Oxy-Fuel Combustor Injector

2021 ◽  
Author(s):  
Shahrokh Etemad ◽  
Benjamin D. Baird ◽  
Sandeep Alavandi
Keyword(s):  
Natural Gas ◽  
Atmospheric Pressure ◽  
Stable Operation ◽  
Low Oxygen ◽  
High Dilution ◽  
Test Conditions ◽  
Wide Range ◽  
Cycle Efficiency ◽  
Oxygen Fuel ◽  
Validation Testing

Abstract Oxygen-fuel-diluent mixing is important for oxy-combustion as it impacts emissions, efficiency (oxygen slippage) and pattern factor. In this work, rapid mixing validation testing was conducted. Combustion testing was performed with natural gas and syngas from atmospheric pressure (1 atm.) to high pressure (10 atm.) to demonstrate stable operation. Oxy-natural gas testing demonstrated stable operation and low CO emissions over a wide range of test conditions. Syngas testing showed low CO emissions and a wider operability range with high dilution/low oxygen levels. Complete oxygen burnout was accomplished, indicating no oxygen slippage occurred at stoichiometric conditions and hence improved cycle efficiency.

A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland

2001 ◽  
pp. 159-166 ◽  
Author(s):  
Jens Konnerup-Madsen
Keyword(s):  
Nepheline Syenite ◽  
Subsequent Development ◽  
High Water ◽  
Vapour Phase ◽  
Low Carbon ◽  
Low Oxygen ◽  
Alkaline Complex ◽  
Hydrocarbon Gases ◽  
Wide Range ◽  
Water Contents

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Konnerup-Madsen, J. (2001). A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 159-166. https://doi.org/10.34194/ggub.v190.5187 _______________ Fluid inclusions in minerals from agpaitic nepheline syenites and hydrothermal veins in the Ilímaussaq complex and in similar agpaitic complexes on the Kola Peninsula, Russia, are dominated by hydrocarbon gases (predominantly methane) and hydrogen. Such volatile compositions differ considerably from those of most other igneous rocks and their formation and entrapment in minerals reflects low oxygen fugacities and a wide range of crystallisation temperatures extending to a low-temperature solidus. Their composition reflects initial low carbon contents and high water contents of the magma resulting in the exsolution of a waterrich CO2–H2O dominated vapour phase. Fractionation of chlorides into the vapour phase results in high salinities and the subsequent development of a heterogeneous vapour phase with a highly saline aqueous-rich fraction and a methane-dominated fraction, with preferential entrapment of the latter, possibly due to different wetting characteristics. The light stable isotope compositions support an abiogenic origin for the hydrocarbons in agpaitic nepheline syenite complexes.

Growth of Ornamental Plants in Compacted Soils in Relation to Root Growth under Low Oxygen and High Atmospheric Pressure

HortScience ◽  
1998 ◽  
Vol 33 (3) ◽  
pp. 479d-479
Author(s):  
Michael Knee ◽  
Ruth Brake
Keyword(s):  
Atmospheric Pressure ◽  
Root Elongation ◽  
Native Plants ◽  
Tagetes Patula ◽  
Low Oxygen ◽  
Compacted Soils ◽  
Bedding Plants ◽  
Four Levels ◽  
Physical Resistance ◽  
High Atmospheric Pressure

In urban situations, particularly after construction, herbaceous ornamentals may be planted into soils that are compacted or have poor structure so that plant roots may encounter poor aeration or physical resistance. Low oxygen concentrations may be the most important aspect of poor aeration and are readily reproduced in the laboratory. High atmospheric pressure might be used to screen for the ability to grow against physical resistance. We tested the suggestion that “native” plants would grow better in compacted soils than typical bedding plants and for differences in tolerance to low oxygen or high pressure. Plants were grown from seed in the greenhouse at four levels of compaction in peat-based medium and in field soil. Shoot dry weights of the native plants Asclepias tuberosa, Echinacea purpurea, and Schizachyrium scoparius, were less affected by growth in compacted soil or peat medium than those of the bedding plants, Antirrhinum majus, Gypsophila elegans, Impatiens balsamina, Tagetes patula and Zinnia elegans. The oxygen content of media declined with compaction to a minimum of 10 kPa. Half maximal root elongation was observed at 1 to 3 kPa oxygen for most species without any separation between the groups. A presure of 1100 kPa reduced root elongation of the bedding plants by 50 to 70% but only 5 to 20% for the native plants.

scholarly journals Atmospheric Pressure Plasma Deposition of TiO2: A Review

Materials ◽  
2020 ◽  
Vol 13 (13) ◽  
pp. 2931
Author(s):  
Soumya Banerjee ◽  
Ek Adhikari ◽  
Pitambar Sapkota ◽  
Amal Sebastian ◽  
Sylwia Ptasinska
Keyword(s):  
Atmospheric Pressure ◽  
Gas Flow ◽  
Plasma Deposition ◽  
Atmospheric Pressure Plasma ◽  
Cost Savings ◽  
Historical Background ◽  
Pressure Plasma ◽  
Wide Range ◽  
The Status ◽  
Deposition Techniques

Atmospheric pressure plasma (APP) deposition techniques are useful today because of their simplicity and their time and cost savings, particularly for growth of oxide films. Among the oxide materials, titanium dioxide (TiO2) has a wide range of applications in electronics, solar cells, and photocatalysis, which has made it an extremely popular research topic for decades. Here, we provide an overview of non-thermal APP deposition techniques for TiO2 thin film, some historical background, and some very recent findings and developments. First, we define non-thermal plasma, and then we describe the advantages of APP deposition. In addition, we explain the importance of TiO2 and then describe briefly the three deposition techniques used to date. We also compare the structural, electronic, and optical properties of TiO2 films deposited by different APP methods. Lastly, we examine the status of current research related to the effects of such deposition parameters as plasma power, feed gas, bias voltage, gas flow rate, and substrate temperature on the deposition rate, crystal phase, and other film properties. The examples given cover the most common APP deposition techniques for TiO2 growth to understand their advantages for specific applications. In addition, we discuss the important challenges that APP deposition is facing in this rapidly growing field.

scholarly journals Research on Zero-Voltage Ride Through Control Strategy of Doubly Fed Wind Turbine

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2287
Author(s):  
Kaina Qin ◽  
Shanshan Wang ◽  
Zhongjian Kang
Keyword(s):  
Wind Turbine ◽  
Wind Power ◽  
Control Strategy ◽  
Large Scale ◽  
Sliding Mode ◽  
Stable Operation ◽  
Wide Range ◽  
Dc Bus ◽  
Doubly Fed ◽  
Zero Voltage

With the rapid increase in the proportion of the installed wind power capacity in the total grid capacity, the state has put forward higher and higher requirements for wind power integration into the grid, among which the most difficult requirement is the zero-voltage ride through (ZVRT) capability of the wind turbine. When the voltage drops deeply, a series of transient processes, such as serious overvoltage, overcurrent, or speed rise, will occur in the motor, which will seriously endanger the safe operation of the wind turbine itself and its control system, and cause large-scale off-grid accident of wind generator. Therefore, it is of great significance to improve the uninterrupted operation ability of the wind turbine. Doubly fed induction generator (DFIG) can achieve the best wind energy tracking control in a wide range of wind speed and has the advantage of flexible power regulation. It is widely used at present, but it is sensitive to the grid voltage. In the current study, the DFIG is taken as the research object. The transient process of the DFIG during a fault is analyzed in detail. The mechanism of the rotor overcurrent and DC bus overvoltage of the DFIG during fault is studied. Additionally, the simulation model is built in DIgSILENT. The active crowbar hardware protection circuit is put into the rotor side of the wind turbine, and the extended state observer and terminal sliding mode control are added to the grid side converter control. Through the cooperative control technology, the rotor overcurrent and DC bus overvoltage can be suppressed to realize the zero-voltage ride-through of the doubly fed wind turbine, and ensure the safe and stable operation of the wind farm. Finally, the simulation results are presented to verify the theoretical analysis and the proposed control strategy.

scholarly journals Ways into Understanding HIF Inhibition

Cancers ◽  
2021 ◽  
Vol 13 (1) ◽  
pp. 159
Author(s):  
Tina Schönberger ◽  
Joachim Fandrey ◽  
Katrin Prost-Fingerle
Keyword(s):  
Protein Interactions ◽  
Target Genes ◽  
Protein Protein Interactions ◽  
Low Oxygen ◽  
Drug Candidates ◽  
Open Questions ◽  
Wide Range ◽  
Hif Pathway

Hypoxia is a key characteristic of tumor tissue. Cancer cells adapt to low oxygen by activating hypoxia-inducible factors (HIFs), ensuring their survival and continued growth despite this hostile environment. Therefore, the inhibition of HIFs and their target genes is a promising and emerging field of cancer research. Several drug candidates target protein–protein interactions or transcription mechanisms of the HIF pathway in order to interfere with activation of this pathway, which is deregulated in a wide range of solid and liquid cancers. Although some inhibitors are already in clinical trials, open questions remain with respect to their modes of action. New imaging technologies using luminescent and fluorescent methods or nanobodies to complement widely used approaches such as chromatin immunoprecipitation may help to answer some of these questions. In this review, we aim to summarize current inhibitor classes targeting the HIF pathway and to provide an overview of in vitro and in vivo techniques that could improve the understanding of inhibitor mechanisms. Unravelling the distinct principles regarding how inhibitors work is an indispensable step for efficient clinical applications and safety of anticancer compounds.

Effects of Air Temperature on Combustion Characteristics of LPG Diffusion Flame

2020 ◽  
Vol 1008 ◽  
pp. 128-138
Author(s):  
Ahmed M. Salman ◽  
Ibrahim A. Ibrahim ◽  
Hamada M. Gad ◽  
Tharwat M. Farag
Keyword(s):  
Air Temperature ◽  
Diffusion Flame ◽  
Nitrogen Addition ◽  
Flame Length ◽  
Combustion Characteristics ◽  
Operating Conditions ◽  
Low Oxygen ◽  
Air Temperatures ◽  
Air Stream ◽  
Wide Range

In the present study, the combustion characteristics of LPG gaseous fuel diffusion flame at elevated air temperatures were experimentally investigated. An experimental test rig was manufactured to examine a wide range of operating conditions. The investigated parameters are the air temperatures of 300, 350, 400, 450, and 500 K with constant percentage of nitrogen addition in combustion air stream of 5 % to give low oxygen concentration of 18.3 % by mass at constant air swirl number, air to fuel mass ratio, and thermal load of 1.5, 30, and 23 kW, respectively. The gaseous combustion characteristics were represented as axial and radial temperatures distributions, temperatures gradient, visible flame length and species concentrations. The results indicated that as the air temperature increased, the chemical reaction rate increased and flame volume decreased, the combustion time reduced leading to a reduction in flame length. The NO concentration reaches its maximum values near the location of the maximum centerline axial temperature. Increasing the combustion air temperature by 200 K, the NO consequently O2 concentrations are increased by about % 355 and 20 % respectively, while CO2 and CO concentrations are decreased by about % 21 and 99 % respectively, at the combustor end.

Analysis of Chinese Natural Gas Interchangeability Predicted by Weaver Indices

2013 ◽  
Vol 724-725 ◽  
pp. 1017-1020 ◽  
Author(s):  
Zhi Guang Chen ◽  
Chao Kui Qin ◽  
Yang Jun Zhan ◽  
Ju Qiu
Keyword(s):  
Natural Gas ◽  
Liquefied Natural Gas ◽  
Incomplete Combustion ◽  
Natural Gases ◽  
Combustion Performance ◽  
Test Conditions ◽  
Critical Attention ◽  
Different Sources

Many cities in China are being supplied with natural gases from different sources including PNGs (Pipeline Natural Gas) and LNG (Liquefied Natural Gas), critical attention should be paid to natural gas interchangeability problems. In this paper, the applicability of Weaver Indices for Chinese natural gas interchangeability prediction has been discussed. Experiment with 17 sets of domestic gas appliances and 11 natural gases about 187 test conditions has been done to analyze the interchangeability. It can conclude from experiment results that some sources of natural gas cannot be interchangeable, and Weaver Indices isnt totally suitable to predict lifting and incomplete combustion performance for Chinese natural gas interchangeability. It suggests the limits of Incomplete Combustion JI should be changed into JI0.04 and Lifting JL to JL0.95.

Electrodeposited Thin Conformal TiO2 Coating Enabling Stable Operation of BiVO4 Photoanodes in Basic Media

2018 ◽  
Vol MA2018-01 (31) ◽  
pp. 1917-1917
Author(s):  
Dongho Lee ◽  
Kyoung-Shin Choi
Keyword(s):  
Oxygen Evolution ◽  
Water Oxidation ◽  
Synthesis Method ◽  
Protective Layer ◽  
Photoelectrochemical Cell ◽  
Semiconductor Surface ◽  
Stable Operation ◽  
Solar Water Splitting ◽  
Wide Range ◽  
Basic Solutions

Producing hydrogen via solar water splitting using a photoelectrochemical cell (PEC) persists as one of the most exciting research topics in the field of solar fuels. The construction of efficient PECs requires the integration of multiple components including a photoanode, a photocathode, an oxygen evolution catalyst, and a hydrogen evolution catalyst. Therefore, the compatibility and stability of all of these elements in a given operating condition are crucial. When the stability of a semiconductor electrode used as the photoanode or photocathode is limited in an acidic or basic condition which is optimum for the operation of the other components, a thin protective layer has been deposited on the semiconductor surface to prevent its chemical dissolution. Surface coating of a thin and conformal TiO2 layer has been proven to be successful for protecting photoelectrodes since TiO2 is chemically and electrochemically stable in a wide range of pH conditions under both anodic and cathodic conditions. In order to prevent the semiconductor surface from coming into direct contact with the corrosive electrolyte, complete coverage of the photoelectrode with TiO2 is required. At the same time, the TiO2 layer should be thin enough not to interfere with the charge transport properties of the photoelectrode. As a result, atomic layer deposition (ALD) has been the only successful tool used to date to produce an effective protective layer. However, the slow processing time and economic viability of ALD methods motivated us to develop an inexpensive and facile solution-based synthesis method for the deposition of high quality TiO2 coating layers. In this presentation, we report a new electrochemical method to deposit a thin and conformal TiO2 layer on nanoporous BiVO4 that has an intricate, high surface area morphology. BiVO4 is a promising n-type photoanode material with a relatively low bandgap (2.4~2.5 eV). However, its usage has been limited to neutral and mildly basic conditions (pH 5~9) because it is chemically unstable in strongly acidic and basic conditions. Our method allows for the deposition of a 5~6 nm thick TiO2 layer on BiVO4 within 1 min and the resulting BiVO4/TiO2 electrodes exhibit chemical stability in basic solutions (pH 12~13). Sulfite oxidation measurements of BiVO4 and BiVO4/TiO2 electrodes show that the thin TiO2 protective layer does not significantly reduce the hole transfer to the electrolyte. Finally, we demonstrate the photoelectrochemical stability of the BiVO4/TiO2 electrode for photoelectrochemical water oxidation in basic solutions by coupling the BiVO4/TiO2 electrode with appropriate oxygen evolution catalysts.

Reaction Model Development of Selected Aromatics as Relevant Molecules of a Kerosene Surrogate – The Importance of M-Xylene Within the Combustion of 1,3,5-Trimethylbenzene

2021 ◽  
Author(s):  
Astrid Ramirez Hernandez ◽  
Trupti Kathrotia ◽  
Torsten Methling ◽  
Marina Braun-Unkhoff ◽  
Uwe Riedel
Keyword(s):  
Atmospheric Pressure ◽  
Burning Velocity ◽  
Model Development ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Reaction Model ◽  
Pollutant Emissions ◽  
Similar Species ◽  
Ignition Delay Times ◽  
Wide Range

Abstract The development of advanced reaction models to predict pollutant emissions in aero-engine combustors usually relies on surrogate formulations of a specific jet fuel for mimicking its chemical composition. 1,3,5-trimethylbenzene is one of the suitable components to represent aromatics species in those surrogates. However, a comprehensive reaction model for 1,3,5-trimethylbenzene combustion requires a mechanism to describe the m-xylene oxidation. In this work, the development of a chemical kinetic mechanism for describing the m-xylene combustion in a wide parameter range (i.e. temperature, pressure, and fuel equivalence ratios) is presented. The m-xylene reaction submodel was developed based on existing reaction mechanisms of similar species such as toluene and reaction pathways adapted from literature. The sub-model was integrated into an existing detailed mechanism that contains the kinetics of a wide range of n-paraffins, iso-paraffins, cyclo-paraffins, and aromatics. Simulation results for m-xylene were validated against experimental data available in literature. Results show that the presented m-xylene mechanism correctly predicts ignition delay times at different pressures and temperatures as well as laminar burning velocities at atmospheric pressure and various fuel equivalence ratios. At high pressure, some deviations of the calculated laminar burning velocity and the measured values are obtained at stoichiometric to rich equivalence ratios. Additionally, the model predicts reasonably well concentration profiles of major and intermediate species at different temperatures and atmospheric pressure.

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