with greater PAR were correlated with a greater proportion of saplings flushing new leaves during subsequent weeks in nine out of ten species. Rainfall was negatively correlated with subsequent leafing during the wet season for six of ten species. However, during the dry season, rainfall was positively correlated with leafing during the following weeks for six species, but the relationship was much weaker. PAR in the dry season was negatively correlated with flushing in eight species. These results support the hypothesis that under well-watered conditions, light limits leaf production, and peaks in insolation result in greater leaf production.


2018 ◽  
Vol 18 (17) ◽  
pp. 13245-13264 ◽  
Author(s):  
Daniela Wimmer ◽  
Stephany Buenrostro Mazon ◽  
Hanna Elina Manninen ◽  
Juha Kangasluoma ◽  
Alessandro Franchin ◽  
...  

Abstract. We investigated atmospheric new particle formation (NPF) in the Amazon rainforest using direct measurement methods. To our knowledge this is the first direct observation of NPF events in the Amazon region. However, previous observations elsewhere in Brazil showed the occurrence of nucleation-mode particles. Our measurements covered two field sites and both the wet and dry season. We measured the variability of air ion concentrations (0.8–12 nm) with an ion spectrometer between September 2011 and January 2014 at a rainforest site (T0t). Between February and October 2014, the same measurements were performed at a grassland pasture site (T3) as part of the GoAmazon 2014/5 experiment, with two intensive operating periods (IOP1 and IOP2 during the wet and the dry season, respectively). The GoAmazon 2014/5 experiment was designed to study the influence of anthropogenic emissions on the changing climate in the Amazon region. The experiment included basic aerosol and trace gas measurements at the ground, remote sensing instrumentation, and two aircraft-based measurements. The results presented in this work are from measurements performed at ground level at both sites. The site inside the rainforest (T0t) is located 60 km NNW of Manaus and influenced by pollution about once per week. The pasture (T3) site is located 70 km downwind from Manaus and influenced by the Manaus pollution plume typically once per day or every second day, especially in the afternoon. No NPF events were observed inside the rainforest (site T0t) at ground level during the measurement period. However, rain-induced ion and particle bursts (hereafter, “rain events”) occurred frequently (643 of 1031 days) at both sites during the wet and dry season, being most frequent during the wet season. During the rain events, the ion concentrations in three size ranges (0.8–2, 2–4, and 4–12 nm) increased up to about 104–105 cm−3. This effect was most pronounced in the intermediate and large size ranges, for which the background ion concentrations were about 10–15 cm−3 compared with 700 cm−3 for the cluster ion background. We observed eight NPF events at the pasture site during the wet season. We calculated the growth rates and formation rates of neutral particles and ions for the size ranges 2–3 and 3–7 nm using the ion spectrometer data. The observed median growth rates were 0.8 and 1.6 nm h−1 for 2–3 nm sized ions and particles, respectively, with larger growth rates (13.3 and 7.9 nm h−1) in the 3–7 nm size range. The measured nucleation rates were of the order of 0.2 cm−3 s−1 for particles and 4–9×10-3 cm−3 s−1 for ions. There was no clear difference in the sulfuric acid concentrations between the NPF event days and nonevent days (∼9×105 cm−3). The two major differences between the NPF days and nonevent days were a factor of 1.8 lower condensation sink on NPF event days (1.8×10-3 s−1) compared to nonevents (3.2×10-3 s−1) and different air mass origins. To our knowledge, this is the first time that results from ground-based sub-3 nm aerosol particle measurements have been obtained from the Amazon rainforest.


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