scholarly journals Manufacture of all-wood sawdust-based particle board using ionic liquid-facilitated fusion process

2021 ◽  
Vol 55 (2) ◽  
pp. 331-349
Author(s):  
Hannes Orelma ◽  
Atsushi Tanaka ◽  
Maija Vuoriluoto ◽  
Alexey Khakalo ◽  
Antti Korpela
Keyword(s):  
Tensile Strength ◽  
Ionic Liquid ◽  
Raw Materials ◽  
Weight Ratio ◽  
Fusion Process ◽  
The Novel ◽  
Particle Board ◽  
Microscopy Technique ◽  
Twin Screw ◽  
Fusion Approach

AbstractTraditional particle board can generate harmful indoor air emissions due to the volatile resin-based compounds present. This study investigated the preparation of sawdust particle board using the novel ionic liquid based fusion approach with [EMIM]OAc. The dissolution parameters were investigated using the thermal optical microscopy technique. The particle board sheets were prepared by hot pressing sawdust in the presence of ionic liquid (IL) ([EMIM]OAc) and subsequently purifying the fusion sawdust matrix from the IL with methanol. The fusion process of the sawdust particles was analysed with SEM and mechanical testing. The raw materials and the produced materials were investigated with elemental analysis, FTIR, and 13C-SS-NMR. IL fusion of the sawdust required a temperature above 150 °C, similar to the glass transition temperature (tg) of lignin. At lower temperatures, strong particle fusion was not obtained. It was observed that the sawdust/IL weight ratio was an important parameter of the fusion process, and a 1:3 weight ratio resulted in the strongest particle boards with a tensile strength of up to 10 MPa, similar to commercial particle boards. The particle fusion process was also studied with a twin-screw extruder. The extrusion enhanced the fusion of the sawdust particles by increasing dissolution of the sawdust particles, which was subsequently seen in elevated tensile strength (20 MPa). The study provides a practical view of how sawdust-based particle board can be manufactured using ionic liquid-based fusion.

scholarly journals Pembuatan Papan Partikel (Particle Board) dari Tandan Kosong Sawit dengan Perekat Kulit Akasia dan Gambir

2013 ◽  
Vol 9 (3) ◽  
pp. 138
Author(s):  
Umi Fathanah ◽  
Sofyana Sofyana
Keyword(s):  
Mechanical Property ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Oil Palm ◽  
Raw Materials ◽  
Research Result ◽  
Particle Board ◽  
Wet Condition ◽  
Dry Conditions ◽  
Wood Consumption

The need of wood as one of raw materials in furniture industry keeps increasing. One of efforts to reduce wood consumption is to develop research by creating composite design from material that contains sellulose to be particle board. Particle board is one of material alternatives that can be wood substitute. The objective of this research is to investigate the effect of natural-adhesive-mixture composition (acacia bark and gambier) with oil-palm-empty bunch toward mechanical property of particle board. Characterization of particle board was carried out by undertaking mechanical property testing (tensile strength and compressive strength) under wet and dry conditions. Composition variations of adhesive and oil-palm-empty bunch were 30:70; 40:60; 50:50; 60:40; 70:30. Making process of particle board is carried out by mixing oil-palm-empty bunch and adhesive with addition of 2% para-formaldehyde and water as much of 10%. Furthermore, the mixture is compressed by using Hot Press at temperature of 150oC and pressure of 10 kg/cm2 for 15 minutes. The research result indicates that the higher the adhesive composition (either adhesives of acacia bark or gambier), particle board resulted is better. In dry condition,  values of the tensile strength of particle boards  that have acacia bark adhesive and gambier adhesive have range of 84.2 - 104 Kgf/cm2 and 83.4 - 81.5 kg/cm2, respectively. Whereas, values of compressive strength of particle boards that have adhesives of acacia bark and gambier are in the range of 6.8 - 10.5 kg/cm2  and 6.3 - 9.3 kg/cm2, respectively. The values of tensile strength and compressive strength are obtained on compositions  of adhesive: oil-palm-empty bunch ≥ 40:60, and they have fulfilled satandard of SNI 03-2105-1996. The values of tensile strength and compressive strength of particle board in wet condition, either adhesives of acacia bark or gambier, have not fulfilled standard of SNI 03-2105-1996.Keywords: empty-bunch-oil palm, acacia bark, gambier, particle board, tensile strength

PAPAN PARTIKEL DARI CAMPURAN LIMBAH ROTAN DAN PENYULINGAN KULIT KAYU GEMOR (Alseodaphne spp)

2014 ◽  
Vol 6 (1) ◽  
pp. 41
Author(s):  
Budi Tri Cahyana
Keyword(s):  
Tensile Strength ◽  
Modulus Of Elasticity ◽  
Raw Materials ◽  
Modulus Of Rupture ◽  
Particle Board ◽  
Materials Used

Utilization of rattan waste and gemor bark (Alseodaphne spp) distillation  for particle board had been carried out. The aim of this research was to know physical mechanical particle board from rattan waste mixed with gemor bark distillation. The raw materials used were cut-rattan waste of 2 cm and gemor bark distillation mashed in 16 mesh. The adhesive used were starch and PVAC. Composition variety of the mixture of rattan waste and gemor bark distillation particle were 50%: 50%, 60%: 40%, 70%: 30% and 5% adhesive. The results showed that highest average of modulus of rupture (26,62 kg/cm2) was obtained in 60% : 40% comparison of rattan waste and gemor bark distillation with starch adhesive (a2b1) and the density was 0.75 gr/cm3. The highest average of modulus of elasticity (633,76 kg/cm2) was in composition of 60%: 40% with PVAc adhesive (a2b2) and the density was 0,71 gr/cm3. The highest average of tensile strength (3,15 kg/cm2) was obtained in composition of 60%: 40% with starch adhesive (a2b1) and the density was  0.75 gr/cm3.Keywords: rattan waste, gemor bark distillation, particle board

scholarly journals Development of Biocomposite Wall Cladding from Kenaf Fibre by Extrusion Molding Process

2011 ◽  
Vol 471-472 ◽  
pp. 239-244 ◽  
Author(s):  
Abdan Khalina ◽  
E.S. Zainudin ◽  
Abdul Rahman Mohd Faizal ◽  
H. Jalaluddin ◽  
A.H. Umar ◽  
...  
Keyword(s):  
Natural Fiber ◽  
Raw Materials ◽  
Weight Ratio ◽  
Tensile Modulus ◽  
Natural Fibre ◽  
Molding Process ◽  
Plastic Composite ◽  
Kenaf Fibre ◽  
Twin Screw ◽  
Materials Used

Nowadays, natural fibre-thermoplastics composites (NFPC) are replacing the conventional wood and timber due to its lower cost, avoid deforestation, higher strength-to-weight ratio and resistant to termites. These composites can be utilized for non-structural components of a building system such as decking, wall cladding, floor tiles and window frame. A natural fiber/plastic composite was produced by extrusion molding process to create a wall cladding profile. The raw materials used for the composites are 40% kenaf fibre and 60% polypropylene (PP). These materials were compounded through a twin-screw extruder and then cut into pellets. The moisture content found in the kenaf/PP composites (KPC) pellets was 2.89%. Therefore, the pellets required to be oven dried every time right before entering the hopper of the extruder. The temperature along the barrel was set to 180°C and the die head temperature is set to 165°C. At the end of the extrusion molding process, pressurized air was used for cooling the profile. Then, samples of the wall cladding were taken back to the laboratory for product quality assurance. Measurements of the samples show that the product experiences 3% of shrinkage in term of width and 1% of shrinkage in term of thickness. Water absorption test indicates an increase of 13.6% of weight after 24 hours immersion of water. Impact strength test was also conducted on the wall cladding samples and the mean result was 2.55 kJ/m². Tensile test on the extruded KPC product indicates a low tensile strength at 4.51 MPa and tensile modulus of 205.01 MPa. The sample also proven to be light weight as the density of the material was found to be 0.618g/cm³.

scholarly journals Mechanical and physical properties of regenerated biomass composite films from lignocellulosic materials in ionic liquid

BioResources ◽  
2019 ◽  
Vol 14 (2) ◽  
pp. 2584-2595
Author(s):  
Kehong Zhang ◽  
Hui Xiao ◽  
Yuhang Su ◽  
Yanrong Wu ◽  
Ying Cui ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Ionic Liquid ◽  
Raw Materials ◽  
Composite Films ◽  
Value Added ◽  
Physical And Mechanical Properties ◽  
Waste Paper ◽  
Cellulose Content ◽  
Lignocellulosic Materials ◽  
Waste Biomass

As an important sustainable source of biomass, lignocellulosic materials are highly recalcitrant to biotransformation, which limits their use and prevents economically viable conversion into value-added products. Ionic liquids (ILs) have emerged as attractive solvents for lignocellulosic biomass pretreatment in the production of biochemical feedstocks. In this work, a mixture of wood powder and waste paper was dissolved in the ionic liquid 1-allyl-3-methylimidazolium chloride ([AMIM]Cl). Composite films were made from the regenerated lignocellulosic materials in [AMIM]Cl by adjusting the ratio of the raw materials. The physical and mechanical properties of biomass composite films were determined by optical microscopy (OM), Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD), and tensile strength tests. The results indicated that lignocellulosic materials were dissolved in [AMIM]Cl by destroying inter- and intramolecular hydrogen bonds between lignocelluloses. With increasing waste paper cellulose content, the dissolution of the fir powder in [AMIM]Cl was accelerated, and the tensile strength and elongation at break of the composite films increased. The rate of dissolution initially rose rapidly with increasing content of waste paper cellulose content, but the rate leveled off when the content was above 40%. This research highlights new opportunities for biodegradable composite films made from waste biomass.

PEMANFAATAN LIMBAH KULIT DURIAN (Durio zibethinus) DAN KULIT CEMPEDAK (Artocarpus integer) SEBAGAI EDIBLE FILM

2014 ◽  
Vol 6 (1) ◽  
pp. 27 ◽  
Author(s):  
Desi Mustika Amaliyah
Keyword(s):  
Tensile Strength ◽  
Food Packaging ◽  
Raw Materials ◽  
Edible Films ◽  
Edible Film ◽  
Durio Zibethinus ◽  
Yield Result ◽  
Pre Treatment

Durian (Durio zibethinus) and cempedak (Artocarpus integer) peels waste are not used by the society. The research aim is to extract pectin from durian and cempedak peels and to formulate the pectin into edible films for food packaging. The research stages were first pre-treatment of durian and cempedak peels, pectin extraction, pectin drying, and  pectin application as edible films with concentration of 0%, 5%, and 15%. Based on this research it was concluded that pectin can be extracted from durian and cempedak peels with yield result of 27.97 % and 55.58 %, respectively. Edible film obtained has  similar characteristics between raw materials cempedak and durian peels. The higher concentration of cempedak peel  pectin increased the thickness, but decreased the tensile strength and elongation at a concentration of 15%. While in edible films from durian peel pectin, the higher concentration of pectin decreased the thickness of edible film on pectin concentration of 15%, lowered tensile strength and raised the edible film elongation.Keywords: waste, durian, cempedak, pectin extraction, edible film

scholarly journals End-of-Life Alternatives of Glass Reinforced Polyester Boat Hulls Compared by LCA

2018 ◽  
Vol 27 (4) ◽  
pp. 096369351802700 ◽  
Author(s):  
Mehmet Önal ◽  
Gökdeniz Neşer
Keyword(s):  
End Of Life ◽  
Environmental Impacts ◽  
Raw Materials ◽  
Weight Ratio ◽  
Cost Effective ◽  
Raw Material ◽  
Photochemical Oxidation ◽  
Human Toxicity ◽  
Vacuum Infusion ◽  
Infusion Method

Glass reinforced polyester (GRP), as a thermoset polymer composites, dominates boat building industry with its several advantages such as high strength/weight ratio, cohesiveness, good resistance to environment. However, proper recovering and recycling of GRP boats is became a current environmental requirement that should be met by the related industry. In this study, to propose in a cost effective and environmentally friendly way, Life Cycle Assessment (LCA) has been carried out for six scenarios include two moulding methods (namely Hand Lay-up Method, HLM and Vacuum Infusion Method, VIM) and three End-of-Life (EoL) alternatives(namely Extruding, Incineration and Landfill) for a recreational boat's GRP hulls. A case study from raw materials purchasing phase to disposal/recycling stages has been established taking 11 m length GRP boat hull as the functional unit. Analysis show that in the production phase, the impacts are mainly due to the use of energy (electricity), transport and raw material manufacture. Largest differences between the methods considered (HLM and VIM) can be observed in the factors of marine aquatic ecotoxicity and eutrophication while the closest ones are abiotic depletion, ozon layer depletion and photochemical oxidation. The environmental impact of VIM is much higher than HLM due to its higher energy consumption while vacuum infusion method has lower risk than hand lay-up method in terms of occupational health by using less raw material (resin) in a closed mold. In the comparison of the three EoL techniques, the mechanical way of recycling (granule extruding) shows better environmental impacts except terrestrial ecotoxicity, photochemical oxidation and acidification. Among the EoL alternatives, landfill has the highest environmental impacts except ‘global warming potential’ and ‘human toxicity’ which are the highest in extrusion. The main cause of the impacts of landfill is the transportation needs between the EoL boats and the licenced landfill site. Although it has the higher impact on human toxicity, incineration is the second cleaner alternative of EoL techniques considered in this study. In fact that the similar trend has been observed both in production and EoL phases of the boat. It is obvious that using much more renewable energy mix and greener transportation alternative can reduce the overall impact of the all phases considerably.

Effect of Microcrystalline Cellulose from Banana Stem Fiber on Mechanical Properties and Crystallinity of PLA Composite Films

2011 ◽  
Vol 695 ◽  
pp. 170-173 ◽  
Author(s):  
Voravadee Suchaiya ◽  
Duangdao Aht-Ong
Keyword(s):  
Tensile Strength ◽  
Young’S Modulus ◽  
Microcrystalline Cellulose ◽  
Young's Modulus ◽  
Agricultural Waste ◽  
Composite Films ◽  
Sem Image ◽  
Biocomposite Films ◽  
Twin Screw ◽  
Banana Stem

This work focused on the preparation of the biocomposite films of polylactic acid (PLA) reinforced with microcrystalline cellulose (MCC) prepared from agricultural waste, banana stem fiber, and commercial microcrystalline cellulose, Avicel PH 101. Banana stem microcrystalline cellulose (BS MCC) was prepared by three steps, delignification, bleaching, and acid hydrolysis. PLA and two types of MCC were processed using twin screw extruder and fabricated into film by a compression molding. The mechanical and crystalline behaviors of the biocomopsite films were investigated as a function of type and amount of MCC. The tensile strength and Young’s modulus of PLA composites were increased when concentration of MCC increased. Particularly, banana stem (BS MCC) can enhance tensile strength and Young’s modulus of PLA composites than the commercial MCC (Avicel PH 101) because BS MCC had better dispersion in PLA matrix than Avicel PH 101. This result was confirmed by SEM image of fractured surface of PLA composites. In addition, XRD patterns of BS MCC/PLA composites exhibited higher crystalline peak than that of Avicel PH 101/PLA composites

scholarly journals Influence of biological origin on the tensile properties of cellulose nanopapers

Cellulose ◽  
2021 ◽  
Author(s):  
Katri S. Kontturi ◽  
Koon-Yang Lee ◽  
Mitchell P. Jones ◽  
William W. Sampson ◽  
Alexander Bismarck ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Cell Wall ◽  
Bacterial Cellulose ◽  
Raw Materials ◽  
Cellulose Nanofibers ◽  
Nanofibrillated Cellulose ◽  
Primary Cell Wall ◽  
Biological Origin ◽  
Basic Principles ◽  
Fiber Mats

Abstract Cellulose nanopapers provide diverse, strong and lightweight templates prepared entirely from sustainable raw materials, cellulose nanofibers (CNFs). Yet the strength of CNFs has not been fully capitalized in the resulting nanopapers and the relative influence of CNF strength, their bonding, and biological origin to nanopaper strength are unknown. Here, we show that basic principles from paper physics can be applied to CNF nanopapers to illuminate those relationships. Importantly, it appeared that ~ 200 MPa was the theoretical maximum for nanopapers with random fibril orientation. Furthermore, we demonstrate the contrast in tensile strength for nanopapers prepared from bacterial cellulose (BC) and wood-based nanofibrillated cellulose (NFC). Endemic amorphous polysaccharides (hemicelluloses) in NFC act as matrix in NFC nanopapers, strengthening the bonding between CNFs just like it improves the bonding between CNFs in the primary cell wall of plants. The conclusions apply to all composites containing non-woven fiber mats as reinforcement. Graphic abstract

scholarly journals Evaluation of Binders in Twin-Screw Wet Granulation

Pharmaceutics ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 241
Author(s):  
Claudia Köster ◽  
Sebastian Pohl ◽  
Peter Kleinebudde
Keyword(s):  
Molecular Weight ◽  
Tensile Strength ◽  
Wet Granulation ◽  
Compression Pressure ◽  
Demineralized Water ◽  
Twin Screw

The binders povidone (Kollidon 30), copovidone (Kollidon VA64), hypromellose (Pharmacoat 606), and three types of hyprolose (HPC SSL-SFP, HPC SSL, and HPC SL-FP) were evaluated regarding their suitability in twin-screw wet granulation. Six mixtures of lactose and binder as well as lactose without binder were twin-screw granulated with demineralized water at different barrel fill levels and subsequently tableted. A screening run with HPC SSL determined the amount of water as an influential parameter for oversized agglomerates. Subsequent examination of different binders, especially Kollidon 30 and Kollidon VA64 resulted in large granules. All binders, except Pharmacoat 606, led to a reduction of fines compared to granulation without a binder. The molecular weight of applied hyproloses did not appear as influential. Tableting required an upstream sieving step to remove overlarge granules. Tableting was possible for all formulations at sufficient compression pressure. Most binders resulted in comparable tensile strengths, while Pharmacoat 606 led to lower and lactose without a binder to the lowest tensile strength. Tablets without a binder disintegrated easily, whereas binder containing tablets of sufficient tensile strength often nearly failed or failed the disintegration test. Especially tablets containing Pharmacoat 606 and HPC SL-FP disintegrated too slowly.

Micro Palm and Kenaf Fibers Reinforced PLA Composite: Effect of Volume Fraction on Tensile Strength

2011 ◽  
Vol 145 ◽  
pp. 1-5 ◽  
Author(s):  
K.W. Neoh ◽  
Kim Yeow Tshai ◽  
P.S. Khiew ◽  
Chin Hua Chia
Keyword(s):  
Tensile Strength ◽  
Mechanical Stability ◽  
Volume Fraction ◽  
Environmental Concern ◽  
Raw Materials ◽  
Kenaf Fiber ◽  
Composite Effect ◽  
Fiber Loading ◽  
Biodegradable Composite ◽  
Kenaf Fibers

Extensive environmental concern associated with the disposal of solid plastic wastes has stirred tremendous interest in the production and use of sustainable biodegradable polymers. Among the vast variety of available materials, Polylactic Acid (PLA) standout as the most commercially viable mass produced resin to date. However, its low thermal and mechanical stability, excessive brittleness, and relatively higher cost have led to numerous research efforts in producing biodegradable polymer composite filled with natural organic fibers. This paper describes the preparation and the mechanical characteristics of a compression molded biodegradable composite made entirely of renewable raw materials. The composites were reinforced with pulverized palm, kenaf and alkali (1M NaOH:fiber in ratio 2:1) treated kenaf fibers, at a fiber mass proportion of 20 to 60% blended PLA and processed in a custom-built compression mold. SEM microscan revealed that the kenaf fiber has a mean diameter of 40μm, length 1236.6μm, and aspect ratio of 31 while the measured values for palm fiber was 58.7μm, 1041.2μm, and 17.7, respectively. All resulting composites showed significant enhancement in tensile strength. At 20, 40 and 60% fiber loading, the palm/PLA composite recorded tensile strength increment of 46.9, 47.8 and 36.6%, respectively. For the kenaf/PLA composite, greatest improvement was achieved at 40% fiber loading with alkali treated kenaf, with approximately 54% higher than the neat PLA while only 12.6% was recorded for the non-treated kenaf/PLA composite, signifying that the surface modification greatly improved fiber-matrix adhesion. SEM observations on the fracture surface showed similar findings. Compared to commercially available palm/Polypropylene (palm/PP) composite at 50% fiber loading, our measured tensile strength for the PLA composite loaded with 40% alkali treated kenaf fiber was still about 20% lower. Further enhancement in the mechanical characteristic of the kenaf/PLA composite is required to push for its wider utilization in the polymer industry.

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