scholarly journals Adhesion Improvement of Thermoplastics-Based Composites by Atmospheric Plasma and UV Treatments

2021 ◽  
Author(s):  
Gennaro Scarselli ◽  
Dong Quan ◽  
Neal Murphy ◽  
Brian Deegan ◽  
Denis Dowling ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Adhesive Bonding ◽  
Contact Angles ◽  
Lap Joints ◽  
Surface Treatments ◽  
Polyphenylene Sulfide ◽  
Atmospheric Plasma ◽  
Thermoplastic Composites ◽  
Lap Shear ◽  
Carbon Fibre Composites

AbstractThe present work is concerned with adhesive bonding of thermoplastic composites used in general aerospace applications, including polyphenylene sulfide (PPS), polyetherimide (PEI) and polyetheretherketone (PEEK) carbon fibre composites. Three different surface treatments have been applied to the PEEK, PPS and PEI-based composites in order to enhance the adhesion: atmospheric plasma, ultraviolet radiation (UV) and isopropanol wiping as a control. Water contact angles and free surface energies were measured following the standard experimental procedure based on the employment of three different liquid droplets. Infrared spectroscopy and X-ray photoelectron spectroscopy (XPS) were subsequently performed to characterize the surface chemistry of the samples after treatment. The single lap joints were manufactured and bonded by an Aerospace grade epoxy-based film adhesive originally developed for use on metals but with the ability to bond treated thermoplastics to good strength (supplied by Henkel Ireland). Quasi-static (QS) tests were conducted. The lap shear strength was evaluated, and the failure mechanisms of the different joints were examined for the range of surface treatments considered. It was found that the performances of the PEEK and PPS joints were considerably improved by the plasma and UV treatments resulting in cohesive and delamination failures, while PEI was unaffected by the plasma and UV treatments and performed very well throughout.

The Consequence on Structural Adhesive Bonding of Humid Thermoplastic Composites and Possibilities of Prevention

2015 ◽  
Vol 825-826 ◽  
pp. 490-497
Author(s):  
Anselm Tobias Bochtler ◽  
Christian Knappe ◽  
Klaus Dilger
Keyword(s):  
Bonding Strength ◽  
Adhesive Bonding ◽  
Lightweight Design ◽  
Dissimilar Materials ◽  
Negative Influence ◽  
Thermoplastic Composites ◽  
Lap Shear ◽  
Lap Shear Test ◽  
Paint Drying ◽  
Cutting Processes

A modern lightweight design with dissimilar materials such as metals in combination with fiber-reinforced polycaprolactam represents a possible lightweight variant in the automotive body shop. One of the issues arising from the use of polycaprolactam is its hygroscopy. The collected moisture evaporates out during the curing of the adhesive in the paint drying process and causes the adhesive to foam up. This leads to a decrease of the structural bonding strength. Many different factors, such as waterjet cutting processes, transportation and storage in undefined environmental conditions before the gluing process, as well as the flushing bath of the painting pretreatment, can contribute to the component humidity.Based on the common lap-shear test, this essay presents the influence of the substrate humidity on the bonding strength as well as possible pretreatment methods to avoid or decrease the negative influence of the substrate humidity. Using infrared radiation or atmosphere plasma localized at the bonding spot, the substrate begins to dry resulting in a bond with better bonding strength. For the future it is planned to test other options like laser substrate drying, adhesive modifications with regard to viscosity and moisture catcher enrichment.

scholarly journals Effect of sizing agent on interfacial properties of carbon fiber-reinforced PMMA composite

2021 ◽  
Vol 30 ◽  
pp. 2633366X2097865
Author(s):  
Li Jian
Keyword(s):  
Shear Strength ◽  
Surface Treatment ◽  
Photoelectron Spectroscopy ◽  
Resin Composite ◽  
Contact Angles ◽  
Static Contact ◽  
Before And After ◽  
C Value ◽  
Interlayer Shear Strength ◽  
Pmma Resin

The surface treatment of carbon fibers (CFs) was carried out using a self-synthesized sizing agent. The effects of sizing agent on the surface of CFs and the interface properties of CF/polymethyl methacrylate (PMMA) composites were mainly studied. Scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and static contact angle were used to compare and study the CFs before and after the surface treatment, including surface morphology, surface chemical element composition, and wettability of the surface. The influence of sizing agent on the mechanical properties of CF/PMMA resin composite interface was investigated. The results show that after sizing treatment, the CF surface O/C value increased by 35.1% and the contact angles of CF and resin decreased by 16.2%. The interfacial shear strength and interlayer shear strength increased by 12.6%.

scholarly journals Multi-Objective Optimization of Resistance Welding Process of GF/PP Composites

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2560
Author(s):  
Guowei Zhang ◽  
Ting Lin ◽  
Ling Luo ◽  
Boming Zhang ◽  
Yuao Qu ◽  
...  
Keyword(s):  
Signal To Noise Ratio ◽  
Welding Process ◽  
Welding Current ◽  
Resistance Welding ◽  
Thermoplastic Composites ◽  
Current Time ◽  
Process Factor ◽  
Welding Equipment ◽  
Lap Shear ◽  
Adhesive Connections

Thermoplastic composites (TPCs) are promising materials for aerospace, transportation, shipbuilding, and civil use owing to their lightweight, rapid prototyping, reprocessing, and environmental recycling advantages. The connection assemblies of TPCs components are crucial to their application; compared with traditional mechanical joints and adhesive connections, fusion connections are more promising, particularly resistance welding. This study aims to investigate the effects of process control parameters, including welding current, time, and pressure, for optimization of resistance welding based on glass fiber-reinforced polypropylene (GF/PP) TPCs and a stainless-steel mesh heating element. A self-designed resistance-welding equipment suitable for the resistance welding process of GF/PP TPCs was manufactured. GF/PP laminates are fabricated using a hot press, and their mechanical properties were evaluated. The resistance distribution of the heating elements was assessed to conform with a normal distribution. Tensile shear experiments were designed and conducted using the Taguchi method to evaluate and predict process factor effects on the lap shear strength (LSS) of GF/PP based on signal-to-noise ratio (S/N) and analysis of variance. The results show that current is the main factor affecting resistance welding quality. The optimal process parameters are a current of 12.5 A, pressure of 2.5 MPa, and time of 540 s. The experimental LSS under the optimized parameters is 12.186 MPa, which has a 6.76% error compared with the result predicted based on the S/N.

scholarly journals Treatment of wood with atmospheric plasma discharge: study of the treatment process, dynamic wettability and interactions with a waterborne coating

Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Jure Žigon ◽  
Matjaž Pavlič ◽  
Pierre Kibleur ◽  
Jan Van den Bulcke ◽  
Marko Petrič ◽  
...  
Keyword(s):  
Plasma Treatment ◽  
Treatment Process ◽  
Beech Wood ◽  
Treated Wood ◽  
Plasma Discharge ◽  
Contact Angles ◽  
Atmospheric Plasma ◽  
Waterborne Coating ◽  
Spruce Wood ◽  
The Impact

AbstractPlasma treatment is becoming a mature technique for modification of surfaces of various materials, including wood. A better insight in the treatment process and the impact of the plasma on properties of wood bulk are still needed. The study was performed on Norway spruce and common beech wood, as well as their thermally modified variations. The formations of the airborne discharge, as well as mass changes of the treated wood, were monitored. The impact of such treatment on wood-coating interaction was investigated by evaluating the dynamic wettability and penetration into wood. At the wood surface, plasma streamers were observed more intense on denser latewood regions. Wood mass loss was higher with increasing number of passes through the plasma discharge and was lower for thermally modified wood than for unmodified wood. Plasma treatment increased the surface free energy of all wood species and lowered the contact angles of a waterborne coating, these together indicating enhanced wettability after treatment. Finally, the distribution and penetration depth of the coating were studied with X-ray microtomography. It was found that the coating penetrated deeper into beech than into spruce wood. However, the treatment with plasma increased the penetration of the coating only into spruce wood.

scholarly journals Clinching of Thermoplastic Composites and Metals—A Comparison of Three Novel Joining Technologies

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2286
Author(s):  
Benjamin Gröger ◽  
Juliane Troschitz ◽  
Julian Vorderbrüggen ◽  
Christian Vogel ◽  
Robert Kupfer ◽  
...  
Keyword(s):  
Computed Tomography ◽  
Composite Material ◽  
Process Design ◽  
Failure Mechanisms ◽  
Thermoplastic Composites ◽  
Material Structure ◽  
Shear Tests ◽  
Load Bearing ◽  
Lap Shear ◽  
Resultant Material

Clinching continuous fibre reinforced thermoplastic composites and metals is challenging due to the low ductility of the composite material. Therefore, a number of novel clinching technologies has been developed specifically for these material combinations. A systematic overview of these advanced clinching methods is given in the present paper. With a focus on process design, three selected clinching methods suitable for different joining tasks are described in detail. The clinching processes including equipment and tools, observed process phenomena and the resultant material structure are compared. Process phenomena during joining are explained in general and compared using computed tomography and micrograph images for each process. In addition the load bearing behaviour and the corresponding failure mechanisms are investigated by means of single-lap shear tests. Finally, the new joining technologies are discussed regarding application relevant criteria.

scholarly journals Time efficient laser modification of steel surfaces for advanced bonding in hybrid materials

2020 ◽  
Author(s):  
D. Voswinkel ◽  
D. Kloidt ◽  
O. Grydin ◽  
M. Schaper
Keyword(s):  
Adhesive Bonding ◽  
Scanning Speed ◽  
Laser Source ◽  
Lap Shear ◽  
Carbon Fibre Reinforced Polymer ◽  
Bonding Properties ◽  
Fibre Reinforced Polymer ◽  
Yvo4 Laser ◽  
Steel Surfaces ◽  
High Scanning Speed

AbstractLaser surface treatment of metals is one option to improve their properties for adhesive bonding. In this paper, a pulsed YVO4 Laser source with a wavelength of 1064 nm and a maximum power of 25 W was utilized to increase the surface area of the steel HCT490X in order to improve its bonding properties with a carbon fibre reinforced polymer (CFRP). Investigated was the influence of the scanning speed of the laser source on the bonding properties. For this purpose, the steel surfaces were ablated at a scanning speed between 1500 and 4500 mm/s. Afterwards the components were bonded with the adhesive HexBond™ 677. After lap shear tests were carried out on the specimen, the surfaces were inspected using scanning electron microscopy (SEM). The experiments revealed that the bonding quality can be improved with a high scanning speed, even when the surface is not completely ablated.

scholarly journals Static ultrasonic welding of carbon fibre unidirectional thermoplastic materials and the influence of heat generation and heat transfer

2021 ◽  
pp. 002199832097681
Author(s):  
F Köhler ◽  
IF Villegas ◽  
C Dransfeld ◽  
A Herrmann
Keyword(s):  
Cross Sections ◽  
Weld Line ◽  
Welding Process ◽  
Ultrasonic Welding ◽  
Thermoplastic Composites ◽  
Squeeze Flow ◽  
Anisotropic Flow ◽  
Lap Shear ◽  
Anisotropic Thermal Conductivity ◽  
Edge Defects

Ultrasonic welding is a promising technology to join fibre-reinforced thermoplastic composites. While current studies are mostly limited to fabric materials the applicability to unidirectional materials, as found in aerospace structures, would offer opportunities for joining primary aircraft structures. However, due to the highly anisotropic flow of a molten unidirectional ply undesired squeeze flow phenomena can occur at the edges of the weld overlap. This paper investigates how the fibre orientation in the plies adjacent to the weld line influences the welding process and the appearance of edge defects. Ultrasonic welding experiments with different layups and energy director configurations were carried out while monitoring temperatures at different locations inside and outside the weld overlap. The joints were characterized by single lap shear tests, analysis of corresponding fracture surfaces and microscopic cross-sections. Results showed that the anisotropic flow and the anisotropic thermal conductivity of the plies adjacent to the weld line have a distinct effect on the appearance and location of edge defects. By using energy directors that cover only part of the weld overlap area a new approach was developed to mitigate edge defects caused by the highly directional properties of the unidirectional plies.

scholarly journals P4VP Modified Zwitterionic Polymer for the Preparation of Antifouling Functionalized Surfaces

Nanomaterials ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 706 ◽  
Author(s):  
Chaoqun Wu ◽  
Yudan Zhou ◽  
Haitao Wang ◽  
Jianhua Hu
Keyword(s):  
Photoelectron Spectroscopy ◽  
Cell Attachment ◽  
Raft Polymerization ◽  
Polymer Brush ◽  
Contact Angles ◽  
Polymerization Process ◽  
Water Contact ◽  
Zwitterionic Polymers ◽  
Ito Glass ◽  
Zwitterionic Polymer

Zwitterionic polymers are suitable for replacing poly(ethylene glycol) (PEG) polymers because of their better antifouling properties, but zwitterionic polymers have poor mechanical properties, strong water absorption, and their homopolymers should not be used directly. To solve these problems, a reversible-addition fragmentation chain transfer (RAFT) polymerization process was used to prepare copolymers comprised of zwitterionic side chains that were attached to an ITO glass substrate using spin-casting. The presence of 4-vinylpyridine (4VP) and zwitterion chains on these polymer-coated ITO surfaces was confirmed using 1H NMR, FTIR, and GPC analyses, with successful surface functionalization confirmed using water contact angle, X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM) studies. Changes in water contact angles and C/O ratios (XPS) analysis demonstrated that the functionalization of these polymers with β-propiolactone resulted in hydrophilic mixed 4VP/zwitterionic polymers. Protein adsorption and cell attachment assays were used to optimize the ratio of the zwitterionic component to maximize the antifouling properties of the polymer brush surface. This work demonstrated that the antifouling surface coatings could be readily prepared using a “P4VP-modified” method, that is, the functionality of P4VP to modify the prepared zwitterionic polymer. We believe these materials are likely to be useful for the preparation of biomaterials for biosensing and diagnostic applications.

Directly bonded single lap joints of SiCp/AA2124 composite with glass fiber-reinforced polypropylene: Hole drilling effects on lap shear strength and out-of-plane impact response

2021 ◽  
pp. 002199832110316
Author(s):  
Nahit Öztoprak
Keyword(s):  
Glass Fiber ◽  
Matrix Composite ◽  
Lap Joints ◽  
Hole Drilling ◽  
Fiber Reinforced ◽  
Single Lap Joints ◽  
Lap Shear ◽  
Glass Fiber Reinforced ◽  
Out Of Plane ◽  
The Impact

Joining dissimilar materials to achieve lightweight design and energy efficiency has been increasingly popular. A joint formed by components of particle-reinforced metal and polymer matrix composite combines the merits of both materials. This paper is mainly focused on the research of the tensile lap shear and impact behavior of the dissimilar single-lap joints (SLJs) between SiCp/AA2124 composite and glass fiber-reinforced polypropylene (PP). The effects of out-of-plane loading applied from different surfaces of SLJs on impact responses are evaluated. Hot pressing technique is introduced to manufacture metal/polymer assembly without using any adhesive. The hole drilling effect is investigated with the idea that it may provide weight reduction and also increase the strength of the dissimilar SLJs. The results indicate that the dissimilar SLJs show more Charpy impact strength when the impact is performed on the metal-matrix composite (MMC). Mechanical properties of SLJs are adversely affected by a drilled hole in the MMC adherend.

Sign in / Sign up

Export Citation Format

Share Document