scholarly journals Water based Release agent for Concrete using Low Cost Photocatalyst Materials

Author(s):  
Jong-Pil Park ◽  
Byoung-Il Hwang ◽  
Byung-Hyun Yoo ◽  
Dong-gyu Lee
Keyword(s):  
Low Cost ◽  
2021 ◽  
Author(s):  
Xiaojing Zhang ◽  
xinyi Ge ◽  
Zhigang Shen ◽  
Han Ma ◽  
Jingshi Wang ◽  
...  

Compared with environmentally harmful binder polyvinylidene fluoride (PVDF) in Li-ion batteries (LIBs), water-based binders have many advantages, such as low cost, rich sources and environmental friendliness. In this study, various...


Coatings ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 821
Author(s):  
Aneeqa Bashir ◽  
Mehwish Farooq ◽  
Abdul Malik ◽  
Shahzad Naseem ◽  
Arshad Saleem Bhatti

An environmentally friendlier solution processing has been introduced to fabricate zirconium oxide (ZrO2) films on quartz substrates, using spin coating of simple water-based solution. The films cured with UV-A = 330 nm for different times (40, 80, 120 min) were investigated for structural and optical properties and compared with thermally annealed film (at 350 °C). XRD and Raman spectroscopy showed amorphous structure in all the samples with no significant phase transformation with UV-A exposure. AFM microscopy showed smooth and crack free films with surface roughness ≤2 nm that reduced with UV-A exposure. Ultraviolet-visible (UV–Vis) spectroscopy demonstrated optical transmittance ≥88% and energy band gap variations as 4.52–4.70 eV. Optical constants were found from spectroscopic ellipsometry (SE). The refractive index (n) values, measured at 470 nm increased from 1.73 to 2.74 as the UV-A exposure prolonged indicating densification and decreasing porosity of the films. The extinction coefficient k decreased from 0.32 to 0.19 indicating reduced optical losses in the films under the UV-A exposure. The photoluminescence (PL) spectra exhibited more pronounced UV emissions which grew intense with UV-A exposure thereby improving the film quality. It is concluded that UV-A irradiation can significantly enhance the optical properties of ZrO2 films with minimal changes induced in the structure as compared to thermally treated film. Moreover, the present work indicates that water-based solution processing has the potential to produce high-quality ZrO2 films for low cost and environmental friendlier technologies. The work also highlights the use of UV-A radiations as an alternate to high temperature thermal annealing for improved quality.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Chenfei Zhao ◽  
Jun Wang ◽  
Lini Lu

Purpose In flexible electronics applications, organic inks are mostly used for inkjet printing. Three-dimensional (3 D) printing technology has the advantages of low cost, high speed and good precision in modern electronic printing. The purpose of this study is to solve the high cost of traditional printing and the pollution emissions of organic ink. It is necessary to develop a water-based conductive ink that is easily degradable and can be 3 D printed. A nano-silver ink printed circuit pattern with high precision, high conductivity and good mechanical properties is a promising strategy. Design/methodology/approach The researched nano-silver conductive ink is mainly composed of silver nanoparticles and resin. The effect of adding methyl cellulose on the ink was also explored. A simple 3 D circuit pattern was printed on photographic paper. The line width, line length, line thickness and conductivity of the printed circuit were tested. The influence of sintering temperature and sintering time on pattern resistivity was studied. The relationship between circuit pattern bending performance and electrical conductivity is analyzed. Findings The experimental results show that the ink has the characteristics of low silver content and good environmental protection effect. The printing feasibility of 3 D printing circuit patterns on paper substrates was confirmed. The best printing temperature is 160°C–180°C, and the best sintering time is 30 min. The circuit pattern can be folded 120°, and the cycle is folded more than 60 times. The minimum resistivity of the circuit pattern is 6.07 µΩ·cm. Methyl cellulose can control the viscosity of the ink. The mechanical properties of the pattern have been improved. The printing method of 3 D printing can significantly reduce the sintering time and temperature of the conductive ink. These findings may provide innovation for the flexible electronics industry and pave the way for alternatives to cost-effective solutions. Originality/value In this study, direct ink writing technology was used to print circuit patterns on paper substrates. This process is simple and convenient and can control the thickness of the ink layer. The ink material is nonpolluting to the environment. Nano-silver ink has suitable viscosity and pH value. It can meet the requirements of pneumatic 3 D printers. The method has the characteristics of simple process, fast forming, low cost and high environmental friendliness.


2022 ◽  
Vol 13 (1) ◽  
Author(s):  
Zhangli Liu ◽  
Jiaxing Xu ◽  
Min Xu ◽  
Caifeng Huang ◽  
Ruzhu Wang ◽  
...  

AbstractThermally driven water-based sorption refrigeration is considered a promising strategy to realize near-zero-carbon cooling applications by addressing the urgent global climate challenge caused by conventional chlorofluorocarbon (CFC) refrigerants. However, developing cost-effective and high-performance water-sorption porous materials driven by low-temperature thermal energy is still a significant challenge. Here, we propose a zeolite-like aluminophosphate with SFO topology (EMM-8) for water-sorption-driven refrigeration. The EMM-8 is characterized by 12-membered ring channels with large accessible pore volume and exhibits high water uptake of 0.28 g·g−1 at P/P0 = 0.2, low-temperature regeneration of 65 °C, fast adsorption kinetics, remarkable hydrothermal stability, and scalable fabrication. Importantly, the water-sorption-based chiller with EMM-8 shows the potential of achieving a record coefficient of performance (COP) of 0.85 at an ultralow-driven temperature of 63 °C. The working performance makes EMM-8 a practical alternative to realize high-efficient ultra-low-temperature-driven refrigeration.


Author(s):  
Bunyami Shafie ◽  
Lee Huei Hong ◽  
Phene Neoh Pei Nee ◽  
Fatin Hana Naning ◽  
Tze Jin Wong ◽  
...  

Drilling mud is a dense, viscous fluid mixture used in oil and gas drilling operations to bring rock cuttings to the earth's surface from the boreholes as well as to lubricate and cool the drill bit. Water-based mud is commonly used due to its relatively inexpensive and easy to dispose of. However, several components and additives in the muds become increasingly cautious and restricted. Starch was introduced as a safe and biodegradable additive into the water-based drilling fluid, in line with an environmental health concern. In this study, the suitability of four local rice flours and their heat moistures derivatives to be incorporated in the formulation of water-based drilling fluid was investigated. They were selected due to their natural amylose contents (waxy, low, intermediate, and high). They were also heat moisture treated to increase their amylose contents. Results showed that the addition of the rice flours into water-based mud significantly reduced the density, viscosity, and filtrate volume. However, the gel strength of the mud was increased. The rice flours, either native or heat moisture treated, could serve as additives to provide a variety of low cost and environmentally friendly drilling fluids to be incorporated and fitted into different drilling activity.


2017 ◽  
Vol 5 (5) ◽  
pp. 2102-2109 ◽  
Author(s):  
Li Xu ◽  
Hansinee Sitinamaluwa ◽  
Henan Li ◽  
Jingxia Qiu ◽  
Yazhou Wang ◽  
...  

A high performance α-Fe2O3 electrode is prepared via a green gum arabic-water based electrode fabrication process for SIBs for the first time.


2021 ◽  
Vol 36 (5) ◽  
pp. 1-12
Author(s):  
Emine Yalman ◽  
Tolga Depci ◽  
Gabriella Federer-Kovacs ◽  
Hani Al Khalaf

This study investigates the possibility of using rice husk ash as an additive to develop an environmentally friendly and low-cost drilling fluid system. The rice husk ash was added as an additive to water-based bentonite drilling fluids at different concentrations ranging from 2 wt% to 15 wt%. Rheological and filtration properties of each drilling fluid developed were measured by using a viscometer and standard low-pressure low-temperature filter press. Subsequently, cutting carrying index, minimum annulus velocity required to clean bottom of the well efficiently, flow behaviour index and permeability of mud cakes of the formulated systems were calculated in order to assess performance of the systems. The results demonstrated that the rheological and properties were improved depending on concentration of rice husk ash introduced. With the introduction of 15 wt% concentration of rice husk ash, while apparent viscosity and yield point increased by 60% and 183%, respectively, thixotropy and plastic viscosity decreased by 29% and 63%, respectively. On the other hand, drilling fluid with 4% wt% content of rice husk ash reduced the fluid loss by 10%. Moreover, results showed that cutting carrying index, minimum annulus velocity required to clean bottom of the well efficiently and flow behaviour index of the enhanced with the exploitation of rice husk ash in the drilling fluid. This study showed that rice husk ash as a promising additive to use in the water-based bentonite drilling fluids when properly implemented, and hence reducing the impact on the environment, and the total cost for drilling.


2020 ◽  
Vol 49 (6) ◽  
pp. 473-482
Author(s):  
H. Abd El-Wahab ◽  
G.A. Meligi ◽  
M.G. Hassaan ◽  
L. Lin

Purpose The purpose of this study is to prepare, characterise and evaluate nano-emulsions of ter-polymers of various compositions as eco-friendly binders for flexographic ink industry. Design/methodology/approach Various nano-emulsions of ter-polymers were prepared based on Vinyl acetate, Vinyl Versatate, butyl acrylate, acrylic acid and acrylamide monomers by means of a conventional seeded emulsion polymerisation technique, using K2S2O8 as the initiator. The characterisation of the prepared emulsions was performed using Fourier transform infrared, thermo-gravimetric analysis, gel permeation chromatography and transmission electron microscopy. A selection of co-polymers and ter-polymers were formulated with pigments and additional ingredients, as water-based flexographic inks. The inks were characterised for their rheological properties, pH, degree of dispersion, water-resistance and colour density. Findings It was found that the low viscosity of the prepared polymers may reduce the film thickness of the flexographic inks and may also increase the spreading of the ink on the surface. As a result, stable modified poly acrylate-based latex with improved physico-mechanical properties was obtained. The prepared latexes showed improved properties such as enhanced thermal stability and better water resistance. The effect of the emulsifier type on the properties of the resulting emulsion latexes and their corresponding films were investigated. Also, as the hydrophobic monomer increases, so does the colour density and increasing the binder ratio enhances the gloss values. The improving in gloss values were obtained and provide excellent adhesion properties for both the pigment particles and the base paper. Research limitations/implications The study focusses on the preparation of new water-based ter-polymer nano-particles and their use as eco-friendly binders for flexographic ink industry. Ink formulations based on other different type emulsion polymers could also be studied to assess the applicability of the ink formulation system found for other binders. Practical implications The ink formulations developed could find use in industrial-scale printing. Originality/value Eco-friendly environment and low-cost ink formulations for printing on paper substrates are novel.


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