Toward Decarbonized Power Generation With Gas Turbines by Using Sequential Combustion for Burning Hydrogen

Author(s):  
Mirko R. Bothien ◽  
Andrea Ciani ◽  
John P. Wood ◽  
Gerhard Fruechtel

Abstract Excess energy generation from renewables can be conveniently stored as hydrogen for later use as a gas turbine fuel. Also, the strategy to sequestrate CO2 from natural gas (NG) will require gas turbines to run with hydrogen-based fuels. In such scenarios, high temperature low emission combustion of hydrogen is a key requirement for the future gas turbine market. Ansaldo Energia's gas turbines featuring sequential combustion have an intrinsic advantage when it comes to fuel flexibility and in particular hydrogen-based fuels. The sequential combustion system is composed of two complementary combustion stages in series: one premix stage followed by an auto-ignited second stage overcoming the limits of traditional premix combustion systems through a highly effective extra tuning parameter, i.e., the temperature between the first and the second stage. The standard constant pressure sequential combustion (CPSC) system as applied in the GT36 engine is tested, at high pressure, demonstrating that a modified operation concept allows stable combustion with no changes in combustor hardware for the whole range of NG and hydrogen blends. It is shown that in the range from 0% to 70% (vol.) hydrogen, stable combustion is achieved at full nominal exit temperature, i.e., without any derating and thus clearly outperforming other available conventional premixed combustors. Operation between 70% and 100% is possible as well and only requires a mild reduction of the combustor exit temperature. By proving the transferability of the single-can high pressure results to the engine, this paper demonstrates the practicality of operating the Ansaldo Energia GT36 H-Class gas turbine on fuels containing unprecedented concentrations of hydrogen while maintaining excellent performance and low emissions both in terms of NOx and CO2.

Author(s):  
Mirko R. Bothien ◽  
Andrea Ciani ◽  
John P. Wood ◽  
Gerhard Fruechtel

Abstract Excess energy generation from renewables can be conveniently stored as hydrogen for later use as a gas turbine fuel. Also, the strategy to sequestrate CO2 from natural gas will require gas turbines to run with hydrogen-based fuels. In such scenarios, high temperature low emission combustion of hydrogen is a key requirement for the future gas turbine market. Ansaldo Energia’s gas turbines featuring sequential combustion have an intrinsic advantage when it comes to fuel flexibility and in particular hydrogen-based fuels. The sequential combustion system is composed of two complementary combustion stages in series: one premix stage followed by an auto-ignited second stage overcoming the limits of traditional premix combustion systems through a highly effective extra tuning parameter, i.e. the temperature between the first and the second stage. The standard Constant Pressure Sequential Combustion (CPSC) system as applied in the GT36 engine is tested, at high pressure, demonstrating that a modified operation concept allows stable combustion with no changes in combustor hardware for the whole range of natural gas and hydrogen blends. It is shown that in the range from 0% to 70% (vol.) hydrogen, stable combustion is achieved at full nominal exit temperature, i.e. without any derating and thus clearly outperforming other available conventional premixed combustors. Operation between 70% and 100% is possible as well and only requires a mild reduction of the combustor exit temperature. By proving the transferability of the single-can high pressure results to the engine, this paper demonstrates the practicality of operating the Ansaldo Energia GT36 H-Class gas turbine on fuels containing unprecedented concentrations of hydrogen while maintaining excellent performance and low emissions both in terms of NOx and CO2.


Author(s):  
Daniel Guyot ◽  
Gabrielle Tea ◽  
Christoph Appel

Reducing gas turbine emissions and increasing their operational flexibility are key targets in today’s gas turbine market. In order to further reduce emissions and increase the operational flexibility of its GT24 (60Hz) and GT26 (50Hz), Alstom has introduced an improved SEV burner and fuel lance into its GT24 upgrade 2011 and GT26 upgrade 2011 sequential reheat combustion system. Sequential combustion is a key differentiator of Alstom GT24 engines in the F-class gas turbine market. The inlet temperature for the GT24 SEV combustor is around 1000 degC and reaction of the fuel/oxidant mixture is initiated through auto-ignition. The recent development of the Alstom sequential combustion system is a perfect example of evolutionary design optimizations and technology transfer between Alstom GT24 and GT26 engines. Better overall performance is achieved through improved SEV burner aerodynamics and fuel injection, while keeping the main features of the sequential burner technology. The improved SEV burner/lance concept has been optimized towards rapid fuel/oxidant mixing for low emissions, improved fuel flexibility with regards to highly reactive fuels (higher C2+ and hydrogen content), and to sustain a wide operation window. In addition, the burner front panel features an improved cooling concept based on near-wall cooling as well as integrated acoustics damping devices designed to reduce combustion pulsations thus extending the SEV combustor’s operation window even further. After having been validated extensively in the Alstom high pressure sector rig test facility, the improved GT24 SEV burner has been retrofitted into a commercial GT24 field engine for full engine validation during long-term operation. This paper presents the obtained high pressure sector rig and engine validation results for the GT24 (2011) SEV burner/lance hardware with a focus on reduced NOX and CO emissions and improved operational behavior of the SEV combustor. The high pressure tests demonstrated robust SEV burner/lance operation with up to 50% lower NOX formation and a more than 70K higher SEV burner inlet temperature compared to the GT24 (2006) hardware. For the GT24 engine with retrofitted upgrade 2011 SEV burner/lance all validation targets were achieved including an extremely robust operation behavior, up to 40% lower GT NOX emissions, significantly lower CO emissions at partload and baseload, a very broad operation window (up to 100K width in SEV combustor inlet temperature) and all measured SEV burner/lance temperatures in the expected range. Sector rig and engine validation results have confirmed the expected SEV burner fuel flexibility (up to 18%-vol. C2+ and up to 5%-vol. hydrogen as standard).


Author(s):  
Wolfgang Kappis ◽  
Stefan Florjancic ◽  
Uwe Ruedel

Market requirements for the heavy duty gas turbine power generation business have significantly changed over the last few years. With high gas prices in former times, all users have been mainly focusing on efficiency in addition to overall life cycle costs. Today individual countries see different requirements, which is easily explainable picking three typical trends. In the United States, with the exploitation of shale gas, gas prices are at a very low level. Hence, many gas turbines are used as base load engines, i.e. nearly constant loads for extended times. For these engines reliability is of main importance and efficiency somewhat less. In Japan gas prices are extremely high, and therefore the need for efficiency is significantly higher. Due to the challenge to partly replace nuclear plants, these engines as well are mainly intended for base load operation. In Europe, with the mid and long term carbon reduction strategy, heavy duty gas turbines is mainly used to compensate for intermittent renewable power generation. As a consequence, very high cyclic operation including fast and reliable start-up, very high loading gradients, including frequency response, and extended minimum and maximum operating ranges are required. Additionally, there are other features that are frequently requested. Fuel flexibility is a major demand, reaching from fuels of lower purity, i.e. with higher carbon (C2+), content up to possible combustion of gases generated by electrolysis (H2). Lifecycle optimization, as another important request, relies on new technologies for reconditioning, lifetime monitoring, and improved lifetime prediction methods. Out of Alstom’s recent research and development activities the following items are specifically addressed in this paper. Thermodynamic engine modelling and associated tasks are discussed, as well as the improvement and introduction of new operating concepts. Furthermore extended applications of design methodologies are shown. An additional focus is set ono improve emission behaviour understanding and increased fuel flexibility. Finally, some applications of the new technologies in Alstom products are given, indicating the focus on market requirements and customer care.


Author(s):  
Douglas A. Pennell ◽  
Mirko R. Bothien ◽  
Andrea Ciani ◽  
Victor Granet ◽  
Ghislain Singla ◽  
...  

This paper introduces and presents validation of the Constant Pressure Sequential Combustion system (denoted CPSC), a second generation concept developed for and applied to the new Ansaldo GT36 H-class gas turbine combustors. It has evolved from the well-established sequential burner technology applied to all current GT26 and GT24 gas turbines, and contains all architectural improvements implemented since original inception of this engine frame in 1994, with beneficial effects on the operation turndown, fuel flexibility, on the overall system robustness, and featuring the required aspects to stay competitive in the present day energy market. The applied air and fuel management therefore facilitate emission and dynamics control at both the extremely high and low firing temperature ranges required for existing and future Ansaldo gas turbine engine classes.


Author(s):  
W. S. Cheung ◽  
G. J. M. Sims ◽  
R. W. Copplestone ◽  
J. R. Tilston ◽  
C. W. Wilson ◽  
...  

Lean premixed prevaporised (LPP) combustion can reduce NOx emissions from gas turbines, but often leads to combustion instability. A flame transfer function describes the change in the rate of heat release in response to perturbations in the inlet flow as a function of frequency. It is a quantitative assessment of the susceptibility of combustion to disturbances. The resulting fluctuations will in turn generate more acoustic waves and in some situations self-sustained oscillations can result. Flame transfer functions for LPP combustion are poorly understood at present but are crucial for predicting combustion oscillations. This paper describes an experiment designed to measure the flame transfer function of a simple combustor incorporating realistic components. Tests were conducted initially on this combustor at atmospheric pressure (1.2 bar and 550 K) to make an early demonstration of the combustion system. The test rig consisted of a plenum chamber with an inline siren, followed by a single LPP premixer/duct and a combustion chamber with a silencer to prevent natural instabilities. The siren was used to induce variable frequency pressure/acoustic signals into the air approaching the combustor. Both unsteady pressure and heat release measurements were undertaken. There was good coherence between the pressure and heat release signals. At each test frequency, two unsteady pressure measurements in the plenum were used to calculate the acoustic waves in this chamber and hence estimate the mass-flow perturbation at the fuel injection point inside the LPP duct. The flame transfer function relating the heat release perturbation to this mass flow was found as a function of frequency. The same combustor hardware and associated instrumentation were then used for the high pressure (15 bar and 800 K) tests. Flame transfer function measurements were taken at three combustion conditions that simulated the staging point conditions (Idle, Approach and Take-off) of a large turbofan gas turbine. There was good coherence between pressure and heat release signals at Idle, indicating a close relationship between acoustic and heat release processes. Problems were encountered at high frequencies for the Approach and Take-off conditions, but the flame transfer function for the Idle case had very good qualitative agreement with the atmospheric-pressure tests. The flame transfer functions calculated here could be used directly for predicting combustion oscillations in gas turbine using the same LPP duct at the same operating conditions. More importantly they can guide work to produce a general analytical model.


2021 ◽  
Author(s):  
Takashi Nishiumi ◽  
Hirofumi Ohara ◽  
Kotaro Miyauchi ◽  
Sosuke Nakamura ◽  
Toshishige Ai ◽  
...  

Abstract In recent years, MHPS achieved a NET M501J gas turbine combined cycle (GTCC) efficiency in excess of 62% operating at 1,600°C, while maintaining NOx under 25ppm. Taking advantage of our gas turbine combustion design, development and operational experience, retrofits of earlier generation gas turbines have been successfully applied and will be described in this paper. One example of the latest J-Series technologies, a conventional pilot nozzle was changed to a premix type pilot nozzle for low emission. The technology was retrofitted to the existing F-Series gas turbines, which resulted in emission rates of lower than 9ppm NOx(15%O2) while maintaining the same Turbine Inlet Temperature (TIT: Average Gas Temperature at the exit of the transition piece). After performing retrofitting design, high pressure rig tests, the field test prior to commercial operation was conducted on January 2019. This paper describes the Ultra-Low NOx combustor design features, retrofit design, high pressure rig test and verification test results of the upgraded M501F gas turbine. In addition, it describes another upgrade of turbine to improve efficiency and of combustion control system to achieve low emissions. Furthermore it describes the trouble-free upgrade of seven (7) units, which was completed by utilizing MHPS integration capabilities, including handling all the design, construction and service work of the main equipment, plant and control systems.


Author(s):  
Katsuyoshi Tada ◽  
Kei Inoue ◽  
Tomo Kawakami ◽  
Keijiro Saitoh ◽  
Satoshi Tanimura

Gas-turbine combined-cycle (GTCC) power generation is clean and efficient, and its demand will increase in the future from economic and social perspectives. Raising turbine inlet temperature is an effective way to increase combined cycle efficiency and contributes to global environmental conservation by reducing CO2 emissions and preventing global warming. However, increasing turbine inlet temperature can lead to the increase of NOx emissions, depletion of the ozone layer and generation of photochemical smog. To deal with this issue, MHPS (MITSUBISHI HITACHI POWER SYSTEMS) and MHI (MITSUBISHI HEAVY INDUSTRIES) have developed Dry Low NOx (DLN) combustion techniques for high temperature gas turbines. In addition, fuel flexibility is one of the most important features for DLN combustors to meet the requirement of the gas turbine market. MHPS and MHI have demonstrated DLN combustor fuel flexibility with natural gas (NG) fuels that have a large Wobbe Index variation, a Hydrogen-NG mixture, and crude oils.


Author(s):  
H. C. Eatock ◽  
M. D. Stoten

United Aircraft Corporation studied the potential costs of various possible gas turbine engines which might be used to reduce automobile exhaust emissions. As part of that study, United Aircraft of Canada undertook the preliminary design and performance analysis of high-pressure-ratio nonregenerated (simple cycle) gas turbine engines. For the first time, high levels of single-stage component efficiency are available extending from a pressure ratio less than 4 up to 10 or 12 to 1. As a result, the study showed that the simple-cycle engine may provide satisfactory running costs with significantly lower manufacturing costs and NOx emissions than a regenerated engine. In this paper some features of the preliminary design of both single-shaft and a free power turbine version of this engine are examined. The major component technology assumptions, in particular the high pressure ratio centrifugal compressor, employed for performance extrapolation are explained and compared with current technology. The potential low NOx emissions of the simple-cycle gas turbine compared to regenerative or recuperative gas turbines is discussed. Finally, some of the problems which might be encountered in using this totally different power plant for the conventional automobile are identified.


Author(s):  
Sepehr Sanaye ◽  
Salahadin Hosseini

A novel procedure for finding the optimum values of design parameters of industrial twin-shaft gas turbines at various ambient temperatures is presented here. This paper focuses on being off design due to various ambient temperatures. The gas turbine modeling is performed by applying compressor and turbine characteristic maps and using thermodynamic matching method. The gas turbine power output is selected as an objective function in optimization procedure with genetic algorithm. Design parameters are compressor inlet guide vane angle, turbine exit temperature, and power turbine inlet nozzle guide vane angle. The novel constrains in optimization are compressor surge margin and turbine blade life cycle. A trained neural network is used for life cycle estimation of high pressure (gas generator) turbine blades. Results for optimum values for nozzle guide vane/inlet guide vane (23°/27°–27°/6°) in ambient temperature range of 25–45 ℃ provided higher net power output (3–4.3%) and more secured compressor surge margin in comparison with that for gas turbines control by turbine exit temperature. Gas turbines thermal efficiency also increased from 0.09 to 0.34% (while the gas generator turbine first rotor blade creep life cycle was kept almost constant about 40,000 h). Meanwhile, the averaged values for turbine exit temperature/turbine inlet temperature changed from 831.2/1475 to 823/1471°K, respectively, which shows about 1% decrease in turbine exit temperature and 0.3% decrease in turbine inlet temperature.


Author(s):  
Y. Wang ◽  
L. Reh ◽  
D. Pennell ◽  
D. Winkler ◽  
K. Döbbeling

Stationary gas turbines for power generation are increasingly being equipped with low emission burners. By applying lean premixed combustion techniques for gaseous fuels both NOx and CO emissions can be reduced to extremely low levels (NOx emissions <25vppm, CO emissions <10vppm). Likewise, if analogous premix techniques can be applied to liquid fuels (diesel oil, Oil No.2, etc.) in gas-fired burners, similar low level emissions when burning oils are possible. For gas turbines which operate with liquid fuel or in dual fuel operation, VPL (Vaporised Premixed Lean)-combustion is essential for obtaining minimal NOx-emissions. An option is to vaporise the liquid fuel in a separate fuel vaporiser and subsequently supply the fuel vapour to the natural gas fuel injection system; this has not been investigated for gas turbine combustion in the past. This paper presents experimental results of atmospheric and high-pressure combustion tests using research premix burners running on vaporised liquid fuel. The following processes were investigated: • evaporation and partial decomposition of the liquid fuel (Oil No.2); • utilisation of low pressure exhaust gases to externally heat the high pressure fuel vaporiser; • operation of ABB premix-burners (EV burners) with vaporised Oil No.2; • combustion characteristics at pressures up to 25bar. Atmospheric VPL-combustion tests using Oil No.2 in ABB EV-burners under simulated gas turbine conditions have successfully produced emissions of NOx below 20vppm and of CO below 10vppm (corrected to 15% O2). 5vppm of these NOx values result from fuel bound nitrogen. Little dependence of these emissions on combustion pressure bas been observed. The techniques employed also ensured combustion with a stable non luminous (blue) flame during transition from gaseous to vaporised fuel. Additionally, no soot accumulation was detectable during combustion.


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