Abstract
Monolithic TiB2 are known to have a good combination of densification and hardness which are sometimes useful but limited in application. However, their usage in service at elevated temperatures such as in power thermal plants, cutting tools, tribological purposes (cutting tools, mechanical seals, blast nozzles, and wheel dressing tools), etc leads to catastrophic failure. Hence, the introduction of sintering additives in the TiB2 matrix has a high influence on the improvement of its sinterability, and properties (fracture toughness, wear resistance etc.,) of the resulting composite needed to meets the requirement for various industrial applications. In this study, the influence of SiC as sintering additives on the microstructure, densification, hardness and wear performance of TiB2 ceramic was observed. Hence, TiB2, TiB2-10wt%SiC and TiB2-20wt%SiC were sintered at 1850 oC for 10 minutes under 50 MPa. The impacts of SiC on the TiB2 were observed to improve the microstructure correspondingly improving densification and mechanical properties, most especially with the composites with 20wt% SiC. Combined excellent densification, hardness and fracture toughness of 99.5%, 25.5 GPa, 4.5 MPa.m1/2 were achieved respectively for TiB2-20wt%SiC. Diverse in-situ phase and microstructural alterations were detected in the sintered composites, and it was discovered that the in-situ phase of TiC serves as the contributing factor to the enhanced features of the composites. Moreover, the coefficient of friction and wear performance outcomes of the synthesized composites described a decrease in the coefficient with an enhanced wear resistance via the increasing SiC particulate, although the application of the load from 10 N-20 N increased the wear rates.