ANALYSIS OF THE HEATING CAPACITY OF ELECTRICALLY HEATED WINDOWS

Electric window heating has been used for some time in Europe and the Americas, but in Ukraine it only enters the market as an independent heating device and raises the question of its heating capacity in winter and the benefits of using them. There are several works in this field that determine the efficiency and contribution to the energy needs of an electric-heated window house, but it is necessary to answer more specifically the question of the heating capacity of such windows as a single heating system, for example rooms of certain sizes.In the work present the design, thermophysical processes occurring in such windows and, by computer simulation of the thermal state of the window with the selected typical room, the results of the study of the heating capacity of the windows, depending on the relative glazing area to the total area of the outer enclosure and the ambient temperature conditions not exceeding the maximum heat emission 450 / and temperature 45 °С on the inner glass of the double-glazed window. the presented thermal model of the window with the room is implemented as a computer program with the possibility of a detailed analysis of the heating capacity of the window, depending on the parameters of the room and the outside temperature, as well as optimization of operational parameters to maintain comfortable conditions.

Single-Step Synthesis Process for High-Entropy Transition Metal Boride Powders Using Microwave Plasma

A novel approach is demonstrated for the synthesis of the high entropy transition metal boride (Ta, Mo, Hf, Zr, Ti)B2 using a single heating step enabled by microwave-induced plasma. The argon-rich plasma allows rapid boro-carbothermal reduction of a consolidated powder mixture containing the five metal oxides, blended with graphite and boron carbide (B4C) as reducing agents. For plasma exposure as low as 1800 °C for 1 h, a single-phase hexagonal AlB2-type structure forms, with an average particle size of 165 nm and with uniform distribution of the five metal cations in the microstructure. In contrast to primarily convection-based (e.g., vacuum furnace) methods that typically require a thermal reduction step followed by conversion to the single high-entropy phase at elevated temperature, the microwave approach enables rapid heating rates and reduced processing time in a single heating step. The high-entropy phase purity improves significantly with the increasing of the ball milling time of the oxide precursors from two to eight hours. However, further improvement in phase purity was not observed as a result of increasing the microwave processing temperature from 1800 to 2000 °C (for fixed ball milling time). The benefits of microwave plasma heating, in terms of allowing the combination of boro-carbothermal reduction and high entropy single-phase formation in a single heating step, are expected to accelerate progress in the field of high entropy ceramic materials.

Specific surface area, crystallite size and thermokinetic of oxide formation γ → α-Al2O3 nano powders at 570 – 1470 K

Powders where the γ≈α-Al2O3-nano phases are the priority precursors for catalysts for heterogeneous catalysis with the maximum content of surface 5-coordinated Al centers for Pt attachment. Hydrogenated nano powders (~8 nm) of γ-, γ '-, θ-, κ-Al2O3 soluble in hydrochloric acid were obtained from the processing of aluminum boride powders with an icosahedral structure. Samples, which underwent a step-by-step and single heating of 50-100K heat treatment for 2 hours at temperatures of 570-1470K, were received in quantity of 34. The specific surface area of SВET, m2g-1 was measured by the thermal nitrogen desorption express method of gas chromatography through the GC-1 device. X-ray (phase and coherent), fluorescence and phase chemical-analytical evaluation of the samples were performed. The thermokinetic characteristics of the processes are calculated using the exponential Arrhenius law. Dimensional characteristics of crystallites (10.4-48 nm); specific surface area of powders (213-8.6 m2g-1, SВET); thermokinetic parameters of α-Al2O3 crystallite growth process (V α-Al2O3 - 1.44 10-3 - 6.67 10-3 nm s-1; E α-Al2O3 = 38.7±2.1kJ mol-1; A0 = 0.16±0.0 s-1 along the temperature line 1220-1470K were determined and calculated. The process of dehydration of two OH-groups occurs in the region 570-720K Ea H2O ↑ = 30.5 ± 0.5 kJ mol-1 A0 = 1.33±0.3 s-1. The last group of OH at temperatures of 820 -1070К and a rate of 2.13 10-4 - 4.93 10-4 mol s-1 Ea H2O ↑ = 13.2 ± 0.8 kJ mol-1 A0 = 16.9 ± 0.9 s-1. The activation energy of the phase transition is Ea., γ → α-Al2O3 = 23.9 ± 1.0 kJ mol-1 A0 = 2.01 ± 0.72 s-1 (770-970K) and Ea., γ → α-Al2O3 = 83.5 ± 0.8 kJ mol-1 A0 =(2,05±0,95) 103 s-1 (1070-1170K). It agrees well with the known heat of conversion Eа, γ→α-Al2O3 = 85 kJ mol-1. The TK of γ≈α-Al2O3-nano phases is at 1170K.

Heat transfer of temperature-sensitive magnetic fluids around single heating pipe

Temperature-sensitive magnetic fluid (TSMF) is a magnetic nanoparticle suspension with strong temperature-dependent magnetization even at room temperature. TSMF is a refrigerant that enables high heat transport capability and pumpless long-distance heat transport. To enhance the heat transport capacity of the magnetically-driven heat transport device using TSMF, it is effective to use a heating body with a very large heat exchange surface such as a heat sink or a porous medium. In the present study, the thermal flow of TSMF around a single heating pipe under a magnetic field was investigated. Visualization of the temperature field by infrared thermography showed that the application of the magnetic field dramatically developed the thermal boundary layer and improved heat transfer. It was clarified by numerical analysis that this dramatic variation in the thermal boundary layer was associated with several vortexes generated by magnetic force in the vicinity of the heating pipe.

Experimental Study on Effect of CO2 Heat Pump Evaporator on Frosting Condition

The theoretical analysis of frost formation had been made. The wind speed, temperature and relative humidity etc. had different effects respectively. A single heating was studied through the experiment. In different outdoor conditions, experimental data showed evaporator frost at the environment temperature of 10 °C, environment relative humidity was 70%. Comparing the experimental data, it is concluded that temperature of evaporator’s outlet is increasing with the outlet temperature. The refrigerant evaporation temperature and COP under different conditions has been tested. The relation of evaporation pressure and environmental temperature under different evaporation temperature had been concluded. According to the experiment, a defrost measure of this experiment equipment had been proposed.

Thermal Decomposition Study of Ferrocene [(C5H5)2Fe]

A single-step thermal decomposition of ferrocene [(C5H5)2Fe] using nonisothermal thermogravimetry (TG) has been studied using single- as well as multiple-heating rate programs. Both mechanistic and nonmechanistic methods have been used to analyze the TG data to estimate the kinetic parameters for the solid state reaction. Two different isoconversional methods (improved iterative method and model-free method) have been employed to analyze the TG results to find out whether the activation energy of the reaction depends on the extent of decomposition and to predict the most probable reaction mechanism of thermal decomposition as well. A comparison of the activation energy values for the single-step thermal reaction of ferrocene estimated by different methods has been made in this work. An appraisal on the applicability of single-heating rate data for the analysis of single-step thermal decompositions over the recommendations by the International Confederation for Thermal Analysis and Calorimetry (ICTAC) is made to look beyond the choice.