Effect of the Average Pore Size on the Adsorption Capacity and Off-Gassing Characteristics of Activated Carbon Fabrics for Decontamination of Surfaces

Author(s):  
Brian MacIver ◽  
Ralph B. Spafford ◽  
James Minicucci ◽  
Ronald Willey ◽  
Adam Kulczyk ◽  
...  
2017 ◽  
Vol 889 ◽  
pp. 215-220 ◽  
Author(s):  
Siti Anis Mohd Amran ◽  
Khudzir Ismail ◽  
Azil Bahari Alias ◽  
Syed Shatir Asghrar Syed-Hassan ◽  
Ali H. Jawad

Single and mixed coconut shell (CS) and palm kernel shell (PKS) were successfully converted to activated carbon by using potassium hydroxide (KOH) as activating agent. Mixed activated carbon was produced from coconut shell: palm kernel shell at different KOH concentrations of 30%, 40% and 50%. Activation process was performed in a conventional microwave oven at fixed power and time of 600W and 20 minutes respectively. The results showed that activated carbon produced from single and mixed biomass at 40% concentration of KOH exhibited higher adsorption capacity for iodine number and percentage removal of MB with comparison to 30% and 50% of KOH concentrations. The highest BET surface area of 441.19 m2/g was obtained by CSAc-40. Further both CSAc-40 and PKSAc-40 produced an average pore size diameter of less than 2.0 nm which is in the range of micropore region. On contrary, the mixed CSPKSAc-40 produced an average pore size diameter of 6.0 nm which is in the region of mesopore. All the CSAc-40, PKSAc-40 and mixed CSPKSAc-40 showed similar adsorption trend for iodine number and percentage removal of MB. Interestingly, this finding showed that in the mixed activated carbon some chemical reactions might have occurred during the activation process producing mesoporous instead of microporous as obtained by the single biomass activated carbon.


Author(s):  
Yuvarat Ngernyen ◽  
Werawit Phiewruangnont ◽  
Narathorn Mahantadsanapong ◽  
Chantakorn Patawat ◽  
Ketsara Silakate ◽  
...  

Dipterocarpus alatus tree grows prolifically throughout Thailand and can be tapped to yield significant quantities of oil to be used as natural diesel. However, such practices lead to waste dried fruit dropping from the tree. At present, there is no utilization of this dropped fruit, therefore costeffective processes need to be applied to obtain higher value products from this waste. A possible to utilization is the conversion to activated carbon for adsorption applications including the removal of heavy metals, dyes, and other contaminants in water purification and other decontamination process. A major challenge of current commercial activated carbon is the high production cost and recently it has been shown that chemical activators comprise a significant proportion of these costs. This feasibility study investigates the use of Dipterocarpus alatus fruit as raw material to produce low cost activated carbon adsorbents. Activated carbon was prepared from Dipterocarpus alatus fruit: endocarp, mesocarp, and wing by chemical activation with ZnCl2, FeCl3, and KOH. Each part of the fruit was impregnated with 30 wt% activating agent at a ratio of 1:2 for 1 h and then carbonized at 500 oC for a further 1 h. The surface area, pore volume, and average pore size of the resulting carbons were characterized by nitrogen gas adsorption. Activation of mesocarp with ZnCl2, KOH, and FeCl3 gave activated carbons with the surface area of 447, 256, and 199 m2/g, respectively. In the same way, ZnCl2 activation gave a maximum surface area of 312 and 278 m2/g for wing and endocarp, respectively. All of the aforementioned samples have an average pore size of around 2 nm. In contrast, KOH and FeCl3 activation of wing and endocarp produced activated carbon with very low surface area (below 25 m2/g), but with an average pore size of 5- 14 nm. The maximum surface area of activated carbon prepared from Dipterocarpus alatus fruit was higher than some literature examples for activated carbon from other biomass. Consequently, Dipterocarpus alatus fruit demonstrated significant potential as a feedstock for the preparation of low cost activated carbons.


10.29007/ps3m ◽  
2020 ◽  
Author(s):  
Yuvarat Ngernyen ◽  
Werawit Phiewruangnont ◽  
Ratchapon Anachai ◽  
Andrew Hunt

This present work aims to reduce the color of biodiesel from crude palm oil through the application of activated carbon prepared from chili stem waste. Chilli stem was converted into activated carbon using 30 wt% KOH at a ratio of 1:2 for 1 h, followed by carbonization at 500 oC under an N2 atmosphere for a further hour. Physico-chemical characteristics of the raw material and activated carbon were analyzed including thermogravimetric analysis, proximate analysis, and porosities. The results demonstrated that the activated carbon was a porous material with a highly mesoporous structure (84.5%). The surface area of activated carbon was 10.6 m2/g and it exhibited an average pore diameter of 27.25 nm which was suitable for the removal of large highly colored molecules. Batch adsorption experiments were performed to investigate the reduction in color of the biodiesel. Ratios of activated carbon to biodiesel of 0.002 and 0.1 w/v were used in the study. For comparison, the adsorption was also tested against a commercial activated carbon with a surface area of 1,130 m2/g, but lower average pore size of 3.72 nm. The chili stem activated carbon can reduce color by approximately 15% within 24 h and the maximum color reduction was 95% after 96 h for both activated carbon to biodiesel ratios. The color of biodiesel changes from dark red to yellow and eventually resulted in a pale yellow color with longer adsorption times and was deemed more attractive for use. Moreover, commercial activated carbon with its small pore size could not reduce the color, with a maximum reduction of only 3%.


2017 ◽  
Vol 54 (3) ◽  
pp. 181-201
Author(s):  
Rebecca Johnson ◽  
Mark Longman ◽  
Brian Ruskin

The Three Forks Formation, which is about 230 ft thick along the southern Nesson Anticline (McKenzie County, ND), has four “benches” with distinct petrographic and petrophysical characteristics that impact reservoir quality. These relatively clean benches are separated by slightly more illitic (higher gamma-ray) intervals that range in thickness from 10 to 20 ft. Here we compare pore sizes observed in scanning electron microscope (SEM) images of the benches to the total porosity calculated from binned precession decay times from a suite of 13 nuclear magnetic resonance (NMR) logs in the study area as well as the logarithmic mean of the relaxation decay time (T2 Log Mean) from these NMR logs. The results show that the NMR log is a valid tool for quantifying pore sizes and pore size distributions in the Three Forks Formation and that the T2 Log Mean can be correlated to a range of pore sizes within each bench of the Three Forks Formation. The first (shallowest) bench of the Three Forks is about 35 ft thick and consists of tan to green silty and shaly laminated dolomite mudstones. It has good reservoir characteristics in part because it was affected by organic acids and received the highest oil charge from the overlying lower Bakken black shale source rocks. The 13 NMR logs from the study area show that it has an average of 7.5% total porosity (compared to 8% measured core porosity), and ranges from 5% to 10%. SEM study shows that both intercrystalline pores and secondary moldic pores formed by selective partial dissolution of some grains are present. The intercrystalline pores are typically triangular and occur between euhedral dolomite rhombs that range in size from 10 to 20 microns. The dolomite crystals have distinct iron-rich (ferroan) rims. Many of the intercrystalline pores are partly filled with fibrous authigenic illite, but overall pore size typically ranges from 1 to 5 microns. As expected, the first bench has the highest oil saturations in the Three Forks Formation, averaging 50% with a range from 30% to 70%. The second bench is also about 35 ft thick and consists of silty and shaly dolomite mudstones and rip-up clast breccias with euhedral dolomite crystals that range in size from 10 to 25 microns. Its color is quite variable, ranging from green to tan to red. The reservoir quality of the second bench data set appears to change based on proximity to the Nesson anticline. In the wells off the southeast flank of the Nesson anticline, the water saturation averages 75%, ranging from 64% to 91%. On the crest of the Nesson anticline, the water saturation averages 55%, ranging from 40% to 70%. NMR porosity is consistent across the entire area of interest - averaging 7.3% and ranging from 5% to 9%. Porosity observed from samples collected on the southeast flank of the Nesson Anticline is mainly as intercrystalline pores that have been extensively filled with chlorite clay platelets. In the water saturated southeastern Nesson Anticline, this bench contains few or no secondary pores and the iron-rich rims on the dolomite crystals are less developed than those in the first bench. The chlorite platelets in the intercrystalline pores reduce average pore size to 500 to 800 nanometers. The third bench is about 55 ft thick and is the most calcareous of the Three Forks benches with 20 to 40% calcite and a proportionate reduction in dolomite content near its top. It is also quite silty and shaly with a distinct reddish color. Its dolomite crystals are 20 to 50 microns in size and partly abraded and dissolved. Ferroan dolomite rims are absent. This interval averages 7.1% porosity and ranges from 5% to 9%, but the pores average just 200 nanometers in size and occur mainly as microinterparticle pores between illite flakes in intracrystalline pores in the dolomite crystals. This interval has little or no oil saturation on the southern Nesson Anticline. Unlike other porosity tools, the NMR tool is a lithology independent measurement. The alignment of hydrogen nuclei to the applied magnetic field and the subsequent return to incoherence are described by two decay time constants, longitudinal relaxation time (T1) and transverse relaxation time (T2). T2 is essentially the rate at which hydrogen nuclei lose alignment to the external magnetic field. The logarithmic mean of T2 (T2 Log Mean) has been correlated to pore-size distribution. In this study, we show that the assumption that T2 Log Mean can be used as a proxy for pore-size distribution changes is valid in the Three Forks Formation. While the NMR total porosity from T2 remains relatively consistent in the three benches of the Three Forks, there are significant changes in the T2 Log Mean from bench to bench. There is a positive correlation between changes in T2 Log Mean and average pore size measured on SEM samples. Study of a “type” well, QEP’s Ernie 7-2-11 BHD (Sec. 11, T149N, R95W, McKenzie County), shows that the 1- to 5-micron pores in the first bench have a T2 Log Mean relaxation time of 10.2 msec, whereas the 500- to 800-nanometer pores in the chlorite-filled intercrystalline pores in the second bench have a T2 Log Mean of 4.96 msec. This compares with a T2 Log Mean of 2.86 msec in 3rd bench where pores average just 200 nanometers in size. These data suggest that the NMR log is a useful tool for quantifying average pore size in the various benches of the Three Forks Formation.


2021 ◽  
Vol 13 (14) ◽  
pp. 7593
Author(s):  
Farooq Khan Niazi ◽  
Malik Adeel Umer ◽  
Ashfaq Ahmed ◽  
Muhammad Arslan Hafeez ◽  
Zafar Khan ◽  
...  

Ultrafiltration membranes offer a progressive and efficient means to filter out various process fluids. The prime factor influencing ultrafiltration to a great extent is the porosity of the membranes employed. Regarding membrane development, alumina membranes are extensively studied due to their uniform porosity and mechanical strength. The present research work is specifically aimed towards the investigation of nanoporous alumina membranes, as a function of sintering parameters, on ultrafiltration performance. Alumina membranes are fabricated by sintering at various temperatures ranging from 1200–1300 °C for different holding times between 5–15 h. The morphological analysis, conducted using Scanning electron microscopy (SEM), revealed a homogeneous distribution of pores throughout the surface and cross-section of the membranes developed. It was observed that an increase in the sintering temperature and time resulted in a gradual decrease in the average pore size. A sample with an optimal pore size of 73.65 nm achieved after sintering at 1250 °C for 15 h, was used for the evaluation of ultrafiltration performance. However, the best mechanical strength and highest stress-bearing ability were exhibited by the sample sintered at 1300 °C for 5 h, whereas the sample sintered at 1250 °C for 5 h displayed the highest strain in terms of compression. The selected alumina membrane sample demonstrated excellent performance in the ultrafiltration of sugarcane juice, compared to the other process liquids.


Molecules ◽  
2021 ◽  
Vol 26 (2) ◽  
pp. 257
Author(s):  
Jie Ren ◽  
Nanwei Chen ◽  
Li Wan ◽  
Guojian Li ◽  
Tao Chen ◽  
...  

In this study, a new method for economical utilization of coffee grounds was developed and tested. The resulting materials were characterized by proximate and elemental analyses, thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and N2 adsorption–desorption at 77 K. The experimental data show bio-oil yields reaching 42.3%. The optimal activated carbon was obtained under vacuum pyrolysis self-activation at an operating temperature of 450 °C, an activation temperature of 600 °C, an activation time of 30 min, and an impregnation ratio with phosphoric acid of 150 wt.%. Under these conditions, the yield of activated carbon reached 27.4% with a BET surface area of 1420 m2·g−1, an average pore size of 2.1 nm, a total pore volume of 0.747 cm3·g−1, and a t-Plot micropore volume of 0.428 cm3·g−1. In addition, the surface of activated carbon looked relatively rough, containing mesopores and micropores with large amounts of corrosion pits.


2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Huaxing Xu ◽  
Biao Gao ◽  
Hao Cao ◽  
Xueyang Chen ◽  
Ling Yu ◽  
...  

Nanoporous activated carbon material was produced from the waste rice husks (RHs) by precarbonizing RHs and activating with KOH. The morphology, structure, and specific surface area were investigated. The nanoporous carbon has the average pore size of 2.2 nm and high specific area of 2523.4 m2 g−1. The specific capacitance of the nanoporous carbon is calculated to be 250 F g−1at the current density of 1 A g−1and remains 80% for 198 F g−1at the current density of 20 A g−1. The nanoporous carbon electrode exhibits long-term cycle life and could keep stable capacitance till 10,000 cycles. The consistently high specific capacitance, rate capacity, and long-term cycle life ability makes it a potential candidate as electrode material for supercapacitor.


2012 ◽  
Vol 174-177 ◽  
pp. 1010-1014 ◽  
Author(s):  
Hong Bin Liu ◽  
Yang Ju ◽  
Kai Pei Tian ◽  
Jin Hui Liu ◽  
Li Wang ◽  
...  

The pore structure characteristics of reactive powder concrete (RPC) were investigated by means of the mercury injection method at seven temperature levels, namely, 20°C, 100°C, 150°C, 200°C, 250°C, 300°C, 350°C, respectively. The characteristic parameters such as porosity, pore volume, average pore size and threshold aperture varied with temperatures were analyzed. The results indicate that the porosity, pore volume, threshold aperture and other characteristic parameters of RPC increased with the temperature increasing.


Author(s):  
Rachel C. Devereux ◽  
Craig J. Sturrock ◽  
Sacha J. Mooney

ABSTRACTBiochar has been reported to improve soil quality and crop yield; however, less is known about its effects on the physical and, in particular, structural properties of soil. This study examines the potential ability of biochar to improve water retention and crop growth through a pot trial using biochar concentrations of 0%, 1·5%, 2·5% and 5% w/w. X-ray computed tomography was used to measure soil structure via pore size characteristics; this showed that pore size is significantly affected by biochar concentration. Increasing biochar is associated with decreasing average pore size, which we hypothesise would impact heavily on hydraulic performance. At the end of the experiment, average pore size had decreased from 0·07 mm2 in the 0% biochar soil to 0·046 mm2 in the 5% biochar soil. Increased biochar concentration also significantly decreases saturated hydraulic conductivity and soil bulk density. It was also observed that increased biochar significantly decreases soil water repellency. Increased water retention was also observed at low matric potentials, where it was shown that increased biochar is able to retain more water as the soil dried out. The application of biochar had little effect on short-term (<10 weeks) wheat growth, but did improve water retention through a change in soil porosity, pore size, bulk density and wetting ability.


2018 ◽  
Vol 80 (2) ◽  
Author(s):  
Klinsmann Cheong Lee Khang ◽  
Mohd Hayrie Mohd Hatta ◽  
Siew Ling Lee ◽  
Leny Yuliati

A series of mesoporous ZnO/TiO2 composites were successfully synthesized using cetyltrimethylammonium bromide surfactant. The composites of different Zn:Ti molar ratios (0.5:1, 0.75:1, and 1:1) were prepared by impregnating ZnO onto mesoporous TiO2. XRD results verified co-existence of both anatase TiO2 and hexagonal wurtzite ZnO in the ZnO/TiO2 composites. Based on the Tauc plots, all the composites showed almost the same band gap energy of approximately 3.21 eV. The fourier transform infrared spectroscopy results successful covering of ZnO on the surface of the TiO2 as the hydrophilicity property of TiO2 decreased remarkably with the loading of ZnO in the composites. N2 adsorption-desorption isotherms of the samples exhibited type-IV isotherm with a hysteresis loop. The Barrett-Joyner-Halenda pore size distribution revealed that the average pore size of the composites was around 3.6 nm, indicating the formation of mesopores dominantly in the samples. The photocatalytic removal of phenol over the samples under UV light irradiation after 3 h decreased in the order: ZnO/TiO2 composites > anatase TiO2 (with surfactant) > anatase TiO2 (without surfactant) > ZnO. The composite with Zn:Ti molar ratio of 0.75:1 has achieved the highest photocatalytic activity of 36.5% in the removal of phenol under UV light irradiation for 3 h.


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