Geochemistry and geochronology of alkaline dykes from the Finero Phlogopite Peridotite (Ivrea-Verbano Zone): insights into the Triassic-Jurassic tectono-magmatic events of the Southern Alps

2021 ◽  
Author(s):  
Abimbola Chris Ogunyele ◽  
Tommaso Giovanardi ◽  
Mattia Bonazzi ◽  
Maurizio Mazzucchelli ◽  
Alberto Zanetti
Keyword(s):  
Continental Crust ◽  
Southern Alps ◽  
Coarse Grained ◽  
Dyke Swarm ◽  
Fine Grained ◽  
Sector Zoning ◽  
Magmatic Stage ◽  
Late Magmatic Stage ◽  
Mesozoic Magmatism ◽  
Peridotite Mantle

<p>The Ivrea-Verbano Zone (IVZ, westernmost sector of the Southern Alps) represents a unique opportunity to investigate the Paleozoic to Mesozoic geodynamic evolution of the Gondwana and Laurasia boundary from the perspective of the lower continental crust. Only recently, the petrochemical record of Triassic-Jurassic magmatism has been recognized. It mainly affected the northernmost tip, the Finero Complex, where the continental crust was tectonically thinned before opening of Alpine Tethys. However, the Mesozoic magmatism in the Finero Complex is still poorly-constrained. Firstly, its extent is largely unknown, because the mantle and crustal intrusives were already enriched by Paleozoic processes. Secondly, Mesozoic melts migration started when the Finero Complex was still placed at P-T conditions typical of a continental crust-mantle transition (1 GPa): this has promoted the reopening of the geochronological clocks in both Paleozoic and Mesozoic rocks, which usually provides wide time intervals. Lastly, the finding of Mesozoic magmatism as composite veins/pods and metasomatised layers has not allowed an exhaustive reconstruction of the primitive melts geochemistry. To place further constraints on such issue, a new dyke swarm cropping out in the Finero Phlogopite Peridotite mantle unit has been investigated. Dykes usually cut at high angle the mantle foliation and are up to 60 cm thick. They are composed by coarse-grained hornblendite to anorthosite, both phlogopite/biotite-bearing. Many dykes are composite, showing variable proportions of hornblendite and anorthosite. In places, the dyke swam was affected by volatiles overpressure as late magmatic stage, which produced plastic flow and development of a porphyroclastic structure by deformation of the early cumulates, with widespread segregation of a fine-grained mica matrix.</p><p>Dykes mainly consist of pargasite, phlogopite/biotite, albite (An 8-10), in association with apatite, monazite, ilmenite, zircon, Nb-rich oxides, carbonates. Enrichments in Fe (amphibole and biotite) and Na (plagioclase) suggest segregation from evolved melts, strongly enriched in H<sub>2</sub>O, P, C. The large LILE and LREE contents in amphiboles, sometimes associated to high Nb, Ta, Zr and Hf concentrations, as well as the mineral assemblage, support an alkaline affinity of the melts. The strongly positive εHf<sub>t </sub>(+10) of zircons and the isotopic Sr composition of amphiboles (0.7042) point to a derivation of the melts from mildly enriched sources, possibly located at the crust-mantle interface.</p><p>Zircons from anorthosite layers are mostly anhedral fragments. They show homogenous internal structure or sector zoning. Concordant <sup>206</sup>Pb/<sup>238</sup>U zircon ages vary from 221 ± 9 Ma to 192 ± 8 Ma. The results of this study confirm that mantle input to the Southern Alps magmatism was of alkaline affinity from Norian to Sinemurian. A widespread fluids circulation induced by such magmatism at high P-T conditions was likely the main cause of the diffuse geochronological reset towards Mesozoic ages of the northern IVZ.</p>

Pb–Zn occurrences and their Pb-isotopic signatures bearing on metallogeny and mineral exploration—Paleozoic sedimentary rocks, northern Appalachians, Quebec

1988 ◽  
Vol 25 (11) ◽  
pp. 1777-1790 ◽  
Author(s):  
K. Schrijver ◽  
E. Marcoux ◽  
G. Beaudoin ◽  
J. Y. Calvez
Keyword(s):  
Continental Crust ◽  
Mineral Exploration ◽  
Sedimentary Rocks ◽  
Isotope Ratios ◽  
Isotopic Signature ◽  
Coarse Grained ◽  
Pb Isotope ◽  
Isotopic Signatures ◽  
Fine Grained ◽  
Quartz Veins

Galena Pb-isotope ratios of epithermal vein and disseminated sulfide occurrences in the Taconian Orogen and Siluro-Devonian basin cluster around 17.90–18.05 for 206Pb/204Pb and 37.70–38.00 for 208Pb/204Pb. The major source of Pb in most, if not all, occurrences is a fairly common continental crust, a characteristic found in published analyses of Grenville feldspar Pb. A southwest to northeast increase in galena 206Pb/204Pb ratios is ascribed to the supply of several types of detritus from Grenville basement during the Cambro-Ordovician: coarse-grained, K-feldspar-bearing in the southwest, grading into fine-grained phyllitic, and relatively more highly radiogenic in the northeast.Emplacement (i) of Pb–Zn–barite veins and disseminations, commonly of homogeneous crustal Pb-isotopic signature, was late Taconian; (ii) of Pb–Zn–quartz veins, of less homogeneous signature, was post-Taconian; and (iii) of Pb–Zn–carbonate veins, relatively highly radiogenic and commonly homogeneous, was late or post-Acadian. Signatures of the first-mentioned group seem to be most useful in exploration.

scholarly journals Agpaitic Alkaline Rocks in Southern Brazilian Platform: A Review

Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 934
Author(s):  
Celso de Barros Gomes ◽  
Rogério Guitarrari Azzone ◽  
Gaston Eduardo Enrich Rojas ◽  
Vincenza Guarino ◽  
Excelso Ruberti
Keyword(s):  
South America ◽  
General Information ◽  
Early Triassic ◽  
Southern Brazil ◽  
Fine Grained ◽  
Mineral Assemblages ◽  
Magmatic Stage ◽  
Poços De Caldas ◽  
Late Magmatic Stage ◽  
Alkaline Massif

General information is presented on ten agpaitic occurrences located in southern Brazil and at the border between Brazil and Paraguay. All the Brazilian agpaitic rocks are Late Cretaceous in age, whereas the Paraguayan ones are older than Early Triassic. The most significant occurrence is Poços de Caldas, the largest alkaline massif in South America. In general, these agpaitic rocks contain mineral assemblages that indicate presence of typical halogen-bearing Na–Ca–HFSE phases, eudialyte-, rinkite- and wöhlerite-group minerals being the most frequent ones. However, these associations are indeed more complex in terms of composition, with accessory phases in some cases consisting of various minerals, including U–Th oxides/silicates, Nb oxides, REE–Sr–Ba bearing carbonates–fluorocarbonates–phosphates–silicates and Zr–Na rich silicates. They usually form late magmatic stage to hydrothermal/deuteric assemblages linked with coarse and fine-grained, mainly silica-undersaturated evolved rocks. Data also indicate significant differences in type, amount and composition of agpaitic minerals in all investigated occurrences.

scholarly journals Petrology and geochemistry of granitoids and their mafic micogranular enclaves (MME) in marginal part of the Małopolska Block (S Poland)

Mineralogia ◽  
2012 ◽  
Vol 43 (1-2) ◽  
pp. 3-127 ◽  
Author(s):  
Anna Wolska
Keyword(s):  
Trace Elements ◽  
Continental Crust ◽  
Coarse Grained ◽  
Granitic Rocks ◽  
Mixing Process ◽  
Na2o Content ◽  
Fine Grained ◽  
Małopolska Block ◽  
First Time ◽  
Different Sources

AbstractGranitic plutons (the Dolina Będkowska valley and Pilica area) were found in a few boreholes in the Małopolska Block (MB). These granitic rocks may represent apical parts (apophyses) of a great magmatic bodies (batholiths) located in deeper level of the Ediacaran/Paleozoic basement. They are described as ‘stitching intrusions’, generated during/after collision in Carboniferous/Permian period (~300 Ma) between the Upper Silesian Block (USB) and the Małopolska Block (MB).These rocks are fresh, unaltered granodiorites that are pale grey in colour. They have holocrystalline, medium- to coarse-grained structure and massive texture. For the first time, several mafic microgranular enclaves (MME), varying in size and colour, were found in the granodioritic host (HG). The occurrence of MME in the host granodioritic rocks is evidence of a mingling process between mafic and felsic magmas.The MME are pale/dark grey in colour, fine-grained rocks with ‘porphyritic’ textures. They consist of large megacrysts/xenocrysts of plagioclase, quartz, alkali feldspars and the fine-grained groundmass of pseudo-doleritic textures (lath-shaped plagioclases, blade-shaped amphiboles/biotites). According to their modal/mineral composition, they represent Q-diorites and tonalites.The MME, similar to the host granodiorites (HG), are I-type rocks, exhibit high Na2O content >3.2 wt%; normative diopside or normative corundum occurs (mainly <1%). They are metaluminous to slightly peraluminous (ASI <1.1) and have calc-alkaline, medium-K to high-K character. They generally belong to magnesian series (#Mg=0.20-0.40) and have low agpaitic index (<0.87). They are low evolved magmatic rocks. The rocks studied are enriched in LREEs (La, Ce, Sm) compared to HREEs. The Eu* negative anomaly and high Sr contents point to varying degrees of plagioclase fractionation connected to the mixing process rather than simple fractional crystallization. Both rocks studied (HG and MME) are characterized by a high content of LILEs (K, Ba, Rb) in normalized patterns and a low HFS/LIL elements ratio (Ta, Nb)/(K, Rb, La). The projection points of the rocks studied plot in different fields of various petrochemical diagrams: mainly in the arc granites that are rare in the pre-collisional granites as well as the syn-subductional to post-collisional granites fields.For the first time, inner textures in rock-forming minerals related to mixing processes are described both in the granodioritic host (HG) and in the MME. Mantled boxy cellular plagioclase megacrysts with ‘old cores’ of labradorite composition, and amphibole aggregates with titanite and opaque minerals, represent peritectic rather than primary residual minerals. The plagioclase, quartz and alkali feldspar megacrysts/xenocrysts were mechanically transferred from the granodioritic host (HG) to MME. The presence of lath-shaped plagioclases, blade-shaped amphiboles/biotites and acicular-shaped apatites in the groundmass of the MME is evidence of undercooling of hot mafic blobs in a relatively cold granodioritic magma chamber. The MME were hybridized by leucocratic melt squeezed from the granodioritic magma in a later stage of the mixing process (quartz and alkali crystals in the interstices in the MME groundmass). In the granodiorites (HG), the spike and spongy cellular zones as well as biotite/amphibole zones in plagioclase megacrysts are connected to the mixing process.Both of the rocks studied are characterized by different amounts of major elements (SiO2, Na2O and K2O), trace elements (Ni, Cr, V, Ti and P), #Mg and modified alkali-lime index (MALI) that is related to their origins from different sources. On the other hand, they have similar chondrite-normalized patterns (for trace elements and REE), LILEs contents (Sr, Ba, Rb), aluminum saturation index (ASI) and isotopic signatures (high 86Sr/87Sr (0.079-0.713) and low 143Nd/144Nd (0.512) values but lower than in continental crust), which are evidence of the strong hybridisation of mafic enclaves by the granodioritic host magma. The parental rocks of both rocks studied have a similar mafic signature but were generated in different sources: the host granodiorites (HG) magma in lower continental crust rocks, and the MME magma in enriched upper mantle. The MME crystallized from strongly hybridized magma of intermediate compositions (Q-diorite, tonalite) rather than from primary mafic magma. The host granodiorites (HG) originated from completely homogenized crustal granodioritic magma which inherited its geochemical signature from ancient arc-rocks in a subduction-related setting

U–Pb age of the Seal Lake Group, Labrador: relationship to Mesoproterozoic extension-related magmatism of Laurasia

1995 ◽  
Vol 32 (9) ◽  
pp. 1401-1410 ◽  
Author(s):  
R. L. Romer ◽  
U. Schärer ◽  
R. J. Wardle ◽  
D. H. C. Wilton
Keyword(s):  
Volcanic Rocks ◽  
Coarse Grained ◽  
Dyke Swarm ◽  
Olivine Gabbro ◽  
Lake Area ◽  
Bed Sediments ◽  
Fine Grained ◽  
Younger Age ◽  
Dyke Swarms ◽  
Red Bed

The Seal Lake Group of eastern Labrador unconformably overlies the 1273 ± 1 Ma (2σ) Harp Dyke Swarm. In its lower parts, the Seal Lake Group includes conglomerates, quartzites, and red-bed sediments, and both the lower and middle parts are intruded by olivine gabbro sills. This magmatism was coeval with the emplacement of basaltic volcanic rocks in the middle and upper sections of the Seal Lake Group. Two different gabbro varieties yield baddeleyite and zircon U–Pb ages of [Formula: see text] Ma and [Formula: see text] Ma, respectively. The older age corresponds to the emplacement of a fine- to medium-grained voluminous olivine gabbro, whereas the younger age was obtained on a coarse-grained gabbro that intrudes the fine-grained gabbro. These ages place magmatism in the Seal Lake area in the ca. 1270–1220 Ma phase of extension-related magmatism of Laurentia and Baltica that was associated with voluminous mafic dyke swarms. Such extension-related mafic Mesoproterozoic magmatism occurs on both cratons during three distinct intervals at 1460–1420, 1270–1220, and 1180–1070 Ma, respectively, suggesting that Laurentia and Baltica formed a coherent unit until at least 1180 Ma.

Correlation between dislocation, grain boundary and interface of duplex SS in stress corrosion cracking(SCC)

1990 ◽  
Vol 48 (4) ◽  
pp. 928-929
Author(s):  
Wang Zheng-fang ◽  
Z.F. Wang
Keyword(s):  
Stainless Steel ◽  
Thermal Cycle ◽  
Secondary Phase ◽  
Corrosion Cracking ◽  
Coarse Grained ◽  
Test Environment ◽  
Fine Grained ◽  
Evaluation Test ◽  
Welding Thermal Cycle ◽  
Micro Analysis

The main purpose of this study highlights on the evaluation of chloride SCC resistance of the material,duplex stainless steel,OOCr18Ni5Mo3Si2 (18-5Mo) and its welded coarse grained zone(CGZ).18-5Mo is a dual phases (A+F) stainless steel with yield strength:512N/mm2 .The proportion of secondary Phase(A phase) accounts for 30-35% of the total with fine grained and homogeneously distributed A and F phases(Fig.1).After being welded by a specific welding thermal cycle to the material,i.e. Tmax=1350°C and t8/5=20s,microstructure may change from fine grained morphology to coarse grained morphology and from homogeneously distributed of A phase to a concentration of A phase(Fig.2).Meanwhile,the proportion of A phase reduced from 35% to 5-10°o.For this reason it is known as welded coarse grained zone(CGZ).In association with difference of microstructure between base metal and welded CGZ,so chloride SCC resistance also differ from each other.Test procedures:Constant load tensile test(CLTT) were performed for recording Esce-t curve by which corrosion cracking growth can be described, tf,fractured time,can also be recorded by the test which is taken as a electrochemical behavior and mechanical property for SCC resistance evaluation. Test environment:143°C boiling 42%MgCl2 solution is used.Besides, micro analysis were conducted with light microscopy(LM),SEM,TEM,and Auger energy spectrum(AES) so as to reveal the correlation between the data generated by the CLTT results and micro analysis.

scholarly journals Balanced Sparsity for Efficient DNN Inference on GPU

2019 ◽  
Vol 33 ◽  
pp. 5676-5683 ◽  
Author(s):  
Zhuliang Yao ◽  
Shijie Cao ◽  
Wencong Xiao ◽  
Chen Zhang ◽  
Lanshun Nie
Keyword(s):  
Deep Neural Networks ◽  
General Purpose ◽  
Coarse Grained ◽  
Efficient Computation ◽  
Model Accuracy ◽  
Sparse Model ◽  
Model Inference ◽  
Fine Grained ◽  
Practical Inference ◽  
Speed Up

In trained deep neural networks, unstructured pruning can reduce redundant weights to lower storage cost. However, it requires the customization of hardwares to speed up practical inference. Another trend accelerates sparse model inference on general-purpose hardwares by adopting coarse-grained sparsity to prune or regularize consecutive weights for efficient computation. But this method often sacrifices model accuracy. In this paper, we propose a novel fine-grained sparsity approach, Balanced Sparsity, to achieve high model accuracy with commercial hardwares efficiently. Our approach adapts to high parallelism property of GPU, showing incredible potential for sparsity in the widely deployment of deep learning services. Experiment results show that Balanced Sparsity achieves up to 3.1x practical speedup for model inference on GPU, while retains the same high model accuracy as finegrained sparsity.

scholarly journals Submarine lava deltas of the 2018 eruption of Kīlauea volcano

2021 ◽  
Vol 83 (4) ◽  
Author(s):  
S. Adam Soule ◽  
Michael Zoeller ◽  
Carolyn Parcheta
Keyword(s):  
Grain Size ◽  
Pore Pressure ◽  
Mechanistic Model ◽  
Large Fraction ◽  
Volcanic Hazards ◽  
Lava Flows ◽  
Coarse Grained ◽  
Fine Grained ◽  
Fine Grain ◽  
Delta Formation

AbstractHawaiian and other ocean island lava flows that reach the coastline can deposit significant volumes of lava in submarine deltas. The catastrophic collapse of these deltas represents one of the most significant, but least predictable, volcanic hazards at ocean islands. The volume of lava deposited below sea level in delta-forming eruptions and the mechanisms of delta construction and destruction are rarely documented. Here, we report on bathymetric surveys and ROV observations following the Kīlauea 2018 eruption that, along with a comparison to the deltas formed at Pu‘u ‘Ō‘ō over the past decade, provide new insight into delta formation. Bathymetric differencing reveals that the 2018 deltas contain more than half of the total volume of lava erupted. In addition, we find that the 2018 deltas are comprised largely of coarse-grained volcanic breccias and intact lava flows, which contrast with those at Pu‘u ‘Ō‘ō that contain a large fraction of fine-grained hyaloclastite. We attribute this difference to less efficient fragmentation of the 2018 ‘a‘ā flows leading to fragmentation by collapse rather than hydrovolcanic explosion. We suggest a mechanistic model where the characteristic grain size influences the form and stability of the delta with fine grain size deltas (Pu‘u ‘Ō‘ō) experiencing larger landslides with greater run-out supported by increased pore pressure and with coarse grain size deltas (Kīlauea 2018) experiencing smaller landslides that quickly stop as the pore pressure rapidly dissipates. This difference, if validated for other lava deltas, would provide a means to assess potential delta stability in future eruptions.

scholarly journals A cooperative DDoS attack detection scheme based on entropy and ensemble learning in SDN

2021 ◽  
Vol 2021 (1) ◽  
Author(s):  
Shanshan Yu ◽  
Jicheng Zhang ◽  
Ju Liu ◽  
Xiaoqing Zhang ◽  
Yafeng Li ◽  
...  
Keyword(s):  
Ensemble Learning ◽  
Denial Of Service ◽  
Attack Detection ◽  
Coarse Grained ◽  
Communication Overhead ◽  
Detection Scheme ◽  
Fine Grained ◽  
Ddos Attack ◽  
Network Status ◽  
Ddos Attack Detection

AbstractIn order to solve the problem of distributed denial of service (DDoS) attack detection in software-defined network, we proposed a cooperative DDoS attack detection scheme based on entropy and ensemble learning. This method sets up a coarse-grained preliminary detection module based on entropy in the edge switch to monitor the network status in real time and report to the controller if any abnormality is found. Simultaneously, a fine-grained precise attack detection module is designed in the controller, and a ensemble learning-based algorithm is utilized to further identify abnormal traffic accurately. In this framework, the idle computing capability of edge switches is fully utilized with the design idea of edge computing to offload part of the detection task from the control plane to the data plane innovatively. Simulation results of two common DDoS attack methods, ICMP and SYN, show that the system can effectively detect DDoS attacks and greatly reduce the southbound communication overhead and the burden of the controller as well as the detection delay of the attacks.

Rheology of hydrocarbon gels

1950 ◽  
Vol 200 (1061) ◽  
pp. 183-188 ◽  
Keyword(s):  
Mechanical Properties ◽  
Experimental Measurement ◽  
Theoretical Basis ◽  
Continuous Media ◽  
Point Of View ◽  
Coarse Grained ◽  
Testing Instrument ◽  
Fine Grained ◽  
Mineral Oils ◽  
Space And Time

Hydrocarbon gels contain a number of materials, such as rubber, greases, saponified mineral oils, etc., of great interest for various engineering purposes. Specific requirements in mechanical properties have been met by producing gels in appropriately chosen patterns of constituent components of visible, colloidal, molecular and atomic sizes, ranging from coarse-grained aggregates, represented by sponges, foams, emulsions, etc.; to fine-grained and apparently homogeneous ones, represented by optically clear compounds. The engineer who has to deal with the whole range of such materials will adopt a macroscopic point of view, based on an apparent continuity of all the material structures and of the distributions in space and time of the displacements and forces occurring under mechanical actions. It has been possible to determine these distributions in the framework of a comprehensive scheme in which the fundamental principles of the mechanics of continuous media provide the theoretical basis, and a testing instrument of new design, termed Rheogoniometer, the means of experimental measurement (Weissenberg 1931, 1934, 1946, 1947, 1948).

Microstructural Refinement in a Commercial Aluminum Alloy Processed by ECAP Using a Die Channel Angle of 110 Degrees

2015 ◽  
Vol 1114 ◽  
pp. 3-8
Author(s):  
Nicolae Şerban ◽  
Doina Răducanu ◽  
Nicolae Ghiban ◽  
Vasile Dănuţ Cojocaru
Keyword(s):  
Grain Refinement ◽  
Cross Section ◽  
High Strength ◽  
Secondary Phase ◽  
Coarse Grained ◽  
Metallographic Analysis ◽  
Second Phase ◽  
Channel Angle ◽  
Ambient Temperatures ◽  
Fine Grained

The properties of ultra-fine grained materials are superior to those of corresponding conventional coarse grained materials, being significantly improved as a result of grain refinement. Equal channel angular pressing (ECAP) is an efficient method for modifying the microstructure by refining grain size via severe plastic deformation (SPD) in producing ultra-fine grained materials (UFG) and nanomaterials (NM). The grain sizes produced by ECAP processing are typically in the submicrometer range and this leads to high strength at ambient temperatures. ECAP is performed by pressing test samples through a die containing two channels, equal in cross-section and intersecting at a certain angle. The billet experiences simple shear deformation at the intersection, without any precipitous change in the cross-section area because the die prevents lateral expansion and therefore the billet can be pressed more than once and it can be rotated around its pressing axis during subsequent passes. After ECAP significant grain refinement occurs together with dislocation strengthening, resulting in a considerable enhancement in the strength of the alloys. A commercial AlMgSi alloy (AA6063) was investigated in this study. The specimens were processed for a number of passes up to nine, using a die channel angle of 110°, applying the ECAP route BC. After ECAP, samples were cut from each specimen and prepared for metallographic analysis. The microstructure of the ECAP-ed and as-received material was investigated using optical (OLYMPUS – BX60M) and SEM microscopy (TESCAN VEGA II – XMU). It was determined that for the as-received material the microstructure shows a rough appearance, with large grains of dendritic or seaweed aspect and with a secondary phase at grain boundaries (continuous casting structure). For the ECAP processed samples, the microstructure shows a finished aspect, with refined, elongated grains, also with crumbled and uniformly distributed second phase particles after a typical ECAP texture.

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