VOC removal from ventilation air by gas-to-particle conversion: Towords the Enhancement of process efficiency

2022 ◽  
Vol 209 ◽  
pp. 108647
Author(s):  
Edvinas Krugly ◽  
Oleh Pitak ◽  
Darius Ciuzas ◽  
Martynas Tichonovas ◽  
Inga Stasiulaitiene ◽  
...  
Keyword(s):  
Process Efficiency ◽  
Voc Removal

Performance Analysis on Eco-friendly Machining of Ti6Al4V using Powder Mixed with Different Dielectrics in WEDM

2020 ◽  
Vol 17 (3) ◽  
pp. 8128-8139
Author(s):  
S. Chakraborty ◽  
S. Mitra ◽  
D. Bose
Keyword(s):  
Metal Removal ◽  
Removal Rate ◽  
Machining Process ◽  
Process Efficiency ◽  
Machining Parameters ◽  
Dielectric Fluids ◽  
High Emission ◽  
Pulse On Time ◽  
Pulse Off Time ◽  
Wedm Process

The recent scenario of modern manufacturing is tremendously improved in the sense of precision machining and abstaining from environmental pollution and hazard issues. In the present work, Ti6Al4V is machined through wire EDM (WEDM) process with powder mixed dielectric and analyzed the influence of input parameters and inherent hazard issues. WEDM has different parameters such as peak current, pulse on time, pulse off time, gap voltage, wire speed, wire tension and so on, as well as dielectrics with powder mixed. These are playing an essential role in WEDM performances to improve the process efficiency by developing the surface texture, microhardness, and metal removal rate. Even though the parameter’s influencing, the study of environmental effect in the WEDM process is very essential during the machining process due to the high emission of toxic vapour by the high discharge energy. In the present study, three different dielectric fluids were used, including deionised water, kerosene, and surfactant added deionised water and analysed the data by taking one factor at a time (OFAT) approach. From this study, it is established that dielectric types and powder significantly improve performances with proper set of machining parameters and find out the risk factor associated with the PMWEDM process.

THEORETICAL STUDY OF THE EFFECT OF GEOMETRICAL PARAMETERS AND LOCATION OF ROTOR IMPACT ELEMENTS OF AN IMPACT-CENTRIFUGAL GRINDER ON SPEED AND ANGLES OF CRUSHED PARTICLES FLIGHT

2020 ◽  
Keyword(s):  
Granulometric Composition ◽  
Theoretical Study ◽  
Process Efficiency ◽  
Geometrical Parameters ◽  
Grinding Process ◽  
Main Work ◽  
Impact Element ◽  
The Impact ◽  
Positive Effect ◽  
Efficiency Indicators

One of efficiency indicators of grain grinders is grain granulometric composition. The basis of mixed fodder is crushed grain, the particles of which must have a leveled granulometric composition for subsequent mixing and obtaining a high-quality feed mixture. In agricultural production, hammer crushers are widely used, in which the destruction of grain occurs due to the impact of a hinged hammer. The main disadvantage of these crushers is that not the entire surface of the hammers is involved in grinding, thus reduces grinding process efficiency. A slightly different principle of material destruction is laid down in the basis of the proposed design of the shock-centrifugal grinder. Main work is performed by flat impact elements located on the rotor, which serve to accelerate crushed particles with subsequent impact of them on the bump elements. An important step in the design of new constructions of shock-centrifugal grinders is to determine size and location of the impact elements on the rotor, without which the grinding process is not possible. In the calculation method presented, the dependencies for determining the velocities and angles of a single particle flight from the surface of a flat impact element for its specified dimensions are proposed. Two variants of an impact element location on the rotor are considered and analyzed: radial and at an angle in the direction of rotor rotation. As a result of research carried out, it is noted that in the case of inclined position of an impact element on the rotor an increase in flight speed and flight angles change in crushed particles, which gives the opportunity to have a positive effect on grinding process.

Experimental Studies Concerning the Semipermeable Membrane Separation Efficiency for 134Cs, 137Cs, 57Co, 58Co, 60Co, 54Mn in Liquid Radioactive Waste I. Treatment of secondary waste from POD decontamination procedure

2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Mirela Dulama ◽  
Nicoleta Deneanu ◽  
Cristian Dulama ◽  
Margarit Pavelescu
Keyword(s):  
Membrane Separation ◽  
Separation Efficiency ◽  
Liquid Radioactive Waste ◽  
Experimental Studies ◽  
Experimental Tests ◽  
Suspended Solid ◽  
Process Efficiency ◽  
Active Charcoal ◽  
Precipitation Process ◽  
Pre Treatment

The paper presents the experimental tests concerning the treatment by membrane techniques of radioactive aqueous waste. Solutions, which have been treated by using the bench-scale installation, were radioactive simulated secondary wastes from the decontamination process with modified POD. Generally, an increasing of the retention is observed for most of the contaminants in the reverse osmosis experiments with pre-treatment steps. The main reason for taking a chemical treatment approach was to selectively remove soluble contaminants from the waste. In the optimization part of the precipitation step, several precipitation processes were compared. Based on this comparison, mixed [Fe(CN)6]4-/Al3+/Fe2+ was selected as a precipitation process applicable for precipitation of radionuclides and flocculation of suspended solid. Increased efficiencies for cesium radionuclides removal were obtained in natural zeolite adsorption pre-treatment stages and this was due to the fact that volcanic tuff used has a special affinity for this element. Usually, the addition of powdered active charcoal serves as an advanced purifying method used to remove organic compounds and residual radionuclides; thus by analyzing the experimental data (for POD wastes) one can observe a decreasing of about 50% for cobalt isotopes subsequently to the active charcoal adsorption.. The semipermeable membranes were used, which were prepared by the researchers from the Research Center for Macromolecular Materials and Membranes, Bucharest. The process efficiency was monitored by gamma spectrometry.

LC–MS-MS Method for the Determination of Antidepressants and Benzodiazepines in Meconium

2020 ◽  
Vol 44 (6) ◽  
pp. 580-588
Author(s):  
A López-Rabuñal ◽  
E Lendoiro ◽  
M Concheiro ◽  
M López-Rivadulla ◽  
A Cruz ◽  
...  
Keyword(s):  
Extraction Efficiency ◽  
Solid Phase ◽  
Gradient Methods ◽  
Reversed Phase ◽  
Process Efficiency ◽  
Limit Of Quantification ◽  
Mode 2 ◽  
Positive Mode ◽  
Compound Method

Abstract An LC–MS-MS method for the determination of 14 benzodiazepines (BZDs) (alprazolam, α-hydroxyalprazolam, clonazepam, bromazepam, diazepam, nordiazepam, lorazepam, lormetazepam, oxazepam, flunitrazepam, 7-aminoflunitrazepam, triazolam, midazolam and zolpidem) and 15 antidepressants (ADs) (amitriptyline, nortriptyline, imipramine, desipramine, clomipramine, norclomipramine, fluoxetine, norfluoxetine, sertraline, norsertraline, paroxetine, venlafaxine, desmethylvenlafaxine, citalopram and desmethylcitalopram) in meconium was developed and validated. Meconium samples (0.25 ± 0.02 g) were homogenized in methanol and subjected to mixed-mode cation exchange solid-phase extraction. Chromatographic separation was performed in reversed phase, with a gradient of 0.1% formic acid in 2 mM ammonium formate and acetonitrile. Two different chromatographic gradient methods were employed, one for the separation of ADs and another for BZDs. Analytes were monitored by tandem mass spectrometry employing electrospray positive mode in MRM mode (2 transitions per compound). Method validation included: linearity [n = 5, limit of quantification (LOQ) to 400 ng/g], limits of detection (n = 6, 1–20 ng/g), LOQ (n = 9, 5–20 ng/g), selectivity (no endogenous or exogenous interferences), accuracy (n = 15, 90.6–111.5%), imprecision (n = 15, 0–14.6%), matrix effect (n = 10, −73 to 194.9%), extraction efficiency (n = 6, 35.9–91.2%), process efficiency (n = 6, 20.1–188.2%), stability 72 h in the autosampler (n = 3, −8.5 to 9%) and freeze/thaw stability (n = 3, −1.2 to −47%). The method was applied to four meconium specimens, which were analyzed with and without hydrolysis (enzymatic and alkaline). The authentic meconium samples tested positive for alprazolam, α-hydroxyalprazolam, clonazepam, diazepam, nordiazepam, fluoxetine, norfluoxetine, clomipramine and norclomipramine. Therefore, the present LC–MS-MS method allows a high throughput determination of the most common BZDs and ADs in meconium, which could be useful in clinical and forensic settings.

scholarly journals Tanning Wastewater Treatment by Ultrafiltration: Process Efficiency and Fouling Behavior

Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 461
Author(s):  
Fu Yang ◽  
Zhengkun Huang ◽  
Jun Huang ◽  
Chongde Wu ◽  
Rongqing Zhou ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Shear Rate ◽  
Membrane Surface ◽  
Filtration Efficiency ◽  
Operating Conditions ◽  
Process Efficiency ◽  
Transmembrane Pressure ◽  
Leather Industry ◽  
Pore Blocking ◽  
The Impact

Ultrafiltration is a promising, environment-friendly alternative to the current physicochemical-based tannery wastewater treatment. In this work, ultrafiltration was employed to treat the tanning wastewater as an upstream process of the Zero Liquid Discharge (ZLD) system in the leather industry. The filtration efficiency and fouling behaviors were analyzed to assess the impact of membrane material and operating conditions (shear rate on the membrane surface and transmembrane pressure). The models of resistance-in-series, fouling propensity, and pore blocking were used to provide a comprehensive analysis of such a process. The results show that the process efficiency is strongly dependent on the operating conditions, while the membranes of either PES or PVDF showed similar filtration performance and fouling behavior. Reversible resistance was the main obstacle for such process. Cake formation was the main pore blocking mechanism during such process, which was independent on the operating conditions and membrane materials. The increase in shear rate significantly increased the steady-state permeation flux, thus, the filtration efficiency was improved, which resulted from both the reduction in reversible resistance and the slow-down of fouling layer accumulate rate. This is the first time that the fouling behaviors of tanning wastewater ultrafiltration were comprehensively evaluated, thus providing crucial guidance for further scientific investigation and industrial application.

scholarly journals Efficiency stagnation in global steel production urges joint supply- and demand-side mitigation efforts

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Peng Wang ◽  
Morten Ryberg ◽  
Yi Yang ◽  
Kuishuang Feng ◽  
Sami Kara ◽  
...  
Keyword(s):  
Supply And Demand ◽  
Flow Analysis ◽  
Steel Production ◽  
Fold Increase ◽  
Process Efficiency ◽  
Mitigation Measures ◽  
Carbon Intensity ◽  
Climate Mitigation ◽  
Past Century ◽  
Demand Side

AbstractSteel production is a difficult-to-mitigate sector that challenges climate mitigation commitments. Efforts for future decarbonization can benefit from understanding its progress to date. Here we report on greenhouse gas emissions from global steel production over the past century (1900-2015) by combining material flow analysis and life cycle assessment. We find that ~45 Gt steel was produced in this period leading to emissions of ~147 Gt CO2-eq. Significant improvement in process efficiency (~67%) was achieved, but was offset by a 44-fold increase in annual steel production, resulting in a 17-fold net increase in annual emissions. Despite some regional technical improvements, the industry’s decarbonization progress at the global scale has largely stagnated since 1995 mainly due to expanded production in emerging countries with high carbon intensity. Our analysis of future scenarios indicates that the expected demand expansion in these countries may jeopardize steel industry’s prospects for following 1.5 °C emission reduction pathways. To achieve the Paris climate goals, there is an urgent need for rapid implementation of joint supply- and demand-side mitigation measures around the world in consideration of regional conditions.

scholarly journals Bio-Based Polyurethane Networks Derived from Liquefied Sawdust

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3138
Author(s):  
Kamila Gosz ◽  
Agnieszka Tercjak ◽  
Adam Olszewski ◽  
Józef Haponiuk ◽  
Łukasz Piszczyk
Keyword(s):  
Biomass Conversion ◽  
Structural Features ◽  
Mechanical Analysis ◽  
Process Efficiency ◽  
Hydroxyl Number ◽  
Step Method ◽  
One Step ◽  
Liquefaction Process ◽  
The Fourier Transform ◽  
Liquefaction Temperature

The utilization of forestry waste resources in the production of polyurethane resins is a promising green alternative to the use of unsustainable resources. Liquefaction of wood-based biomass gives polyols with properties depending on the reagents used. In this article, the liquefaction of forestry wastes, including sawdust, in solvents such as glycerol and polyethylene glycol was investigated. The liquefaction process was carried out at temperatures of 120, 150, and 170 °C. The resulting bio-polyols were analyzed for process efficiency, hydroxyl number, water content, viscosity, and structural features using the Fourier transform infrared spectroscopy (FTIR). The optimum liquefaction temperature was 150 °C and the time of 6 h. Comprehensive analysis of polyol properties shows high biomass conversion and hydroxyl number in the range of 238–815 mg KOH/g. This may indicate that bio-polyols may be used as a potential substitute for petrochemical polyols. During polyurethane synthesis, materials with more than 80 wt% of bio-polyol were obtained. The materials were obtained by a one-step method by hot-pressing for 15 min at 100 °C and a pressure of 5 MPa with an NCO:OH ratio of 1:1 and 1.2:1. Dynamical-mechanical analysis (DMA) showed a high modulus of elasticity in the range of 62–839 MPa which depends on the reaction conditions.

ODOR AND VOC REMOVAL IN A BIOTRICKLING FILTER SYSTEM AT HYPERION

2003 ◽  
Vol 2003 (7) ◽  
pp. 138-152
Author(s):  
Gayle P. Van Durme ◽  
Daniel L. Cearley ◽  
Connie J. Leonard ◽  
James H. Clark ◽  
Cyrous Gilani ◽  
...  
Keyword(s):  
Biotrickling Filter ◽  
Voc Removal ◽  
Filter System

scholarly journals Conversion of biomass to biofuels and life cycle assessment: a review

2021 ◽  
Author(s):  
Ahmed I. Osman ◽  
Neha Mehta ◽  
Ahmed M. Elgarahy ◽  
Amer Al-Hinai ◽  
Ala’a H. Al-Muhtaseb ◽  
...  
Keyword(s):  
Life Cycle Assessment ◽  
Life Cycle ◽  
Energy Demand ◽  
Fossil Fuels ◽  
Biomass Conversion ◽  
Biofuel Production ◽  
Process Efficiency ◽  
Liquid Fuels ◽  
Thermochemical Processes ◽  
Lower Temperature

AbstractThe global energy demand is projected to rise by almost 28% by 2040 compared to current levels. Biomass is a promising energy source for producing either solid or liquid fuels. Biofuels are alternatives to fossil fuels to reduce anthropogenic greenhouse gas emissions. Nonetheless, policy decisions for biofuels should be based on evidence that biofuels are produced in a sustainable manner. To this end, life cycle assessment (LCA) provides information on environmental impacts associated with biofuel production chains. Here, we review advances in biomass conversion to biofuels and their environmental impact by life cycle assessment. Processes are gasification, combustion, pyrolysis, enzymatic hydrolysis routes and fermentation. Thermochemical processes are classified into low temperature, below 300 °C, and high temperature, higher than 300 °C, i.e. gasification, combustion and pyrolysis. Pyrolysis is promising because it operates at a relatively lower temperature of up to 500 °C, compared to gasification, which operates at 800–1300 °C. We focus on 1) the drawbacks and advantages of the thermochemical and biochemical conversion routes of biomass into various fuels and the possibility of integrating these routes for better process efficiency; 2) methodological approaches and key findings from 40 LCA studies on biomass to biofuel conversion pathways published from 2019 to 2021; and 3) bibliometric trends and knowledge gaps in biomass conversion into biofuels using thermochemical and biochemical routes. The integration of hydrothermal and biochemical routes is promising for the circular economy.

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