Influence of the length of the spacer group on the performance of the sulfate-based Gemini surfactants

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Wang Yu ◽  
Gang Chen ◽  
Haiyan Yang ◽  
Sisi Li
Keyword(s):  
Gemini Surfactants ◽  
Anionic Surfactants ◽  
Lime Soap ◽  
Raw Materials ◽  
Chlorosulfonic Acid ◽  
Content Type ◽  
Spacer Group ◽  
Orthogonal Experiments ◽  
Foam Properties ◽  
Dispersing Ability

PurposeA series of sulfate-based Gemini anionic surfactants were synthesized via etherification, ring opening and sulfation reactions using epichlorohydrin, fatty alcohol, ethylene glycol and chlorosulfonic acid as the main raw materials. Orthogonal experiments for 1,8-bisalkoxymethylene-3,6-dioxin-1,8-octane disulfate were performed on the sulfation reaction to determine the optimal reaction conditions.Design/methodology/approachA series of sulfate-based Gemini anionic surfactants were synthesized via etherification, ring opening and sulfation reactions using epichlorohydrin, fatty alcohol, ethylene glycol and chlorosulfonic acid as the main raw materials. Orthogonal experiments for 1,8-bisalkoxymethylene-3,6-dioxin-1,8-octane disulfate were performed on the sulfation reaction to determine the optimal reaction conditions. The structures of the intermediate and final products were characterized by FT-IR (Fourier transform infrared spectroscopy analysis), 1H-NMR (proton nuclear magnetic resonance spectroscopy) methods. The thermal performance of surfactants was analyzed using thermogravimetric analysis (TGA). The thermogravimetric results showed that the sulfate-based Gemini surfactants had good heat resistance (the thermal decomposition temperature of which was in the range of 140∼170?). The Krafft point, surface tension, foaming, Hydrophile–Lipophile Balance Number (HLB), emulsifying, wetting, and lime-soap dispersing performance were measured by visual observation, hanging drop method, aqueous surfactant solution method and Borghetti–Bergman method, respectively. The results have shown that all the sulfate-based Gemini surfactants had good water solubility and lime-soap dispersing ability. When spacer group was -(CH2)2-, with the increase of the carbon chain length from C12 to C14, the micellar concentration critical micelle concentration and surface tension (CMC) gradually increased from 8.25 × 10–4 mol/L to 8.75 × 10–4 mol/L and 27.5 mN/m to 30.9 mN/m, respectively. Also, the sulfate-based Gemini surfactants with the different length of the spacer group had a different effect on their performance on foaming properties and foam properties, HLB and emulsifying ability and wetting ability. FindingsIn view of the important role of the spacer group and the general use of anionic surfactants in oil fields, this article considers the preparation of a series of sulfate-based Gemini surfactants by changing the spacer group and the chain length of the hydrophobic group and evaluating their surface activity, and finally its Kraffi, on the foam properties, HLB value, emulsifying performance, lime soap dispersing ability etc.Originality/valueSulfate-based Gemini surfactants have broad application prospects in the fields of oil and gas exploitation, environmental protection, chemistry and daily chemical industry and so on.

Application of lean practices in small and medium-sized food enterprises

2013 ◽  
Vol 116 (1) ◽  
pp. 125-141 ◽  
Author(s):  
Manoj Dora ◽  
Dirk Van Goubergen ◽  
Maneesh Kumar ◽  
Adrienn Molnar ◽  
Xavier Gellynck
Keyword(s):  
Food Processing ◽  
Lean Manufacturing ◽  
Raw Materials ◽  
Current Status ◽  
Food Sector ◽  
Statistical Process ◽  
Content Type ◽  
Lean Practices ◽  
The Status ◽  
Manufacturing Techniques

Purpose – Recent literature emphasizes the application of lean manufacturing practices to food processing industries in order to improve operational efficiency and productivity. Only a very limited number of studies have focused on the implementation of lean manufacturing practices within small and medium-sized enterprises (SMEs) operating in the food sector. The majority of these studies used the case study method and concentrated on individual lean manufacturing techniques geared towards resolving efficiency issues. This paper aims to analyze the status of the lean manufacturing practices and their benefits and barriers among European food processing SMEs. Design/methodology/approach – A structured questionnaire was developed to collect data. A total of 35 SMEs' representatives, mostly CEOs and operations managers, participated in the survey. The study investigated the role of two control variables in lean implementation: size of the company and country of origin. Findings – The findings show that lean manufacturing practice deployment in food processing SMEs is generally low and still evolving. However, some lean manufacturing practices are more prevalent than others; e.g. flow, pull and statistical process control are not widely used by the food processing SMEs, whereas total productive maintenance, employee involvement, and customer association are more widespread. The key barriers encountered by food SMEs in the implementation of lean manufacturing practices result from the special characteristics of the food sector, such as highly perishable products, complicated processing, extremely variable raw materials, recipes and unpredictable demand. In addition, lack of knowledge and resources makes it difficult for food processing SMEs to embark on the lean journey. Originality/value – The gap in the literature regarding the application of lean manufacturing in the food sector is identified and addressed in this study. The originality of this paper lies in analyzing the current status of the use of lean manufacturing practices among food SMEs in Europe and identifying potential barriers.

The international strength of the euro will grow

2021 ◽  
Keyword(s):  
Euro Area ◽  
Financial Services ◽  
Raw Materials ◽  
Domestic Demand ◽  
Content Type ◽  
The Us ◽  
Us Dollar ◽  
Strategic Autonomy ◽  
Geopolitical Risks ◽  
The Eu

Significance The proposals identified areas where the euro could potentially become more dominant, such as the issuance of green bonds, digital currencies, and international trade in raw materials and energy. Ambitions to enhance the international leverage of the euro are being driven by the aim to strengthen EU strategic autonomy amid rising geopolitical risks. Impacts Developing its digital finance sector would be an opportunity for the EU to enhance its strategic autonomy in financial services. Challenging the US dollar would require the euro-area to rebalance its economy away from foreign to domestic demand. Member state division will prevent the economic reconfiguration the euro-area needed to make the euro a truly global currency.

Vegan cheeses vs processed cheeses – traceability issues and monitoring countermeasures

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Moawiya A. Haddad ◽  
Sharaf S. Omar ◽  
Salvatore Parisi
Keyword(s):  
Food Supply ◽  
Design Methodology ◽  
Raw Materials ◽  
Production Method ◽  
Animal Origin ◽  
Information Load ◽  
Supply Chain Risk ◽  
Supply Networks ◽  
Content Type ◽  
Traceability System

PurposeThe purpose of this study comes from the need of defining improved durability values and the realization of a good traceability management for selected vegan cheeses has suggested the comparison between a processed cheese and its analogous version without animal-origin raw materials. The durability should be studied at a well-defined temperature, probably agreed among the food producer and the food processor. In addition, the traceability system should consider many components and related suppliers.Design/methodology/approachA supply chain risk assessment analysis has been carried out with relation to two different products: an analogue cheese and a vegan cheese-like preparation. Raw materials and ingredients have been evaluated (production method and origin; geographical identification), with the aim of identifying simplified food.FindingsAn assessment of food supply networks has been carried out. In the first situation (analogue cheeses), the ingredient “cheeses” shows an important complexity: five suppliers with a related six-interconnection hub. On the other side, vegan cheeses are obtained from 11 ingredients (a challenging hub); four of them may be produced from 2–5 components of different origin (five total hubs). Tested processed cheeses are represented by means of a linear food supply network with two hubs (cheeses and “arrival” show degrees 6 and 9, respectively). Networks concerning vegan cheeses include five different hubs: four complex raw materials (degree: 2, 3, 4 and 5) and the “arrival” step (degree: 12).Originality/valueThe information load of vegan cheeses (two hubs, degrees >> average degree) appears high if compared with processed cheeses (two hubs), although the complexity of networks appears similar. Vegan cheeses may seem technologically simpler than processed cheeses and be sometimes questioned because of important traceability issues. Adequate traceability countermeasures in terms of preventive monitoring actions should be recommended when speaking of vegan cheeses. Anyway, a centralized manager would be always required.

Development of two dosimetry systems based on basic violet dye for possible use as radiation dosimeters

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Nehad Magdy ◽  
Sameh Gafar
Keyword(s):  
Gamma Ray ◽  
Raw Materials ◽  
Absorbed Dose ◽  
Chemical Yield ◽  
Radiation Sensitivity ◽  
Vital Role ◽  
Radiation Chemical ◽  
Content Type ◽  
Before And After

Purpose The purpose of this research paper is to study a comparison between two dosimetry systems, both of them based on basic violet dye (BV). Design/methodology/approach The first system depends on (BV) (incorporating polyvinyl alcohol) as a thin-film dosimeter. The second system also relies on (BV) as a solution dosimeter, which is more sensitive to gamma rays. The two prepared film/solutions have a considerable signal that decreases upon irradiation and the strength of the signal decreases with increasing radiation dose. Findings The gamma ray absorbed dose for these dosimeters was found to be up to 35 kGy for films and 1 kGy for the liquid phase. All dosimetric characteristics as radiation chemical yield, additive substance, dose-response function, radiation sensitivity, also before and after-irradiation stability under various conditions were considered. Practical implications It is expected the vital role of gamma radiation on this dye in its two forms or two media. This reveals their wide applications in the field of gamma irradiation processing. Originality/value These two dosimetry systems which depend upon the same dye are safe to handle, inexpensive, available raw materials and can be applied in various dosimetry applications as mentioned above.

Operationalising resilience in tropical agricultural value chains

2019 ◽  
Vol 24 (2) ◽  
pp. 271-300 ◽  
Author(s):  
Joshua Aboah ◽  
Mark M.J. Wilson ◽  
Karl M. Rich ◽  
Michael C. Lyne
Keyword(s):  
Value Chain ◽  
Food System ◽  
Raw Materials ◽  
Citation Network ◽  
System Level ◽  
Value Chains ◽  
Common Source ◽  
Content Type ◽  
The Individual ◽  
Stakeholder Interactions

Purpose The analysis of the concept of resilience in supply chain management studies mostly focuses on the downstream side of the value chain and tacitly assumes an unlimited supply of raw materials. This assumption is unreasonable for agricultural value chains, as upstream disruptions clearly have a material impact on the availability of raw materials, and indeed, are a common source of supply problems. This paper aims to present a framework for the operationalisation of the concept of socioecological resilience in agricultural value chains that incorporates upstream activities. Design/methodology/approach A citation network analysis was adopted to review articles. A conceptual framework is then advanced to identify elements of resilience and indicators relevant to tropical agricultural value chains. Findings There are limited studies that assess resilience in the food chain context. Flexibility, collaboration, adaptability and resourcefulness are key elements for assessing resilience at the individual chain actor level. However, the paper argues that adaptability is the relevant element for the assessment of resilience at an aggregate food system level because it considers the alteration of a system’s state of resilience. Practical implications The proposed framework and propositions accommodate stakeholder interactions in the value chain and could serve as a tool to guide the assessment of resilience in agricultural value chains. Originality/value This paper is one of the few to extend resilience to cover the socioecological interaction aspects for supply chains that yield the raw materials needed for continuity in channel-wide value creation processes.

Research on waste reduction technologies in Europe

2014 ◽  
Vol 25 (2) ◽  
pp. 216-226 ◽  
Author(s):  
André Martinuzzi ◽  
Francesca Montevecchi
Keyword(s):  
Raw Materials ◽  
Waste Reduction ◽  
Content Type ◽  
Related Research ◽  
Research Fields ◽  
Leading Role ◽  
Management Processes ◽  
Cradle To Cradle ◽  
Environmental Technologies ◽  
Manufacturing Technologies

Purpose – The purpose of this paper is to offer a profound overview of recent research trends and structures in European waste-related research based on the 7th Framework Programme (FP7), the most important RTD programme in Europe. Design/methodology/approach – In order to analyse Europe-wide research efforts on waste technologies, the authors conducted a qualitative and quantitative analysis of 50 FP7-funded research projects to assess which approaches they take, which technologies they develop and which types of organisations play a leading role. Findings – FP7 waste-related projects care for a multiplicity of environmental technologies concerning waste. The most prominent research fields comprise: first, the recovery of by-products and waste into biomass and other valuable products; second, the development of technologies to rework manufacturing discarded products and, therefore, reduce the total use of raw materials; third, the improvement of manufacturing technologies in order to cut down on industrial waste; and finally, the support of the development of recycling management processes. In total, 52 per cent of all the participants are from the industry sector, which therefore plays an essential role. Practical implications – The analysis show that FP7 supports the shift to a cradle-to-cradle society and is partly in line with the aims of the new Flagship Initiative “A resource-efficient Europe”. Originality/value – This analysis gives the possibility to benchmark the trend of waste-related research carried out at European level against priorities set within European directives.

A systematic literature review on green manufacturing concepts in cement industries

2017 ◽  
Vol 34 (1) ◽  
pp. 68-90 ◽  
Author(s):  
Sanjeev Shrivastava ◽  
Shrivastava R.L.
Keyword(s):  
Manufacturing Systems ◽  
Industrial Ecology ◽  
Raw Materials ◽  
Green Manufacturing ◽  
Green Technology ◽  
Cement Industry ◽  
Content Type ◽  
Technical Performance ◽  
Cement Manufacturing ◽  
The Impact

Purpose The purpose of this paper is to survey the technical performance of the cement industry including those related to procedures; groundwork of raw materials, fuels and semi-finished products for processing; accessibility of machinery, plant and equipment for various operations; arrangement and process control management. Design/methodology/approach A broad range of survey and research was reviewed, and all revealed the methods to recognize the key influences for development of green technology. The study explores the present scenario of green manufacturing (GM) strategies of Indian cement companies and provides the industrial ecology, ways of reducing energy consumption, environmental impact data collection, design and control of manufacturing systems and integration of product and manufacturing system. It also reveals the problems in decision-making systems owing to the impact of the green product design. Here, in this paper, all information is obtained by the medium of internet, journals, articles, and magazines. Findings This paper describes a problem of global warming, gas, water and other wastages emissions at the time of cement manufacturing and put forward a path that enables decision makers to assess the perception of GM in their organization and in prioritizing GM efforts. Originality/value This perspective survey is to provide an integrative outlook of performance methods for GM practices in the Indian cement industries. It gives important information, which expectantly will help in cement industry to adopt GM practices. This paper fills the gap in the literature on identification, establishment, and validation of performance measures of GM for Indian cement industries.

scholarly journals Prospects of applying 3-D printing to economics of remote communities

2018 ◽  
Vol 12 (4) ◽  
pp. 488-509 ◽  
Author(s):  
Svetlana Obydenkova ◽  
Nicholas C. Anzalone ◽  
Joshua M. Pearce
Keyword(s):  
Open Source ◽  
Case Studies ◽  
Raw Materials ◽  
Economic Feasibility ◽  
Environmental Benefits ◽  
Remote Communities ◽  
Fused Filament Fabrication ◽  
Content Type ◽  
Climate Conditions ◽  
Reindeer Herder

Purpose Isolated communities face a variety of inconveniences including severe remoteness, poor roads and extreme climate conditions, resulting in the lack of security of supply chains and exorbitant prices for cargo delivery. This paper aims to investigate the present advantages and prospects of applying 3-D printing to improve economics and everyday life of remote communities, reindeer herder case taken as an example. Design/methodology/approach This study covers the use of a low-cost open-source 3-D printer (RepRap) capable of fused filament fabrication to reduce operating costs for nomadic reindeer herder groups. Three case studies are provided for reindeer-specific applications to probe economic and technical viability of the technology, namely, ear-tags, electric fence components and lasso accessories. Findings 3-D printed objects feature technical characteristics similar to those of analogues available on the market while reducing the price by 63 per cent. Distributed 3-D printing reduces the cost of raw materials by 68 per cent and shipping costs by 50 because of lower trip frequency. If all reindeer herders globally were to adopt distributed manufacturing of the three aforementioned sample items only, their annual savings from such solution would amount to US$2m. The paper discovers other economic, entrepreneurial, technical and environmental opportunities offered by 3-D printing put to service the needs of remote communities. Research limitations As the paper is the first-ever study of 3-D printing potential applied to the reindeer husbandry case, it is based on a more thorough analysis of the techno-economic feasibility of the technology, while cultural and entrepreneurial factors have been discussed as preconditions only. Practical implications The paper might serve as a valuable source of information for entrepreneurs, as well as for students and academics for further case studies in this area. Originality/value In remote conditions, 3-D printing offers a more sustainable way of good manufacturing. Numerous open source designs already available for specialists, financial effectiveness, environmental benefits and vast opportunities for entrepreneurs are among the most promising advantages of the technology.

scholarly journals Burden or blessing in disguise: interactions in supply chain complexity

2018 ◽  
Vol 38 (2) ◽  
pp. 314-332 ◽  
Author(s):  
Hendryk Dittfeld ◽  
Kirstin Scholten ◽  
Dirk Pieter Van Donk
Keyword(s):  
Supply Chain ◽  
Food Processing ◽  
Raw Materials ◽  
Structured Interviews ◽  
Food Processing Industry ◽  
Dynamic Complexity ◽  
Processing Industry ◽  
Case Study Methodology ◽  
Content Type ◽  
Different Types

Purpose While systems theory explicitly considers interactions as part of a system’s complexity, supply chain complexity (SCC) is mostly conceptualized and measured as a linear summation of several aspects. The purpose of this paper is to challenge the general understanding by explicitly investigating interactions between and across different types (detail and dynamic) and levels (plant, supply chain, environment) of SCC. Design/methodology/approach An exploratory multiple case study methodology is adopted drawing on in-depth semi-structured interviews with respondents from eight manufacturing plants in the food processing industry. Findings On the one hand, it is found that different types add and increase overall SCC. On the other hand, the study also shows the opposite: interactions between detail and dynamic complexity can reduce the overall SCC experienced. Additionally, the findings highlight the specific food processing characteristics such as the variability of quality and quantity of raw materials that underlie interactions between types and levels of SCC. Originality/value This study adds to theory by empirically showing that interactions across and between types and levels do not automatically increase, but might also reduce SCC. As such, the findings contribute new detail to the concept of SCC: aspects of complexity do not necessarily add up linearly. Additionally, this study is one of the first to demonstrate how specific contextual aspects from the food processing industry relate to SCC.

Germinating seeds in dry soil: examining the process of frugal innovation in micro- and small-enterprises at the base of the pyramid

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Miriam Borchardt ◽  
Charbel José Chiappetta Jabbour ◽  
José de Figueiredo Belém ◽  
Venkatesh Mani ◽  
Giancarlo Medeiros Pereira ◽  
...  
Keyword(s):  
Business Models ◽  
Raw Materials ◽  
Life Cycles ◽  
Small Enterprises ◽  
Base Of The Pyramid ◽  
Frugal Innovation ◽  
Content Type ◽  
Fashion Products ◽  
Poor Region ◽  
Micro And Small Enterprises

Purpose This study aims to examine the process of frugal innovation (FI) in micro- and small-enterprises (MSEs) at the base of the pyramid (BOP) through the analytical lens of business models. Design/methodology/approach A case study was conducted with 30 MSEs from three different industries in a very poor region in Brazil. Findings The findings indicate that, in cases where FI is intense and dynamic, the start of the FI process is based on the reinterpretation of fashion trends and influences from the business ecosystem while the consolidation of FI in MSEs occurs through the reconfiguration of resources. Additionally, this study shows that FI depends on conditions other than the production of frugal products for BOP consumers. Research limitations/implications This study points out that the presence of end-of-life non-BOP raw materials distributed by large distributors in the case of fashion products, along with the interaction between MSEs at the BOP and these distributors, trigger FI and are profitable for both. For non-fashion products with long life cycles, there is no demand for innovation. Originality/value This study addresses the research void present in the literature on FI by presenting the process of FI and the conditions that leverage or stagnate FI in MSEs at the BOP, as well as how business models are shaped by these conditions.

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