Development and properties of a new oil binding system for marine application

2014 ◽  
Vol 2014 (1) ◽  
pp. 1474-1484 ◽  
Author(s):  
Holger Unbehaun ◽  
Till Hieronymus ◽  
Sören Tech ◽  
André Wagenführ

ABSTRACT Traditional marine oil response technology is based on ship borne techniques with oil/water separation by skimmer. These systems are very sensitive to weather conditions and have a long response time. Furthermore, conventional solid binder systems are unsuitable for marine application. Within the research project BIOBIND, a new binder system for marine application was developed and evaluated. The oil binders are made of biogenic and biodegradable wood-fiber, which cause only a small environmental impact and are very cost-efficient. They show a high porosity of 85 %, a high oil absorption capacity of approx. 600 kg m−3 (especially for thin oil films down to 0.03 mm), and a high retention capacity for oil. On the water surface, these binders achieve an oil recovery rate of 80 % with a coverage dosage of 11 %. Having a square geometry of 50 x 50 mm and a thickness of 4 mm, the binder has superior properties for manufacturing, storage, oil adsorption and recovery. The binder system was produced in industrial scale and tested during a large scale field experiment at the Baltic Sea in the summer of 2013. Its binding capacity and flotation ability were evaluated in mesocosm tests. Because of its hydrophobic properties, the binder floated for more than 8 days. Experiments of airborne application, monitoring, and ship borne recovery confirmed the suitability of the binder system. Due to airborne distribution, the binder system is also suitable for application during bad weather conditions and on shallow water territories. The paper describes the development of a solid oil binding system suitable for new marine application and presents the results of laboratory scale, mesocosm and field experiments.

2020 ◽  
Vol 80 (2) ◽  
pp. 133-146
Author(s):  
L Zhang ◽  
Z Zhang ◽  
J Cao ◽  
Y Luo ◽  
Z Li

Grain maize production exceeds the demand for grain maize in China. Methods for harvesting good-quality silage maize urgently need a theoretical basis and reference data in order to ensure its benefits to farmers. However, research on silage maize is limited, and very few studies have focused on its energetic value and quality. Here, we calibrated the CERES-Maize model for 24 cultivars with 93 field experiments and then performed a long-term (1980-2017) simulation to optimize genotype-environment-management (G-E-M) interactions in the 4 main agroecological zones across China. We found that CERES-Maize could reproduce the growth and development of maize well under various management and weather conditions with a phenology bias of <5 d and biomass relative root mean square error values of <5%. The simulated results showed that sowing long-growth-cycle cultivars approximately 10 d in advance could yield good-quality silage. The optimal sowing dates (from late May to July) and harvest dates (from early October to mid-November) gradually became later from north to south. A high-energy yield was expected when sowing at an early date and/or with late-maturing cultivars. We found that Northeast China and the North China Plain were potential silage maize growing areas, although these areas experienced a medium or even high frost risk. Southwestern maize experienced a low risk level, but the low soil fertility limited the attainable yield. The results of this paper provide information for designing an optimal G×E×M strategy to ensure silage maize production in the Chinese Maize Belt.


2018 ◽  
Vol 1 (94) ◽  
pp. 38-44
Author(s):  
А.M. Malienkо ◽  
N.E. Borуs ◽  
N.G. Buslaeva

In the article, the results of research on the methodology for conducting studies with corn culture under various methods of sowing and weather conditions. The aim of the research was to establish and evaluate the reliability and high accuracy of the experiment, with a decrease in the area's acreage and taking one plant per repetition. Based on the results of the analysis of biometric parameters and yields, the possibility of sampling from 5 to 108 plants was established statistically and mathematically to establish the accuracy of the experiment. The established parameters of sites in experiments with maize indicate the possibility of obtaining much more information from a smaller unit of area, that is, to increase labor productivity not only with tilled crops. This is the goal of further scientific research with other field crops taking 1 plant of repetitions, observing the conditions of leveling the experimental plot according to the fertility of the soil and sowing seeds with high condition. The data obtained give grounds for continuing research on the minimum space required and the sample in the experiments.


Biomolecules ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 153 ◽  
Author(s):  
Emilia Drozłowska ◽  
Łukasz Łopusiewicz ◽  
Monika Mężyńska ◽  
Artur Bartkowiak

Flaxseed oil cake extract (residual from cold-press oil production and rich in proteins and polysaccharides) was evaluated as a potential substrate for the preparation of spray-dried powders with emulsifying activity. Three variants of powders were obtained using different spray-drying process inlet temperatures: 160 °C, 180 °C, and 200 °C. The influence of temperature on physicochemical features (water holding capacity, oil binding capacity, water activity, solubility, color, chemical composition, antioxidant activity, and surface morphology) of the powders was estimated. Additionally, the emulsifying activity of the powders and the stability of oil-in-water emulsions prepared with their various content (0.5%, 1%, and 3%) were determined. Results showed that inlet temperature had significant influence on all physicochemical and functional properties of the powders. Increased inlet temperature decreased solubility and antioxidant activity but increased water-holding capacity, oil-binding capacity, and emulsifying activity. The emulsions prepared with the powder obtained at 200 °C showed the highest stability. SEM images showed the production of relatively spherical particles which were folded or wrinkled with a lot of dentures. This study could open a promising pathway for producing natural and plant-based spray-dried powders for food applications as emulsion stabilizers.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Dianyu Yu ◽  
Yan Chen ◽  
Xing Chen ◽  
Yunyan Huang ◽  
Liqi Wang ◽  
...  

Abstract This research focuses on the use of protein-polyphenol complex and protein-polyphenol: polysaccharide complexes to prepare oleogels through an emulsion-templated approach. Electrolysis soy protein isolate (ESPI) could be effectively adsorbed on the surface of a single-layer emulsion to increase the particle size. The order of the negative charges of the emulsion after adding polysaccharides was xanthan gum (XG)> pectin> carboxymethyl cellulose (CMC). Rheological behavior showed that the stability of the double-layer emulsions increased, and the viscoelasticity increased around one order of magnitude with the addition of polysaccharides. The oil binding capacity (OBC) of the oleogel prepared by adding polysaccharides increased to more than 97%. The peroxide value (PV) and anisidine value (AV) of XG oleogel were the minimum values in all samples. The AV and POV were within the regulatory limits of China after storage for 21 days. This provides a reference to design of ESPI-based oleogel for different applications.


BioResources ◽  
2019 ◽  
Vol 14 (2) ◽  
pp. 3339-3351 ◽  
Author(s):  
Baowen Wang ◽  
Zhihui Li ◽  
Xinglai Qi ◽  
Nairong Chen ◽  
Qinzhi Zeng ◽  
...  

Wood fibers were prepared as core materials for a vacuum insulation panel (VIP) via a dry molding process. The morphology of the wood fibers and the microstructure, pore structure, transmittance, and thermal conductivity of the wood fiber VIP were tested. The results showed that the wood fibers had excellent thermal insulation properties and formed a porous structure by interweaving with one another. The optimum bulk density that led to a low-cost and highly thermally efficient wood fiber VIP was 180 kg/m3 to 200 kg/m3. The bulk density of the wood fiber VIP was 200 kg/m3, with a high porosity of 78%, a fine pore size of 112.8 μm, and a total pore volume of 7.0 cm3·g-1. The initial total thermal conductivity of the wood fiber VIP was 9.4 mW/(m·K) at 25 °C. The thermal conductivity of the VIP increased with increasing ambient temperature. These results were relatively good compared to the thermal insulation performance of current biomass VIPs, so the use of wood fiber as a VIP core material has broad application prospects.


2021 ◽  
Vol 210 (07) ◽  
pp. 55-65
Author(s):  
Larisa Ikoeva ◽  
Oksana Haeva

Abstract. The purpose of the work is to study the influence of the growth regulator “Regoplant” and microfertilizer “Ultramag Kombi” on the photosynthetic productivity of the potatoes of the Barna variety based on the results of field experiments in the forest-steppe zone Republic of North Ossetia-Alania. Methods. Studies on the tasks were carried out in 2018–2020. at the experimental site of the NCRIMFA branch of the VSC of RAS in the conditions of the forest-steppe zone Republic of North Ossetia-Alania according to generally accepted methods. The soil of the experimental plot is medium-power heavy loamy leached chernozem, lined with pebbles. Results. It is established, that biological products under identical soil and weather conditions assisted different progress of plants and approach of phases of vegetation. For all variants of the experiment, the number of stems increased by 0,3–0,7 pcs., the height of the stems of potato plants – by 3,8–4,9 cm in comparison with the control. An intense increase in the mass of tops occurred when using a tank mixture (growth regulator “Regoplant” (25 ml/ha) + microfertilizer “Ultramag Combi” (0,75 l/ha)) – by 74 g/bush, or 15.5 % compared with the control variant. During the growing season, the sum of the photosynthetic potential (FP) was 1,070 thousand m2 •days/ha in the control, and on average 1198–1406 thousand m2•days/ha in the experimental variants. The greatest accumulation of dry matter was noted when using a tank mixture – 917 g/m2. The maximum pure photosynthetic productivity was observed in experimental variant IV – 6,52 g/m2•day compared to the control option. Scientific novelty. For the first time in the forest-steppe zone Republic of North Ossetia-Alania the effect of the growth regulator “Regoplant” and microfertilizer “Ultramag Kombi” on photosynthetic activity of potatoes was studied. Practical significance. The studies carried out make it possible to recommend in potato production the use of a tank mixture of an effective growth regulator “Regoplant” at a dose of 25 ml/ha and microfertilizer “Ultramag Combi” at a dose of 0,75 l/ha, as an ecologically safe and low-cost agricultural method when processing vegetative plants, providing an increase in yield and quality of tubers.


2020 ◽  
Vol 12 (17) ◽  
pp. 6833
Author(s):  
Piotr Szulc ◽  
Katarzyna Ambroży-Deręgowska ◽  
Iwona Mejza ◽  
Joanna Kobus-Cisowska ◽  
Marta Ligaj

The subject of the work was the evaluation of maize protein yield conditioned by various agrotechnical factors. The test results are derived from two different field experiments covering a total of seven years of observation. Protein yield was significantly dependent on changing weather conditions in the growing seasons. Protein yield was significantly lower in the dry and hot years. The sum of precipitation for the month of May was positively correlated with maize protein yield. However, there was no correlation between the average air temperature and the amount of protein yield. The sum of atmospheric precipitation for the entire growing season (IV–X) shaped maize protein yield in over 96%. A non-linear relationship of the 2nd degree was determined between these traits. Sowing maize into the soil cultivated traditionally (autumn tillage), “stay-green” type cultivars and row fertilization positively influenced maize protein yield. Initial fertilization (regardless of depth) with two-component NP fertilizer, in relation to broadcast fertilization, significantly increased maize protein yield from 11.4% to 18%, respectively. The type of nitrogen fertilizer did not differentiate the value of this trait. Pre-sowing nitrogen application was more effective compared to the top dressing, and significantly increased protein yield. Row fertilization with two-component NP fertilizer clearly affected the content protein in grain. The interdependence of genetic and agronomic progress is an important factor shaping the potential of maize protein yield and cannot be attributed to either breeding (cultivar) or agronomy.


2016 ◽  
Vol 33 (No. 5) ◽  
pp. 474-479 ◽  
Author(s):  
J. Ren ◽  
Ch. Song ◽  
P. Wang ◽  
S. Li ◽  
N. Kopparapu ◽  
...  

The structural and functional properties such as solubility, emulsifying properties, foaming properties, oil binding capacity, and surface hydrophobicity of sunflower 11S globulin hydrolysates generated by Alcalase at hydrolysis time of 30, 60, 90, and 120 min were evaluated. Circular dichroism analysis showed the hydrolysates possessed a decreased α-helix and β-structure. The hydrolysates exhibited lower surface hydrophobicity. Hydrolysates with shorter hydrolysis time showed the higher emulsifying activity index, but the same emulsion stability and oil binding capacity compared to the original 11S globulin. The longer hydrolysis resulted in lower foaming and emulsion stability. Thus it was demonstrated that by controlling the hydrolysis time of sunflower 11S globulin, hydrolysate with a desirable functional properties can be obtained.


2020 ◽  
Vol 10 (15) ◽  
pp. 5092
Author(s):  
Ana Salvatierra-Rojas ◽  
Victor Torres-Toledo ◽  
Joachim Müller

The sun drying of agricultural products is a complicated process involving heat transfer, mass transfer, and variable weather conditions. Surface reflection (albedo), a crop’s radiative property, plays an essential role in energy balance, and understanding its contribution can improve the thermal analysis. In this study, field experiments were conducted in the Philippines to explore the influence of surface albedo on the sun drying of paddy rice. First, we implemented energy and mass balance equations in a transient model with the surroundings using a graphical programming language in Matlab/Simulink®. Second, we identified the influence of albedo on the sun drying model by using a sensitivity analysis. Third, we investigated the relationship of paddy rice albedo and the solar zenith angle. Lastly, we integrated the albedo function into the sun drying model. The simulation outputs were validated with field experiments. A better estimation of the measured exit temperature and instantaneous mass were obtained when a variable albedo was applied. This study makes clear that introducing a variable albedo has a positive impact on model improvement. This information is important for application in solar drying technologies, so that the drying process can be better assessed.


2019 ◽  
Vol 6 (2) ◽  
pp. 181823 ◽  
Author(s):  
Guangyu Shi ◽  
Yizhu Qian ◽  
Fengzhi Tan ◽  
Weijie Cai ◽  
Yuan Li ◽  
...  

Oil/water separation is a field of high significance as it might efficiently resolve the contamination of industrial oily wastewater and other oil/water pollution. In this paper, an environmentally-friendly hydrophobic aerogel with high porosity and low density was successfully synthesized with renewable pomelo peels (PPs) as precursors. Typically, a series of sponge aerogels (HPSA-0, HPSA-1 and HPSA-2) were facilely prepared via high-speed dispersion, freeze-drying and silanization with methyltrimethoxysilane. Indeed, the physical properties of aerogel such as density and pore diameter could be tailored by different additives (filter paper fibre and polyvinyl alcohol). Hence, their physico-chemical properties including internal morphology and chemical structure were characterized in detail by Fourier transform infrared, Brunauer–Emmett–Teller, X-ray diffraction, scanning electron microscope, Thermal gravimetric analyzer (TG) etc. Moreover, the adsorption capacity was further determined and the results revealed that the PP-based aerogels presented excellent adsorption performance for a wide range of oil products and/or organic solvents (crude oil 49.8 g g −1 , soya bean oil 62.3 g g −1 , chloroform 71.3 g g −1 etc.). The corresponding cyclic tests showed the absorption capacity decreased slightly from 94.66% to 93.82% after 10 consecutive cycles, indicating a high recyclability.


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