Aerosol Synthesis of Nano and Micro-Scale Zero Valent Nickel Particles From Oxide Precursors

2010 ◽  
Author(s):  
Haytham Soliman ◽  
Jonathan Phillips ◽  
Claudia Luhrs ◽  
Hugo Zea ◽  
Zayd C. Leseman
Keyword(s):  
Particle Size ◽  
Metal Oxide ◽  
Residence Time ◽  
Rapid Expansion ◽  
Metal Particles ◽  
Micro Scale ◽  
Nickel Particles ◽  
Solid Liquid ◽  
Urea Decomposition ◽  
Reduction Of Oxides

In this work a novel aerosol method, derived from the batch Reduction/Expansion Synthesis (RES) method, for production of nano / micro-scale metal particles from oxides and hydroxides is presented. In the Aersosol-RES (A-RES) method, an aerosol, consisting of a physical mixture of urea and metal oxide or hydroxides, is passed through a heated oven (1000 °C) with a residence time of the order of 1 second, producing pure (zero valent) metal particles. It appears that the process is flexible regarding metal or alloy identity, allows control of particle size and can be readily scaled to very large throughput. Current work is focused on creating nanoparticles of metal and metal alloy using this method. Although this is primarily a report on observations, some key elements of the chemistry are clear. In particular, the reducing species produced by urea decomposition are the primary agents responsible for reduction of oxides and hydroxides to metal. It is also likely that the rapid expansion that takes place when solid/liquid urea decomposes to form gas species influences the final morphology of the particles.

Analytical Electron Microscopy study of two vehicle-aged automotive exhaust catalysts having dissimilar activities

1989 ◽  
Vol 47 ◽  
pp. 272-273
Author(s):  
Sooho Kim ◽  
M. J. D’Aniello
Keyword(s):  
Electron Microscopy ◽  
Particle Size ◽  
Noble Metal ◽  
Catalyst Deactivation ◽  
Analytical Electron Microscopy ◽  
Microscopy Study ◽  
Metal Particles ◽  
Automotive Exhaust ◽  
Exhaust Catalysts ◽  
Analytical Electron

Automotive catalysts generally lose-agtivity during vehicle operation due to several well-known deactivation mechanisms. To gain a more fundamental understanding of catalyst deactivation, the microscopic details of fresh and vehicle-aged commercial pelleted automotive exhaust catalysts containing Pt, Pd and Rh were studied by employing Analytical Electron Microscopy (AEM). Two different vehicle-aged samples containing similar poison levels but having different catalytic activities (denoted better and poorer) were selected for this study.The general microstructure of the supports and the noble metal particles of the two catalysts looks similar; the noble metal particles were generally found to be spherical and often faceted. However, the average noble metal particle size on the poorer catalyst (21 nm) was larger than that on the better catalyst (16 nm). These sizes represent a significant increase over that found on the fresh catalyst (8 nm). The activity of these catalysts decreases as the observed particle size increases.

scholarly journals Continuous citrate‐capped gold nanoparticle synthesis in a two‐phase flow reactor

2021 ◽  
Author(s):  
Spyridon Damilos ◽  
Ioannis Alissandratos ◽  
Luca Panariello ◽  
Anand N. P. Radhakrishnan ◽  
Enhong Cao ◽  
...  
Keyword(s):  
Particle Size ◽  
Gold Nanoparticles ◽  
Residence Time ◽  
Flow Reactor ◽  
Phase Flow ◽  
Continuous Manufacturing ◽  
Two Phase ◽  
Process Yield ◽  
Au Nps ◽  
Manufacturing Platform

AbstractA continuous manufacturing platform was developed for the synthesis of aqueous colloidal 10–20 nm gold nanoparticles (Au NPs) in a flow reactor using chloroauric acid, sodium citrate and citric acid at 95 oC and 2.3 bar(a) pressure. The use of a two-phase flow system – using heptane as the continuous phase – prevented fouling on the reactor walls, while improving the residence time distribution. Continuous syntheses for up to 2 h demonstrated its potential application for continuous manufacturing, while live quality control was established using online UV-Vis photospectrometry that monitored the particle size and process yield. The synthesis was stable and reproducible over time for gold precursor concentration above 0.23 mM (after mixing), resulting in average particle size between 12 and 15 nm. A hydrophobic membrane separator provided successful separation of the aqueous and organic phases and collection of colloidal Au NPs in flow. Process yield increased at higher inlet flow rates (from 70 % to almost 100 %), due to lower residence time of the colloidal solution in the separator resulting in less fouling in the PTFE membrane. This study addresses the challenges for the translation of the synthesis from batch to flow and provides tools for the development of a continuous manufacturing platform for gold nanoparticles.Graphical abstract

scholarly journals A thermodynamic assessment of precipitation, growth, and control of MnS inclusion in U75V heavy rail steel

2021 ◽  
Vol 40 (1) ◽  
pp. 178-192
Author(s):  
Wen-Qiang Ren ◽  
Lu Wang ◽  
Zheng-Liang Xue ◽  
Cheng-Zhi Li ◽  
Hang-Yu Zhu ◽  
...  
Keyword(s):  
Particle Size ◽  
Rail Steel ◽  
Solidification Process ◽  
Segregation Ratio ◽  
Two Phase ◽  
Final Particle ◽  
Solid Liquid ◽  
And Control ◽  
Heavy Rail ◽  
Heavy Rail Steel

Abstract Thermodynamic analysis of the precipitation behavior, growth kinetic, and control mechanism of MnS inclusion in U75V heavy rail steel was conducted in this study. The results showed that solute element S had a much higher segregation ratio than that of Mn, and MnS would only precipitate in the solid–liquid (two-phase) regions at the late stage during the solidification process at the solid fraction of 0.9518. Increasing the cooling rate had no obvious influence on the precipitation time of MnS inclusion; however, its particle size would be decreased greatly. The results also suggested that increasing the concentration of Mn would lead to an earlier precipitation time of MnS, while it had little effect on the final particle size; as to S, it was found that increasing its concentration could not only make the precipitation time earlier but also make the particle size larger. Adding a certain amount of Ti additive could improve the mechanical properties of U75V heavy rail steel due to the formation of TiO x –MnS or MnS–TiS complex inclusions. The precipitation sequences of Ti3O5 → Ti2O3 → TiO2 → TiO → MnS → TiS for Ti treatment were determined based on the thermodynamic calculation.

Use of Municipal Solid Waste Incineration Bottom Ash in Adsorption of Heavy Metals

2011 ◽  
Vol 474-476 ◽  
pp. 1099-1102
Author(s):  
Hai Ying Zhang ◽  
Yi Zheng ◽  
Hong Tao Hu ◽  
Jing Yu Qi
Keyword(s):  
Heavy Metals ◽  
Particle Size ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Residence Time ◽  
Bottom Ash ◽  
Waste Incineration ◽  
Synthetic Wastewater ◽  
High Porosity ◽  
Municipal Solid Waste Incineration

Bottom ash from municipal solid waste incineration (MSWI) has been previously suggested as an adsorbent for removing heavy metals from wastewater due to its high porosity and large surface area. In this study the adsorption characteristics of heavy metals were investigated using various particle sizes of MSWI bottom ash. The adsorption experiment was conducted using synthetic wastewater containing Cu, Zn, Pb and Cd as a function of residence time, initial pH, ash dosage and particle size, respectively. The adsorption rate increased with decreasing particle size and with increasing residence time. Through the above analysis, this work proved that bottom ash was effective in adsorbing the four heavy metals.

greater the probability that the particles will miss the high shear zones on a single pass through the device. For this reason the discharge of many rotor/stator devices is re-stricted with a series of holes or bars, or with a grid, which performs two separate tasks. First, a discharge grid absolutely limits the maximum particle size that can exit the mixer. If the holes on the discharge grid are 2 mm, it is virtually impossible for par-ticles larger than that diameter to pass through the machine. Rotor/stator in-line mix-ers are made with restricting grids as small as 0.5 mm, and a wide range of larger sizes up to 50 mm or even unrestricted outlets. A sample of such grids is presented in Fig. 29. But even the smallest usable discharge grid does not necessarily provide abso-lute control of the required size distributions in the range of fine dispersion. This is the second reason for the restriction on the discharge. By putting a more limiting dis-charge on the outlet, the flow rate through the device for a given set of pumping cir-cumstances (viscosity, density, system suction, and discharge head) is reduced and the residence time in the machine for a given particle or droplet is increased. The longer residence time increases the probability that a particle has to travel through the highest shearing zones and, thereby, be reduced to the smallest size that the machine is capable of producing. • • • • " ' ; • " * * «L £ J- •-

1998 ◽  
pp. 358-360
Keyword(s):  
Particle Size ◽  
Residence Time ◽  
Flow Rate ◽  
Shear Zones ◽  
High Shear ◽  
Single Pass ◽  
Fine Dispersion ◽  
Wide Range ◽  
Maximum Particle ◽  
Pass Through

Multiscale Analysis of Particle Size-dependent Steady Compaction Waves in Granular Energetic Materials

2012 ◽  
Vol 13 (2) ◽  
pp. 165-175
Author(s):  
Xin-Ming Zhang ◽  
Yan-Qing Wu ◽  
Feng-Lei Huang
Keyword(s):  
Particle Size ◽  
Liquid Phase ◽  
Yield Strength ◽  
Thermal Energy ◽  
Coarse Particles ◽  
Localization Strategy ◽  
Solid Liquid ◽  
Particle Beds ◽  
Compaction Waves ◽  
Grain Temperature

Abstract A multiscale model is used to analyze the compaction processes in granular HMX beds composed of different particle sizes (coarse particles, d=40 μm and microfine particles, d=4 μm). The localization strategy of Gonthier is extended to include changes in thermal energy induced by compression. The variation in yield strength caused by solid-liquid phase change is also considered. Analysis of the steady-state wave structure indicates that the compaction behavior of a porous material is dependent on particle size. For solid volume fraction φs < 0.88, the fine particle beds provide greater resistance to compaction than the coarse particle beds, and they propagate compaction waves that travel at faster speeds. When φs > 0.88, the physical state of the compacted bed has become very similar for the two materials. For subsonic compaction waves, the evolution of the grain temperature shows that large particles lead to large hot spots and high temperature and coarse particles are more shock sensitive at low shock pressures. For supersonic compaction waves, compression induced changes in thermal energy play an important role in localization strategy. It increases the localization sphere center radius. The dissipated energy is deposited over a larger localization volume so that the grain temperature near the intergranular contact surface is reduced significantly. The localization center radius further increases because of the decrease in the yield strength caused by solid–liquid phase change. Consequently, the peak grain temperature is reduced further.

scholarly journals Patterned nanofiber air filters with high optical transparency, robust mechanical strength, and effective PM2.5 capture capability

RSC Advances ◽  
2020 ◽  
Vol 10 (34) ◽  
pp. 20155-20161 ◽  
Author(s):  
Jinshan Cao ◽  
Zhiqiang Cheng ◽  
Lijuan Kang ◽  
Meng Lin ◽  
Lihao Han
Keyword(s):  
Particle Size ◽  
Mechanical Strength ◽  
Human Health ◽  
Residence Time ◽  
Small Particle ◽  
Toxic Substances ◽  
Small Particle Size ◽  
Daily Production ◽  
Air Filters ◽  
Strong Activity

PM2.5, due to its small particle size, strong activity, ease of the attachment of toxic substances and long residence time in the atmosphere, has a great impact on human health and daily production.

scholarly journals Sustainable Micro-Scale Extraction of Bioactive Phenolic Compounds from Vitis vinifera Leaves with Ionic Liquid-Based Surfactants

Molecules ◽  
2020 ◽  
Vol 25 (13) ◽  
pp. 3072 ◽  
Author(s):  
Giulia Mastellone ◽  
Idaira Pacheco-Fernández ◽  
Patrizia Rubiolo ◽  
Verónica Pino ◽  
Cecilia Cagliero
Keyword(s):  
Ionic Liquid ◽  
Phenolic Compounds ◽  
Vitis Vinifera ◽  
High Performance ◽  
Photodiode Array Detection ◽  
Micro Scale ◽  
Simple Strategy ◽  
Analytical System ◽  
Solid Liquid ◽  
Extraction Phase

This paper proposes a new sustainable and simple strategy for the micro-scale extraction of phenolic compounds from grapevine leaves with analytical purpose. The method is based on a microwave-assisted solid-liquid extraction approach (MA-SLE), using an aqueous solution of an ionic liquid (IL)-based surfactant as extraction phase. The method does not require organic solvents, nor any clean-up step, apart from filtration prior to the injection in the analytical system. Two IL-based surfactants were evaluated, and the method was optimized by using experimental designs, resulting in the use of small amounts of sample (100 mg) and extraction phase (2.25 mL), low concentrations of the selected 1-hexadecyl-3-butyl imidazolium bromide IL (0.1 mM), and 30 min of extraction time. The proposed methodology was applied for the determination of the polyphenolic pattern of six different varieties of Vitis vinifera leaves from the Canary Islands, using high-performance liquid chromatography and photodiode array detection for the quantification of the compounds. The proposed MA-SLE approach was greener, simpler, and more effective than other methods, while the results from the analysis of the leaves samples demonstrate that these by-products can be exploited as a source of natural compounds for many applications.

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