Modeling the Hydrogen Redistribution at the Grain Boundary of Misoriented Bicrystals in Austenite Stainless Steel

Hydrogen embrittlement, as one of the major concerns for austenitic stainless steel, is closely linked to the diffusion of hydrogen through the grain boundary of materials. The phenomenon is still not well understood yet, especially the full interaction between hydrogen diffusion and the misorientation of the grains. This work aimed at the development of a robust numerical strategy to model the full coupling of the hydrogen diffusion and the anisotropic behavior of crystals in 316 stainless steel. A constitutive model, which allows easy incorporation of crystal orientation, various loading conditions, and arbitrary model geometries, was established by using the finite element package ABAQUS. The study focuses on three different bicrystal models composed of misoriented crystals, and the results indicate that the redistribution of hydrogen is significant closely to the grain boundary, and the redistribution is driven by the hydrostatic pressure caused by the misorientation of two neighboring grains. A higher elastic modulus ratio along the tensile direction will lead to a higher hydrogen concentration difference in the two grains equidistant from the grain boundary. The hydrogen concentration shows a high value in the crystal along the direction with stiff elastic modulus. Moreover, there exists a large hydrogen concentration gradient in a narrow region very close to the grain boundary to balance the concentration difference of the neighboring grains.

Biocompatibility Evaluation of Hollow Pollen Grains/Fe3 O4 Nanoparticles Composites as Potential Medical Devices

Recently, pollen grains (PGs) have been introduced as drug carriers and scaffolding building blocks. This study aimed to assess the in-vitro biocompatibility of Pistacia vera L. hollow PGs/Fe3O4 nanoparticles (HPGs/Fe3O4NPs) composites using human adipose-derived mesenchymal stem cells (hAD-MSCs). In this regard, iron oxide nanoparticles (Fe3O4NPs) were assembled on the surface of HPGs at different concentrations. The biocompatibility of the prepared composites was assessed through MTT assay, apoptosis-related gene expression and field emission scanning electron microscopy (FE-SEM) analysis. Compared to the bare HPGs, the HPGs/Fe3O4NPs exhibited a biphasic impact on hAD-MSCs. The composite containing 1% Fe3O4NPs demonstrated no cytotoxicity up to 21 days while higher Fe3O4NPs contents and long-term exposure revealed adverse effects on the hAD-MSCs’ growth. The obtained result was verified by the qRT-PCR and morphological analysis carried out through FE-SEM which suggests that a narrow region below 1% Fe3O4NPs may be the optimum choice for medicinal applications of HPGs/Fe3O4NPs microdevices.

Power transport efficiency during O-X-B 2nd harmonic electron cyclotron heating in a helicon linear plasma device

The principal objective of this work is to report on the power coupled to a tungsten target in the Proto-MPEX device during oblique injection of a microwave beam (< 70 kW at 28 GHz) into a high-power (~100 kW at 13.56 MHz) over-dense (n_e>1×10^19 m^(-3)) deuterium helicon plasma column. The experimental setup, electron heating system, electron heating scheme, and IR thermographic diagnostic for quantifying the power transport is described in detail. It is demonstrated that the power transported to the target can be effectively controlled by adjusting the magnetic field profile. Using this method, heat fluxes up to 22 MWm-2 and power transport efficiencies in the range of 17-20% have been achieved using 70 kW of microwave power. It is observed that most of the heat flux is confined to narrow region at the plasma periphery. Ray-tracing calculations are presented which indicate that power is coupled to the plasma electrons via an O-X-B mode conversion process. Calculations indicate that the microwave power is absorbed in a single pass at the plasma periphery via collisions and in the over-dense region via 2nd harmonic cyclotron resonance of the electron Bernstein wave. The impact of these results is discussed in the context of MPEX.

Spatially Highly Resolved Solar-wind-induced Magnetic Field on Venus

The current work investigates the Venusian solar-wind-induced magnetosphere at a high spatial resolution using all Venus Express (VEX) magnetic observations through an unbiased statistical method. We first evaluate the predictability of the interplanetary magnetic field (IMF) during VEX’s Venusian magnetospheric transits and then map the induced field in a cylindrical coordinate system under different IMF conditions. Our mapping resolves structures on various scales, ranging from the ionopause to the classical IMF draping. We also resolve two recently reported structures, a low-ionosphere magnetization over the terminator, and a global “looping” structure in the near magnetotail. In contrast to the reported IMF-independent cylindrical magnetic field of both structures, our results illustrate their IMF dependence. In both structures, the cylindrical magnetic component is more intense in the hemisphere with an upward solar wind electric field (E SW) than in the opposite hemisphere. Under downward E SW, the looping structure even breaks, which is attributable to an additional draped magnetic field structure wrapping toward −E SW. In addition, our results suggest that these two structures are spatially separate. The low-ionosphere magnetization occurs in a very narrow region, at about 88°–95° solar zenith angle and 185–210 km altitude. A least-squares fit reveals that this structure is attributable to an antisunward line current with 191.1 A intensity at 179 ± 10 km altitude, developed potentially in a Cowling channel.

Solving the electron and muon $$g-2$$ anomalies in $$Z'$$ models

We consider simultaneous explanations of the electron and muon $$g-2$$ g - 2 anomalies through a single $$Z'$$ Z ′ of a $$U(1)'$$ U ( 1 ) ′ extension to the Standard Model (SM). We first perform a model-independent analysis of the viable flavour-dependent $$Z'$$ Z ′ couplings to leptons, which are subject to various strict experimental constraints. We show that only a narrow region of parameter space with an MeV-scale $$Z'$$ Z ′ can account for the two anomalies. Following the conclusions of this analysis, we then explore the ability of different classes of $$Z'$$ Z ′ models to realise these couplings, including the SM$$+U(1)'$$ + U ( 1 ) ′ , the N-Higgs Doublet Model$$+U(1)'$$ + U ( 1 ) ′ , and a Froggatt–Nielsen style scenario. In each case, the necessary combination of couplings cannot be obtained, owing to additional relations between the $$Z'$$ Z ′ couplings to charged leptons and neutrinos induced by the gauge structure, and to the stringency of neutrino scattering bounds. Hence, we conclude that no $$U(1)'$$ U ( 1 ) ′ extension can resolve both anomalies unless other new fields are also introduced. While most of our study assumes the Caesium $$(g-2)_e$$ ( g - 2 ) e measurement, our findings in fact also hold in the case of the Rubidium measurement, despite the tension between the two.

Effective Online Order Acceptance Policies for Omnichannel Fulfillment

Problem definition: Omnichannel retailing has led to the use of traditional stores as fulfillment centers for online orders. Omnichannel fulfillment problems have two components: (1) accepting a certain number of online orders prior to seeing store demands and (2) satisfying (or filling) some of these accepted online demands as efficiently as possible with any leftover inventory after store demands have been met. Hence, there is a fundamental trade-off between store cancellations of accepted online orders and potentially increased profits because of more acceptances of online orders. We study this joint problem of online order acceptance and fulfillment (including cancellations) to minimize total costs, including shipping charges and cancellation penalties in single-period and limited multiperiod settings. Academic/practical relevance: Despite the growing importance of omnichannel fulfillment via online orders, our work provides the first study incorporating cancellation penalties along with fulfillment costs. Methodology: We build a two-stage stochastic model. In the first stage, the retailer sets a policy specifying which online orders it will accept. The second stage represents the process of fulfilling online orders after the uncertain quantities of in-store purchases are revealed. We analyze threshold policies that accept online orders as long as the inventories are above a global threshold, a local threshold per region, or a hybrid. Results: For a single period, total costs are unimodal as a function of the global threshold and unimodal as a function of a single local threshold holding all other local thresholds at constant values, motivating a gradient search algorithm. Reformulating as an appropriate linear program with network flow structure, we estimate the derivative (using infinitesimal perturbation analysis) of the total cost as a function of the thresholds. We validate the performance of the threshold policies empirically using data from a high-end North American retailer. Our two-location experiments demonstrate that local thresholds perform better than global thresholds in a wide variety of settings. Conversely, in a narrow region with negatively correlated online demand between locations and very low shipping costs, global threshold outperforms local thresholds. A hybrid policy only marginally improves on the better of the two. In multiple periods, we study one- and two-location models and provide insights into effective solution methods for the general case. Managerial implications: Our methods provide effective algorithms to manage fulfillment costs for online orders, demonstrating a significant reduction over policies that treat each location separately and reflecting the significant advantage of incorporating shipping in computing thresholds. Numerical studies provide insights as to why local thresholds perform well in a wide variety of situations.

Research on the Hole Length Ratio of Fan-Shaped Holes in Flat Plate Film Cooling

To study the influence of different hole length ratios on the flow structure and film cooling efficiency, a calculation model of fan-shaped hole was constructed and numerically studied. The effect of different hole length ratios on the cooling efficiency under different blowing ratios was compared and analyzed. The results showed that as the blowing ratio increases, the overall average efficiency of most of the hole length ratio cases first increases and then decreases. Only in the case with a cylindrical part length/total length ratio of 0.5 did the efficiency continue to increase. When the blowing ratio is small, the spanwise average efficiency of each hole length ratio case is closer, but the flow structure and efficiency distribution are quite different. For the medium blowing ratio, the overall average efficiency of the small hole length ratio case is higher, and the efficiency decreases as the hole length ratio increases. When the cylindrical part length/total length ratio is further increased to 1, the cooling efficiency region basically converges into a spanwise narrow region. For larger blowing ratio conditions, after 10D after the hole outlet, the case with a cylindrical part length/total length of 0.5 is more efficient.

Experimental Study on the Stabilization Mechanism of Diffusion Flames in a Curved Impinging Spray Combustion Field in a Narrow Region

HVAF (High Velocity Air Flame) flame spraying can generate supersonic high-temperature gas jets, enabling thermal spraying at unprecedented speeds. However, there is a problem with the energy cost of this device. This study focused on combustors that used cheap liquid fuel (kerosene) as the fuel for HVAF. In this research, we have developed a compact combustor with a narrow channel as a heat source for the HVAF heat atomizer. Using this combustor, the stability of the flame formed in the combustor, the morphology of the flame, and the temperature behavior in the combustion chamber were investigated in detail. As a result, the magnitude of the swirling airflow had a great influence on the structure of the flame formed in the combustor, and the stable combustion range of the combustor could be determined. As the swirling air flow rate changes, the equivalent ratio of the entire combustor changes significantly, and the flame structure also transition from the premixed flame to the diffusion flame. From this study, it was confirmed that the temperature inside the combustor has great influence on the flame structure.

A Simple Method for Bounding the Elasticity of Growing Demand with Applications to the Analysis of Historic Antitrust Cases

We propose a simple method, requiring only minimal data, for bounding demand elasticities in growing, homogeneous-product markets. Since growing demand curves cannot cross, shifts in market equilibrium over time can be used to “funnel” the demand curve into a narrow region, bounding its slope. Our featured application assesses the antitrust remedy in the 1952 DuPont decision, ordering incumbents to license patents for commercial plastics. We bound the demand elasticity significantly below 1 in many post-remedy years, inconsistent with monopoly, supporting the remedy’s effectiveness. A second application investigates whether the 1911 dissolution of American Tobacco fostered competition in the cigarette market. (JEL K21, L24, L65, L66, N41, N42, O34)

Occurrence of malformed calves in April - May 2021 indicates an unnoticed 2020 emergence of Schmallenberg virus in Denmark

During the European emergence of Schmallenberg virus (SBV) in 2011, examination of Culicoides spp. showed that SBV infected midges were present across Denmark. However, SBV associated malformations in ruminant species have not been reported in Denmark. In April 2021, seven calves with severe congenital generalized arthrogryposis and reduced body weight originating from a narrow region of the Jutlandic peninsula were submitted for examination. Analysis of fetal brain tissue for SBV viral RNA and pleural effusion for fetal anti-SBV antibodies identified SBV as the cause of the congenital syndrome. Backwards calculation from the calving dates indicated the occurrence of an unnoticed emergence of SBV in Denmark from early August 2020 and during the late summer and autumn. As SBV associated malformations may lead to dystocia urging for fetotomy or Cesarean section, veterinarians performing obstetric intervention are first line personnel in recognition of SBV emergence in domestic ruminants.