scholarly journals Effect of processing parameters on in situ screen printing-assisted synthesis and electrical properties of Ti3SiC2-based structures

2021 ◽  
Vol 10 (1) ◽  
pp. 129-138
Author(s):  
Mylena Lorenz ◽  
Nahum Travitzky ◽  
Carlos R. Rambo

AbstractThis work reports on the development of pastes containing Ti, TiC, Si, and C elementary powders for in situ synthesis of Ti3SiC2 via screen printing. Four paste compositions were manufactured using two powder mixtures (Ti/Si/C and Ti/TiC/Si/C) with different stoichiometry. The pastes were screen printed onto Al2O3 substrates and sintered at 1400 ℃ in argon varying the dwell time from 1 to 5 h. The printed pastes containing TiC and excess of Si exhibited the lowest surface roughness and after 5 h sintering comprised of Ti3SiC2 as the majority phase. The electrical conductivity of this sample was found to range from 4.63×104 to 2.57×105 S·m–1 in a temperature range of 25–400 ℃.

2019 ◽  
Vol 50 (3) ◽  
pp. 333-345 ◽  
Author(s):  
Danmei Sun ◽  
Meixuan Chen ◽  
Symon Podilchak ◽  
Apostolos Georgiadis ◽  
Qassim S Abdullahi ◽  
...  

Smart and interactive textiles have been attracted great attention in recent years. This research explored three different techniques and processes in developing textile-based conductive coils that are able to embed in a garment layer. Coils made through embroidery and screen printing have good dimensional stability, although the resistance of screen printed coil is too high due to the low conductivity of the print ink. Laser cut coil provided the best electrical conductivity; however, the disadvantage of this method is that it is very difficult to keep the completed coil to the predetermined shape and dimension. The tested results show that an electromagnetic field has been generated between the textile-based conductive coil and an external coil that is directly powered by electricity. The magnetic field and electric field worked simultaneously to complete the wireless charging process.


Energies ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 2849 ◽  
Author(s):  
Yong Du ◽  
Haixia Li ◽  
Xuechen Jia ◽  
Yunchen Dou ◽  
Jiayue Xu ◽  
...  

Graphite/poly(3,4-ethyenedioxythiophene) (PEDOT) nanocomposites were prepared by an in-situ oxidative polymerization process. The electrical conductivity and Seebeck coefficient of the graphite/PEDOT nanocomposites with different content of graphite were measured in the temperature range from 300 K to 380 K. The results show that as the content of graphite increased from 0 to 37.2 wt %, the electrical conductivity of the nanocomposites increased sharply from 3.6 S/cm to 80.1 S/cm, while the Seebeck coefficient kept almost the same value (in the range between 12.0 μV/K to 15.1 μV/K) at 300 K, which lead to an increased power factor. The Seebeck coefficient of the nanocomposites increased from 300 K to 380 K, while the electrical conductivity did not substantially depend on the measurement temperature. As a result, a power factor of 3.2 μWm−1 K−2 at 380 K was obtained for the nanocomposites with 37.2 wt % graphite.


2019 ◽  
Vol 2019 ◽  
pp. 1-8
Author(s):  
Hector R. Mendez-Rossal ◽  
Gernot M. Wallner

Conductive inks’ performance is affected by the printing conditions and the substrate’s properties. In this study, one graphite-, one polymer-, and two silver-based conductive inks were printed on four primer-coated metal substrates by screen printing. The compatibility and wettability between the inks and the primers were evaluated by infrared spectroscopy and surface energy measurements. The printed structures were characterized by laser confocal microscopy, peel-off tape testing, and four-point probe electrical resistivity testing. In general, silver inks exhibited the best performance in terms of printability and electrical conductivity. The graphite ink presented the worst printing, adhesion, and functional properties. The polymer-based ink revealed poor wettability but good adhesion and functionality. The surface roughness, energy, and polarity of the primer coating had no significant influence on the electrical conductivity of the printed inks.


1991 ◽  
Vol 235 ◽  
Author(s):  
Jung H. Shin ◽  
J. S. Im ◽  
H. A. Atwater

ABSTRACTThe dynamics of relaxation of amorphous silicon after unrelaxation (creation of defects) by irradiation with 600 KeV Kr++ ions is investigated using the changes in electrical conductivity of amorphous silicon. By measuring the conductivity of such unrelaxed amorphous silicon after being partially relaxed by isochronal anneals in a temperature range from 383 to 873° K, it is shown that conductivity of amorphous silicon decreases monotonically by up to 3 orders of magnitude as it relaxes; i.e. that conductivity is a measure of the degree of relaxation. Furthermore, it is found that such change in conductivity can be completely reversed by a subsequent unrelaxation with ion irradiation. Continuous in situ measurements of conductivity of amorphous silicon before, during and immediately after irradiation in a temperature range from 77 to 573° K show that relaxation occurs even at 77°K. Finally, the relaxation of amorphous silicon thus measured is linear when plotted against ln(t), a behavior that is characteristic of relaxation with a spectrum of activation energies.


2017 ◽  
Vol 35 (1) ◽  
pp. 105-110 ◽  
Author(s):  
Mohammad Hassan Omidi ◽  
Mahboobeh Alibeygi ◽  
Farideh Piri ◽  
Mohammad Masoudifarid

AbstractIn this work, a novel polystyrene/Fe3O4 nanocomposite prepared by in-situ method is presented. Magnetic Fe3O4 nanoparticles were encapsulated by polystyrene. The FT-IR spectra confirmed polystyrene/Fe3O4 nanocomposite preparation. The electrical properties of prepared nanocomposite were investigated by cyclic voltammetry (CV). The CV analysis showed good electrical conductivity of the synthesized nanocomposite. Magnetic properties of the nanocomposite were studied by vibrating sample magnetometer (VSM). The VSM analysis confirmed magnetic properties of the nanocomposite. The morphology and the size of the synthesized nanocomposite were investigated by field emission scanning electron microscope (FESEM). According to the VSM and CV results, such nanocomposite can be used in microelectromechanical systems.


2012 ◽  
Vol 2012 ◽  
pp. 1-4 ◽  
Author(s):  
S. Chenna Krishna ◽  
N. Supriya ◽  
Abhay K. Jha ◽  
Bhanu Pant ◽  
S. C. Sharma ◽  
...  

In the present investigation, thermal conductivity of Cu-Cr-Zr-Ti alloy was determined as the product of the specific heat (), thermal diffusivity (), and density () in the temperature range of 300–873 K. The experimental results showed that the thermal conductivity of the alloy increased with increase in temperature up to 873 K and the data was accurately modeled by a linear equation. For comparison, thermal conductivity was also evaluated for OFHC copper in the same temperature range. The results obtained were discussed using electrical conductivity and hardness measurements made at room temperature. Transmission electron microscopy (TEM) was done to understand the microstructural changes occurring in the sample after the test. Wiedemann-Franz-Lorenz law was employed for calculating electronic and phonon thermal conductivity using electrical conductivity. On the basis of studies conducted it was deduced that in situ aging may be one of the reasons for the increase in thermal conductivity with temperature for Cu-Cr-Zr-Ti alloy.


2019 ◽  
Vol 33 (02) ◽  
pp. 1950010
Author(s):  
D. K. Das ◽  
Jit Sarkar

Silicene, the honeycomb 2D structured silicon, is addressed as cousin of graphene, by many researchers. Its unique properties draw the attention of researchers round the globe. Electrical properties of silicene are also reported by other researchers. In this paper, we estimate electrical resistivity, electrical conductivity and Lorenz number for silicene within the temperature range from 100 K to 500 K. Variation of these parameters with respect to sample size is also reported. The novelty of our work is that till now the Lorenz number and variation of electrical properties within this wide temperature range of 100–500 K for silicene have not yet been reported. We also observed that with variation of sample sizes electrical resistance of silicene sheet remains unaffected whereas the other electrical properties vary. This is due to tunneling effect of semiconductors, which is due to uneven distribution of atoms (buckled structure) in planes.


2006 ◽  
Vol 977 ◽  
Author(s):  
Charles J. Capozzi ◽  
Rosario A. Gerhardt

AbstractThere are few studies that discuss the effect of the fabrication conditions and bulk thickness on the electrical conductivity of hot pressed polymer-matrix composites. For polymer-matrix composites that possess a segregated-network microstructure, the processing parameters can significantly impact the electrical properties and microstructure of the composite material. Our group has recently fabricated novel polymer-matrix nanocomposites, which possess a segregated network microstructure containing regular, polyhedral-shaped polymer matrix particles1-2. This paper investigates the effect of processing pressure and specimen thickness on the electrical properties and microstructure of hot pressed poly(methyl methacrylate) (PMMA) containing segregated networks of indium tin oxide (ITO) nanopowders.


2013 ◽  
Vol 200 ◽  
pp. 193-198 ◽  
Author(s):  
Aleksandr V. Yatsenko ◽  
A.S. Pritulenko ◽  
S.V. Yevdokimov ◽  
Dmytro Yu. Sugak ◽  
I.M. Solskii

The low-frequency impedance spectroscopy method has been used to investigate the electrical conductivity peculiarities of lithium niobate (LN) crystals reduced in hydrogen. It has been found that the activation energy value of the dark electrical conductivity of such crystals in a temperature range of 288...370 К is equal to 0.68±0.02 eV. It has been demonstrated that the multiple heating of «black» LN crystals up to a temperature of about 420 K results in surface layers with modified electrical properties to occur in the crystal’s polar faces. The electrical conductivity mechanism of LiNbO3 crystals reduced in the hydrogen-containing atmosphere, and the causes of the instability of these properties are discussed.


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