scholarly journals Study of influence of the alkaline component on the physico-mechanical properties of the low clinker and clinkerless waterproof compositions

2018 ◽  
Vol 230 ◽  
pp. 03018 ◽  
Author(s):  
Yuliya Savchuk ◽  
Andrii Plugin ◽  
Vitalii Lyuty ◽  
Oleksii Pluhin ◽  
Olga Borziak
Keyword(s):  
Mechanical Properties ◽  
Sodium Hydroxide ◽  
Hydration Products ◽  
Extreme Wave ◽  
Sodium Calcium ◽  
Alkaline Component ◽  
Complex Salts ◽  
Composition Structure ◽  
Furnace Slag ◽  
Very High

The influence of the alkaline component on the physico-mechanical properties and the structure of the clinkerless waterproof composition on the basis of Kryvyi Rih blast furnace slag and an alkaline component – sodium hydroxide – have been investigated. High and very high correlation between the compressive strength f of the composition and the alkali – sodium hydroxide – strength A/S has been established. The dependence f on A/S has an extreme wave-like pattern with maxima at A/S = 1.5% and 15-20%, which is explained by the formation of one and two series of hydration products between slag particles similarly to Portland cement-based compositions. It has been established that the hydration products of the composition are predominantly gel-like one, such as hydrosilicate gel and zeolite-like sodium calcium hydroalumosilicates; fewer crystalline hydration products include prismatic and needle-like crystals of complex salts of aluminate phases. The pore size in the composition structure mostly does not exceed 2 microns, although single pores up to 10 microns in size also occur.

scholarly journals MICRO-MECHANICAL PROPERTIES OF CEMENT AND SLAG COMPOSITES MEASURED BY NANOINDENTATION

2020 ◽  
Vol 26 ◽  
pp. 45-49
Author(s):  
Jiří Němeček ◽  
Jiří Němeček
Keyword(s):  
Mechanical Properties ◽  
Portland Cement ◽  
Modulus Of Elasticity ◽  
Volume Fraction ◽  
Blended Cement ◽  
Hydration Products ◽  
Granulated Blast Furnace Slag ◽  
The Difference ◽  
Portland Cement Paste ◽  
Furnace Slag

In this study, the micromechanical response of two cementitious composites was characterized by nanoindentation. Pure Portland cement paste and Portland cement with 50 vol. % replaced with granulated blast furnace slag (GBFS) paste were investigated at the age of 28 days. Grid nanoindentation, statistical deconvolution and scanning electron microscopy were used to characterize the main hydration products. Several grids with approximately 500 indents on each sample were performed to obtain modulus of elasticity, hardness and creep indentation parameter. Similar mechanical phases containing calcium silica hydrate, crystalline calcium hydroxide and un-hydrated clinker were found in both samples varying by volume fraction. Blended cement, moreover, contains a phase of slag hydration products with a significantly lower modulus of elasticity. This phase with a high portion of unreacted GBFS is mostly responsible for the difference of mechanical properties of the whole composite.

The Role of Alkalis in Hydraulic Mixtures

2019 ◽  
Vol 955 ◽  
pp. 62-67
Author(s):  
Lukáš Procházka ◽  
Jana Boháčová
Keyword(s):  
Mechanical Properties ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Alkali Silica Reaction ◽  
Type Ii ◽  
Hydration Products ◽  
Experimental Part ◽  
Ph Values ◽  
Furnace Slag

Alkali substances are present in cements used as a binder in concrete only in a minimum content. The most known process that alkali causes is the alkali-silica reaction. In this reaction, the alkali contained in the cement or supplied from the outside with an inappropriately selected aggregate containing amorphous SiO2. This reaction results in the development of hydration products, resulting in an increase in the volume of the original components, which can cause a breakage of the concrete structure and subsequent disintegration. The range of alkali-silica reaction can be reduced by the use of a suitable aggregate or the use of Type II admixtures which are characterized by pozzolanic or latently hydraulic activity. These admixtures react with alkali and then no longer react with the amorphous SiO2 contained in the aggregate. Alkalis also affect other properties of concrete such as basic physical-mechanical properties, frost resistance and pH.In the experimental part the pH values were compared between mixtures of Portland cement and alkaline activated blast furnace slag using slag aggregate from the heap Koněv.

Mechanical Properties and Microstructure Analysis of Copper Tailings Solidifying with Different Cementitious Materials

2014 ◽  
Vol 878 ◽  
pp. 171-176 ◽  
Author(s):  
Xu Quan Huang ◽  
Hao Bo Hou ◽  
Min Zhou ◽  
Wei Xin Wang
Keyword(s):  
Mechanical Properties ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Calcium Silicate Hydrate ◽  
Steel Slag ◽  
Cementitious Materials ◽  
Cementitious Material ◽  
Hydration Products ◽  
New Type ◽  
Furnace Slag

With new type steel slag-blast furnace slag-fluorgypsum-based cemented material, P O42.5 cement, commonly used cementation agent in China, mechanical properties and microstructure of tailings solidification bodies are studied. The hydration products and morphology tailings concretion body in 60 days are analyzed by SEM and XRD test, which reveals the tailings cementation mechanism solidifying with different cementitious material. Furthermore, a large number of slender bar-like ettringite crystals and filamentous network-like calcium-silicate-hydrate gels bond firmly each other, which is the most important reason why steel slag-blast furnace slag-fluorgypsum base cemented material has the best tailings cementation mechanical properties.

Utilization of CFB Fly Ash in Eco-Cement: Mechanical Properties and Microstructural Analysis

2010 ◽  
Vol 150-151 ◽  
pp. 885-889 ◽  
Author(s):  
Xiao Ming Liu ◽  
Yu Li ◽  
Ling Ling Zhang ◽  
Da Qing Cang
Keyword(s):  
Mechanical Properties ◽  
Fly Ash ◽  
Circulating Fluidized Bed ◽  
Microstructural Analysis ◽  
Hydration Products ◽  
X Ray Diffraction ◽  
Cement Pastes ◽  
X Ray ◽  
Xrd Techniques ◽  
Furnace Slag

The disposal of circulating fluidized bed (CFB) fly ash has been a serious environmental problem in the development of our society. In this work, the feasibility of recycling CFB fly ash as a blended material incorporating blast furnace slag (BFS), clinker and gypsum for the preparation of Eco-cement has been investigated. The mechanical properties of CFB fly ash based Eco-cements, including CFB fly ash–clinker system, CFB fly ash–ground BFS system, and CFB fly ash–ground BFS–clinker system, were evaluated in this paper. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques were used to analyze the microstructural changes and the hydration products of the CFB fly ash based Eco-cement pastes. The results indicated that it is feasible to use CFB fly ash along with BFS and clinker to produce Eco-cement. The hydration products of CFB fly ash based Eco-cement are mostly ettringite and amorphous C-S-H gel, which are principally responsible for the strength and structure development of CFB fly ash based Eco-cement in the hydration process.

UNS A97075

Alloy Digest ◽  
1986 ◽  
Vol 35 (7) ◽  
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Aluminum Alloy ◽  
High Strength ◽  
Heat Treating ◽  
Good Resistance ◽  
Temperature Performance ◽  
Structural Applications ◽  
Structural Parts ◽  
Very High

Abstract UNS No. A97075 is a wrought precipitation-hardenable aluminum alloy. It has excellent mechanical properties, workability and response to heat treatment and refrigeration. Its typical uses comprise aircraft structural parts and other highly stressed structural applications where very high strength and good resistance to corrosion are required. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and shear strength as well as fatigue. It also includes information on low temperature performance as well as forming, heat treating, and machining. Filing Code: Al-269. Producer or source: Various aluminum companies.

KAISER ALUMINUM ALLOY 7050

Alloy Digest ◽  
2000 ◽  
Vol 49 (1) ◽  
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Tensile Strength ◽  
Aluminum Alloy ◽  
Heat Treating ◽  
High Fracture Toughness ◽  
High Fracture ◽  
Kaiser Aluminum ◽  
Structural Parts ◽  
Very High

Abstract Kaiser Aluminum Alloy 7050 has very high mechanical properties including tensile strength, high fracture toughness, and a high resistance to exfoliation and stress-corrosion cracking. The alloy is typically used in aircraft structural parts. This datasheet provides information on composition, physical properties, hardness, tensile properties, and shear strength as well as fracture toughness and fatigue. It also includes information on forming, heat treating, machining, and joining. Filing Code: AL-366. Producer or source: Tennalum, A Division of Kaiser Aluminum.

TIMKEN 16-15-6

Alloy Digest ◽  
1963 ◽  
Vol 12 (12) ◽  
Keyword(s):  
Mechanical Properties ◽  
Creep Resistance ◽  
Elevated Temperatures ◽  
Roller Bearing ◽  
Heat Treating ◽  
Resistant Steel ◽  
Heat Resistant Steel ◽  
Corrosion And Oxidation ◽  
Very High ◽  
High Creep Resistance

Abstract Timken 16-15-6 is a non-magnetic, austenitic, corrosion and heat resistant steel having high creep resistance at elevated temperatures and good corrosion and oxidation resistance. It age-hardens at elevated temperatures after solution quenching, and possesses very high mechanical properties. This datasheet provides information on composition, microstructure, hardness, and tensile properties as well as creep. It also includes information on forming, heat treating, machining, and joining. Filing Code: SS-150. Producer or source: Timken Roller Bearing Company.

scholarly journals Formulation, Mechanical Properties and Phase Analysis of Fly Ash Geopolymer with Ladle Furnace Slag Replacement

2021 ◽  
Author(s):  
Ng Hui-Teng ◽  
Heah Cheng-Yong ◽  
Liew Yun-Ming ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Kong Ern Hun ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Fly Ash ◽  
Phase Analysis ◽  
Ladle Furnace ◽  
Furnace Slag

scholarly journals Regulating Effect of Cement Accelerator on High Content Solid-Wastes Autoclaved Aerated Concrete (HCS-AAC) Slurry Performance and Subsequent Influence

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 799
Author(s):  
Dingkun Xie ◽  
Lixiong Cai ◽  
Jie Wang
Keyword(s):  
Mechanical Properties ◽  
Mechanical Property ◽  
Solid Wastes ◽  
Hydration Products ◽  
Promoting Effect ◽  
Adverse Side Effects ◽  
Foaming Process ◽  
Carbide Slag ◽  
Negative Effect ◽  
Aerated Concrete

Adverse side-effects occurred in slurry foaming and thickening process when carbide slag was substituted for quicklime in HCS-AAC. Cement accelerators were introduced to modify the slurry foaming and coagulating process during pre-curing. Meanwhile, the affiliated effects on the physical-mechanical properties and hydration products were discussed to evaluate the applicability and influence of the cement accelerator. The hydration products were characterized by mineralogical (XRD) and thermal analysis (DSC-TG). The results indicated that substituting carbide slag for quicklime retarded slurry foaming and curing progress; meanwhile, the induced mechanical property declination had a negative effect on the generation of C–S–H (I) and tobermorite. Na2SO4 and Na2O·2.0SiO2 can effectively accelerate the slurry foaming rate, but the promoting effect on slurry thickening was inconspicuous. The compressive strength of HCS-AAC obviously declined with increasing cement coagulant content, which was mainly ascribed to the decrease in bulk density caused by the accelerating effect on the slurry foaming process. Dosing Na2SO4 under 0.4% has little effect on the generation of strength contributing to hydration products while the addition of Na2O·2.0SiO2 can accelerate the generation and crystallization of C–S–H, which contributed to the high activity gelatinous SiO2 generated from the reaction between Na2O·2.0SiO2 and Ca(OH)2.

scholarly journals Influence of Applied Bias Voltage on the Composition, Structure, and Properties of Ti:Si-Codoped a-C:H Films Prepared by Magnetron Sputtering

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Jinlong Jiang ◽  
Qiong Wang ◽  
Yubao Wang ◽  
Zhang Xia ◽  
Hua Yang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Surface Roughness ◽  
Magnetron Sputtering ◽  
Bias Voltage ◽  
Tribological Properties ◽  
Structure And Properties ◽  
Applied Bias ◽  
Applied Bias Voltage ◽  
Methane Mixture ◽  
Composition Structure

The titanium- and silicon-codoped a-C:H films were prepared at different applied bias voltage by magnetron sputtering TiSi target in argon and methane mixture atmosphere. The influence of the applied bias voltage on the composition, surface morphology, structure, and mechanical properties of the films was investigated by XPS, AFM, Raman, FTIR spectroscopy, and nanoindenter. The tribological properties of the films were characterized on an UMT-2MT tribometer. The results demonstrated that the film became smoother and denser with increasing the applied bias voltage up to −200 V, whereas surface roughness increased due to the enhancement of ion bombardment as the applied bias voltage further increased. The sp3carbon fraction in the films monotonously decreased with increasing the applied bias voltage. The film exhibited moderate hardness and the superior tribological properties at the applied bias voltage of −100 V. The tribological behaviors are correlated to the H/E or H3/E2ratio of the films.

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