Aerosol pH and regime transition of sulfate formation in aerosol water during winter haze events in northern China

2020 ◽  
Author(s):  
Wei Tao ◽  
Hang Su ◽  
Guangjie Zheng ◽  
Jiandong Wang ◽  
Lixia Liu ◽  
...  
Keyword(s):  
Northern China ◽  
Chem Phys ◽  
Heterogeneous Reactions ◽  
Lower Atmosphere ◽  
Spatial And Temporal Variability ◽  
Oh Radicals ◽  
Night Time ◽  
Sulfate Formation ◽  
Iron Manganese ◽  
The Impact

<p>Understanding the formation mechanism of severe haze is crucial for the development of efficient pollution control strategy. Recently, multiphase reactions in aerosol water has been suggested as an important source of sulfate aerosol during severe haze (Zheng et al., 2015;Cheng et al., 2016). Though several oxidation mechanisms have been recognized, the dominant oxidation pathway is still under debate reflecting a missing consensus. Based on a model survey with Weather Research and Forecasting model coupled with Chemistry (WRF-Chem), we have investigated the variability of aerosol pH and regimes of sulfate formation through multiphase oxidation during the haze episodes in January of 2013. Our results show a large spatial and temporal variability in the aerosol pH and sulfate formation regimes. Surface aerosol pH shows a clear diurnal variation with low pH during daytime and high pH during night-time for most cases. Aerosol pH tends to decrease with increasing altitude in the lower atmosphere. For the scenario best reproduces the observations in Beijing, NO<sub>2</sub>, TMI+O<sub>2</sub>, O<sub>3</sub> and H<sub>2</sub>O<sub>2</sub> pathways can all dominate the production of sulfate in specific areas of the Beijing-Tianjin-Hebei (BTH) region. With the increasing height, O<sub>3</sub> pathway and gas phase oxidation by OH radicals become more important. Moreover, sensitivity tests also suggest that, emissions of crustal particles, NH<sub>3</sub> and soluble iron/manganese have great impacts on aqueous phase chemistry, and should be better constrained in future studies.</p><p>References:</p><p>Zheng, G. J., Duan, F. K., Su, H., Ma, Y. L., Cheng, Y., Zheng, B., Zhang, Q., Huang, T., Kimoto, T., Chang, D., Poschl, U., Cheng, Y. F., and He, K. B.: Exploring the severe winter haze in Beijing: the impact of synoptic weather, regional transport and heterogeneous reactions, Atmos. Chem. Phys., 15, 2969-2983, 10.5194/acp-15-2969-2015, 2015.</p><p>Cheng, Y. F., Zheng, G. J., Wei, C., Mu, Q., Zheng, B., Wang, Z. B., Gao, M., Zhang, Q., He, K. B., Carmichael, G., Poschl, U., and Su, H.: Reactive nitrogen chemistry in aerosol water as a source of sulfate during haze events in China, Sci Adv, 2, e1601530, UNSP e1601530,10.1126/sciadv.1601530, 2016.</p>

scholarly journals Effect of the Assimilation Frequency of Radar Reflectivity on Rain Storm Prediction by Using WRF-3DVAR

2021 ◽  
Vol 13 (11) ◽  
pp. 2103
Author(s):  
Yuchen Liu ◽  
Jia Liu ◽  
Chuanzhe Li ◽  
Fuliang Yu ◽  
Wei Wang
Keyword(s):  
Data Assimilation ◽  
Northern China ◽  
Horizontal Resolution ◽  
Radar Reflectivity ◽  
Small Scale ◽  
Time Interval ◽  
Outer Domain ◽  
Storm Prediction ◽  
The Impact ◽  
Assimilation Time

An attempt was made to evaluate the impact of assimilating Doppler Weather Radar (DWR) reflectivity together with Global Telecommunication System (GTS) data in the three-dimensional variational data assimilation (3DVAR) system of the Weather Research Forecast (WRF) model on rain storm prediction in Daqinghe basin of northern China. The aim of this study was to explore the potential effects of data assimilation frequency and to evaluate the outputs from different domain resolutions in improving the meso-scale NWP rainfall products. In this study, four numerical experiments (no assimilation, 1 and 6 h assimilation time interval with DWR and GTS at 1 km horizontal resolution, 6 h assimilation time interval with radar reflectivity, and GTS data at 3 km horizontal resolution) are carried out to evaluate the impact of data assimilation on prediction of convective rain storms. The results show that the assimilation of radar reflectivity and GTS data collectively enhanced the performance of the WRF-3DVAR system over the Beijing-Tianjin-Hebei region of northern China. It is indicated by the experimental results that the rapid update assimilation has a positive impact on the prediction of the location, tendency, and development of rain storms associated with the study area. In order to explore the influence of data assimilation in the outer domain on the output of the inner domain, the rainfall outputs of 3 and 1 km resolution are compared. The results show that the data assimilation in the outer domain has a positive effect on the output of the inner domain. Since the 3DVAR system is able to analyze certain small-scale and convective-scale features through the incorporation of radar observations, hourly assimilation time interval does not always significantly improve precipitation forecasts because of the inaccurate radar reflectivity observations. Therefore, before data assimilation, the validity of assimilation data should be judged as far as possible in advance, which can not only improve the prediction accuracy, but also improve the assimilation efficiency.

scholarly journals Prevalence of nocturia among community-dwelling adults: a population-based study in Malaysia

BMC Urology ◽  
2021 ◽  
Vol 21 (1) ◽  
Author(s):  
Hui-Yin Yow ◽  
John Jeh Lung Tiong ◽  
Chun-Wai Mai ◽  
Esther van der Werf ◽  
Zulkifli Md Zainuddin ◽  
...  
Keyword(s):  
Medical Condition ◽  
Population Based ◽  
Community Dwelling ◽  
Medical Attention ◽  
Night Time ◽  
Cross Sectional ◽  
Population Based Study ◽  
Waking Up ◽  
The Impact

Abstract Background Nocturia is widely prevalent condition with detrimental effects on quality of life and general health. In Malaysia, there is a lack of up-to-date prevalence study on nocturia. This study aimed to investigate the prevalence of nocturia and awareness pertaining to nocturia among Malaysian adults. Methods A cross-sectional population-based study was conducted among Malaysian adults aged ≥ 18 years old. The data was collected by mixed mode self-administered questionnaire from May 2019 to September 2019. Nocturia was defined as one or more voids at night. Results There were a total of 4616 respondents with 74.5% of response rate. The overall prevalence of nocturia among Malaysian adults was found to be 57.3%. In multivariate analysis, respondents aged 31–40 (1.91 [1.52–2.40]) or > 60 years old (2.03 [1.48–2.71]), and those who presented with hypertension (2.84 [2.28–3.53]), diabetes mellitus (1.78 [1.42–2.25]), renal disease (3.58 [1.93–6.63]) or overactive bladder (1.61 [1.10–2.35]) were associated with higher prevalence of nocturia. A significantly lower disease prevalence (p < 0.05) was noted among those aged 41–50 (0.73 [0.59–0.91]), male (0.78 [0.69–0.88]) and Chinese (0.47 [0.30–0.74]) or Indian (0.34 [0.21–0.54]) ethnicities. A total of 37.3% of respondents with nocturia reported that they faced sleeping difficulty about half the time or more after waking up in the middle of night. Those who had ≥ 2 voids per night experienced significantly higher mean bother score than those who had 1 void per night (p < 0.001). Approximately half (56.7%) of all respondents were not aware that night time urination is a medical condition. Only 25.2% of respondents with nocturia had sought medical attention for their nocturia. Conclusions The prevalence of nocturia among Malaysian adults is high and strongly influenced by age, sex, race and comorbidities. However, the general awareness pertaining to nocturia being a health issue remains low among Malaysians. The findings also highlighted the impact of nocturia on sleep and the need for nocturia education to better address this disease.

scholarly journals Caffeine may disrupt the impact of real-time drowsiness on cognitive performance: a double-blind, placebo-controlled small-sample study

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
E. Aidman ◽  
M. Balin ◽  
K. Johnson ◽  
S. Jackson ◽  
G. M. Paech ◽  
...  
Keyword(s):  
Real Time ◽  
Cognitive Performance ◽  
Small Sample ◽  
Night Time ◽  
Double Blind ◽  
Infra Red ◽  
Procedural Decisions ◽  
Performance Gains ◽  
The Impact ◽  
Modest Reduction

AbstractCaffeine is widely used to promote alertness and cognitive performance under challenging conditions, such as sleep loss. Non-digestive modes of delivery typically reduce variability of its effect. In a placebo-controlled, 50-h total sleep deprivation (TSD) protocol we administered four 200 mg doses of caffeine-infused chewing-gum during night-time circadian trough and monitored participants' drowsiness during task performance with infra-red oculography. In addition to the expected reduction of sleepiness, caffeine was found to disrupt its degrading impact on performance errors in tasks ranging from standard cognitive tests to simulated driving. Real-time drowsiness data showed that caffeine produced only a modest reduction in sleepiness (compared to our placebo group) but substantial performance gains in vigilance and procedural decisions, that were largely independent of the actual alertness dynamics achieved. The magnitude of this disrupting effect was greater for more complex cognitive tasks.

Hybrid nanofluid flow over a stretched cylinder with the impact of homogeneous–heterogeneous reactions and Cattaneo–Christov heat flux: Series solution and numerical simulation

Heat Transfer ◽  
2021 ◽  
Author(s):  
Anthonysamy John Christopher ◽  
Nanjundan Magesh ◽  
Ramanahalli Jayadevamurthy Punith Gowda ◽  
Rangaswamy Naveen Kumar ◽  
Ravikumar Shashikala Varun Kumar
Keyword(s):  
Numerical Simulation ◽  
Heat Flux ◽  
Series Solution ◽  
Heterogeneous Reactions ◽  
Hybrid Nanofluid ◽  
Nanofluid Flow ◽  
The Impact

scholarly journals Vertical air motions derived from a descending radiosonde using a lightweight hard ball as the parachute

2013 ◽  
Vol 6 (5) ◽  
pp. 8107-8127 ◽  
Author(s):  
H. Chen ◽  
Y. Zhu ◽  
J. Zhang ◽  
Y. Xuan
Keyword(s):  
Northern China ◽  
Lower Atmosphere ◽  
Radiosonde Data ◽  
Small Magnitude ◽  
Abstract Knowledge ◽  
Launch Site ◽  
Wind Profiler Radar ◽  
Vertical Wind Speed ◽  
The Difference ◽  
Hard Ball

Abstract. Knowledge of vertical air motions in the atmosphere is important for meteorological and climate studies due to its impact on clouds, precipitation and the vertical transport of air masses, heat, momentum, and composition. It is among the most difficult quantities to measure because of its small magnitude. In this study, a descending radiosonde technique has been developed to detect the vertical wind speed (VW) in the atmosphere. The system is composed of a radiosonde and a 0.5-m diameter hard ball made of plastic foam that acts as a parachute. The radiosonde hangs under the hard ball by a string which is then cut when the instrument is elevated into the upper troposphere by a balloon. The VW is derived from the difference between the observed radiosonde descent rate and the calculated radiosonde descent rate in still air based on fluid dynamics. Deduction of the appropriate drag coefficient for the radiosonde is facilitated by the symmetrical shape of the parachute. An intensive radiosonde launch experiment was held in northern China during the summer seasons of 2010 to 2012. This study uses radiosonde data collected during the campaign to retrieve the vertical air velocity within the radiosonde altitude-detecting range. In general, the VW ranges from −1 to 1 m s−1. Strong vertical air motion (~2 m s−1) is seen in a few radiosonde measurements. Although considerable uncertainties exist in measuring weak vertical air motions, a case study shows that there is reasonable agreement between retrievals of VW in the lower atmosphere from the radiosonde and a wind profiler radar located at the launch site.

scholarly journals The influence of riparian woodland on the spatial and temporal variability of stream water temperatures in an upland salmon stream

2004 ◽  
Vol 8 (3) ◽  
pp. 449-459 ◽  
Author(s):  
I. A. Malcolm ◽  
D. M. Hannah ◽  
M. J. Donaghy ◽  
C. Soulsby ◽  
A. F. Youngson
Keyword(s):  
Thermal Regime ◽  
Temporal Variability ◽  
Heat Budget ◽  
Riparian Forest ◽  
Stream Water ◽  
Spatial And Temporal Variability ◽  
Substantial Impact ◽  
Site Specific ◽  
The Impact ◽  
Riparian Woodland

Abstract. The spatio-temporal variability of stream water temperatures was investigated at six locations on the Girnock Burn (30km2 catchment), Cairngorms, Scotland over three hydrological years between 1998 and 2002. The key site-specific factors affecting the hydrology and climatology of the sampling points were investigated as a basis for physical process inference. Particular emphasis was placed on assessing the effects of riparian forest in the lower catchment versus the heather moorland riparian zones that are spatially dominant in the upper catchment. The findings were related to river heat budget studies that provided process detail. Gross changes in stream temperature were affected by the annual cycle of incoming solar radiation and seasonal changes in hydrological and climatological conditions. Inter-annual variation in these controlling variables resulted in inter-annual variability in thermal regime. However, more subtle inter-site differences reflected the impact of site-specific characteristics on various components of the river energy budget. Inter-site variability was most apparent at shorter time scales, during the summer months and for higher stream temperatures. Riparian woodland in the lower catchment had a substantial impact on thermal regime, reducing diel variability (over a period of 24 hours) and temperature extremes. Observed inter-site differences are likely to have a substantial effect on freshwater ecology in general and salmonid fish in particular. Keywords: temperature, thermal regime, forest, salmon, hydrology, Girnock Burn, Cairngorm

ASSOCIATION BETWEEN QUALITY OF SLEEPAND OTHER PARAMETERS IN PATIENTS WITH GASTROESOPHAGEAL REFLUX DISEASE.

2021 ◽  
pp. 25-27
Author(s):  
Umesh kr. Mishra ◽  
Sunita Tiwari ◽  
Sumit Rungta ◽  
Pooja Mishra ◽  
Gulam Akhtar
Keyword(s):  
Sleep Disorders ◽  
Quality Of Sleep ◽  
Night Time ◽  
Rem Latency ◽  
The Mean ◽  
Potential Impact ◽  
Nocturnal Polysomnography ◽  
The Impact ◽  
Gerd Symptoms

Background: Night time reux has been shown to be associated with fragmented sleep. However, few studies have assessed the quality of sleep on gastroesophageal reux and the impact of gastroesophageal reux on reported quality of sleep and quality of sleep on gastroesophageal reux. The aims of this study were to evaluate the quality of sleep and other parameters in patients with gastroesophageal reux disease.50 Subjects with typical GERD symptoms ≥3 times a week and All subjects were administered 3 questionnaires: PSQI , ESS, GERD-HRQL . All the subjects underwent nocturnal polysomnography and completed a all 3 questionnaire before NPSG. Results: Overall ,the mean percentage of N1 was 9.10±9.74 ,N2 was 83.97±13.81 , N3 was 3.44±4.16 , N4 was 0.60±2.04 , REM was 2.14±3.79 , PSQI was 12.48±1.23 , ESS was 11.80±0.76 , TST (hr) was 5.19±0.74 , SPT(hr) was 6.58±0.77 , sleep efciency(%) was 52.50±27.16 , Latency (mint) was 22.79±30.85 , REM Latency (mints) was 96.99±151.86 ,and Microarousal index was 36.05±25.93 . To assess the potential impact of sleep quality via nocturnal polysomnography on severity of gastroesophageal reux , we performed correlations between the GERD questionnaire and nocturnal polysomnography reports . We observed that PSQI(r= -0.285, p<0.045) , ESS(r=0.206, p=0.05) , N1(r=0.202 , p>0.160) , N2(r=- 0.045 ,p>0.758) , N3(r=-0.079, p>0.583) , N4(r-0.209 ,p>0.145),REM(r=0.045 ,p>0.756) , TST(r=0.036 ,p>0.803), SPT(r=0.015,p>0.917) , Sleep Efciency (r=-0.113,p>0.435) , Sleep Latency (r=-0.045 ,p>0.756), REM Latency (r=0.165, p >0.253), Microarousal index (r=0.058 , p>0.683). Conclusions: Gastroesophageal reux disease and sleep disorders are extremely prevalent conditions, and it seems intuitive that there must be some overlap between the two. Sleep disorders may in fact be one of the most prevalent of the extraesophageal complications of GERD and often goes unrecognized.

scholarly journals Modelling Atmospheric Mineral Aerosol Chemistry to Predict Heterogeneous Photooxidation of SO<sub>2</sub>

2017 ◽  
Author(s):  
Zechen Yu ◽  
Myoseon Jang ◽  
Jiyeon Park
Keyword(s):  
Mineral Dust ◽  
Uv Light ◽  
Full Range ◽  
Saharan Dust ◽  
Dust Particles ◽  
Oh Radicals ◽  
Desorption Kinetics ◽  
So2 Oxidation ◽  
Photocatalytic Ability ◽  
Sulfate Formation

Abstract. The photocatalytic ability of airborne mineral dust particles is known to heterogeneously promote SO2 oxidation, but prediction of this phenomenon is not fully taken into account by current models. In this study, the Atmospheric Mineral Aerosol Reaction (AMAR) model was developed to capture the influence of air-suspended mineral dust particles on sulfate formation in various environments. In the model, SO2 oxidation proceeds in three phases including the gas phase, the inorganic-salted aqueous phase (non-dust phase), and the dust phase. Dust chemistry is described as the adsorption-desorption kinetics (gas-particle partitioning) of SO2 and NOx. The reaction of adsorbed SO2 on dust particles occurs via two major paths: autoxidation of SO2 in open air and photocatalytic mechanisms under UV light. The kinetic mechanism of autoxidation was first leveraged using controlled indoor chamber data in the presence of Arizona Test Dust (ATD) particles without UV light, and then extended to photochemistry. With UV light, SO2 photooxidation was promoted by surface oxidants (OH radicals) that are generated via the photocatalysis of semiconducting metal oxides (electron–hole theory) of ATD particles. This photocatalytic rate constant was derived from the integration of the combinational product of the dust absorbance spectrum and wave-dependent actinic flux for the full range of wavelengths of the light source. The predicted concentrations of sulfate and nitrate using the AMAR model agreed well with outdoor chamber data that were produced under natural sunlight. For seven consecutive hours of photooxidation of SO2 in an outdoor chamber, dust chemistry at the low NOx level was attributed to 70 % of total sulfate (60 ppb SO2, 290 μg m−3 ATD, and NOx less than 5 ppb). At high NOx (> 50 ppb of NOx with low hydrocarbons), sulfate formation was also greatly promoted by dust chemistry, but it was significantly suppressed by the competition between NO2 and SO2 that both consume the dust-surface oxidants (OH radicals or ozone). The AMAR model, derived in this study with ATD particles, will provide a platform for predicting sulfate formation in the presence of authentic dust particles (e.g. Gobi and Saharan dust).

scholarly journals The impact of diurnal variations of air traffic on contrail radiative forcing

2007 ◽  
Vol 7 (12) ◽  
pp. 3153-3162 ◽  
Author(s):  
N. Stuber ◽  
P. Forster
Keyword(s):  
Radiative Forcing ◽  
Western Europe ◽  
Analysis Data ◽  
Air Traffic ◽  
Diurnal Variations ◽  
Night Time ◽  
The North ◽  
Framework Programme Project ◽  
Sky Conditions ◽  
The Impact

Abstract. We combined high resolution aircraft flight data from the EU Fifth Framework Programme project AERO2k with analysis data from the ECMWF's integrated forecast system to calculate diurnally resolved 3-D contrail cover. We scaled the contrail cover in order to match observational data for the Bakan area (eastern-Atlantic/western-Europe). We found that less than 40% of the global distance travelled by aircraft is due to flights during local night time. Yet, due to the cancellation of shortwave and longwave effects during daytime, night time flights contribute a disproportional 60% to the global annual mean forcing. Under clear sky conditions the night flights contribute even more disproportionally at 76%. There are pronounced regional variations in night flying and the associated radiative forcing. Over parts of the North Atlantic flight corridor 75% of air traffic and 84% of the forcing occurs during local night, whereas only 35% of flights are during local night in South-East Asia, yet these contribute 68% of the radiative forcing. In general, regions with a significant local contrail radiative forcing are also regions for which night time flights amount to less than half of the daily total of flights. Therefore, neglecting diurnal variations in air traffic/contrail cover by assuming a diurnal mean contrail cover can over-estimate the global mean radiative forcing by up to 30%.

scholarly journals The Effects of Assimilating Conventional and ATOVS Data on Forecasted Near-Surface Wind with WRF-3DVAR

2015 ◽  
Vol 143 (1) ◽  
pp. 153-164 ◽  
Author(s):  
Feimin Zhang ◽  
Yi Yang ◽  
Chenghai Wang
Keyword(s):  
Data Assimilation ◽  
Surface Wind ◽  
Lower Atmosphere ◽  
Observation Data ◽  
Initial Field ◽  
Infrared Observation ◽  
Forecast Performance ◽  
Near Surface ◽  
The Impact ◽  
Positive Effect

Abstract In this paper, the Weather Research and Forecasting (WRF) Model with the three-dimensional variational data assimilation (WRF-3DVAR) system is used to investigate the impact on the near-surface wind forecast of assimilating both conventional data and Advanced Television Infrared Observation Satellite (TIROS) Operational Vertical Sounder (ATOVS) radiances compared with assimilating conventional data only. The results show that the quality of the initial field and the forecast performance of wind in the lower atmosphere are improved in both assimilation cases. Assimilation results capture the spatial distribution of the wind speed, and the observation data assimilation has a positive effect on near-surface wind forecasts. Although the impacts of assimilating ATOVS radiances on near-surface wind forecasts are limited, the fine structure of local weather systems illustrated by the WRF-3DVAR system suggests that assimilating ATOVS radiances has a positive effect on the near-surface wind forecast under conditions that ATOVS radiances in the initial condition are properly amplified. Assimilating conventional data is an effective approach for improving the forecast of the near-surface wind.

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