Ocean Alkalinity Enhancement – Avoiding runaway CaCO₃ precipitation during quick and hydrated lime dissolution

Ocean Alkalinity Enhancement (OAE) has been proposed as a method to remove carbon dioxide (CO2) from the atmosphere and to counteract ocean acidification. It involves the dissolution of alkaline minerals such as quick lime, CaO, and hydrated lime, Ca(OH)2. However, a critical knowledge gap exists regarding their dissolution in natural seawater. Particularly, how much can be dissolved before secondary precipitation of calcium carbonate (CaCO3) occurs is yet to be established. Secondary precipitation should be avoided as it reduces the atmospheric CO2 uptake potential of OAE. Here we show that both CaO and Ca(OH)2 powders (> 63 µm of diameter) dissolved in seawater within a few hours. However, CaCO3 precipitation, in the form of aragonite, occurred at a saturation (ΩAr) threshold of about 5. This limit is much lower than what would be expected for typical pseudo-homogeneous precipitation in the presence of colloids and organic materials. Secondary precipitation at unexpectedly low ΩAr was the result of so-called heterogeneous precipitation onto mineral phases, most likely onto CaO and Ca(OH)2 prior to full dissolution. Most importantly, this led to runaway CaCO3 precipitation by which significantly more alkalinity (TA) was removed than initially added, until ΩAr reached levels below 2. Such runaway precipitation would reduce the CO2 uptake efficiency from about 0.8 moles of CO2 per mole of TA down to only 0.1 mole of CO2 per mole of TA. Runaway precipitation appears to be avoidable by dilution below the critical ΩAr threshold of 5, ideally within hours of the addition to minimise initial CaCO3 precipitation. Finally, model considerations suggest that for the same ΩAr threshold, the amount of TA that can be added to seawater would be more than three times higher at 5 °C than at 30 °C, and that equilibration to atmospheric CO2 levels during mineral dissolution would further increase it by a factor of ~6 and ~3 respectively.

Experimental study of one-step economical retarded sandstone acid

The objective of this study is to experimentally evaluate a new acid combination of HEDP: CH3COOH as a retarded acid to minimize some limitations of high-temperature sandstone acidizing, such as fast acid-rock reaction and secondary precipitation pipeline corrosion. In this work, the acid–base titration, core-powder solubility test, scale deposition test, corrosion rate measurement and corefloods were carried out to evaluate the performances of the acid combination, including acidity characteristics, retarded performance, preventing scale rate, corrosivity and improving permeability. And then the microstructure and mineral content in sandstone samples were observed and analyzed with SEM–EDS. The results of evaluation tests indicated that the new acid combination has excellent performances on retarded rate, preventing scale deposition, permeability enhancement and lower corrosivity, comparing with conventional mud acid. The results of SEM and EDS showed that the microstructure and mineral content of sandstone changed after acid treatment. Compared with mud acid, the new acid system can react more with small particles on sandstone surface and less with the skeleton of samples and the decrease in the contents of Mg, Al, Na, K, Ca and Fe is relatively lower.

Dissolution-Repackaging of Hellandite-(Ce), Mottanaite-(Ce)/Ferri-Mottanaite-(Ce)

We investigated hellandite-group mineral phases from the Roman Region, alkali syenite ejecta, by multimethod analyses. They show a complex crystallisation history including co-precipitation of hellandite-(Ce) with brockite, resorption, sub-solidus substitution with mottanaite-(Ce), exsolution of perthite-like ferri-mottanaite-(Ce), overgrowth of an oscillatory-zoned euhedral shell of ferri-mottanaite-(Ce) and late, secondary precipitation of pyrochlore in the cribrose hellandite-(Ce) core. LREE/HREE crossover and a negative Eu anomaly in hellandite-group minerals follows fO2 increase during magma cooling. The distinction among the hellandite-group minerals is based on the element distribution in the M1, M2, M3, M4 and T sites. Additional information on miscibility relationship among the hellandite sensu strictu, tadzhikite, mottanaite, ferri-mottanaite and ciprianiite endmembers derives from molar fraction calculation. We observed that change in composition of hellandite-group minerals mimic the ligands activity in carbothermal-hydrothermal fluids related to carbonatitic magmatism.

Characteristics of Historical Precipitation in High Mountain Asia Based on a 15-Year High Resolution Dynamical Downscaling

The mountains of High Mountain Asia serve as an important source of water for roughly one billion people living downstream. This research uses 15 years of dynamically downscaled precipitation produced by the Weather Research and Forecasting (WRF) model to delineate contrasts in precipitation characteristics and events between regions dominated by the Indian Summer Monsoon (ISM) versus westerly disturbances during the cool season (December to March). Cluster analysis reveals a more complex spatial pattern than indicated by some previous studies and illustrates the increasing importance of westerly disturbances at higher elevations. Although prior research suggests that a small number of westerly disturbances dominate precipitation in the western Himalaya and Karakoram, the WRF-downscaled precipitation is less dominated by infrequent large events. Integrated vapor transport (IVT) and precipitation are tightly coupled in both regions during the cool season, with precipitation maximizing for IVT from the south-southwest over the Karakoram and southeast-southwest over the western Himalaya. During the ISM, Karakoram precipitation is not strongly related to IVT direction, whereas over the western Himalaya, primary and secondary precipitation maxima occur for flow from the west-southwest and northwest, respectively. These differences in the drivers and timing of precipitation have implications for hydrology, glacier mass balance, snow accumulation, and their sensitivity to climate variability and change.

Secondary Precipitation Estimate Merging Using Machine Learning: Development and Evaluation over Krishna River Basin, India

The study proposes Secondary Precipitation Estimate Merging using Machine Learning (SPEM2L) algorithms for merging multiple global precipitation datasets to improve the spatiotemporal rainfall characterization. SPEM2L is applied over the Krishna River Basin (KRB), India for 34 years spanning from 1985 to 2018, using daily measurements from three Secondary Precipitation Products (SPPs). Sixteen Machine Learning Algorithms (MLAs) were applied on three SPPs under four combinations to integrate and test the performance of MLAs for accurately representing the rainfall patterns. The individual SPPs and the integrated products were validated against a gauge-based gridded dataset provided by the Indian Meteorological Department. The validation was applied at different temporal scales and various climatic zones by employing continuous and categorical statistics. Multilayer Perceptron Neural Network with Bayesian Regularization (NBR) algorithm employing three SPPs integration outperformed all other Machine Learning Models (MLMs) and two dataset integration combinations. The merged NBR product exhibited improvements in terms of continuous and categorical statistics at all temporal scales as well as in all climatic zones. Our results indicate that the SPEM2L procedure could be successfully used in any other region or basin that has a poor gauging network or where a single precipitation product performance is ineffective.

Microstructural processes occurring during creep of friction stir welded AA2024-T3 alloy

The poor weldability of AA2024 aluminum alloy limits its use for industrial applications. Being a non-fusion welding process, Friction Stir Welding (FSW) seems to be a promising solution for welding this alloy. FSW was applied in the current study in order to butt weld AA2024-T3 aluminum alloy plates and to study the creep behavior of the weld. Creep tests were conducted at 250 0C and 315 0C both on the parent material and on the friction stir welded specimens. A comprehensive Transmission Electron Microscopy (TEM) study together with High Resolution Scanning Electron Microscopy (HRSEM) study and Energy Dispersive X-ray Spectroscopy (EDS) analysis were conducted in order to investigate the microstructural processes. The parent material seems to contain two kinds of Curich precipitates - coarse precipitates having the size of a few microns each and uniformly dispersed fine nanosized precipitates. However, this microstructure was found to be unstable at the temperature range of 250-315 0C, secondary precipitation was found to take place, this secondary precipitation is responsible for grain boundary decoration and the appearance of secondary rod-shaped precipitates and for some degree of coarsening of the nanosized precipitates inside the grains. TEM study yielded that the material undergoes dynamic recrystallization (DRX) during creep as well as during the FSW process. Various stages of the development of dislocation networks into a cellular dislocation structure and finally into dislocation free recrystallized grains were recorded. The friction stir welded material, which has already recrystallized during welding, undergoes DRX during creep so that ultra-fine grains are being created concurrently. Precipitation processes at the friction stir welded material occur as well during creep. The instability of the microstructure during creep and exposure to high temperature plays an important role in the analysis of the creep results. The influence of the above microstructure changes occurring during creep on the creep behavior will be referred and discussed.

Development of an online monitoring method for electrostatic precipitators on commercial biomass combustion plants

Combustion plants based on wooden biomass as fuel can contribute to a decarbonization of the energy sector by reducing the need for fossil energy usage, which decreases the net carbon dioxide output in the atmosphere. However, the flue gas of biomass-based combustion plants contains increased amounts of particulate matter, which need to be separated before release into the environment because of legal emission limits. In medium-sized plants, electrostatic precipitators (ESP) are commonly used separators to minimize the particulate matter concentration. Due to new regulations based on the medium combustion plants directive introduced by the EU, continuous surveillance of secondary precipitation technologies like ESP has to be implemented. The method proposed in this paper focuses on the readily available current (I) and voltage (U) data of the high-voltage unit supply of an ESP to calculate the efficiency of the particle separation. Consequently, a continuous proof of function can be delivered without high cost for additional measurement equipment. This article proves the effectiveness of the method in calculating the precipitation effectiveness of the ESP. It is shown that the deviation from the separation efficiency calculated by the method and the measured efficiency is smaller than 7%. Additionally, it is necessary to define a suitable reference signal that indicates whether the combustion plant is running or not. Hence, the availability of the system can be evaluated. This method will help operators to meet legal requirements.

KINETIC ANALYSIS OF SECONDARY PRECIPITATION IN A HP40-Nb ALLOY

<p class="AMSmaintext1">The HP40-Nb heat resistant alloy (35Ni-25Cr-Nb) was analysed by means of optical microscopy after aging treatments at 1073 and 1173 K for different times, in order to apply the classic Johnson – Mehl - Avrami – Kolmogorov kinetic model (JMAK), and thus calculate the activation energy of secondary M₂₃C₆precipitation, which occurs during thermal aging. The relevance of this theoretical analysis is to infer the mechanism that controls the nucleation and growth of M₂₃C₆ secondary carbides, since the amount and morphology of these phase influences the mechanical properties as well as the corrosion resistance in service. After performing the kinetic analysis using the JMAK model, the activation energy was found to be 208 kJ/mol, which would indicate that the secondary precipitation in this alloy is controlled by the Cr-diffusion phenomenon along the austenitic matrix.</p>

Phase Separation and Development of the Microstructure for Stainless Steel to Copper Alloy Weld Joints Using a Fiber Laser

Stainless steel and copper alloys joints are often applied in aerospace, marine and power industries where both high thermal and electrical conductivity (Cu) and corrosion resistance (steel) are required. In the aerospace industry, in particular for the combustion chamber of rocket engines, copper and steel combinations offer perfect materials selection due to their combined high thermal conductivity and good stiffness. In this work, laser welds were produced with intensity between 3.8 × 104 and 5.7 × 104 W/mm2 and a heat input between 72 and 108 J/mm, giving an aspect ratio of 1.8. The microstructure of the weld beads was marked by chemical heterogeneities due to the phase separation between Cu and Fe in the liquid state. The phase separation gave rise to globular precipitates which further transform due to a secondary precipitation at temperatures below 1000 °C. The steel side part of the weld presents around 20% Cu, leading to a liquation of the grain boundaries and cracking at high heat inputs. The hardness values situated between both base materials and the tensile shear behavior, when the weld is sufficiently tough, present strength up to 350 MPa and elongation up to 10%.