Development of Porous Injection Technology to Reduce Emissions for Dry Low NOx Combustors: Micromixer and Swirl Injectors

Author(s):  
Umesh Bhayaraju ◽  
Mahmoud Hamza ◽  
San-Mou Jeng

The Combustion and Fire Research Laboratory (CFRL) at the University of Cincinnati (UC) is working on the development of advanced next generation injectors for DLN combustors. Several inputs were received from the project partners during the development phase. In the present paper, developmental work on two novel injectors with Porous Injection Technology (PIT) is presented. The technology has the potential to reduce NOx emissions to single digit PPM level with a stable combustion across wide range of load conditions. One of the key factors that are essential for lowering NOx levels is the efficient mixing of fuel-air in both spatial and temporal domains. The porous injection technology has the potential to reduce the spatial and temporal gradients to a minimum. In the present paper, two measurement techniques were used to evaluate the fuel-air mixing under atmospheric conditions. The CO2 mixing technique was used to quantify the spatial variations in the fuel mass fraction. Planar Laser Induced Fluorescence (PLIF) was used to obtain both spatial and temporal fuel mass fractions. The CO2 mixing measurements were used to validate the PLIF data for quantification. The RMS fluctuations in spatial and temporal domains were quantified from PLIF data. The combustion experiments were carried out at atmospheric pressure with a preheated temperature of air of 500–650 K and equivalence ratio of 0.5–0.8. The pressure drop across the injector was 4%. Natural gas with 90% methane and 9% ethane was used as fuel. The results show a stable flame for both injectors without combustion instabilities. Both injectors show low NOx levels. For conventional swirl stabilized design with PIT, the NOx levels were of the order of 1.5 ppm at the firing temperature of 1866 K whereas for the novel micromixer design, the NOx levels were of the order of 4 ppm @ ∼1866 K.

Author(s):  
Wessam Estefanos ◽  
Mahmoud Hamza ◽  
Umesh Bhayaraju ◽  
San-Mou Jeng

In the present study, two measurement techniques are adopted to evaluate the fuel–air mixing under atmospheric conditions using an industrial fuel–air premixer. These techniques are CO2 mixing and planar laser induced fluorescence (PLIF) in water. In these techniques, CO2 and fluorescent dye are injected as fuel simulants. CO2 measurements are used to validate PLIF in water. In the CO2 technique, CO2 concentrations are converted to fuel mass fractions, whereas in the PLIF technique, a modified post processing method is used to convert the LIF signal into fuel mass fraction. The experiments are conducted at the same Reynolds number and momentum flux ratio for two injection strategies. To study the effect of the flow aerodynamics on the mixing results, high-speed particle image velocimetry (PIV) measurements are conducted in water at the same Reynolds number. A comparison of fuel concentrations measured with the CO2 and PLIF techniques shows good quantitative agreement at all momentum flux ratios. However, deviations between the two techniques are observed at locations of high fuel concentration gradients. The unsteady mixing is evaluated using the PLIF technique with high temporal resolution. Analysis of PIV and PLIF data shows that unsteady mixing is lower at regions of high fluctuations in velocity. Moreover, it is found that there is high unsteady mixing at locations of high concentration gradient.


Energies ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 348 ◽  
Author(s):  
Rafał Ślefarski

The article presents the results of experimental and numerical investigation of turbulent premixed methane flames diluted by carbon dioxide (up to 30%) at atmospheric and elevated pressures (up to 0.5 MPa). The study included the influence of fuel properties and operation parameters on the emission of NOx and CO as well as flame properties. The investigation has been prepared for two combustion system configurations (axisymmetric flames and flames supported by a pilot flame) in a wide range of air/fuel equivalence ratios (ϕ = 0.42 ÷ 0.85). It has been reported that reduction of NOx emission by CO2 fuel dilution reached a level of up to 45% in atmospheric conditions and 30% at elevated pressure, decreasing with a drop in the equivalence ratio. The results have shown influence of pressure on NOx composition, where for pressurized tests, NO2 was doubled compared to atmospheric tests. Carbon monoxide emission rises with CO2 content in the fuel as a result of thermal dissociation, but this phenomenon is mitigated by a pressure increase. Planar laser induced fluorescence (PLIF) study has shown that flame length decreases with an increase in pressure and CO2 content in the fuel. Fuel staging increased NOx emission, especially for richer flames (ϕ > 0.6) at low pressure, while CO increased in the whole range of equivalence ratios.


Author(s):  
Wessam Estefanos ◽  
Umesh Bhayaraju ◽  
Mahmoud Hamza ◽  
San-Mou Jeng

In the present study, two measurement techniques are adopted to evaluate the fuel-air mixing under atmospheric conditions using an industrial fuel-air pre-mixer. These techniques are CO2 mixing and Planar Laser Induced Fluorescence (PLIF) in water. In these techniques, CO2 and fluorescent dye are injected as fuel simulants. CO2 measurements are used to validate PLIF in water. In the CO2 technique, CO2 concentrations are converted to fuel mass fractions whereas, in the PLIF technique, a modified post processing method is used to convert the LIF signal into fuel mass fraction. The experiments are conducted at the same Reynolds number and momentum flux ratio for two injection strategies. To study the effect of the flow aerodynamics on the mixing results, high speed PIV measurements are conducted in water at the same Reynolds number. A comparison of fuel concentrations measured with the CO2 and PLIF techniques shows good quantitative agreement at all momentum flux ratios. However, deviations between the two techniques are observed at high fuel concentration gradients. The unsteady mixing is evaluated using PLIF technique with high temporal resolution. Analysis of PIV and PLIF data shows that unsteady mixing is lower at regions of high fluctuations in velocity. Moreover, it is found that there is high unsteady mixing at locations where there is high concentration gradient.


2019 ◽  
Vol 92 ◽  
pp. 01005
Author(s):  
Georgios Birmpilis ◽  
Reza Ahmadi-Naghadeh ◽  
Jelke Dijkstra

X-ray scattering is a promising non-invasive technique to study evolving nano- and micromechanics in clays. This study discusses the experimental considerations and a successful method to enable X-ray scattering to study clay samples at two extreme stages of consolidation. It is shown that the proposed sample environment comprising flat capillaries with a hydrophobic coating can be used for a wide range of voids ratios ranging from a clay suspension to consolidated clay samples, that are cut from larger specimens of reconstituted or natural clay. The initial X-ray scattering results using a laboratory instrument indicate that valuable information on, in principal evolving, clay fabric can be measured. Features such as characteristic distance between structural units and particle orientations are obtained for a slurry and a consolidated sample of kaolinite. Combined with other promising measurement techniques from Materials Science the proposed method will help advance the contemporary understanding on the behaviour of dense colloidal systems of clay, as it does not require detrimental sample preparation


Author(s):  
Bogdan Solnica ◽  
Jan Skupien ◽  
Beata Kusnierz-Cabala ◽  
Krystyna Slowinska-Solnica ◽  
Przemyslaw Witek ◽  
...  

AbstractThe aim of the study was to evaluate the effect of hematocrit (HCT) on glucose meter assays based on different measurement techniques.This paper studied glucose meters utilizing the glucose dehydrogenase reaction and four measurement techniques: colorimetry (HemoCue), reflectometry (Accu-Chek Active), amperometry (Optium Xido) and coulometry (Optium Omega). The EDTA venous blood samples HCT were modified by adding or removing defined aliquots of plasma. Glucose concentration was measured using each meter in 27 batches of blood samples, with HCT ranging from 20% to 60% in 10% increments. The data were analyzed using repeated measures models and a linear random effects model.A significant relationship between HCT and glucose reading in all meters was found and, for all meters except Optium Xido, there was a significant modification of this relationship by glucose level. The relative decrease in glucose concentration per 1% increase of the HCT value varied from 0.30% for Optium Omega in samples with glucose concentrations <5.55 mmol/L to 1.37% for Optium Xido in the same stratum (p<0.0001). The 5% glucose meter error (the ADA recommendation) was reached in the <5.55 mmol/L stratum after HCT change by 3.9%–16.7%.There is a significant continuous effect of HCT on measurement accuracy of glucose meters across its wide range of values and glucose concentrations. The most sensitive to the HCT interference was the system utilizing amperometric technique (Optium Xido) followed by the one with reflectometric technique (Accu-Chek Active), while the systems with the coulometric technique (Optium Omega) or colorimetric measurements in whole blood haemolysate (HemoCue) were less sensitive.


Author(s):  
Dominik Ebi ◽  
Peter Jansohn

Abstract Operating stationary gas turbines on hydrogen-rich fuels offers a pathway to significantly reduce greenhouse gas emissions in the power generation sector. A key challenge in the design of lean-premixed burners, which are flexible in terms of the amount of hydrogen in the fuel across a wide range and still adhere to the required emissions levels, is to prevent flame flashback. However, systematic investigations on flashback at gas turbine relevant conditions to support combustor development are sparse. The current work addresses the need for an improved understanding with an experimental study on boundary layer flashback in a generic swirl burner up to 7.5 bar and 300° C preheat temperature. Methane-hydrogen-air flames with 50 to 85% hydrogen by volume were investigated. High-speed imaging was applied to reveal the flame propagation pathway during flashback events. Flashback limits are reported in terms of the equivalence ratio for a given pressure, preheat temperature, bulk flow velocity and hydrogen content. The wall temperature of the center body along which the flame propagated during flashback events has been controlled by an oil heating/cooling system. This way, the effect any of the control parameters, e.g. pressure, had on the flashback limit was de-coupled from the otherwise inherently associated change in heat load on the wall and thus change in wall temperature. The results show that the preheat temperature has a weaker effect on the flashback propensity than expected. Increasing the pressure from atmospheric conditions to 2.5 bar strongly increases the flashback risk, but hardly affects the flashback limit beyond 2.5 bar.


2021 ◽  
Author(s):  
James Harding

&lt;p&gt;Earth Observation (EO) satellites are drawing considerable attention in areas of water resource management, given their potential to provide unprecedented information on the condition of aquatic ecosystems. Despite ocean colours long history; water quality parameter retrievals from shallow and inland waters remains a complex undertaking. Consistent, cross-mission retrievals of the primary optical parameters using state-of-the-art algorithms are limited by the added optical complexity of these waters. Less work has acknowledged their non- or weakly optical parameter counterparts. These can be more informative than their vivid counterparts, their potential covariance would be regionally specific. Here, we introduce a multi-input, multi-output Mixture Density Network (MDN), that largely outperforms existing algorithms when applied across different bio-optical regimes in shallow and inland water bodies. The model is trained and validated using a sizeable historical database in excess of 1,000,000 samples across 38 optical and non-optical parameters, spanning 20 years across 500 surface waters in Scotland. The single network learns to predict concurrently Chlorophyll-a, Colour, Turbidity, pH, Calcium, Total Phosphorous, Total Organic Carbon, Temperature, Dissolved Oxygen and Suspended Solids from real Landsat 7, Landsat 8, and Sentinel 2 spectra. The MDN is found to fully preserve the covariances of the optical and non-optical parameters, while known one-to-many mappings within the non-optical parameters are retained. Initial performance evaluations suggest significant improvements in Chl-a retrievals from existing state-of-the-art algorithms. MDNs characteristically provide a means of quantifying the noise variance around a prediction for a given input, now pertaining to real data under a wide range of atmospheric conditions. We find this to be informative for example in detecting outlier pixels such as clouds, and may similarly be used to guide or inform future work in academic or industrial contexts.&amp;#160;&lt;/p&gt;


2021 ◽  
pp. 54-59
Author(s):  
Md. Mahidy Hossain ◽  
Nadim Khandaker

In every aspect of Engineering more advanced, efficient and progressive solutions are required. The modern age of science requires innovative minds. The field of environmental engineering is also advancing with modern science and technology innovations. Measuring of methane concentration and flow rate is nothing new, yet a complicated process. The need for more accurate measurement is a necessity in proper operation of bio digesters for methane generation. The traditional process of the measuring methane content in biogas is time consuming yet complicated. The need for development and application of methane measurement techniques is not only limited to biogas but has other monitoring value as well in other health and safety applications in built environments. Winsen Electronics and Hanwei Electronics are two of the leading sensor-manufactures of China who are providing a wide range of gas detecting sensors that are locally available in Bangladesh and yet has not been applied to methane content measurement in biogas operations. In This paper we are reporting on the application of a purpose-built propane, butane detector for methane gas detection within the range of accuracy for it to be applied in methane detection in a biogas stream. This paper, reports on application and calibration of the methane detecting sensor MQ-4 with promising result. Based on the study we postulate that the sensor can be used to detect methane for an on-line monitoring of many environmental, industrial purposes such as bio digesters, integrated waste management facility. The cost of fabrication of the sensor system is only $18 making it a viable sensor with respect to cost for application in Bangladesh.


2021 ◽  
Author(s):  
Brian J. Carroll ◽  
Amin R. Nehrir ◽  
Susan Kooi ◽  
James Collins ◽  
Rory A. Barton-Grimley ◽  
...  

Abstract. Airborne differential absorption lidar (DIAL) offers a uniquely capable solution to the problem of measuring water vapor (WV) with high precision, accuracy, and resolution throughout the troposphere and lower stratosphere. The High Altitude Lidar Observatory (HALO) airborne WV DIAL was recently developed at NASA Langley Research Center and was first deployed in 2019. It uses four wavelengths at 935 nm to achieve sensitivity over a wide dynamic range, and simultaneously employs 1064 nm backscatter and 532 nm high spectral resolution lidar (HSRL) measurements for aerosol and cloud profiling. A key component of the WV retrieval framework is flexibly trading resolution for precision to achieve optimal data sets for scientific objectives across scales. A technique for retrieving WV in the lowest few hundred meters of the atmosphere using the strong surface return signal is also presented. The five maiden flights of the HALO WV DIAL spanned the tropics through midlatitudes with a wide range of atmospheric conditions, but opportunities for validation were sparse. Comparisons to dropsonde WV profiles were qualitatively in good agreement, though statistical analysis was impossible due to systematic error in the dropsonde measurements. Comparison of HALO to in situ WV measurements onboard the aircraft showed no substantial bias across three orders of magnitude, despite variance (R2 = 0.66) that may be largely attributed to spatiotemporal variability. Precipitable water vapor measurements from the spaceborne sounders AIRS and IASI compared very well to HALO with R2 > 0.96 over ocean and R2 = 0.86 over land.


2021 ◽  
Author(s):  
◽  
Daniel P. Lowry

<p>Reconstructing past grounding-line evolution can help inform future sea level projections by constraining marine ice sheet sensitivities to changes in climate. The Ross Embayment, the largest sector of Antarctica, experienced substantial grounding-line retreat since the Last Glacial Maximum. However, different interpretations for the timing and spatial pattern of deglacial grounding-line retreat in this region persist, suggesting either very high or low sensitivity to external forcings. Complicating matters is the sparse paleoclimate record, which is limited spatially and temporally. In this thesis, I address these issues by analysing the output of two transient climate simulations in relation to Antarctic ice core and marine sediment records, and performing and analysing the largest ensemble to date of regional ice sheet model simulations of the last deglaciation in the Ross Sea. The climate models and paleoclimate proxy records exhibit key differences in the timing, magnitude and duration of millennial-scale climate change events through the deglacial period. Using this diverse set of deglacial climate trajectories as ocean and atmosphere forcings, the ice sheet model ensemble produces a wide range of ice sheet responses, supporting the view that external forcings are the main drivers of past grounding-line retreat in the region. The simulations demonstrate that atmospheric conditions early in the deglacial period can enhance or diminish ice sheet sensitivity to rising ocean temperatures, thereby controlling the initial timing and spatial pattern of grounding-line retreat. Through the Holocene, grounding-line position is more sensitive to sub-shelf melt rates as the ocean cavity below the ice shelf expands. Model parameters that control the physical properties of the bed, deformation of the continental shelf, and rheological properties of the ice strongly influence the sensitivity of ice sheets to external forcing. Basin-wide differences in these forcings, driven by oceanic and atmospheric circulation, and spatial heterogeneity of bed properties likely contribute to the asynchronous pattern of retreat in the eastern and western parts of the embayment, as indicated by marine and terrestrial proxy records.</p>


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