scholarly journals Sources and sinks of acetone, methanol, and acetaldehyde in North Atlantic marine air

2005 ◽  
Vol 5 (7) ◽  
pp. 1963-1974 ◽  
Author(s):  
A. C. Lewis ◽  
J. R. Hopkins ◽  
L. J. Carpenter ◽  
J. Stanton ◽  
K. A. Read ◽  
...  
Keyword(s):  
North Atlantic ◽  
Degradation Mechanism ◽  
Chemical Degradation ◽  
Oh Radical ◽  
Detailed Model ◽  
Atmospheric Lifetime ◽  
Sources And Sinks ◽  
Marine Air ◽  
Made In

Abstract. Measurements of acetone, methanol, acetaldehyde and a range of non-methane hydrocarbons have been made in North Atlantic marine air at the Mace Head observatory. Under maritime conditions the combination of OVOCs (acetone, methanol and acetaldehyde) contributed up to 85% of the total mass of measured non methane organics in air and up to 80% of the OH radical organic sink, when compared with the sum of all other organic compounds including non-methane hydrocarbons, DMS and OH-reactive halocarbons (trichloromethane and tetrachloroethylene). The observations showed anomalies in the variance and abundance of acetaldehyde and acetone over that expected for species with a remote terrestrial emission source and OH controlled chemical lifetime. A detailed model incorporating an explicit chemical degradation mechanism indicated in situ formation during air mass transport was on timescales longer than the atmospheric lifetime of precursor hydrocarbons or primary emission. The period over which this process was significant was similar to that of airmass motion on intercontinental scales, and formation via this route may reproduce that of a widespread diffuse source. The model indicates that continued short chain OVOC formation occurs many days from the point of emission, via longer lived intermediates of oxidation such as organic peroxides and long chain alcohols.

scholarly journals Sources and sinks of acetone, methanol, and acetaldehyde in North Atlantic air

2005 ◽  
Vol 5 (2) ◽  
pp. 1285-1317 ◽  
Author(s):  
A. C. Lewis ◽  
J. R. Hopkins ◽  
L. J. Carpenter ◽  
J. Stanton ◽  
K. A. Read ◽  
...  
Keyword(s):  
North Atlantic ◽  
Degradation Mechanism ◽  
Chemical Degradation ◽  
Oh Radical ◽  
Detailed Model ◽  
Atmospheric Lifetime ◽  
Sources And Sinks ◽  
Marine Air ◽  
Made In

Abstract. Measurements of acetone, methanol, acetaldehyde and a range of non-methane hydrocarbons have been made in North Atlantic marine air at the Mace Head observatory. Under maritime conditions the combination of OVOCs (acetone, methanol and 5 acetaldehyde) contributed up to 85% of the total mass of measured non methane organics in air and up to 80% of the OH radical organic sink, when compared with the sum of all other organic compounds including non-methane hydrocarbons, DMS and OH-reactive halocarbons (trichloromethane and tetrachloroethylene). The observations showed anomalies in the variance and abundance of acetaldehyde and acetone 10 over that expected for species with a remote terrestrial emission source and OH controlled chemical lifetime. A detailed model incorporating an explicit chemical degradation mechanism indicated in situ formation during air mass transport was on timescales longer than the atmospheric lifetime of precursor hydrocarbons or primary emission. The period over which this process was significant was similar to that of airmass mo15 tion on intercontinental scales, and formation via this route may reproduce that of a widespread diffuse source. The model indicates that continued short chain OVOC formation occurs many days from the point of emission, via longer lived intermediates of oxidation such as organic peroxides and long chain alcohols.

scholarly journals Marine Wind and Wave Height Trends at Different ERA-Interim Forecast Ranges

2015 ◽  
Vol 28 (2) ◽  
pp. 819-837 ◽  
Author(s):  
Ole Johan Aarnes ◽  
Saleh Abdalla ◽  
Jean-Raymond Bidlot ◽  
Øyvind Breivik
Keyword(s):  
Wind Speed ◽  
Wave Height ◽  
North Atlantic ◽  
Wave Model ◽  
Altimeter Data ◽  
The North ◽  
The Impact ◽  
Global Reanalysis ◽  
Made In

Abstract Trends in marine wind speed and significant wave height are investigated using the global reanalysis ERA-Interim over the period 1979–2012, based on monthly-mean and monthly-maximum data. Besides the traditional reanalysis, the authors include trends obtained at different forecast range, available up to 10 days ahead. Any model biases that are corrected differently over time are likely to introduce spurious trends of variable magnitude. However, at increased forecast range the model tends to relax, being less affected by assimilation. Still, there is a trade-off between removing the impact of data assimilation at longer forecast range and getting a lower level of uncertainty in the predictions at shorter forecast range. Because of the sheer amount of assimilations made in ERA-Interim, directly and indirectly affecting the data, it is difficult, if not impossible, to distinguish effects imposed by all updates. Here, special emphasis is put on the introduction of wave altimeter data in August 1991, the only type of data directly affecting the wave field. From this, it is shown that areas of higher model bias introduce quite different trends depending on forecast range, most apparent in the North Atlantic and eastern tropical Pacific. Results are compared with 23 in situ measurements, Envisat altimeter winds, and two stand-alone ECMWF operational wave model (EC-WAM) runs with and without wave altimeter assimilation. Here, the 48-h forecast is suggested to be a better candidate for trend estimates of wave height, mainly due to the step change imposed by altimeter observations. Even though wind speed seems less affected by undesirable step changes, the authors believe that the 24–48-h forecast more effectively filters out any unwanted effects.

scholarly journals In-Situ Synthesis of TiO2@GO Nanosheets for Polymers Degradation in a Natural Environment

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2158
Author(s):  
Yueqin Shi ◽  
Zhanyang Yu ◽  
Zhengjun Li ◽  
Xiaodong Zhao ◽  
Yongjun Yuan
Keyword(s):  
Natural Environment ◽  
New Technologies ◽  
Separation Efficiency ◽  
Basic Mechanism ◽  
Chemical Degradation ◽  
Natural Environments ◽  
Additional Energy ◽  
Photogenerated Electrons ◽  
Main Components

Plastic photodegradation naturally takes 300–500 years, and their chemical degradation typically needs additional energy or causes secondary pollution. The main components of global plastic are polymers. Hence, new technologies are urgently required for the effective decomposition of the polymers in natural environments, which lays the foundation for this study on future plastic degradation. This study synthesizes the in-situ growth of TiO2 at graphene oxide (GO) matrix to form the TiO2@GO photocatalyst, and studies its application in conjugated polymers’ photodegradation. The photodegradation process could be probed by UV-vis absorption originating from the conjugated backbone of polymers. We have found that the complete decomposition of various polymers in a natural environment by employing the photocatalyst TiO2@GO within 12 days. It is obvious that the TiO2@GO shows a higher photocatalyst activity than the TiO2, due to the higher crystallinity morphology and smaller size of TiO2, and the faster transmission of photogenerated electrons from TiO2 to GO. The stronger fluorescence (FL) intensity of TiO2@GO compared to TiO2 at the terephthalic acid aqueous solution indicates that more hydroxyl radicals (•OH) are produced for TiO2@GO. This further confirms that the GO could effectively decrease the generation of recombination centers, enhance the separation efficiency of photoinduced electrons and holes, and increase the photocatalytic activity of TiO2@GO. This work establishes the underlying basic mechanism of polymers photodegradation, which might open new avenues for simultaneously addressing the white pollution crisis in a natural environment.

Engaging with the science and politics of biodiversity futures: a literature review

2021 ◽  
pp. 1-8
Author(s):  
Carina Wyborn ◽  
Elena Louder ◽  
Mike Harfoot ◽  
Samantha Hill
Keyword(s):  
Human Life ◽  
Global Environmental Change ◽  
Life Forms ◽  
Trade Offs ◽  
Global Environmental ◽  
Science And Politics ◽  
Science Community ◽  
Impact On Biodiversity ◽  
Made In

Summary Future global environmental change will have a significant impact on biodiversity through the intersecting forces of climate change, urbanization, human population growth, overexploitation, and pollution. This presents a fundamental challenge to conservation approaches, which seek to conserve past or current assemblages of species or ecosystems in situ. This review canvases diverse approaches to biodiversity futures, including social science scholarship on the Anthropocene and futures thinking alongside models and scenarios from the biophysical science community. It argues that charting biodiversity futures requires processes that must include broad sections of academia and the conservation community to ask what desirable futures look like, and for whom. These efforts confront political and philosophical questions about levels of acceptable loss, and how trade-offs can be made in ways that address the injustices in the distribution of costs and benefits across and within human and non-human life forms. As such, this review proposes that charting biodiversity futures is inherently normative and political. Drawing on diverse scholarship united under a banner of ‘futures thinking’ this review presents an array of methods, approaches and concepts that provide a foundation from which to consider research and decision-making that enables action in the context of contested and uncertain biodiversity futures.

scholarly journals North Atlantic warming over six decades drives decreases in krill abundance with no associated range shift

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Martin Edwards ◽  
Pierre Hélaouët ◽  
Eric Goberville ◽  
Alistair Lindley ◽  
Geraint A. Tarling ◽  
...  
Keyword(s):  
North Atlantic ◽  
Range Shift ◽  
The Core ◽  
Krill Abundance ◽  
The North ◽  
Living Space ◽  
Warming Climate ◽  
Two Temperatures ◽  
The North Atlantic

AbstractIn the North Atlantic, euphausiids (krill) form a major link between primary production and predators including commercially exploited fish. This basin is warming very rapidly, with species expected to shift northwards following their thermal tolerances. Here we show, however, that there has been a 50% decline in surface krill abundance over the last 60 years that occurred in situ, with no associated range shift. While we relate these changes to the warming climate, our study is the first to document an in situ squeeze on living space within this system. The warmer isotherms are shifting measurably northwards but cooler isotherms have remained relatively static, stalled by the subpolar fronts in the NW Atlantic. Consequently the two temperatures defining the core of krill distribution (7–13 °C) were 8° of latitude apart 60 years ago but are presently only 4° apart. Over the 60 year period the core latitudinal distribution of euphausiids has remained relatively stable so a ‘habitat squeeze’, with loss of 4° of latitude in living space, could explain the decline in krill. This highlights that, as the temperature warms, not all species can track isotherms and shift northward at the same rate with both losers and winners emerging under the ‘Atlantification’ of the sub-Arctic.

scholarly journals Degradation Mechanism of Porous Metal-Organic Frameworks by In Situ Atomic Force Microscopy

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 722
Author(s):  
Ioanna Christodoulou ◽  
Tom Bourguignon ◽  
Xue Li ◽  
Gilles Patriarche ◽  
Christian Serre ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Degradation Mechanism ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Force Microscopy ◽  
Atomic Force ◽  
Metal Organic ◽  
The Media ◽  
Ph Conditions

In recent years, Metal-Organic Frameworks (MOFs) have attracted a growing interest for biomedical applications. The design of MOFs should take into consideration the subtle balance between stability and biodegradability. However, only few studies have focused on the MOFs’ stability in physiological media and their degradation mechanism. Here, we investigate the degradation of mesoporous iron (III) carboxylate MOFs, which are among the most employed MOFs for drug delivery, by a set of complementary methods. In situ AFM allowed monitoring with nanoscale resolution the morphological, dimensional, and mechanical properties of a series of MOFs in phosphate buffer saline and in real time. Depending on the synthetic route, the external surface presented either well-defined crystalline planes or initial defects, which influenced the degradation mechanism of the particles. Moreover, MOF stability was investigated under different pH conditions, from acidic to neutral. Interestingly, despite pronounced erosion, especially at neutral pH, the dimensions of the crystals were unchanged. It was revealed that the external surfaces of MOF crystals rapidly respond to in situ changes of the composition of the media they are in contact with. These observations are of a crucial importance for the design of nanosized MOFs for drug delivery applications.

Surface modification of sewage sludge derived carbonaceous catalyst for m-cresol catalytic wet peroxide oxidation and degradation mechanism

RSC Advances ◽  
2015 ◽  
Vol 5 (52) ◽  
pp. 41867-41876 ◽  
Author(s):  
Yang Yu ◽  
Huangzhao Wei ◽  
Li Yu ◽  
Tong Zhang ◽  
Sen Wang ◽  
...  
Keyword(s):  
Surface Modification ◽  
Sewage Sludge ◽  
Organic Synthesis ◽  
Degradation Mechanism ◽  
Peroxide Oxidation ◽  
Wet Peroxide Oxidation ◽  
Carbonaceous Catalyst ◽  
Catalytic Wet Peroxide Oxidation

Organic synthesis is used to investigate the degradation of m-cresol and the intermediates are identified by in situ NMR.

scholarly journals Progress on Coronal, Interplanetary, Foreshock, and Outer Heliospheric Radio Emissions

2000 ◽  
Vol 17 (1) ◽  
pp. 22-34 ◽  
Author(s):  
Iver H. Cairns ◽  
P. A. Robinson ◽  
G. P. Zank
Keyword(s):  
Solar Wind ◽  
Plasma Waves ◽  
Recent Theory ◽  
Type Ii ◽  
Solar Radio Bursts ◽  
Radio Emissions ◽  
Source Regions ◽  
Earth’S Bow Shock ◽  
Made In

AbstractType II and III solar radio bursts are associated with shock waves and streams of energetic electrons, respectively, which drive plasma waves and radio emission at multiples of the electron plasma frequency as they move out from the corona into the interplanetary medium. Analogous plasma waves and radiation are observed from the foreshock region upstream of Earth's bow shock. In situ spacecraft observations in the solar wind have enabled major progress to be made in developing quantitative theories for these phenomena that are consistent with available data. Similar processes are believed responsible for radio emissions at 2–3 kHz that originate in the distant heliosphere, from where the solar wind interacts with the local interstellar medium. The primary goal of this paper is to review the observations and theories for these four classes of emissions, focusing on recent progress in developing detailed theories for the plasma waves and radiation in the source regions. The secondary goal is to introduce and review stochastic growth theory, a recent theory which appears quantitatively able to explain the wave observations in type III bursts and Earth's foreshock and is a natural theory to apply to type II bursts, the outer heliospheric emissions, and perhaps astrophysicalemissions.

Sign in / Sign up

Export Citation Format

Share Document