scholarly journals Chemical Analysis of Itobe Limestone Deposit for Potential in Cement Manufacturing

Author(s):  
Temitope Emmanuel-Alonge ◽  
Dorcas Joseph ◽  
Emily Dada ◽  
Jamil Baba ◽  
Abere Victor ◽  
...  

In this research, the assessment of the chemical composition of the Itobe marble deposit for comparison with the general limestone requirements for cement making was investigated.  Six pits were dug and carefully studied in the area. The research work is aimed at determining the suitability of the Itobe marble deposit in the manufacturing of cement, establish the nature, size and type of the deposit and to estimate the various impurities present and at what concentrations. The soil samples collected were analysed for their chemical properties. Samples were also obtained from river channels and from outcrops of the deposits. The result showed that an appreciable amount of the marble deposit, with CaO in the range of 32.95% to 50.05% and Silica ranging from 1.40% to 7.20%. From these chemical analyses, Itobe limestone showed a great potential in cement production to augment cement availability for building and civil engineering construction in Nigeria.

2019 ◽  
Vol 5 (2) ◽  
pp. 111-117
Author(s):  
Djilali Tahri ◽  
Fatiha Elhouiti ◽  
Mohamed Ouinten ◽  
Mohamed Yousfi

Abstract Modeling the distribution of Rhanterium adpressum, an endemic species from southwestern Algeria, and the interactions of soil’s chemical properties with the variability of chemical composition of its essential oils makes the objective of this study. Obtained MaxEnt model (AUC = 0.98) showed that the general distribution of genus Rhanterium established mainly by the contribution of eight bioclimatic variables derived from temperature and precipitation (90.5%). Projection of the model in future conditions until 2070 reveals that the habitats of this species will be very affected by climate changes. The analysis of 9 soil samples shows a sandy (77–96%), alkaline, and calcareous character with an electrical conductivity between 0.2 and 1.8 dS/m at 20°C. The chemical composition of terpenoids families during a period of 5 months was dominated by monoterpene hydrocarbons (70–90%) followed by oxygen monoterpenes (4.5–9.2%), hydrocarbon sesquiterpenes (1.6–9.9%), and oxygenated sesquiterpenes (4.3–7.2%). The variation of this composition in relation with phenological cycle and physicochemical properties of the soil was discussed.


2020 ◽  
pp. 10-15
Author(s):  
A. Ojo ◽  
V. N. Enujiugha ◽  
H. N. Ayo- Omogie ◽  
O. A. Abiodun

Aims: To determine the chemical composition of serendipity berry (Dioscoreophyllum cumminsii) and miracle fruit (Thaumatococcus daniellii). Study Design: The mean and standard deviation of the data obtained were  analyzed. Place and Duration of Study: Samples were prepared in Department of Food Science and Technology, Osun State Polytechnic, between November 2018 and December 2019. Methodology: Chemical properties of two natural sweeteners namely the miracle fruit (Thaumatococcus danielli) and serendipity berry (Dioscoreophyllum cumminsii) were studied in this work. The fresh fruits were obtained from a farm, sorted, washed and the tissues were scraped, dried in the oven at 45°C for 12 hrs, milled and packed in airtight plastic containers. Proximate, vitamins and amino acid contents of the sweeteners were determined. Results: The results revealed that the protein contents of miracle fruit and serendipity berry were 75.57% and 62.54% respectively. Moisture contents of the sweeteners ranged from 56.95-58.33% while ash contents ranged from 19.33-22.90%. The sweeteners had low carbohydrate and lipid contents. Crude fiber was not detected in miracle fruit but serendipity berry had crude fibre of 5.38%. The fruits had β-carotene contents ranging from 8.44 mg/100 g and 23.00 mg/100 g, vitamin C (20.40 mg/100 g and 22.01 mg/100 g) and vitamin D (17.02 mg/100 g and 19.02 mg/100 g) in miracle fruit and serendipity berry respectively. However, low values were recorded for vitamin E 0.55 mg/100 g and 0.89 mg/100 g in miracle fruit and serendipity berry respectively. The fruits had appreciable amount of essential amino acid which was above 50% of the total amino acid content. Miracle fruit had 51.96% and serendipity berry had 58.07% of the essential amino acid. Aromatic essential amino were 10.78 and 12.79% in miracle fruits and serendipity respectively. Conclusion: This study showed that the two natural sweeteners are good source of essential nutrients and could be used as food supplements in our diet.


2018 ◽  
Vol 9 (1) ◽  
pp. 1-11
Author(s):  
Evandro Franklin de Mesquista ◽  
Lúcia |Helena Garófalo Chaves ◽  
Emanuela Candida Melo ◽  
Lourival Ferreira Cavalcante ◽  
Anailson Sousa Alves ◽  
...  

The objective of this experiment was to evaluate the effect of organic fertilization on changes of chemical properties of a “Neossolo Flúvico Eutrófico” (Fluvent) and okra production, cultivated with and without mulching and irrigation depths. The experiment was installed in the Agroecology sector at Universidade Estadual da Paraíba. The treatments were designed in a randomized blocks using the 2 x 5 x 2 factorial, which  corresponding to two irrigation depths (100 and 50% of the crop evapotranspiration - ETc), five doses of cattle manure to increase the level from 1.8 % to 2.8; 3.8; 4.8 and 5.8%, in soil with and without mulching (plant residues), with four replications, totaling 80 plots with 27 plants per plot. 140 days after planting okra, soil samples were collected at each plot and chemical analyses were performed. The okra production was evaluated based on the number of green fruits and crop yield. The data were submitted to analysis of variance. The application of cattle manures to the soil between 4.8 and 5.8% and irrigation with 100% of crop evapotranspiration - Etc, with and without mulching, was suitable for the cultivation of okra under semi-arid climatic conditions, which provided increases in the chemical attributes of a Fluvent and in the okra production.


2021 ◽  
Vol 3 (2) ◽  
pp. 175-182
Author(s):  
Odimegwu Vitus Chinonso ◽  
Weli Vincent Ezikornwor ◽  
Nwagbara Moses Okemini

This study evaluated the growth responses of C3 and C4 crops to soil physico-chemical properties in Rivers State. The C3 crop refers to Pumpkin and Cucumber while C4 crop refers to Amaranthus in this study. The research work made use of three crops (Pumpkin, Cucumber and Amaranthus in some selected sites in Rivers State and the study was carried out both in the dry and wet seasons. Soil samples were collected from both topsoil (0-15cm) and subsoil (15-30cm). The crops and soil samples were taken to the laboratory for further analysis. Mean values and standard deviations were used to describe the analysis while analysis of variance (ANOVA), Duncan, and Kruskal Wallis were used to test the hypotheses. All analyses were carried out using Statistical Package for Social Sciences (SPSS) 21.1 Version. Findings showed that sand content in Oyigbo had the highest in the topsoil at 95.37% while Etche had highest in silt content at 1.87%. For the subsoil, Oyigbo also had the highest sand content at 93.30% while Ikwerre had the highest clay content at 6.63% in subsoil. For chemical properties of soil, total organic carbon and magnesium were highest in Oyigbo at 1.91% and 24.00% respectively for topsoil while for subsoil potassium was highest in Ikwerre at 8.30%. It was also discovered C3 and C4 crops planted in Oyigbo, Etche and Ikwerre varied from the nutrients standards recommended by USDA (2014). The following nutrients and minerals were considered: energy, carbohydrates, protein, total fat, cholesterol, dietary fiber, vitamins, folates, niacin, pantogenic acid, pyridoxine, riboflavin, thiamin, Electrolytes, sodium, potassium, calcium, iron, magnesium, manganese phosphorus, and zinc. For standards recommended by (USDA 2014), only energy, iron, zinc, manganese, vitamin E, riboflavin, pyridoxine, niacin and pantothenic acid at Oyigbo met the standards, also Riboflavin and iron at Ikwerre met the (USDA 2014) standards while only folates at Etche met the (USDA 2014) standards. The study recommended that the soil nutrients and pH should be improved across the three locations and the acidic nature of both topsoil and subsoil should be improved by neutralizing the soil with lime.


Holzforschung ◽  
2005 ◽  
Vol 59 (6) ◽  
pp. 669-674 ◽  
Author(s):  
Ting-Feng Yeh ◽  
Barry Goldfarb ◽  
Hou-min Chang ◽  
Ilona Peszlen ◽  
Jennifer L. Braun ◽  
...  

Abstract In conifers, juvenile wood (JW) is always associated with compression wood (CW). Due to their similar properties, there is a common belief that JW is the same as CW. To resolve whether JW is identical to CW, 24 rooted cuttings of one loblolly pine clone were planted in growth chambers under normal, artificial bending, and windy environments. The results show that the morphology of JW is significantly different from CW. Furthermore, chemical analyses revealed that JW and CW are significantly different in chemical composition. Our results indicate that JW is different from CW, and the wood formed under a controlled windy environment is a mild type of compression wood.


Author(s):  
Catherine Mayowa Ikumapayi ◽  
Fakorede Ebenezer Oluwabusuyi

The notable demand for the want of cement in our time has stimulated increment in cement production and increment in manufacturers to be had in our day. These in turn amongst others have brought about failure of buildings and other construction members. As a result, the need to ensure the quality of available cement in circulation is of utmost paramount. This research work studies the available Portland lime cement of grade 42.5 only, in Nigeria from such company as company A, company B, and company C. The qualities and properties of the Portland lime cement from every of the above-named companies were investigated and as compared. Properties like Fineness, Setting Time, Chemical composition, Specific gravity, Consistency, Loss of ignition, Strength (compressive strength, and flexural strength), Micro structural analysis were determined according to relevant BS EN 197-1 (2011) and (ASTMC) 150-92 standards. These tests were carried out with the usage of scanning electron microscope, X-ray fluorescence spectrometer, Vicat apparatus, compressive strength machine, consistency apparatus and Chatelier flask, among others. The results showed that the chemical composition mostly of CaO, SiO2, AL2O3 and MgO in the cement +are within the acceptable limit of 60.0-67.0, 17.0-25.0, 3.0-8.0 and 0.1-4.0 respectively in the BS 4550: Part 3 (1979). The results of the compressive strength acquired for all the cement have been a way beneath the standardized result expected for grade 42.5. These could partly be traced to the cement micro-structure as Company C with the best morphology exhibits better compressive strength than others. Improvement on the cement morphology by the manufacturers could lead to compressive strength improvement. It was also discovered that one of the important factors that would have contributed to the low compressive strength was excessive amount of silt/clay content material inside the sand used.


2021 ◽  
Vol 57 (4) ◽  
pp. 166-180
Author(s):  
Maria-Minodora Marin ◽  
Madalina Georgiana Albu Kaya ◽  
George Mihail Vlasceanu ◽  
Jana Ghitman ◽  
Ionut Cristian Radu ◽  
...  

Type II collagen has been perceived as the indispensable element and plays a crucial role in cartilage tissue engineering. Thus, materials based on type II collagen have drawn farther attention in both academic and research for developing new systems for the cartilage regeneration. The disadvantage of using type II collagen as a biomaterial for tissue repairing is its reduced biomechanical properties. This can be solved by physical, enzymatic or chemical cross-linking processes, which provide biomaterials with the required mechanical properties for medical applications. To enhance type II collagen properties, crosslinked collagen scaffolds with different cross-linking agents were prepared by freeze-drying technique. The present research work studied the synthesis of type II collagen biomaterials with and without crosslinking agents. Scaffolds morphology was observed by MicroCT, showing in all cases an appropriate microstructure for biological applications, and the mechanical studies were performed using compressive tests. DSC showed an increase in denaturation temperature with an increase in cross-linking agent concentration. FTIR suggested that the secondary structure of collagen is not affected after the cross-linking; supplementary, to confirm the characteristic triple-helix conformation of collagen, the CD investigation was performed. The results showed that the physical-chemical properties of type II collagen were improved by cross-linking treatments.


Author(s):  
Priyobrata Nath ◽  
Agnish Mukherjee ◽  
Sougata Mukherjee ◽  
Sabyasachi Banerjee ◽  
Samarpita Das ◽  
...  

: Isatin is an endogenous and a significant category of fused heterocyclic component, widely been a part of several potential biologically useful synthetics. Since its discovery, tons of research work has been conducted with respect to the synthesis, chemical properties, and biological and industrial applications. It contains indole nucleus having both lactam and keto moiety which while being a part of a molecular framework exerted several biological effects, viz.; antimicrobial, antitubercular, anticonvulsant, anticancer etc. Isatin derivatives are synthetically significant substrates, which can be utilized for the synthesis of huge diversified chemical entities of which few members emerged to be a drug. The reason for this review is to provide extensive information pertaining to the chemistry and its significance in altering several pathological states of isatin and its derivatives. A Structure Activity Relationships study thus developed through a gamut of scientific information indicates the importance of mostly electron withdrawing groups, halogens, nitro, alkoxy and to a minor extent groups with positive inductive effects, such as methyl at position 1, 5, 6 and 7 of isatin in alleviating several clinical conditions. It is also observed from the survey that the presence of two oxo groups at position 2 and 3 sometimes become insignificant as fusion with a heterocycle at those position resulted in a biologically relevant compound.


2021 ◽  
Vol 11 (15) ◽  
pp. 7099
Author(s):  
Inkyeong Moon ◽  
Honghyun Kim ◽  
Sangjo Jeong ◽  
Hyungjin Choi ◽  
Jungtae Park ◽  
...  

In this study, the geochemical properties of heavy metal-contaminated soils from a Korean military shooting range were analyzed. The chemical behavior of heavy metals was determined by analyzing the soil pH, heavy metal concentration, mineral composition, and Pb isotopes. In total, 24 soil samples were collected from a Korean military shooting range. The soil samples consist of quartz, albite, microcline, muscovite/illite, kaolinite, chlorite, and calcite. Lead minerals, such as hydrocerussite and anglesite, which are indicative of a transformation into secondary mineral phases, were not observed. All soils were strongly contaminated with Pb with minor concentrations of Cu, Ni, Cd, and Zn. Arsenic was rarely detected. The obtained results are indicated that the soils from the shooting range are contaminated with heavy metals and have evidences of different degree of anthropogenic Pb sources. This study is crucial for the evaluation of heavy metal-contaminated soils in shooting ranges and their environmental effect as well as for the establishment of management strategies for the mitigation of environmental risks.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Marta Cybulak ◽  
Zofia Sokołowska ◽  
Patrycja Boguta

AbstractThere is limited information regarding the effect of biochar (BioC) on the fertility of fallow and grassland soils, as well as on the properties of their humic acids (HAs). The objective of this study was to evaluate with a 3-year field experiment the influence of BioC on the organic matter (OM) in Haplic Luvisol. BioC (obtained via wood waste pyrolysis at 650 °C) was applied to the soil of subplots under fallow and grassland at doses of 0, 1, 2 and 3 kg m−2. The soil samples were collected eight times. The physicochemical properties were determined for the soil and BioC by analysing the density, pH, surface charge, ash, and organic carbon content. Based on the changes in the structure of the HAs and their quantity in the soils, the chemical properties of the HAs were determined. The maximum BioC dose caused an increase in the content of Corg and HAs. BioC did not influence the humification degree coefficients of the HAs originated from fallow, whereas in the grassland, there were significant changes observed in these coefficient values, indicating that BioC may stimulate and accelerate the humification process of soil HAs. Increasing the BioC doses caused an increase in the soil’s HA content, suggesting an increase in soil sorption capacity. The fluorescence data showed BioC addition to the soil caused an increase in the number of structures characterised by low molecular weight and a low degree of humification.


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