High Resolution Mapping of PM2.5 Concentrations in Paris (France) Using Mobile Pollutrack Sensors Network in 2020

There is a need for accurate monitoring of PM2.5 that adversely affects human health. Consequently, in addition to the monitoring performed by fixed microbalance instruments installed under legal obligation, we are proposing to deploy the Pollutrack network of mobile sensors within the city of Paris (France). The measurements are performed by mobile aerosol counters mounted on the roof of cars, providing a constant series of readings in the 0.3–10 µm size range that are then aggregated to identify areas of mass concentrations of pollution. The performance of the Pollutrack sensors has been established in ambient air in comparison with the microbalance measurement devices and with the Light Optical Aerosols Counter (LOAC) aerosol counter. A measurement uncertainty of about 5 µg. m−3 is obtained with absolute values from the Pollutrack measurements made at a given location. Instead of the current modelizations based on very few PM2.5 values, maps built from real measurements with a spatial resolution down to 100 m can now be produced each day for Paris, and potentially for specific times of the day, thanks to the high number of measurements achievable with the Pollutrack system (over 70,000 on weekdays). Interestingly, the global trend of PM2.5 content shows several significant pollution events in 2020 despite the COVID-19 crisis and the lockdown. The Pollutrack pollution maps recorded during different PM2.5 pollution conditions in the city frequently identified a strong spatial heterogeneity where the North and the East of Paris were more polluted than the west. These “hot spots” could be due to the city topology and its sensitivity to wind direction and intensity. These high-resolution maps will be crucial in creating evidence for the relevant authorities to respond appropriately to local sources of pollution and to improve the understanding of transportation of urban PM.

Origins and Spatial Distribution of Non-Pure Sulfate Particles (NSPs) in the Stratosphere Detected by the Balloon-Borne Light Optical Aerosols Counter (LOAC)

While water and sulfuric acid droplets are the main component of stratospheric aerosols, measurements performed for about 30 years have shown that non-sulfate particles (NSPs) are also present. Such particles, released from the Earth mainly through volcanic eruptions, pollution or biomass burning, or coming from space, present a wide variety of compositions, sizes, and shapes. To better understand the origin of NSPs, we have performed measurements with the Light Optical Aerosol Counter (LOAC) during 151 flights under weather balloons in the 2013–2019 period reaching altitudes up to 35 km. Coupled with previous counting measurements conducted over the 2004–2011 period, the LOAC measurements indicate the presence of stratospheric layers of enhanced concentrations associated with NSPs, with a bimodal vertical repartition ranging between 17 and 30 km altitude. Such enhancements are not correlated with permanent meteor shower events. They may be linked to dynamical and photophoretic effects lifting and sustaining particles coming from the Earth. Besides, large particles, up to several tens of μm, were detected and present decreasing concentrations with increasing altitudes. All these particles can originate from Earth but also from meteoroid disintegrations and from the interplanetary dust cloud and comets.

Vertical Profiles of Pollution Particle Concentrations in the Boundary Layer above Paris (France) from the Optical Aerosol Counter LOAC Onboard a Touristic Balloon

Atmospheric pollution by particulate matter represents a significant health risk and needs continuous monitoring by air quality networks that provide mass concentrations for PM10 and PM2.5 (particles with diameter smaller than 10 μm and 2.5 μm, respectively). We present here a new approach to monitor the urban particles content, using six years of aerosols number concentration measurements for particles in the 0.2−50 μm size range. These measurements are performed by the Light Optical Aerosols Counter (LOAC) instrument onboard the tethered touristic balloon “Ballon de Paris Generali”, in Paris, France. Such measurements have allowed us first to detect at ground a seasonal variability in the particulate matter content, due to the origin of the particles (anthropogenic pollution, pollens), and secondly, to retrieve the mean evolution of particles concentrations with height above ground up to 150 m. Measurements were also conducted up to 300 m above ground during major pollution events. The vertical evolution of concentrations varies from one event to another, depending on the origin of the pollution and on the meteorological conditions. These measurements have shown the interest of performing particle number concentrations measurements for the air pollution monitoring in complement with regulatory mass concentrations measurement, to better evaluate the intensity of the pollution event and to better consider the effect of smallest particles, which are more dangerous for human health.

Dynamics of Accumulation of Aerosols and Microscopic Fungi Spores in the Air of a Hermetic Inhabited Object during a Four-Month Isolation Experiment SIRIUS-19

A four-month experiment which reproduced the main temporal characteristics of the real space flight to the Moon in a medico-technical complex has been carried out. The content of aerosols in the indoor air of the hermetic inhabited object was continuously monitored using a Handheld 3016 laser aerosol counter (Lighthouse WS Co, United States). The number of particles was counted automatically, and the number of viable propagules and the species composition of the fungal population were determined by seeding. The results obtained by these two methods were compared, the regularities in dynamics of neutral particles and micromycete spores, as well as their relationship with the crew activity were revealed, and a possibility to use a particle counter on a spacecraft as an indicator of the microbiological situation was analyzed. A general tendency of an increase in the content of fungal spores in the air of the examined premises was observed from 2--5 at the beginning of the experiment to 287 ± 36 CFU/m3 closer to its end; however, this value did not exceed the sanitary standard recommended by WHO. Species potentially harmful for human health (Aspergillus fumigatus, A. niger and A. sydowii) were detected, but their spore load was extremely low. indoor air, spaceships, microbiological contamination, aerosol particle counter The work was supported by the National Research Center "Kurchatov Institute" (decree no. 1807 from 14.08.2019) and by the Moscow State University (grant for Leading Scientific Schools «Depository of the Living Systems» within the framework of the MSU Development Program).

In situ measurements of desert dust particles above the western Mediterranean Sea with the balloon-borne Light Optical Aerosol Counter/sizer (LOAC) during the ChArMEx campaign of summer 2013

Mineral dust from arid areas is a major component of global aerosol and has strong interactions with climate and biogeochemistry. As part of the Chemistry-Aerosol Mediterranean Experiment (ChArMEx) to investigate atmospheric chemistry and its impacts in the Mediterranean region, an intensive field campaign was performed from mid-June to early August 2013 in the western basin including in situ balloon-borne aerosol measurements with the light optical aerosol counter (LOAC). LOAC is a counter/sizer that provides the aerosol concentrations in 19 size classes between 0.2 and 100 µm, and an indication of the nature of the particles based on dual-angle scattering measurements. A total of 27 LOAC flights were conducted mainly from Minorca Island (Balearic Islands, Spain) but also from Ile du Levant off Hyères city (SE France) under 17 light dilatable balloons (meteorological sounding balloons) and 10 boundary layer pressurised balloons (quasi-Lagrangian balloons). The purpose was to document the vertical extent of the plume and the time evolution of the concentrations at constant altitude (air density) by in situ observations. LOAC measurements are in agreement with ground-based measurements (lidar, photometer), aircraft measurements (counters), and satellite measurements (CALIOP) in the case of fair spatial and temporal coincidences. LOAC has often detected three modes in the dust particle volume size distributions fitted by lognormal laws at roughly 0.2, 4 and 30 µm in modal diameter. Thanks to the high sensitivity of LOAC, particles larger than 40 µm were observed, with concentrations up to about 10−4 cm−3. Such large particles were lifted several days before and their persistence after transport over long distances is in conflict with calculations of dust sedimentation. We did not observe any significant evolution of the size distribution during the transport from quasi-Lagrangian flights, even for the longest ones (∼ 1 day). Finally, the presence of charged particles is inferred from the LOAC measurements and we speculate that electrical forces might counteract gravitational settling of the coarse particles.

In situ measurements of desert dust particles above the western Mediterranean Sea with the balloon-borne Light Optical Aerosol Counter/sizer (LOAC) during the ChArMEx campaign of summer 2013

Mineral dust from arid areas is a major component of the global aerosol and has strong interactions with climate and biogeochemistry. As part of the Chemistry-Aerosol Mediterranean Experiment (ChArMEx) to investigate atmospheric chemistry and its impacts in the Mediterranean region, an intensive field campaign was performed from mid-June to early August 2013 in the western basin including in situ balloon-borne aerosol measurements with the Light Optical Aerosol Counter (LOAC). LOAC is a counter/sizer that provides the aerosol concentrations in 19 size classes between 0.2 and 100 μm, and an indication of the nature of the particles based on dual angle scattering measurements. A total of 27 LOAC flights were conducted mainly from Minorca Island (Balearic Islands, Spain) but also from Ile du Levant off Hyères city (SE France) under 17 Light Dilatable Balloons (meteorological sounding balloons) and 10 Boundary Layer Pressurized Balloons (quasi-Lagrangian balloons). The purpose was to document the vertical extent of the plume and the time-evolution of the concentrations at constant altitude (air density) by in situ observations. LOAC measurements are in agreement with ground-based measurements (lidar, photometer), aircraft measurements (counters), and satellite measurements (CALIOP) in case of fair spatial and temporal coincidences. LOAC has often detected 3 modes in the dust particle volume size distributions fitted by lognormal laws at roughly 0.2, 4 and 30 µm in modal diameter. Particles larger than 40 μm were observed, with concentrations up to about 10−4 cm−3. Such large particles were lifted several days before and their persistence after transport over long distances is in conflict with calculations of dust sedimentation. We did not observe any significant evolution of the size distribution during the transport from quasi-Lagrangian flights, even for the longest ones (~ 1 day). Finally, the presence of charged particles is inferred from the LOAC measurements and we speculate that electrical forces might counteract gravitational settling of the coarse particles.

LOAC: a small aerosol optical counter/sizer for ground-based and balloon measurements of the size distribution and nature of atmospheric particles – Part 1: Principle of measurements and instrument evaluation

The study of aerosols in the troposphere and in the stratosphere is of major importance both for climate and air quality studies. Among the numerous instruments available, optical aerosol particles counters (OPCs) provide the size distribution in diameter range from about 100 nm to a few tens of µm. Most of them are very sensitive to the nature of aerosols, and this can result in significant biases in the retrieved size distribution. We describe here a new versatile optical particle/sizer counter named LOAC (Light Optical Aerosol Counter), which is light and compact enough to perform measurements not only at the surface but under all kinds of balloons in the troposphere and in the stratosphere. LOAC is an original OPC performing observations at two scattering angles. The first one is around 12°, and is almost insensitive to the refractive index of the particles; the second one is around 60° and is strongly sensitive to the refractive index of the particles. By combining measurement at the two angles, it is possible to retrieve the size distribution between 0.2 and 100 µm and to estimate the nature of the dominant particles (droplets, carbonaceous, salts and mineral particles) when the aerosol is relatively homogeneous. This typology is based on calibration charts obtained in the laboratory. The uncertainty for total concentrations measurements is ±20 % when concentrations are higher than 1 particle cm−3 (for a 10 min integration time). For lower concentrations, the uncertainty is up to about ±60 % for concentrations smaller than 10−2 particle cm−3. Also, the uncertainties in size calibration are ±0.025 µm for particles smaller than 0.6 µm, 5 % for particles in the 0.7–2 µm range, and 10 % for particles greater than 2 µm. The measurement accuracy of submicronic particles could be reduced in a strongly turbid case when concentration of particles > 3 µm exceeds a few particles cm−3. Several campaigns of cross-comparison of LOAC with other particle counting instruments and remote sensing photometers have been conducted to validate both the size distribution derived by LOAC and the retrieved particle number density. The typology of the aerosols has been validated in well-defined conditions including urban pollution, desert dust episodes, sea spray, fog, and cloud. Comparison with reference aerosol mass monitoring instruments also shows that the LOAC measurements can be successfully converted to mass concentrations.