Microwave Accelerated Methanolysis of Poly(ethylene terephthalate)

Poly(ethylene terephthalate) (PET) is an important commodity polymer that has the potential to be 100% recycled, but this is currently not economically viable as the costs of recovering the starting materials are greater than virgin materials. As well as PET, there are a number of other interesting poly(terephthalate)s which have higher economic value. However, for many of these, virgin material is necessary to avoid contamination with ET units. This can be avoided by chemically deconstructing the PET to simple terephthalates. In this work, we show that dimethyl terephthalate (DMT) can be easily obtained from PET, in high purity (> 99.5% for the crude) with a relatively low energy use (ca. 0.3 Mj.g-1), by using a microwave reactor. In a microwave reactor the methanolysis proceeds an order of magnitude faster than in a conventional reactor. This is apparently due to cavitation caused by hot-spots, which break up the PET, increasing the active surface, and an increased population of PET particles above the Ea in the hot zones.

An Evaluation of Recycled Polymeric Materials Usage in Denim with Lifecycle Assesment Methodology

Today, World economy is only 8.6% circular, which creates a huge potential in materials reuse. To close the Emission Gap by 2032, this percentage needs to be doubled. The circular economy ensures that with less virgin material input and fewer emissions. With the help of effective recycling technologies, virgin material use can be decreased and especially petroleum based materials impact can fall within planetary boundaries. This book chapter analyzes different chemical and biological recycling technologies, their advantages and challenges in denim production. Moreover, Life Cycle Assessment (LCA) analysis will be used to evaluate the environmental impact of recycled polymeric materials usage in denim fabrics. Finally, it concludes by challenges and the future of chemically recycled materials in denim production and opportunities to evaluate waste as a raw material to design circular systems.

Enhanced Processing of Regrind as Recycling Material in Single-Screw Extruders

Regrind processing poses challenges for single-screw extruders due to the irregularly shaped particles. For grooved feed zones, the output is lessened by the reduction of bulk density in comparison to virgin material. Simultaneously, the melt temperature increases, reducing the extruder’s process window. Through experimental investigations on a test stand, a novel feed zone geometry (nominal diameter 35 mm) is developed. It aligns the regrind’s specific throughput with that of virgin material. The regrind processing window is essentially increased. As the solids conveying in the novel feed zone cannot be simulated with existing methods, numerical simulations using the discrete element method are performed. Since plastic deformation occurs in the novel feed zone geometry, a new hysteresis contact model is developed. In addition to spheres, the regrind and virgin particles are modeled as superquadrics to better approximate the irregular shape. The new contact model’s simulation results show excellent agreement with experimental compression tests. The throughput of the extruder simulations is considerably underestimated when using spheres to represent the real particles than when using irregularly shaped superquadrics. Corresponding advantages can be seen especially for virgin material.

Effects of Forming Parameters on Fatigue Life in Incremental Sheet Punching

In order to investigate the effects of main forming parameters on the fatigue life in incremental sheet punching, wavelength and amplitude were selected as factors, and fatigue life of truncated pyramids and virgin material was selected as indicator. The effects of the parameters were identified whereby the design of full factorial experiment, fatigue comparative test, analysis of variance, Tukey test, and t-test. It was found that wavelength and amplitude significantly affect the fatigue life. In addition, the improvement of fatigue life decreased with the increment of wavelength and increased with the increment of amplitude when it is less than a certain value, followed by decreasing.

Sustainability of concrete using recycled aggregate: a review

Sustainable development is essential to the well-being of our planet, human development, and the continued growth of society. As we know, concrete are the most commonly used substance in the world, after water. However, recycled concrete is the biggest advantage for us. Nowadays the construction industry also tries to replace the virgin material to reduce the environmental impact, global warming, pollution, etc. The construction activity and old structural building also is an issue for the environment. The reuse and recycle of concrete would therefore also reduce the burden on the environment. So this paper will give a summary of recycled concrete aggregate, their sustain on the environment, properties of the application of recycled aggregate, and the resultant of their properties of recycled concrete aggregate. Keywords- Aggregate, Concrete, Construction Development, Environment, Recycled, Sustainable.

Prediction of SLS parts properties using reprocessing powder

Purpose Owing to the operating principle of powder bed fusion processes, selective laser sintering (SLS) requires effective management of the mixture ratio of processed material previously exposed to the high temperatures of processing with new virgin material. Therefore, this paper aims to fully understand the effect that the successive reprocessing has in the powder material and to evaluate its influence on the properties of SLS parts produced at different building orientations. Design/methodology/approach Polyamide 12 material with 0%, 30% and 50% of virgin powder and parts produced from them were studied through five consecutive building cycles and their mass, mechanical, thermal and microstructural properties were evaluated. Then, the experimental data was used to validate a theoretical algorithm of prediction capable to define the minimum amount of virgin powder to be added on the processed material to produce parts without significant loss of properties. Findings Material degradation during SLS influences the mass and mechanical properties of the parts, exhibiting an exponential decay property loss until 50% of the initial values. The theoretical algorithms of reprocessing proved the appropriateness to use a mixture of 30% of virgin with 70% of processed material for the most common purposes. Practical implications This paper validates a methodology to define the minimum amount of virgin material capable to fulfil the operational specifications of SLS parts as a function of the number of building cycles, depending on the requirements of the final application. Originality/value The use of theoretical models of prediction allows to describe the degradation effects of SLS materials during the sintering, ensuring the sustainable management of the processed powder and the economic viability of the process.

Principles and Policies for Recycling Decisions and Risk Management

Swedish recycling businesses argue that the Non-Toxic Environmental target gets too much weight and that resource efficiency gets too little focus, which results in decreased recycling. The purpose of this paper is to highlight different factors that recycling of waste decisions should consider, as well as contributing to a constructive discussion of the overall principles and policies for recycling. How recycling works in practice is explored based on nine interviews with stakeholders from the governmental agency level to recycling businesses. Theory with regards to ethics, risk, decision-making, governmental policy and laws is summarised. Finally, the discrepancy and connection between practice and theory is analysed. If recycling of waste is seen as a decision problem, the choice is between to recycle (in different ways) or not to recycle (i.e., energy recovery and/or landfill). Based on risk and decision theory, all relevant goals should be considered. This requires a broader problem framing when goals are in conflict. All parties agree that recycled and virgin material should be treated equally. From a higher policy perspective, it should then be demonstrated that any use of material (recycled and/or virgin) minimize environmental impact and promotes long-term sustainability.

Adsorption of organic pollutants from the aqueous phase using graphite as a model adsorbent

Although graphite is not effective as an adsorbent in water treatment, it provides a homogenous, non-porous, carbonaceous structure that is ideal for studying fundamental adsorption mechanisms. High-purity graphite powder (C content 99.5%) was oxidized in an ozone stream, producing a near-surface oxygen content of 5.9 at.%, and was used together with the virgin material to establish adsorption isotherms for organic compounds in aqueous solutions. We examined how the aromaticity and substituents of the adsorptives affect adsorption on the model-activated carbon surface. For both virgin and oxidized graphite, the adsorption capacity for the aromatic compounds decreased in the order 1-naphthol > 2-methoxynaphthalene > naphthalene > anisole > phenol, with significant differences in the adsorption capacities of the two graphite species observed only for anisole, naphthalene, and 1-naphthol. The Freundlich constants (KF) for the five compounds on virgin graphite were 23.9, 10.3, 5.5, 1.4, and 0.8 (nmol mg−1 )/(µmol L−1) n, respectively. Naphthalene and 1-naphthol were slightly more adsorbed on the virgin material, whereas oxidized graphite had marginally better adsorption properties for anisole. The results underline the importance of dispersive and π– π interactions in the adsorption of organic compounds on carbonaceous adsorbents; a second aromatic ring in 1-naphthol and 2-methoxynaphthalene greatly increased the adsorption capacity for these compounds compared with their one-ring counterparts phenol and anisole. Differences were also observed in the adsorption of compounds containing hydroxyl or methoxy substituents, which have electron-donating properties (a resonance effect) but different electron-withdrawal characteristics (caused by induction). Two amino acids occurring as zwitterions, l-tryptophan and l-tyrosine, were also tested as adsorptives. l-Tryptophan, which has a larger aromatic system, achieved higher loading on graphite, suggesting an adsorption mechanism primarily governed by dispersive and π– π interactions for these two ionic compounds as well.