Intermetallic wetting enabled high resolution liquid metal patterning for 3D and flexible electronics

Author(s):  
Lucy Johnston ◽  
Jiong Yang ◽  
Jialuo Han ◽  
Kourosh Kalantar-Zadeh ◽  
Jianbo Tang

Liquid metals, highly conductive and flowable metals, are increasingly becoming versatile choices for soft electronics and wearable devices. High resolution liquid metal patterning strategies accommodative to different substrate materials and...

Nanoscale ◽  
2021 ◽  
Author(s):  
Hiroki Ota ◽  
Nyamjargal Ochirkhuyag ◽  
Ryosuke Matsuda ◽  
Zihao Song ◽  
Fumika Nakamura ◽  
...  

Research on liquid metals has been steadily garnering more interest in recent times because the properties of these metals are conducive to flexible electronics applications; further, these metals are in...


Soft Matter ◽  
2018 ◽  
Vol 14 (17) ◽  
pp. 3296-3303 ◽  
Author(s):  
Tim Shay ◽  
Orlin D. Velev ◽  
Michael D. Dickey

Liquid metals interfaced with hydrogels create soft, deformable electrodes for emerging wearable devices and soft robotics. This paper quantifies and tunes the impedance of this interface for use in ECG electrodes.


Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2283 ◽  
Author(s):  
Stephan Handschuh-Wang ◽  
Lifei Zhu ◽  
Tao Wang

The liquid metal lyophobicity of a rough substrate was, in previous articles, found to be rather independent on the surface wettability. In this article, we scrutinize the impact of surface wettability of a structured (rough) surface on the liquid metal wettability and adhesion. As a model system, a structured diamond coating was synthesized and modified by air plasma. We show that surface wettability (surface free energy) does not play a prominent role for static contact angle measurements and for the liquid metal repelling properties of the diamond coating in droplet impact experiments. In contrast, roll off angles and repeated deposition experiments illustrate that the increased hydrophilicity impacts the long-term liquid metal repellency of our coating. Liquid metal adhered after around 50 deposition/removal cycles on the hydrophilic diamond coating, while no liquid metal adhesion was visible after 100 cycles on the hydrophobic diamond coating, illustrating the fundamental role for the adhesion of liquid metal. The effect of repeated deposition in conjunction with gentle applied force was employed for coating the liquid metal lyophobic (hydrophilic) diamond coating with a thin liquid metal layer. The observed effect may find application in flexible electronics and thermal management systems as a means to improve interfacing of the liquid metal with conductive non-metal coatings.


2019 ◽  
Vol 9 (8) ◽  
pp. 1565 ◽  
Author(s):  
Elassy ◽  
Akau ◽  
Shiroma ◽  
Seo ◽  
Ohta

Patterned conformal conductive structures are used to realize flexible electronics for applications such as electronic skin, communication devices, and sensors. Thus, there is a demand for low-cost rapid fabrication techniques for flexible and stretchable conductors. Spray-coating of liquid metals is a prototyping method that is compatible with elastic substrates. In this work, UV-curable and polyimide masks were used to pattern sprayed liquid metal (LM). The effect of the spraying parameters on the thickness and conductivity of the LM was characterized. A minimum LM linewidth of 48 µm was achieved, along with a minimum gap width of 34 µm. A LM patch antenna and transmission line, which can potentially be used for communication systems, were demonstrated using this fabrication process.


Micromachines ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 54 ◽  
Author(s):  
Jordan Melcher ◽  
Kareem Elassy ◽  
Richard Ordonez ◽  
Cody Hayashi ◽  
Aaron Ohta ◽  
...  

Advancements in flexible circuit interconnects are critical for widespread adoption of flexible electronics. Non-toxic liquid-metals offer a viable solution for flexible electrodes due to deformability and low bulk resistivity. However, fabrication processes utilizing liquid-metals suffer from high complexity, low throughput, and significant production cost. Our team utilized an inexpensive spray-on stencil technique to deposit liquid-metal Galinstan electrodes in top-gated graphene field-effect transistors (GFETs). The electrode stencils were patterned using an automated vinyl cutter and positioned directly onto chemical vapor deposition (CVD) graphene transferred to polyethylene terephthalate (PET) substrates. Our spray-on method exhibited a throughput of 28 transistors in under five minutes on the same graphene sample, with a 96% yield for all devices down to a channel length of 50 μm. The fabricated transistors possess hole and electron mobilities of 663.5 cm2/(V·s) and 689.9 cm2/(V·s), respectively, and support a simple and effective method of developing high-yield flexible electronics.


Author(s):  
Lei Wang ◽  
Jing Liu

Flexible electronics and 3D printing are quickly reshaping the world in many aspects spanning from science, technology to industry and social society. However, there still exist many barriers to impede further progress of the areas. One of the biggest bottlenecks lies in the strong shortage of appropriate functional inks. Among the many printable materials ever tried such as conductive polymers, powdered plastic, metal particles or other adhesive materials, the liquid metal or its alloy is quickly emerging as a powerful electronic ink with diverse capabilities from which direct printing of flexible electronics and room temperature 3D printing for manufacturing metal structures are enabled. All these fabrication capabilities are attributed to the unique properties of such metal’s low melting point (generally less than 100 °C), flowable feature and high electrical conductivity etc. To better push forward the research and application of the liquid metal printed electronics and 3D manufacture, this article is dedicated to present an overview on the fundamental research advancements in processing and developing the liquid metal inks. Particularly, the flow, thermal, phase change and electrical properties of a group of typical liquid metals and their alloy inks will be systematically summarized and comparatively evaluated. Some of the practical applications of these materials in a wide variety of flexible electronics fabrication, 3D printing and medical sensors etc. will be briefly illustrated. Further, we also explained the basic categories of the liquid metal material genome towards discovering new functional alloy ink materials as initiated in the authors’ lab and interpret the important scientific and technical challenges lying behind. Perspective and future potentials of the liquid metal inks in more areas were also suggested.


2017 ◽  
Vol 5 (7) ◽  
pp. 1586-1590 ◽  
Author(s):  
Suqing Liang ◽  
Yaoyao Li ◽  
Yuzhen Chen ◽  
Jinbin Yang ◽  
Taipeng Zhu ◽  
...  

Liquid metal sponges were developed by loading nontoxic liquid metals (GaInSn) into 3D-interconnected porous poly(dimethylsiloxane) (PDMS) sponges for flexible electronics.


Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3251
Author(s):  
Katharina Foremny ◽  
Steven Nagels ◽  
Michaela Kreienmeyer ◽  
Theodor Doll ◽  
Wim Deferme

Galinstan, a liquid metal at room temperature, is a promising material for use in flexible electronics. Since it has been successfully integrated in devices for external use, e.g., as stretchable electronic skin in tactile sensation, the possibility of using galinstan for flexible implant technology comes to mind. Usage of liquid metals in a flexible implant would reduce the risk of broken conductive pathways in the implants and therefore reduce the possibility of implant failure. However, the biocompatibility of the liquid metal under study, i.e., galinstan, has not been proven in state-of-the-art literature. Therefore, in this paper, a material combination of galinstan and silicone rubber is under investigation regarding the success of sterilization methods and to establish biocompatibility testing for an in vivo application. First cell biocompatibility tests (WST-1 assays) and cell toxicity tests (LDH assays) show promising results regarding biocompatibility. This work paves the way towards the successful integration of stretchable devices using liquid metals embedded in a silicone rubber encapsulant for flexible surface electro-cortical grid arrays and other flexible implants.


2021 ◽  
Vol 13 (6) ◽  
pp. 7443-7452
Author(s):  
Jianyu Xu ◽  
Hongda Guo ◽  
Hongyao Ding ◽  
Qiao Wang ◽  
Ziqing Tang ◽  
...  

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