scholarly journals Laboratory study on the use of natural zeolite from Gunungkidul, Indonesia for Cu, Pb, Zn and Cd immobilization in soil

2020 ◽  
Vol 200 ◽  
pp. 06006
Author(s):  
Wawan Budianta
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Laboratory Study ◽  
Contaminated Soil ◽  
Natural Zeolite ◽  
Concentration Level ◽  
Cu And Zn

An experiment of the immobilization of heavy metals Pb, Cu, Zn, and Cd in contaminated soil by using the natural zeolite was performed in the laboratory. The natural zeolite was obtained from Gunungkidul, Yogyakarta, Indonesia. Artificially contaminated levels on 100, 300 and 500 mg/kg were prepared and then mixed with three different dosages of 5%, 10% and 20% of the natural zeolite. The result revealed that the addition of natural zeolite effect on reducing the heavy metal in the contaminated soil. The addition 5% dosage of the natural zeolite was sufficient to reduce the concentration of Pb, Cu and Zn from 500 mg/kg to the maximum permissible of concentration level. Finally, the natural zeolite immobilized the heavy metals in the contaminated soil by following in order: Pb2+>Cu2+>Zn2+>Cd2+.

Effects of Phosphate Rock on Absorption and Accumulation of Heavy Metals of Ryegrass in Heavy Metal Contaminated Soil

2014 ◽  
Vol 522-524 ◽  
pp. 752-757 ◽  
Author(s):  
Ying Zhe Wang ◽  
Zhong Qiu Zhao ◽  
Guang Yu Jiang
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Perennial Ryegrass ◽  
Significant Influence ◽  
Contaminated Soil ◽  
Contaminated Soils ◽  
Phosphate Rock ◽  
Particle Sizes ◽  
Cu And Zn ◽  
Soil Weight

The effects of phosphates rock (PR) with different particle sizes {D97<4.26 (the diameters of 97% of the particles are less than 4.26 µm.), <36.83, <71.12 and <101.43 µm} and different concentration (2.5% and 5% content of try soil weight) on immobilizing heavy metal-contaminated soils by a perennial ryegrass greenhouse experiment are conducted. Results indicate that remediation effect of applying 5% content is more significant than 2.5%. Ryegrass biomass in shoots in the former applying content is much larger than the latter and for both roots and shoots, PR reduces the absorption and accumulation of Pb, Cu and Zn, but no significant influence on Cd. While adding the same amount of different sizes of PR doesn’t show significant differences between these treatments. Pb content at 5% level of the finest size of PR is the minimum, decreased by 33% and 56% compared to the control in roots and shoots respectively, which was also suitable for Zn, decreased by 12.65% and 39.61% respectively.

HEAVY METALS IN WATER, SEDIMENTS AND MARINE FISHES FROM BULGARIAN BLACK SEA

2017 ◽  
Author(s):  
Katya Peycheva ◽  
Katya Peycheva ◽  
Mona Stancheva ◽  
Mona Stancheva ◽  
Stanislava Georgieva ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Black Sea ◽  
Fish Species ◽  
Distribution Patterns ◽  
Marine Fishes ◽  
Marine Water ◽  
Mean Values ◽  
Sprattus Sprattus ◽  
Cu And Zn

In this study, the ecosystem marine water-sediment-biota was investigated and the pollution was assessed. The concentrations of eight elements were determined in marine water, sediments and four fish species collected from Black Sea (Varna), Bulgaria during 2013. Marine water recorded the highest concentrations of Zn (15-22 μg/L), As (1.1–1.2 μg/L) and Pb (0.7-0.8 μg/L) while Zn (31-52 μg/g), Pb (21-29 μg/g) and Cu (20-34 μg/g) and show the highest concentrations in sediments. Water and sediments showed similar spatial distribution patterns for the highest mean values of the different metals. In the analysed fish species, the highest concentration of the metals Cu and Zn were found in Trachurus Mediterrneus (0.42 mg/kg w.w) and in Sprattus Sprattus (12.7 mg/kg w.w), respectively while the heavy metals As and Hg were found with maximum values in Pseta Maxima (3.99 mg/kg w.w and 0.08 mg/kg w.w respectively). The results from this study were compared with our data for a previous period (2004-2006) and they show decrease in the levels of heavy metal.

scholarly journals Combined Influence of Low-Grade Metakaolins and Natural Zeolite on Compressive Strength and Heavy Metal Adsorption of Geopolymers

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 486
Author(s):  
Alcina Johnson Sudagar ◽  
Slávka Andrejkovičová ◽  
Fernando Rocha ◽  
Carla Patinha ◽  
Maria R. Soares ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Compressive Strength ◽  
Natural Zeolite ◽  
Metal Adsorption ◽  
Low Grade ◽  
Heavy Metal Adsorption ◽  
Adsorption Model ◽  
X Ray ◽  
Adsorption Capacities

Metakaolins (MKs) prepared from low-grade kaolins located in the Alvarães (A) and Barqueiros (B) regions of Portugal were used as the aluminosilicate source to compare their effect on the compressive strength and heavy metal adsorption of geopolymers. Natural zeolite, an inexpensive, efficient adsorbent, was used as an additive in formulations to enhance geopolymers’ adsorption capacities and reduce MK utilization’s environmental footprint. Geopolymers were synthesized with the replacement of MK by zeolite up to 75 wt.% (A25, B25—25% MK 75% zeolite; A50, B50—50% MK 50% zeolite; A75, B75—75% MK 25% zeolite; A100, B100—100% MK). The molar ratios of SiO2/Al2O3 and Na2O/Al2O3 were kept at 1 to reduce the sodium silicate and sodium hydroxide environmental impact. Geopolymers’ crystallography was identified using X-ray diffraction analysis. The surface morphology was observed by scanning electron microscopy to understand the effect of zeolite incorporation. Chemical analysis using X-ray fluorescence spectroscopy and energy dispersive X-ray spectroscopy yielded information about the geopolymers’ Si/Al ratio. Compressive strength values of geopolymers obtained after 1, 14, and 28 days of curing indicate high strengths of geopolymers with 100% MK (A100—15.4 MPa; B100—32.46 MPa). Therefore, zeolite did not aid in the improvement of the compressive strength of both MK-based geopolymers. The heavy metal (Cd2+, Cr3+, Cu2+, Pb2+, and Zn2+) adsorption tests exhibit relatively higher adsorption capacities of Barqueiros MK-based geopolymers for all the heavy metals except Cd2+. Moreover, zeolite positively influenced divalent cations’ adsorption on the geopolymers produced from Barqueiros MK as B75 exhibits the highest adsorption capacities, but such an influence is not observed for Alvarães MK-based geopolymers. The general trend of adsorption of the heavy metals of both MK-based geopolymers is Pb2+ > Cd2+ > Cu2+ > Zn2+ > Cr3+ when fitted by the Langmuir isotherm adsorption model. The MK and zeolite characteristics influence geopolymers’ structure, strength, and adsorption capacities.

scholarly journals Optimization of pH, temperature and carbon source for bioleaching of heavy metals by Aspergillus flavus isolated from contaminated soil

2019 ◽  
Vol 42 (1) ◽  
pp. 1-7 ◽  
Author(s):  
Sadia Qayyum ◽  
Ke Meng ◽  
Sidra Pervez ◽  
Faiza Nawaz ◽  
Changsheng Peng
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Aspergillus Flavus ◽  
Contaminated Soil ◽  
Ph Value ◽  
Optimal Conditions ◽  
Batch Experiments ◽  
Molecular Biological Analysis ◽  
One Step ◽  
Industrial Mining

Abstract Soil contamination with heavy metal content is a growing concern throughout the world as a result of industrial, mining, agricultural and domestic activities. Fungi are the most common and efficient group of heavy metal resistant microbe family which have potential for metal bioleaching. The use of filamentous fungi in bioleaching of heavy metals from contaminated soil has been developed recently. The current study intends to isolate a strain with the ability to degrade the pH value of the liquid medium. Identification results based on morphological and molecular biological analysis gave a 98% match to Aspergillus flavus. Batch experiments were conducted to select the optimal conditions for bioleaching process which indicated that 130 mg/ L sucrose, neutral pH and temperature of 30°C were more suitable during 15-day bioleaching experiments using A. flavus. In one-step bioleaching, the bioleaching efficiencies were 18.16% for Pb, 39.77% for Cd and 58.22% for Zn+2, while two-step bioleaching showed efficiencies of 16.91% for Pb, 49.66% for Cd and 65.73% for Zn+2. Overall, this study indicates that bioleaching of heavy metals in contaminated soil using A. flavus has the potential for contaminated soil remediation.

scholarly journals Kestabilan Inokulan Azotobacter selama Penyimpanan pada Dua Suhu

2012 ◽  
Vol 14 (1) ◽  
pp. 52
Author(s):  
Reginawanti Hindersah ◽  
Rija Sudirja
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Root Growth ◽  
Contaminated Soil ◽  
Metal Uptake ◽  
Room Temperature ◽  
Heavy Metal Uptake ◽  
Total N ◽  
The Stability ◽  
Temperature Storage

Azotobacter might be used as biological agents in bioremediation of heavy metal-contaminated soil since this rhizobacteria produceexopolysachharides (EPS) that mobilize soil heavy metals, and phytohormones that regulate root growth. So that heavy metal uptake bythe roots could be increased. The objective of this research was to verify the stability of EPS and phytohormones in Azotobacter liquidinoculants during four months in different temperature storage. Liquid inoculants has been produced in EPS-induced media and stored in200C and room temperature (24-270C) during four months. The results showed that the better temperature storage was room temperatureinstead of 20 0C since pH, total N, and EPS and phytohormones content was relatively stable during storage.

scholarly journals Phytoremediation of Special Metals in Emerging Industries

2018 ◽  
Vol 1 (3) ◽  
Author(s):  
T Y TEH ◽  
Min-Hao Wu ◽  
Kf Chen ◽  
Yp Peng
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Growth Rate ◽  
Environmental Factors ◽  
Contaminated Soil ◽  
Morphological Analysis ◽  
Energy Crop ◽  
Emerging Industries ◽  
Incremental Growth ◽  
Conventional Methods

This project is carried out to assess the remediation effect on soil contaminated by molybdenum (Mo), one of heavy metals, through the use of an energy crop, sunflowers. This project explores the integration of phytohormones and chelates in the phytoremediation of soils contaminated by heavy metals, and further assesses the operational measures of remedying heavy-metal contaminated soil with sunflowers, in addition to the related environmental factors. Then the project explores phytohormones and heavy metals on the growth scenario explants (explants morphological analysis) through the experiment. The results indicate that GA3 can increase the growth rate of the plants. The average incremental growth of the heavy-metal-added-only group is 21.0 cm; of the GA3-added group it is 21.9 cm; of the EDDS-added group, it is 20.3 cm; of the GA3+ EDDS-added group, it is 21.7 cm. Compared with the conventional methods of phytoremediation, these integrated measures can actually spur the growth of plants. 

scholarly journals Health Risk Assessment of Heavy Metals in Traditional Cosmetics Sold in Tunisian Local Markets

2016 ◽  
Vol 2016 ◽  
pp. 1-12 ◽  
Author(s):  
Mohamed Anouar Nouioui ◽  
Salah Mahjoubi ◽  
Asma Ghorbel ◽  
Marouen Ben Haj Yahia ◽  
Dorra Amira ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Heavy Metal ◽  
Health Risk ◽  
Atomic Absorption ◽  
Good Manufacturing Practice ◽  
Potential Threat ◽  
Analytical Test ◽  
Metal Contents ◽  
Cu And Zn

This study was undertaken in order to determine heavy metal contents in twelve (n=12) henna brands and eleven (n=11) kohl products. An analytical test was performed for Pb, Cd, Cu, and Zn in henna and kohl products using atomic absorption spectrophotometery. The overall mean concentrations of heavy metals in henna varied between 1.2 and 8.9 μg g−1 for Pb; 0.8 and 18.6 μg g−1 for Cd; 0.5 μg g−1 and 3.3 μg g−1 for Cu; and 3.7 μg g−1 and 90.0 μg g−1 for Zn. As for kohl products, Pb concentrations ranged between 51.1 μg g−1 and 4839.5 μg g−1, Cd concentrations ranged between 1.0 μg g−1 and 158.6 μg g−1, Cu concentrations ranged between 2.5 μg g−1 and 162.5 μg g−1, and Zn concentrations ranged between 0.7 μg g−1 and 185.0 μg g−1. The results of our study revealed that Pb, Cd, Cu, and Zn contents in investigated samples were high, making from the prolonged use of such products a potential threat to human health. Therefore, major quality controls are recommended in order to enforce acceptable limits of potential contaminants in cosmetics and good manufacturing practice.

Use of Polyacrylamide Superabsorbent Polymers and Plantain Peel Biochar to Reduce Heavy Metal Mobility and Uptake by Wastewater-Irrigated Potato Plants

2020 ◽  
Vol 63 (1) ◽  
pp. 11-28 ◽  
Author(s):  
Jaskaran Dhiman ◽  
Shiv O. Prasher ◽  
Eman ElSayed ◽  
Ramanbhai Patel ◽  
Christopher Nzediegwu ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Synthetic Wastewater ◽  
List Type ◽  
Cd Uptake ◽  
Superabsorbent Polymers ◽  
Zn Uptake ◽  
Tuber Flesh ◽  
Acrylamide Monomers ◽  
Cu And Zn

HighlightsAmending soil with SAP+BC and SAP reduced Cd, Cu, and Zn uptake into potato tubers.SAP+BC treatment led to greater Cd and Zn retention in topsoil.Acrylamide monomers were not detected in potatoes grown in SAP-amended soil.Potato peels accumulated higher concentrations of heavy metals than tuber flesh.Abstract. Agriculture is the largest consumer of freshwater; therefore, use of alternate sources for irrigation, such as wastewater, could alleviate increasing stress on freshwater resources. However, wastewater may contain contaminants such as heavy metals (Cd, Cr, Cu, Fe, Pb, and Zn), which could be taken up by food crops and/or contaminate groundwater. To reduce the mobility of heavy metals in soil and deter their uptake by potatoes ( L.) irrigated with synthetic wastewater, polyacrylamide superabsorbent polymer (SAP) and a mixture of SAP and plantain peel biochar (SAP+BC) were tested as soil amendments. The experiment was performed in field lysimeters packed with sandy soil. SAP was incorporated into the soil layer from 0.15 to 0.25 m below the surface and BC was mixed into the top 0.10 m of soil, both at an application rate of 1% (w/w). Leachate and composite soil samples from different depths, collected after each irrigation event, were analyzed for heavy metals. Upon harvest, different plant parts were subjected to heavy metal analysis. Compared to the untreated control, the SAP+BC treatment led to significantly greater (p &lt; 0.05) retention of Cd and Zn in the topsoil while significantly reducing (p &lt; 0.05) Cd, Cu, and Zn uptake into potato tuber flesh tissue and Cd uptake into tuber peels. The SAP treatment also significantly reduced (p &lt; 0.05) Cd uptake in the tuber as compared to the control. Acrylamide monomers were not detected in tuber flesh and peel samples for all treatments, indicating possible safe use of SAP and BC in soils to reduce heavy metal leaching and uptake by plants. Keywords: Biochar, Heavy metals, Hydrogels, Lysimeter, Plant uptake, Superabsorbent polymers, Wastewater.

scholarly journals Effect of Pig and Cattle Slurry Application on Heavy Metal Composition of Maize Grown on Different Soils

2018 ◽  
Vol 10 (8) ◽  
pp. 2684 ◽  
Author(s):  
Giorgio Provolo ◽  
Giulia Manuli ◽  
Alberto Finzi ◽  
Giorgio Lucchini ◽  
Elisabetta Riva ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Organic Fertilizer ◽  
Pig Manure ◽  
Soil Enrichment ◽  
Maize Cultivation ◽  
Time Required ◽  
Cu And Zn ◽  
Different Soils

Cattle and pig manure contain useful mineral nutrients (N, P, and K) and are therefore used as organic fertilizer. However, excessive applications of manure can cause environmental problems and threaten animal and human health because these materials also hold significant amounts of heavy metals, particularly Cu and Zn. To assess the potential risk due to the increased concentrations of heavy metals (Cu, Mn, Zn, and Cr) in a harvested crop, two maize hybrids were grown in pots on four different soils with three different fertilisers (urea, pig manure, and cattle manure). Both soil and manure characteristics influenced the heavy metal concentrations in the plant shoots. Organic fertilisation strongly interacted with the soils and, in general, reduced the shoot content of Cu, Mn, and Zn. A preliminary assessment of the heavy metal balance of the agricultural systems based on the intensive livestock production and maize cultivation showed that the potential soil enrichment of the long-term application of livestock manure arises mainly from the application of pig slurries that have a high content of Cu and Zn. The time required to apply an amount of metal that is equal to the initial soil content is 60–300 years for Zn and 240–450 years for Cu, depending on the soil type and the initial heavy metal content.

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