scholarly journals Improvement of reagent flotation modes of sphalerite and pyrite from deposits of copper-zinc pyrite, polymetallic copper-zinc pyrite and polymetallic ores

2021 ◽  
Vol 942 (1) ◽  
pp. 012004
Author(s):  
Z Y Kyaw ◽  
Z A Tiagalieva ◽  
Z O Htet ◽  
K K Phyo

Abstract Copper-zinc pyrite (Sulphide) and polymetallic ores of Russia are complex and difficult to process mineral raw materials. The main technology for the enrichment of this ores are flotation. Currently, the improvement of the flotation technology of this mineral raw materials is carried out in several way. It has been established by the practice of beneficiation of copper-zinc ores that obtaining high-quality zinc and pyrite concentrates is impossible without adding flotation modifiers of sphalerite and pyrite to various flotation operations. This reagent are copper (II) sulfates, zinc and iron (II) sulfates in an alkaline calcareous medium. Therefore, studies on the flotation of sphalerite and pyrite in an alkaline calcareous medium with the addition of one of these metal sulfates to the mineral flotation operation were performed. The effect of each copper (II) sulfates zinc, and iron (II) on the flotability of sphalerite and pyrite was studied during flotation of the mineral and xanthate and dithiophosphate at pH = 8, 10, and 12. The aim of this work was to study the effect of the flotation size class (- 0.074 + 0.044 mm) sphalerite and pyrite of one of the Russian deposits by sulfhydryl collectors in the presence of copper, zinc and iron sulfates in the liquid phase of flotation pulp

2021 ◽  
Vol 4 (1) ◽  
pp. 374-388
Author(s):  
Zay Ya Kyaw ◽  
◽  
Kyaw Kyaw Phyo ◽  
A.B. Kopylov ◽  
R.A. Kovalev

Pyrite copper-zinc (sulfide) and polymetallic ores in Russia are complex and refracto-ry mineral raw materials. The main processing technology for such ores is flotation. Currently, the improvement of the flotation technology of such mineral raw materials is carried out in several directions. It has been established by the practice of enrichment of copper-zinc ores that obtaining high-quality zinc and pyrite concentrates is impossible without the use of various modifiers in the practice of flotation of sphalerite and pyrite. Such reagents are copper (II), zinc and iron (II) sulfates in an alkaline lime environment. Therefore, studies were carried out to float sphalerite and pyrite in an alkaline lime medium with the addition of one of the indicat-ed sulfates to the mineral flotation operation. The effect of each of the sulfates of copper (II), zinc and iron (II) on the flotation of sphalerite and pyrite was studied during flotation of the mineral with butyl xanthate and dithiophosphate at pH = 8, 10, and 12. The aim of this work was to study the effect of sulfhydryl collectors in the presence of copper sulfates , zinc and iron for flotation of sphalerite and pyrite with a size class (-0.074 + 0.044 mm) from one of the Rus-sian deposits.


2021 ◽  
Vol 13 (2) ◽  
pp. 224-237
Author(s):  
Valentin CHANTURIA ◽  
◽  
Irina SHADRUNOVA ◽  
Olga GORLOVA ◽  
◽  
...  

Innovative processes of deep and complex processing of technogenic raw materials in the context of sustainable development of the mining industry and the economic challenges facing the mining industry should ensure the transition to a circular economy and the maximum use of natural resources. The article reflects the priority scientific and technological research on the involvement of technogenic mineral resources in efficient processing. Presented, developed at ICEMR RAS, including jointly with universities, research and production organizations and enterprises, modern innovative processes of deep and environmentally friendly processing of refractory mineral raw materials of complex material composition (tailings of enrichment of non-ferrous and noble metal ores, poor off-balance ores, slags ferrous and nonferrous metallurgy, sludge of metallurgical production) and hydro-mineral technogenic resources (acidic mineralized bottom-dump waters of mining enterprises of the copper-zinc complex of the Urals, saponite-containing circulating waters of diamond processing factories). Among other things, new directions in the field of selective disintegration of finely dispersed mineral raw materials based on energy effects and deep processing of slags are outlined; increasing the selectivity of enrichment processes; combined processing of technogenic raw materials; resource-saving processing of technogenic and hydro-mineral resources, obtaining secondary products from processing waste. It is shown that in the face of new economic challenges, Russia has sufficient scientific and technological potential in the field of deep and environmentally safe processing of technogenic raw materials in the form of developed and, to varying degrees, tested innovative resource-saving technologies that correspond to the world level, and in a number of technologies are superior to it.


Land Science ◽  
2020 ◽  
Vol 2 (2) ◽  
pp. p1
Author(s):  
Rashidova R K ◽  
Kurbanov Abdirakhim Ahmedovich ◽  
Aliyev T ◽  
Jiyanov A B ◽  
Turdieva O J ◽  
...  

This paper presents the results of the analysis of the quality of basalts, their heat treatment and studies of changes in the chemical composition of basalts, which leads to a change in the external color of partially processed basalt raw materials (hereinafter referred to as semi-finished product). The results of a study of purified basalt from slime, impurities and hydroxides, changes in the chemical composition of basalt rock are presented. The prospects of heat treatment of a semi-finished product and obtaining multi-colored products from mineral raw materials is shown. It was found that the optimal firing temperature of the semi-finished product, the possible options for changing the external color and the criterion points of the thermal effect at which the basalt semi-finished product changes the external shade. These statements are of great scientific and practical interest in the fact that during the heat treatment of a semifinished product, basalt easily overheats and gradually acquires a different color, which occurs to a liquids temperature and allows the future to plan to obtain high-quality multi-colored products from basalts, for example, products for design.


2021 ◽  
Author(s):  
S. Dyussenova ◽  
◽  
Ahmed A. M. El-Amir ◽  
◽  
◽  
...  

In the Republic of Kazakhstan, the most promising are kaolinite clays of the Alekseevsky deposit. For effective processing of clays, it is necessary to develop special methods of processing, since satisfactory results were not achieved when using standard methods of gravity processing. The article provides the results of studies of the effect of preliminary chemical activation on the yield of the kaolinite fraction during gravitational processing. Previously, the method of preliminary chemical activation of raw materials in a solution of sodium bicarbonate has proven itself well in the processing of various mineral raw materials. It is determined that as a result of preliminary chemical activation, changes in the phase composition occurred. The dependence of the yield of the kaolinite fraction on the temperature of chemical activation, duration, and the ratio of W:T and the concentration of the sodium bicarbonate solution. Based on the results obtained, a technology for the complex processing of kaolinite clays has been developed, which provides for the preliminary chemical activation of the feedstock at the beginning of the process, which will effectively isolate high-quality kaolinite and quartz products, which will significantly reduce the flow of materials entering for sintering. As a result of activation, the phase composition of the kaolinite fraction has changed: the percentage of the kaolinite fraction has decreased; new phases of muscovite and sodium aluminosilicate appeared; the amount of quartz increased.


Author(s):  
I. A. Ilina ◽  
I. A. Machneva ◽  
E. S. Bakun

  The article is devoted to the study of the chemical composition, physical and thermal-pfysical characteristics of damp apple pomaces and the identifying patterns of influence of drying temperature the functional composition and gel-forming ability of pectin. The research is aimed at obtaining initial data for the subsequent calculation of the main technological, hydro-mechanical, thermal, structural and economic characteristics of devices for drying the plant raw materials, ensuring the environmental safety and high quality of pectin-containing raw materials, the reducing heat and energy costs. As a result of the study of the thermal characteristics of apple pomaces, the critical points (temperature conductivity – 16.5 x 10-8 m2/s, thermal conductivity – 0.28 W/m K, heat capacity – 1627 j/(kg K)) at a humidity of 56 % are determined, which characterizing the transition from the extraction of weakly bound moisture to the extraction of moisture with strong bonds (colloidal, adsorption). It was found that the pomaces obtained from apples of late ripening have a higher content of solids (21-23 %), soluble pectin and protopectin (2.5-4.5 %). Dried pomaces obtained from apple varieties of late ripening contain up to 25 % pectin, which allow us to recommend them as a source of raw materials for the production of pectin. The optimum modes of preliminary washing of raw materials are offered, allowing to the remove the ballast substances as much as possible. It is established that when the drying temperature increases, the destructive processes are catalyzed: the strength of the pectin jelly and the uronide component and the degree of pectin esterification are reduced. The optimum drying temperature of damp apple pomaces is 80 0C, at which the quality of pectin extracted from the dried raw materials is maintained as much as possible. It is shown that the most effective for the pectin production is a fraction with a particle size of 3-5 mm, which allow us to extract up to 71 % of pectin from raw materials.


Author(s):  
Oksana Bitlian ◽  
Oksana Kravchenko ◽  
Tetiana Kodak ◽  
Andrii Onyshchenko ◽  
Tetiana Konks

The analysis of literature sources shows that the type and material from which the packaging is made has an important place in the system of factors which influence on the storage of feed products and also prevents reducing the quality of raw materials and finished products. Therefore, the purpose of our research is the technological justification of changing the quality indexes of premix samples with salts of trace elements of different chemical nature in the process of storage. For the solution of the tasks, common zootechnical and statistical methods of the research were used. The use of premixes in feeding pigs is based on the fact that they should be used taking into account the biogeochemical properties of the region for which they are calculated. Foods depending on regional properties have a special biochemical composition and excess or lack of individual substances should be offset by the composition of premix. Ignoring this provision necessarily leads to the inappropriate use of BAR, the misbalance of the diet in relation to the physiological needs and inefficiency of the industry. In turn, it requires the purchase and conservation of products for the period of use. Various chemical structures and structures of BAR during the storage process react differently and change qualitative indexes, which leads to a decrease in the productive activity of active substances. It was determined that the humidity of premixes varied within the limits of 12.0-13.0 %, which exceeded the normative, but was not critical, the highest acidity had premix with sulfuric acid salts (6.9 units), the least - premix with lysates (5.7 unit). According to the results of the study, positive qualitative responses were found for the presence of vitamins A, D and B2, macro- and micronutrients: potassium, magnesium, copper, zinc, cobalt, iodine. The above facts of changes in the properties of premixes in the process of storage must be taken into account when providing technological bases for feeding pigs in order to obtain high gains and the quality of manufactured products. Key words: premix, micro-and macro elements, combined fodders, fodder mixes, chelating compounds, feeding, using, pigs' livestock.


Physics ◽  
2021 ◽  
Vol 3 (2) ◽  
pp. 320-351
Author(s):  
Serge Nagorny

Recent progress in Cs2HfCl6 (CHC) crystal production achieved within the last five years is presented. Various aspects have been analyzed, including the chemical purity of raw materials, purification methods, optimization of the growth and thermal conditions, crystal characterization, defect structure, and internal radioactive background. Large volume, crack-free, and high quality CHC crystals with an ultimate scintillating performance were produced as a result of such extensive research and development (R & D) program. For example, the CHC crystal sample with dimensions ∅23 × 30 mm3 demonstrates energy resolution of 3.2% FWHM at 662 keV, the relative light output at the level of 30,000 ph/MeV and excellent linearity down to 20 keV. Additionally, this material exhibits excellent pulse shape discrimination ability and low internal background of less than 1 Bq/kg. Furthermore, attempts to produce a high quality CHC crystal resulted in research on this material optimization by constitution of either alkali ions (Cs to Tl), or main element (Hf to Zr), or halogen ions (Cl to Br, I, or their mixture in different ratio), as well as doping with various active ions (Te4+, Ce3+, Eu3+, etc.). This leads to a range of new established scintillating materials, such as Tl2HfCl6, Tl2ZrCl6, Cs2HfCl4Br2, Cs2HfCl3Br3, Cs2ZrCl6, and Cs2HfI6. To exploit the whole potential of these compounds, detailed studies of the material’s fundamental properties, and understanding of the variety of the luminescence mechanisms are required. This will help to understand the origin of the high light yield and possible paths to further extend it. Perspectives of CHC crystals and related materials as detectors for rare nuclear processes are also discussed.


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