Experiments on double-diffusive sugar–salt fingers at high stability ratio

1996 ◽  
Vol 321 ◽  
pp. 315-333 ◽  
Author(s):  
John R. Taylor ◽  
George Veronis

In a series of laboratory experiments the growth of double-diffusive salt fingers from an initial configuration of two homogeneous reservoirs with salt in the lower and sugar in the upper layer was investigated. For most of the experiments the stability ratio was between 2.5 and 3, where the latter value is at the upper limit (the ratio of salt to sugar diffusivities) for which fingers can exist. In these experiments long slender fingers are generated at the interface. Essentially all theories or physical bases for models of salt fingers presuppose such a configuration of long fingers. Our measurements show that the length of fingers at high stability ratio increases with time like t1/2, with a coefficient that is consistent with the diffusive spread of the faster diffusing component (salt). When the initial stability ratio is closer to unity, fingers penetrate into the reservoirs very rapidly carrying with them large anomalies of salt and sugar which give rise to convective overturning of the reservoirs. The convection sweeps away the ends of the fingers, and when it is intense enough (as it is when the sugar anomaly is large) it can reduce the finger height to a value less than the width. After this initial phase the finger length grows linearly with time as has been found in previous studies. These results show that salt fingers can evolve in quite different ways depending on the initial stability ratio and must cast doubt on the use of simple similarity arguments to parameterize the heat and salt fluxes produced by fingers.

2010 ◽  
Vol 14 (4) ◽  
pp. 667-674 ◽  
Author(s):  
C. von Rohden ◽  
B. Boehrer ◽  
J. Ilmberger

Abstract. We present CTD-measurements from two shallow meromictic mining lakes. The lakes, which differ in size and depth, show completely different seasonal mixing patterns in their mixolimnia. However, the measurements document the occurrence of similar seasonal convective mixing in discrete layers within their monimolimnia. This mixing is induced by double diffusion and can be identified by the characteristic step-like structure of the temperature and electrical conductivity profiles. The steps develop in the upper part of the monimolimnion, when in autumn cooling mixolimnion temperatures have dropped below temperatures of the underlying monimolimnion. The density gradient across the chemocline due to solutes overcompensates the destabilizing temperature gradient, and moreover, keeps the vertical transport close to molecular level. In conclusion, preconditions for double diffusive effects are given on a seasonal basis. At in general high local stabilities N2 in the monimolimnia of 10−4–10−2s−2, the stability ratio Rρ was in the range of 1–20. This quantitatively indicates that double diffusion can become visible. Between 1 and 6 sequent steps, with sizes between 1 dm and 1 m, were visually identified in the CTD-profiles. In the lower monimolimnion of the deeper lake, the steps systematically emerge at a time delay of more than half a year, which matches with the progression of the mixolimnetic temperature changes into the monimolimnion. In none of the lakes, the chemocline interface is degraded by these processes. However, double diffusive convection is essential for the redistribution of solutes in the inner parts of the monimolimnion at longer time scales, which is crucial for the assessment of the ecologic development of such lakes.


1985 ◽  
Vol 50 (7) ◽  
pp. 1594-1601 ◽  
Author(s):  
Jiří Klíma ◽  
Larisa Baumane ◽  
Janis Stradinš ◽  
Jiří Volke ◽  
Romualds Gavars

It has been found that the decay in dimethylformamide and dimethylformamide-water mixtures of radical anions in five of the investigated 5-nitrofurans is governed by a second-order reaction. Only the decay of the radical anion generated from 5-nitro-2-furfural III may be described by an equation including parallel first- and second-order reactions; this behaviour is evidently caused by the relatively high stability of the corresponding dianion, this being an intermediate in the reaction path. The presence of a larger conjugated system in the substituent in position 2 results in a decrease of the unpaired electron density in the nitro group and, consequently, an increase in the stability of the corresponding radical anions.


2021 ◽  
Vol 13 (3) ◽  
pp. 1326
Author(s):  
Hongfang Li ◽  
Huixiao Wang ◽  
Yaxue Yang ◽  
Ruxin Zhao

The interactions of water, energy, and food, which are essential resources for human survival, livelihoods, production, and development, constitute a water–energy–food (WEF) nexus. Applying symbiosis theory, the economic, social, and natural factors were considered at the same time in the WEF system, and we conducted a micro-level investigation focusing on the stability, coordination, and sustainability of the symbiotic units (water, energy, and food), and external environment of the WEF system in 36 prefecture-level cities across three northeastern provinces of China. Finally, we analyzed the synergistic safety and coupling coordination degree of the WEF system by the combination of stability, coordination, and sustainability, attending to the coordination relationship and influences of the external environment. The results indicated that the synergistic safety of the WEF system in three northeastern provinces need to equally pay attention to the stability, coordination, and sustainability of the WEF system, since their weights were 0.32, 0.36 and 0.32, respectively. During 2010–2016, the synergistic safety indexes of the WEF system ranged between 0.40 and 0.60, which was a state of boundary safety. In the current study, the coupling coordination degree of the WEF system fluctuated around a value of 0.6, maintaining a primary coordination level; while in the future of 2021–2026, it will decline to 0.57–0.60, dropping to a weak coordinated level. The conclusion could provide effective information for decision-makers to take suitable measures for the security development of a WEF system.


Photonics ◽  
2021 ◽  
Vol 8 (3) ◽  
pp. 70
Author(s):  
Maria Raposo ◽  
Carlota Xavier ◽  
Catarina Monteiro ◽  
Susana Silva ◽  
Orlando Frazão ◽  
...  

Thin graphene oxide (GO) film layers are being widely used as sensing layers in different types of electrical and optical sensor devices. GO layers are particularly popular because of their tuned interface reflectivity. The stability of GO layers is fundamental for sensor device reliability, particularly in complex aqueous environments such as wastewater. In this work, the stability of GO layers in layer-by-layer (LbL) films of polyethyleneimine (PEI) and GO was investigated. The results led to the following conclusions: PEI/GO films grow linearly with the number of bilayers as long as the adsorption time is kept constant; the adsorption kinetics of a GO layer follow the behavior of the adsorption of polyelectrolytes; and the interaction associated with the growth of these films is of the ionic type since the desorption activation energy has a value of 119 ± 17 kJ/mol. Therefore, it is possible to conclude that PEI/GO films are suitable for application in optical fiber sensor devices; most importantly, an optical fiber-based interrogation setup can easily be adapted to investigate in situ desorption via a thermally stimulated process. In addition, it is possible to draw inferences about film stability in solution in a fast, reliable way when compared with the traditional ones.


Plants ◽  
2020 ◽  
Vol 9 (11) ◽  
pp. 1554
Author(s):  
Chao Liu ◽  
Zhao-Jun Bu ◽  
Azim Mallik ◽  
Yong-Da Chen ◽  
Xue-Feng Hu ◽  
...  

In a natural environment, plants usually interact with their neighbors predominantly through resource competition, allelopathy, and facilitation. The occurrence of the positive effect of allelopathy between peat mosses (Sphagnum L.) is rare, but it has been observed in a field experiment. It is unclear whether the stability of the water table level in peat induces positive vs. negative effects of allelopathy and how that is related to phenolic allelochemical production in Sphagnum. Based on field experiment data, we established a laboratory experiment with three neighborhood treatments to measure inter-specific interactions between Sphagnum angustifolium (Russ.) C. Jens and Sphagnum magellanicum Brid. We found that the two species were strongly suppressed by the allelopathic effects of each other. S. magellanicum allelopathically facilitated S. angustifolium in the field but inhibited it in the laboratory, and relative allelopathy intensity appeared to be positively related to the content of released phenolics. We conclude that the interaction type and intensity between plants are dependent on environmental conditions. The concentration of phenolics alone may not explain the type and relative intensity of allelopathy. Carefully designed combined field and laboratory experiments are necessary to reveal the mechanism of species interactions in natural communities.


2010 ◽  
Vol 24 (3-4) ◽  
pp. 349-353 ◽  
Author(s):  
Olga I. Povarova ◽  
Olga V. Stepanenko ◽  
Anna I. Sulatskaya ◽  
Irina M. Kuznetsova ◽  
Konstantin K. Turoverov ◽  
...  

Fluorescence and circular dichroism in far-UV region were used to study the stability of trehalose/maltose binding protein (TMBP) from hyper thermophilic archaeonThermococcus litoralisand its complex with glucose (TMBP/Glc). The evaluation of difference between free energy of native and unfolded state for TMBP and TMBP/Glc showed that both of them are several times higher than that of proteins from mesophilic organisms. Due to the high stability and innate ability to bind glucose this protein is a good candidate as a sensitive element in biosensor systems for sugar control.


Author(s):  
Swaminathan Ganesan ◽  
Sampath Vedamanickam

In this study, the influence of upper cycle temperature (maximum temperature in a cycle) and the magnitude of applied stress on the functional properties of an SMA during partial thermomechanical cycling has been studied. A near-equiatomic NiTi SMA was chosen and tested under different upper cycle temperatures (between martensite finish (Mf) and austenite finish (Af) temperatures) and stress level (below and above the yield strength of the martensite). The upper cycle temperature was varied by controlling the magnitude of the current supply. The results show that a raise in the upper cycle temperature causes the permanent strain to increase and also lowers the stability. However, decreasing the stress imposed to a value lower than the yield strength of the martensite improves cyclic stability. The upper cycle temperature was found to influence the crack nucleation, whereas the applied stress level the crack propagation during partial thermomechanical cycling of SMAs. Therefore, decreasing the upper cycle temperature as well as the magnitude of stress applied to lower than the yield stress of martensite have been found to be suitable strategies for increasing the lifespan of SMA-based actuators during partial thermomechanical cycling.


1999 ◽  
Vol 392 ◽  
pp. 213-232 ◽  
Author(s):  
OLIVER S. KERR ◽  
KIT YEE TANG

A fluid stably stratified by a salinity gradient and enclosed between two vertical boundaries can become unstable when it is subjected to a temperature difference between the walls. The linear stability of such a fluid in a vertical slot is investigated. Errors in earlier results are found, confirming recent results of Young & Rosner (1998). Four different asymptotic regimes on the stability boundary are identified. One of these, the limit of a strong salinity gradient, has previously been analysed. The analyses of the separate asymptotic limits of weak salinity gradient, large temperature difference and small wavenumber are also given. These four cases make up much of the total boundary between stability and instability for double-diffusive instabilities in a vertical slot, and so most of this boundary can be mapped out for general Prandtl numbers and salt/heat diffusivity ratios using these results.


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