scholarly journals Modelling the High Mercury Wet deposition in the Southeastern US by WRF-GC

2022 ◽  
Author(s):  
Xiaotian Xu ◽  
Xu Feng ◽  
Haipeng Lin ◽  
Peng Zhang ◽  
Shaojian Huang ◽  
...  
Keyword(s):  
United States ◽  
Wet Deposition ◽  
Deep Convection ◽  
Southeastern United States ◽  
Convective Precipitation ◽  
Mercury Deposition ◽  
Southeastern Us ◽  
Different Types ◽  
High Mercury ◽  
Simulation Results

Abstract. High mercury wet deposition in southeastern United States has been noticed for many years. Previous studies came up with a theory that it was associated with high-altitude divalent mercury scavenged by convective precipitation. Given the coarse resolution of previous models (e.g. GEOS-Chem), this theory is still not fully tested. Here we employed a newly developed WRF-GEOS-Chem (WRF-GC) model implemented with mercury simulation. We conduct extensive model benchmarking by comparing WRF-GC with different resolutions (from 50 km to 25 km) to GEOS-Chem output (4° × 5°) and data from Mercury Deposition Network (MDN) in July–September 2013. The comparison of mercury wet deposition from two models both present high mercury wet deposition in southeastern United States. We divided simulation results by heights, different types of precipitation and combination of these two variations together and find most of mercury wet deposition concentrates on higher space and caused by convective precipitation. Therefore, we conclude that it is the deep convection caused enhanced mercury wet deposition in the southeastern United States.

scholarly journals Public entrepreneurs and the adoption of broad-based merit aid beyond the Southeastern United States

2013 ◽  
Vol 21 ◽  
pp. 58
Author(s):  
William Kyle Ingle ◽  
Ruth Ann Petroff
Keyword(s):  
United States ◽  
Diffusion Theory ◽  
Full Range ◽  
Southeastern United States ◽  
Merit Aid ◽  
Theoretical Frameworks ◽  
Southeastern Us ◽  
Public Colleges And Universities ◽  
Aid Programs ◽  
K 12

The concentration of broad-based merit aid adoption in the southeastern United States has been well noted in the literature. However, there are states that have adopted broad-based merit aid programs outside of the Southeast.  Guided by multiple theoretical frameworks, including innovation diffusion theory (e.g., Gray, 1973, 1994; Rogers, 2003), Roberts and King’s (1991) typology of public entrepreneurs, and Anderson’s (2003) stages of the policymaking process, this qualitative study sought to answer the following questions. First, in the absence of regional diffusion pressures, what internal determinants are reported as accounting for the diffusion of broad-based merit aid programs outside of the Southeastern US?  What types of public entrepreneurs were identified as playing key roles in establishing merit aid in states outside the southeastern US?  During which stages of the policymaking process were they active? We found that merit aid was a means of addressing an array of public problems, including low college going rates at in-state public colleges and universities, and weak K-12 accountability. Consistent factors reported as facilitating merit aid creation included a strong, vocal public advocate (governors and a university system president) and a desire to strengthen state economies and diversify workforces.  A full range of public entrepreneurs played key roles in developing merit aid in the sampled states. Political and executive entrepreneurs were in the forefront of merit aid efforts, but our data suggest that a cast of supporting public entrepreneurs were integral to the eventual adoption of broad-based merit aid in the sampled states.

scholarly journals Model analyses of atmospheric mercury: present air quality and effects of transpacific transport on the United States

2013 ◽  
Vol 13 (4) ◽  
pp. 9849-9893 ◽  
Author(s):  
H. Lei ◽  
X.-Z. Liang ◽  
D. J. Wuebbles ◽  
Z. Tao
Keyword(s):  
United States ◽  
Air Quality ◽  
Wet Deposition ◽  
Total Mercury ◽  
The United States ◽  
Atmospheric Mercury ◽  
Anthropogenic Sources ◽  
Mercury Deposition ◽  
Transpacific Transport ◽  
Mercury Cycle

Abstract. Atmospheric mercury is a toxic air and water pollutant that is of significant concern because of its effects on human health and ecosystems. A mechanistic representation of the atmospheric mercury cycle is developed for the state-of-the-art global climate-chemistry model, CAM-Chem (Community Atmospheric Model with Chemistry). The model simulates the emission, transport, transformation and deposition of atmospheric mercury (Hg) in three forms: elemental mercury (Hg(0)), reactive mercury (Hg(II)), and particulate mercury (PHg). Emissions of mercury include those from human, land, ocean, biomass burning and volcano related sources. Land emissions are calculated based on surface solar radiation flux and skin temperature. A simplified air–sea mercury exchange scheme is used to calculate emissions from the oceans. The chemistry mechanism includes the oxidation of Hg(0) in gaseous phase by ozone with temperature dependence, OH, H2O2 and chlorine. Aqueous chemistry includes both oxidation and reduction of Hg(0). Transport and deposition of mercury species are calculated through adapting the original formulations in CAM-Chem. The CAM-Chem model with mercury is driven by present meteorology to simulate the present mercury air quality during the 1999–2001 periods. The resulting surface concentrations of total gaseous mercury (TGM) are then compared with the observations from worldwide sites. Simulated wet depositions of mercury over the continental United States are compared to the observations from 26 Mercury Deposition Network stations to test the wet deposition simulations. The evaluations of gaseous concentrations and wet deposition confirm a strong capability for the CAM-Chem mercury mechanism to simulate the atmospheric mercury cycle. The results also indicate that mercury pollution in East Asia and Southern Africa is very significant with TGM concentrations above 3.0 ng m−3. The comparison to wet deposition indicates that wet deposition patterns of mercury are more affected by the spatial variability of precipitation. The sensitivity experiments show that 22% of total mercury deposition and 25% of TGM concentrations in the United States are resulted from domestic anthropogenic sources, but only 9% of total mercury deposition and 7% of TGM concentrations are contributed by transpacific transport. However, the contributions of domestic and transpacific sources on the western United States levels of mercury are of comparable magnitude.

scholarly journals Improving Numerical Weather Predictions of Summertime Precipitation over the Southeastern United States through a High-Resolution Initialization of the Surface State

2011 ◽  
Vol 26 (6) ◽  
pp. 785-807 ◽  
Author(s):  
Jonathan L. Case ◽  
Sujay V. Kumar ◽  
Jayanthi Srikishen ◽  
Gary J. Jedlovec
Keyword(s):  
United States ◽  
Soil Moisture ◽  
High Resolution ◽  
Land Surface ◽  
Weather Prediction ◽  
Southeastern United States ◽  
Model Verification ◽  
Sea Surface ◽  
Convective Precipitation ◽  
Numerical Weather

Abstract It is hypothesized that high-resolution, accurate representations of surface properties such as soil moisture and sea surface temperature are necessary to improve simulations of summertime pulse-type convective precipitation in high-resolution models. This paper presents model verification results of a case study period from June to August 2008 over the southeastern United States using the Weather Research and Forecasting numerical weather prediction model. Experimental simulations initialized with high-resolution land surface fields from the National Aeronautics and Space Administration’s (NASA) Land Information System (LIS) and sea surface temperatures (SSTs) derived from the Moderate Resolution Imaging Spectroradiometer (MODIS) are compared to a set of control simulations initialized with interpolated fields from the National Centers for Environmental Prediction’s (NCEP) 12-km North American Mesoscale model. The LIS land surface and MODIS SSTs provide a more detailed surface initialization at a resolution comparable to the 4-km model grid spacing. Soil moisture from the LIS spinup run is shown to respond better to the extreme rainfall of Tropical Storm Fay in August 2008 over the Florida peninsula. The LIS has slightly lower errors and higher anomaly correlations in the top soil layer but exhibits a stronger dry bias in the root zone. The model sensitivity to the alternative surface initial conditions is examined for a sample case, showing that the LIS–MODIS data substantially impact surface and boundary layer properties. The Developmental Testbed Center’s Meteorological Evaluation Tools package is employed to produce verification statistics, including traditional gridded precipitation verification and output statistics from the Method for Object-Based Diagnostic Evaluation (MODE) tool. The LIS–MODIS initialization is found to produce small improvements in the skill scores of 1-h accumulated precipitation during the forecast hours of the peak diurnal convective cycle. Because there is very little union in time and space between the forecast and observed precipitation systems, results from the MODE object verification are examined to relax the stringency of traditional gridpoint precipitation verification. The MODE results indicate that the LIS–MODIS-initialized model runs increase the 10 mm h−1 matched object areas (“hits”) while simultaneously decreasing the unmatched object areas (“misses” plus “false alarms”) during most of the peak convective forecast hours, with statistically significant improvements of up to 5%. Simulated 1-h precipitation objects in the LIS–MODIS runs more closely resemble the observed objects, particularly at higher accumulation thresholds. Despite the small improvements, however, the overall low verification scores indicate that much uncertainty still exists in simulating the processes responsible for airmass-type convective precipitation systems in convection-allowing models.

scholarly journals Impact of lightning-NO on Eastern United States photochemistry during the summer of 2006 as determined using the CMAQ model

2011 ◽  
Vol 11 (6) ◽  
pp. 17699-17757 ◽  
Author(s):  
D. J. Allen ◽  
K. E. Pickering ◽  
R. W. Pinder ◽  
B. H. Henderson ◽  
K. W. Appel ◽  
...  
Keyword(s):  
United States ◽  
Air Quality ◽  
Wet Deposition ◽  
Surface Ozone ◽  
Convective Precipitation ◽  
Eastern United States ◽  
Ozone Monitoring Instrument ◽  
Monitoring Instrument ◽  
Ozone Monitoring ◽  
The Impact

Abstract. A lightning-nitrogen oxide (NO) algorithm is developed for the regional Community Multiscale Air Quality Model (CMAQ) and used to evaluate the impact of lightning-NO emissions (LNOx) on tropospheric photochemistry over the Eastern United States during the summer of 2006. The scheme assumes flash rates are proportional to the model convective precipitation rate but then adjusts the flash rates locally to match monthly average observations. Over the Eastern United States, LNOx is responsible for 20–25 % of the tropospheric nitrogen dioxide (NO2) column. This additional NO2 reduces the low-bias of simulated NO2 columns with respect to satellite-retrieved Dutch Ozone Monitoring Instrument NO2 (DOMINO) columns from 41 to 14 %. It also adds 10–20 ppbv to upper tropospheric ozone and 1.5–4.5 ppbv to 8-h maximum surface layer ozone, although, on average, the contribution of LNOx to surface ozone is 1–2 ppbv less on poor air quality days. Biases between modeled and satellite-retrieved tropospheric NO2 columns vary greatly between urban and rural locations. In general, CMAQ overestimates columns at urban locations and underestimates columns at rural locations. These biases are consistent with in situ measurements that also indicate that CMAQ has too much NO2 in urban regions and not enough in rural regions. However, closer analysis suggests that most of the differences between modeled and satellite-retrieved urban to rural ratios are likely a consequence of the horizontal and vertical smoothing inherent in columns retrieved by the Ozone Monitoring Instrument (OMI). Within CMAQ, LNOx increases wet deposition of nitrate by 50 % and total deposition of nitrogen by 11 %. This additional deposition reduces the magnitude of the CMAQ low-bias in nitrate wet deposition with respect to National Atmospheric Deposition monitors to near zero. In order to obtain an upper bound on the contribution of uncertainties in chemistry to upper tropospheric NOx low biases, sensitivity calculations with updated chemistry were run for the time period of the Intercontinental Chemical Transport Experiment (INTEX-A) field campaign (summer 2004). After adjusting for possible interferences in NO2 measurements and averaging over the entire campaign, these updates reduced 7–9 km biases from 32 to 17 % and 9–12 km biases from 57 to 46 %. While these changes lead to better agreement, a considerable NO2 low-bias remains in the uppermost troposphere.

Scanning electron microscopy of three types of ectomycorrhizae formed on Eucalyptus nova-anglica in the southeastern United States

1981 ◽  
Vol 59 (5) ◽  
pp. 683-688 ◽  
Author(s):  
R. W. Rose Jr. ◽  
C. Gerald Van Dyke ◽  
C. B. Davey
Keyword(s):  
Electron Microscopy ◽  
United States ◽  
Scanning Electron Microscopy ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Southeastern United States ◽  
The Other ◽  
Cenococcum Geophilum ◽  
Different Types ◽  
Scanning Electron

Three different types of ectomycorrhizae found in the Southeastern United States on Eucalyptus nova-anglica and identified as being formed by Cenococcum geophilum, Pisolithus tinctorius, and Scleroderma geaster were examined with a scanning electron microscope (SEM). In overall appearance the three types of mycorrhizae could be distinguished easily from each other, particularly C. geophilum, which had a relatively smooth, undulate surface in comparison with the other two types. Detailed descriptions and comparisons of these ectomycorrhizae are given and the value of SEM in characterizing ectomycorrhizae is discussed

scholarly journals Aerosol optical properties in the southeastern United States in summer – Part 2: Sensitivity of aerosol optical depth to relative humidity and aerosol parameters

2016 ◽  
Vol 16 (8) ◽  
pp. 5009-5019 ◽  
Author(s):  
Charles A. Brock ◽  
Nicholas L. Wagner ◽  
Bruce E. Anderson ◽  
Andreas Beyersdorf ◽  
Pedro Campuzano-Jost ◽  
...  
Keyword(s):  
United States ◽  
Refractive Index ◽  
Relative Humidity ◽  
Aerosol Optical Depth ◽  
Optical Depth ◽  
Mixed Boundary ◽  
Southeastern United States ◽  
Geometric Standard Deviation ◽  
Aerosol Mass ◽  
Southeastern Us

Abstract. Aircraft observations of meteorological, trace gas, and aerosol properties were made between May and September 2013 in the southeastern United States (US). Regionally representative aggregate vertical profiles of median and interdecile ranges of the measured parameters were constructed from 37 individual aircraft profiles made in the afternoon when a well-mixed boundary layer with typical fair-weather cumulus was present (Wagner et al., 2015). We use these 0–4 km aggregate profiles and a simple model to calculate the sensitivity of aerosol optical depth (AOD) to changes in dry aerosol mass, relative humidity, mixed-layer height, the central diameter and width of the particle size distribution, hygroscopicity, and dry and wet refractive index, while holding the other parameters constant. The calculated sensitivity is a result of both the intrinsic sensitivity and the observed range of variation in these parameters. These observationally based sensitivity studies indicate that the relationship between AOD and dry aerosol mass in these conditions in the southeastern US can be highly variable and is especially sensitive to relative humidity (RH). For example, calculated AOD ranged from 0.137 to 0.305 as the RH was varied between the 10th and 90th percentile profiles with dry aerosol mass held constant. Calculated AOD was somewhat less sensitive to aerosol hygroscopicity, mean size, and geometric standard deviation, σg. However, some chemistry–climate models prescribe values of σg substantially larger than we or others observe, leading to potential high biases in model-calculated AOD of  ∼  25 %. Finally, AOD was least sensitive to observed variations in dry and wet aerosol refractive index and to changes in the height of the well-mixed surface layer. We expect these findings to be applicable to other moderately polluted and background continental air masses in which an accumulation mode between 0.1–0.5 µm diameter dominates aerosol extinction.

scholarly journals Aerosol optical properties in the southeastern United States in summer – Part 1: Hygroscopic growth

2015 ◽  
Vol 15 (18) ◽  
pp. 25695-25738 ◽  
Author(s):  
C. A. Brock ◽  
N. L. Wagner ◽  
B. E. Anderson ◽  
A. R. Attwood ◽  
A. Beyersdorf ◽  
...  
Keyword(s):  
United States ◽  
Layer Structure ◽  
Southeastern United States ◽  
Field Studies ◽  
Hygroscopic Growth ◽  
Particle Volume ◽  
Aerosol Composition ◽  
Optical Extinction ◽  
Airborne Measurements ◽  
Southeastern Us

Abstract. Aircraft observations of meteorological, trace gas, and aerosol properties were made during May–September 2013 in the southeastern United States (US) under fair-weather, afternoon conditions with well-defined planetary boundary layer structure. Optical extinction at 532 nm was directly measured at three relative humidities and compared with extinction calculated from measurements of aerosol composition and size distribution using the κ-Köhler approximation for hygroscopic growth. Using this approach, the hygroscopicity parameter κ for the organic fraction of the aerosol must have been < 0.10 to be consistent with 75 % of the observations within uncertainties. This subsaturated κ value for the organic aerosol in the southeastern US is consistent with several field studies in rural environments. We present a new parameterization of the change in aerosol extinction as a function of relative humidity that better describes the observations than does the widely used power-law (gamma, γ) parameterization. This new single-parameter κext formulation is based upon κ-Köhler and Mie theories and relies upon the well-known approximately linear relationship between particle volume (or mass) and optical extinction (Charlson et al., 1967). The fitted parameter, κext, is nonlinearly related to the chemically derived κ parameter used in κ-Köhler theory. The values of κext we determined from airborne measurements are consistent with independent observations at a nearby ground site.

scholarly journals Supplementary material to "Modelling the High Mercury Wet deposition in the Southeastern US by WRF-GC"

2022 ◽  
Author(s):  
Xiaotian Xu ◽  
Xu Feng ◽  
Haipeng Lin ◽  
Peng Zhang ◽  
Shaojian Huang ◽  
...  
Keyword(s):  
Wet Deposition ◽  
Southeastern Us ◽  
High Mercury ◽  
Supplementary Material

scholarly journals Aerosol optical properties in the southeastern United States in summer – Part 1: Hygroscopic growth

2016 ◽  
Vol 16 (8) ◽  
pp. 4987-5007 ◽  
Author(s):  
Charles A. Brock ◽  
Nicholas L. Wagner ◽  
Bruce E. Anderson ◽  
Alexis R. Attwood ◽  
Andreas Beyersdorf ◽  
...  
Keyword(s):  
United States ◽  
Boundary Layer ◽  
Planetary Boundary Layer ◽  
Layer Structure ◽  
Southeastern United States ◽  
Organic Aerosol ◽  
Hygroscopic Growth ◽  
Aerosol Composition ◽  
Optical Extinction ◽  
Southeastern Us

Abstract. Aircraft observations of meteorological, trace gas, and aerosol properties were made during May–September 2013 in the southeastern United States (US) under fair-weather, afternoon conditions with well-defined planetary boundary layer structure. Optical extinction at 532 nm was directly measured at relative humidities (RHs) of  ∼  15,  ∼  70, and  ∼  90 % and compared with extinction calculated from measurements of aerosol composition and size distribution using the κ-Köhler approximation for hygroscopic growth. The calculated enhancement in hydrated aerosol extinction with relative humidity, f(RH), calculated by this method agreed well with the observed f(RH) at  ∼  90 % RH. The dominance of organic aerosol, which comprised 65 ± 10 % of particulate matter with aerodynamic diameter  <  1 µm in the planetary boundary layer, resulted in relatively low f(RH) values of 1.43 ± 0.67 at 70 % RH and 2.28 ± 1.05 at 90 % RH. The subsaturated κ-Köhler hygroscopicity parameter κ for the organic fraction of the aerosol must have been  <  0.10 to be consistent with 75 % of the observations within uncertainties, with a best estimate of κ  =  0.05. This subsaturated κ value for the organic aerosol in the southeastern US is broadly consistent with field studies in rural environments. A new, physically based, single-parameter representation was developed that better described f(RH) than did the widely used gamma power-law approximation.

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