Development of an Environmentally Friendly Adsorbent for the Removal of Toxic Heavy Metals from Aqueous Solution

2011 ◽  
Vol 223 (4) ◽  
pp. 1837-1846 ◽  
Author(s):  
Jae-Woo Choi ◽  
Seung-Gun Chung ◽  
Seok-Won Hong ◽  
Dong-Ju Kim ◽  
Sang-Hyup Lee
2006 ◽  
Vol 55 (1-6) ◽  
pp. 263-268 ◽  
Author(s):  
Scott A. Merkle

Abstract Pollution of soil and water with heavy metals such as mercury, cadmium and arsenic, is a worldwide problem. Phytoremediation, the use of plants to remove, sequester or detoxify pollutants, including heavy metals, offers an environmentally-friendly alternative to engineering- based methods for remediation. Forest trees have multiple features that make them particularly useful for removal of toxic heavy metals, especially if they can be engineered with genes allowing them to handle high levels of these elements. Although still in its infancy, research with transgenic trees carrying genes allowing them to detoxify or sequester some heavy metals has already made promising progress. Most of the work to date has been performed using poplar species and hybrids, although other woody species could be equally as useful. Trees have been engineered with genes for the handling of mercury, cadmium, copper and arsenic following two main approaches, phytoextraction and phytotransformation/ phytovolatilizaton. In vitro studies have shown the transgenic trees to have enhanced abilities to tolerate and/or accumulate these metals, and preliminary results from field tests indicate that the trees are functioning. New combinations of genes involved in metal transport or conversion may further enhance the heavy metal remediation capabilities of the transgenic trees. Given the environmentally friendly application, forest trees engineered for phytoremediation may be some of the first transgenic forest trees approved for operational deployment.


Our Nature ◽  
2013 ◽  
Vol 11 (1) ◽  
pp. 11-16 ◽  
Author(s):  
N. Gandhi ◽  
D. Sirisha ◽  
K.B. Chandra Sekhar

The presence of toxic heavy metals such as chromium (VI) contaminants in aqueous streams, arising from the discharge of untreated metal containing effluents into water bodies, is one of the most important environmental problems. Adsorption is one of the effective techniques for chromium (VI) removal from wastewater. In the present study, adsorbent was prepared from low cost adsorbents and studies were carried out for chromium (VI) removal. Batch adsorption studies demonstrated that the adsorbents had significant capacity to adsorb the chromium from aqueous solution. It was found that the adsorption increased with increase in contact time and adsorbent dosage. An attempt was made to study mixed algae as an adsorbent for removal of chromium (VI).DOI: http://dx.doi.org/10.3126/on.v11i1.8238 Our Nature Vol.11(1) 2013: 11-16?


2018 ◽  
Vol 42 (24) ◽  
pp. 19785-19794 ◽  
Author(s):  
Li-Ping Jiang ◽  
Hai-Xiong Shi ◽  
Feng-Ying Chai

A simplified “water-in-oil” “one-pot” production process for preparing a covalently bonded nanocomposite soft magnetic beadlike adsorbent is developed.


Water ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1257 ◽  
Author(s):  
Houwaida Nefzi ◽  
Manef Abderrabba ◽  
Sameh Ayadi ◽  
Jalel Labidi

Environmental contamination by toxic heavy metals is a serious worldwide phenomenon. Thus, their removal is a crucial issue. In this study, we found an efficient adsorbent to remove Cu2+ and Ni2+ from aqueous solution using two materials. Chemical modification was used to obtain palygorskite clay from diatomite. The adsorbents were characterized using X-ray florescence, Fourier transform infrared spectroscopy and X-ray diffraction. The effects of contact time, initial concentration, temperature and pH on the adsorption process were investigated. Our results showed that the (%) of maximum adsorption capacity of diatomite was 78.44% for Cu2+ at pH 4 and 77.3% for Ni2+ at pH 7, while the (%) of the maximum adsorption on palygorskite reached 91% for Cu2+ and 87.05% for Ni2+, in the same condition. The results indicate that the pseudo-second-order model can describe the adsorption process. Furthermore, the adsorption isotherms could be adopted by the Langmuir and the Freundlich models with good correlation coefficient (R2). Thus, our results showed that palygorskite prepared from Tunisian diatomite is a good adsorbent for the removal of heavy metals from water.


RSC Advances ◽  
2015 ◽  
Vol 5 (107) ◽  
pp. 88331-88338 ◽  
Author(s):  
Kamal Kumar Bhatluri ◽  
Sushma Chakraborty ◽  
Mriganka Sekhar Manna ◽  
Aloke Kumar Ghoshal ◽  
Prabirkumar Saha

This paper presents an experimental investigation of simultaneous extraction and recovery of harmful heavy metals from the industrial wastewater through Bulk Liquid Membrane (BLM) based technology.


Author(s):  
MdDidarul Islam, Ashiqur Rahaman, Aboni Afrose

This study was based on determining concentration of essential and toxic heavy metal in coconut water available at a local Hazaribagh area in Dhaka, Bangladesh. All essential minerals, if present in the drinking water at high concentration or very low concentration, it has negative actions. In this study, fifteen samples and eight heavy metals were analyzed by Atomic Absorption Spectroscopy (AAS) method which was followed by wet ashing digestion method. The concentration obtained in mg/l were in the range of 0.3 to 1.5, 7.77 to 21.2, 0 to 0.71, 0 to 0.9, 0 to 0.2, 0.9 to 17.3, 0.1 to 0.9, 0 to 0.9 and 0 to 0.7 for Fe, Ni, Cu, Cd, Cr, Zn, Pb and Se respectively. From this data it was concluded that any toxic heavy metals like Cd, Cr, Pb and Ni exceed their toxicity level and some essential nutrients were in low concentration in those samples. 


2017 ◽  
Vol 1 ◽  
pp. 264
Author(s):  
Md Didarul Islam ◽  
Ashiqur Rahaman ◽  
Fahmida Jannat

This study was based on to determine the concentration of macro and micro nutrients as well as toxic and nontoxic heavy metals present in the chicken feed available in Dhaka city of Bangladesh. All macro nutrients, if present in the feed at high concentration have some adverse effect, at the same time if this nutrient present in the feed at low concentration this have some adverse effect too. So that this nutrient level should be maintained at a marginal level. On the other side toxic heavy metals if present in the feed at very low concentration those can contaminate the total environment of the ecosystem. In this study six brand samples (starter, grower, finisher and layer) which was collected from different renowned chicken feed formulation industry in Bangladesh. Those samples were prepared for analysis by wet ashing and then metals were determined by Atomic Absorption Spectroscopy. It was found that 27.7 to 68.4, 57.3 to 121.9, 0.21 to 4.1, 0.32 to 2.1, 0.11 to 1.58, 0.28 to 2.11 and 0.28 to 1.78 for zinc, iron, copper, mercury, cadmium, nickel and cobalt respectively. It was found that essential macro and micro nutrients were present in the feed in low concentration on the other side mercury was present in high concentration in the feed samples.


2017 ◽  
Vol 68 (10) ◽  
pp. 2363-2366
Author(s):  
Delia Nica Badea

The paper evaluates the presence and content of traces of heavy metals Hg, Pb, Ni, Cd (total forms) from coal and solid combustion products, the degree of transfer and accessibility in the area of influence of a lignite power plant. The content of toxic heavy metals in residues are characterized by RE Meiji [ 1 (Pb and Hg) and REMeij �1 (Ni and Cd) for the filter ash. Pb and Ni content in the soil exceeds normal values, and Pb exceeds and alert value for sensitive soils around the residue deposit (70.20 mg.Kg-1). The degree of accessibility of the metals in plants (TF), reported at the Khan reference value (0.5), indicates a significant bioaccumulation level for the metals: Cd (1.9) and Hg (0.6) inside the deposit; Cd (0.39) at the base of the deposit, Hg (0.8) in the area of the thermal power plant. The trace levels of heavy metals analyzed by GFAAS and CVAAS (Hg), indicates a moderate risk potential for food safety and quality of life in the studied area.


Author(s):  
Varsha Shukla ◽  
Siddharth Kumar Das ◽  
Abbas Ali Mahdi ◽  
Shweta Agarwal ◽  
Ragini Alok ◽  
...  

BACKGROUND: Fibromyalgia syndrome (FMS) is an extra-articular rheumatological disease characterised by widespread chronic musculoskeletal pain. Metal-induced oxidative stress contributes to the severity of FMS. AIMS: First, this study evaluated the association between plasma levels of toxic heavy metals and essential metals with oxidative stress (OS) markers. Second, the OS markers and metal contents were correlated with the disease severity by assessing the Fibromyalgia Impact Questioner Revised (FIQR) and tender points (TP). METHOD: A total of 105 FMS patients and 105 healthy controls of similar age and sex were recruited. OS parameter such as lipid peroxidation (LPO), protein carbonyl group (PCG), nitric oxide (NO) and essential metals such as zinc (Zn), magnesium (Mg), manganese (Mn), copper (Cu) and toxic heavy metals such as aluminium (Al), arsenic (As), lead (Pb) were estimated. RESULTS: Levels of LPO, PCG, NO (p< 0.001) and Cu, Mn, and Al (p< 0.001), were significantly higher, and Mg (p< 0.001) and Zn (p< 0.001) were significantly lower in patients compared to controls. A positive association was observed between OS parameters, FIQR and TP with Cu, Al and Mn. A significant negative association was observed between Zn and Mg with FIQR, TP and OS parameters. CONCLUSION: Heavy metals such as Al induce OS parameters and decrease the levels of essential trace elements such as Mg and Zn, which may be responsible for the severity of FMS.


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