Evidence for mixed contribution of mantle and lower and upper crust to the genesis of Jurassic I-type granites from Macao, SE China

2020 ◽  
Vol 133 (1-2) ◽  
pp. 37-56 ◽  
Author(s):  
Pedro Quelhas ◽  
João Mata ◽  
Ágata Alveirinho Dias
Keyword(s):  
Magma Mixing ◽  
Mineral Chemistry ◽  
Granitic Rocks ◽  
Geochemical Data ◽  
Mafic Enclaves ◽  
Group I ◽  
High K ◽  
Depleted Mantle ◽  
Charge And Radius ◽  
Se China

Abstract Much controversy has occurred in the past few decades regarding the nature of the sources, the petrogenetic processes, and the tectonic regime(s) of the Jurassic magmatism within the Southeast China magmatic belt. This study aims to contribute to the discussion with mineral chemistry, and whole-rock element and Sr-Nd-Hf-Pb isotopic geochemical data from granitic rocks and microgranular mafic enclaves from Macao, where two discrete groups of I-type biotite granites have been identified (referred to as Macao Group I [MGI] and Macao Group II [MGII]). It is proposed that the granitic magmas were generated by partial melting of infracrustal medium- to high-K, basaltic Paleoproterozoic to Mesoproterozoic protoliths (Nd depleted mantle model age [TDM2] = 1.7–1.6 Ga and Hf TDM2 = 1.8–1.6 Ga), triggered by underplating of hot mantle-derived magmas in an extensional setting related to the foundering of a previously flat slab (paleo–Pacific plate) beneath the SE China continent. The main differences between the two groups of Macao granites are attributed to assimilation and fractional crystallization processes, during which upper-crustal Paleozoic metasediments were variably assimilated by MGI magmas. This is evidenced by an increase in initial 87Sr/86Sr ratios with degree of evolution, presence of metasedimentary enclaves, and high percentage of zircon xenocrysts with Paleozoic ages. In addition, other processes like late-stage fluid/melt interaction and magma mixing also left some imprints on granite compositions (rare earth element tetrad effect plus non–charge-and-radius-controlled behavior of trace elements and decoupling between different isotope systems, respectively). The distribution of isotopically distinct granites in SE China reflects the nature of the two Cathaysia crustal blocks juxtaposed along the Zhenghe-Dapu fault.

scholarly journals Petrology and mineral chemistry of peraluminous Marziyan granites, Sanandaj-Sirjan metamorphic belt (NW Iran)

2015 ◽  
Vol 66 (5) ◽  
pp. 361-374 ◽  
Author(s):  
Esmaiel Darvishi ◽  
Mahmoud Khalili ◽  
Roy Beavers ◽  
Mohammad Sayari
Keyword(s):  
Mineral Chemistry ◽  
White Mica ◽  
Granitic Rocks ◽  
Calc Alkaline ◽  
Metamorphic Belt ◽  
Nw Iran ◽  
The North ◽  
Continental Plate ◽  
High K ◽  
Type Granite

AbstractThe Marziyan granites are located in the north of Azna and crop out in the Sanandaj-Sirjan metamorphic belt. These rocks contain minerals such as quartz, K-feldspars, plagioclase, biotite, muscovite, garnet, tourmaline and minor sillimanite. The mineral chemistry of biotite indicates Fe-rich (siderophyllite), low TiO2, high Al2O3, and low MgO nature, suggesting considerable Al concentration in the source magma. These biotites crystallized from peraluminous S-type granite magma belonging to the ilmenite series. The white mica is rich in alumina and has muscovite composition. The peraluminous nature of these rocks is manifested by their remarkably high SiO2, Al2O3and high molar A/CNK (> 1.1) ratio. The latter feature is reflected by the presence of garnet and muscovite. All field observations, petrography, mineral chemistry and petrology evidence indicate a peraluminous, S-type nature of the Marziyan granitic rocks that formed by partial melting of metapelite rocks in the mid to upper crust possibly under vapour-absent conditions. These rocks display geochemical characteristics that span the medium to high-K and calc-alkaline nature and profound chemical features typical of syn-collisional magmatism during collision of the Afro-Arabian continental plate and the Central Iranian microplate.

scholarly journals PETROGRAPHY AND MINERAL CHEMISTRY OF OLIGOCENE SHOSHONITIC DACITES FROM THE CENTRAL BOSNIA

2020 ◽  
Vol 1 (22) ◽  
Author(s):  
Zehra Salkić ◽  
Boško Lugović ◽  
Elvir Babajić
Keyword(s):  
Pannonian Basin ◽  
Magma Mixing ◽  
Volcanic Rocks ◽  
Mafic Magma ◽  
Mineral Chemistry ◽  
Southeastern Part ◽  
Vardar Zone ◽  
High K ◽  
Insight Into ◽  
Zoned Plagioclase

Postorogenic volcanic rocks of different Tertiary ages are very common in the Sava-Vardar Zone of the Dinarides and in the southeastern part of adjoing Pannonian Basin. South of the Sava-Vardar Zone, in central Bosnia, Tertiary volcanic rocks occur within ophiolite sequences and genetically related sedimentary formations of the Dinaride Ophiolite Zone. Central Bosnia volcanic rocks are mostly dacites, and highly subordinately andesites as the members of the high-K calc-alkaline series.It appears from the mineralogical and petrographic characteristics obtained some insight into the processes that occurred during the genesis of the rocks. The presence of primary igneous minerals: clinopyroxene, orthopyroxene, hornblende and biotite from ferromagnesian minerals, and plagioclase, sanidine and quartz, indicates that the fractional crystallization played a significant role in the genesis of the rocks. Reaction edge on many rounded quartz phenocrysts indicates the possibility of magma mixing with the formation of Tertiary volcanic rocks of the central Bosnia. On magma mixing different temperature and chemical composition also indicates the existence of zoned plagioclase and amphibole phenocrysts.Complex compositional and zoning patterns of biotite and plagioclase phenocrysts and disequilibrium microstructures of plagioclase and quartz phenocrysts suggest interaction of fractionating, mantle derived melts with continental crust during a shalow level pre-eruptive stage and mixing with small amount of devolatilized phlogopite-phyric mafic magma before eruption.

New geological model of the Lagoa Real uraniferous albitites from Bahia (Brazil)

2013 ◽  
Vol 5 (3) ◽  
Author(s):  
Alexandre Oliveira Chaves
Keyword(s):  
Inductively Coupled Plasma ◽  
Melt Inclusions ◽  
Shear Zones ◽  
Mineral Chemistry ◽  
Granitic Rocks ◽  
Geochemical Data ◽  
Magmatic Differentiation ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Brasiliano Orogeny

AbstractNew evidence supported by petrography (including mineral chemistry), lithogeochemistry, U-Pb geochronology by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS), and physicochemical study of fluid and melt inclusions by LA-ICP-MS and microthermometry, point to an orogenic setting of Lagoa Real (Bahia-Brazil) involving uraniferous mineralization. Unlike the previous models in which uraniferous albitites represent Na-metasomatised 1.75 Ga anorogenic granitic rocks, it is understood here that they correspond to metamorphosed sodium-rich and quartz-free 1.9 Ga late-orogenic syenitic rocks (Na-metasyenites). These syenitic rocks are rich not only in albite, but also in U-rich titanite (source of uranium). The interpretation of geochemical data points to a petrogenetic connection between alkali-diorite (local amphibolite protolith) and sodic syenite by fractional crystallization through a transalkaline series. This magmatic differentiation occurred either before or during shear processes, which in turn led to albitite and amphibolite formation. The metamorphic reactions, which include intense recrystallization of magmatic minerals, led uraninite to precipitate at 1.87 Ga under Oxidation/Reduction control. A second population of uraninites was also generated by the reactivation of shear zones during the 0.6 Ga Brasiliano Orogeny. The geotectonic implications include the importance of the Orosirian event in the Paramirim Block during paleoproterozoic Săo Francisco Craton edification and the influence of the Brasiliano event in the Paramirim Block during the West-Gondwana assembly processes. The regional microcline-gneiss, whose protolith is a 2.0 Ga syn-collisional potassic granite, represents the albitite host rock. The microcilne-gneiss has no petrogenetic association to the syenite (albitite protolith) in magmatic evolutionary terms.

scholarly journals GEOCHEMICAL CHARACTERISTICS OF THE ERENLERDAGI VOLCANICS, KONYA, CENTRAL TURKEY

2017 ◽  
Vol 50 (4) ◽  
pp. 2057
Author(s):  
C. Uyanık ◽  
K. Koçak
Keyword(s):  
Fractional Crystallization ◽  
Magma Mixing ◽  
Primitive Mantle ◽  
Geochemical Data ◽  
Calc Alkaline ◽  
High K ◽  
Microgranular Enclaves ◽  
Mafic Microgranular Enclaves ◽  
Central Turkey ◽  
Pyroclastic Fall

Late Miocene to Pliocene volcanism produced lava domes with mafic microgranular enclaves (MMEs), nuée ardentes and pyroclastic fall and flow (ignimbrites) deposits in the WSW and NW of Konya city. All samples are predominantly high K-calc alkaline in composition but calc-alkaline and shoshonitic composition also exist. The felsic volcanics are mainly dacite, andesite, basaltic trachyandesite and rare trachyandesite in compositon. But, the MMEs have basaltic andesite and andesite compositon. SiO2 increases with decreasing TiO2, FeOt, MgO and CaO, suggesting fractional crystallization of mafic minerals. All samples have fractionated chondritenormalised REE pattern (La/YbN: 6.7-18.1), and negative Eu anomaly (Eu/Eu*: 0.67- 0.89), indicating plagioclase fractionation. In primitive mantle-normalized spider diagram, the samples show an enrichment in large ion litophile elements (LILE) such as Cs and Ba, and depletion in high field strength elements (HFSE), e.g. Dy and Y. They show negative Nb, Ta and Ti anomalies, indicating a subduction signature for their genesis. Based on geochemical data, the volcanics are suggested to have been formed by Assimilation-Fractional Crystallization (AFC) and/or magma mixing process. Various geotectonic diagrams imply volcanic arc to post collisional setting for the samples.

Petrogenesis and tectonic implications of Late Jurassic – Early Cretaceous granitic magmatism in the Xing’an Block, Northeast China: geochronological, geochemical, and Hf isotopic evidence

2018 ◽  
Vol 55 (6) ◽  
pp. 571-588 ◽  
Author(s):  
Yue He ◽  
Zhong-Hua He ◽  
Wen-Chun Ge ◽  
Hao Yang ◽  
Zhi-Hui Wang ◽  
...  
Keyword(s):  
Partial Melting ◽  
Early Cretaceous ◽  
Northeast China ◽  
Late Jurassic ◽  
Granitic Rocks ◽  
Geochemical Data ◽  
Magma Source ◽  
Isotopic Evidence ◽  
Depleted Mantle ◽  
Microgranular Enclaves

This study presents new geochronological, whole-rock geochemical, and zircon Hf isotopic evidence for the age, petrogenesis, and source of Mesozoic granitic rocks of the Xing’an Block, Northeast China. This evidence reveals the Late Mesozoic tectonic evolution of the eastern section of the Central Asian Orogenic Belt. Laser-ablation inductively coupled plasma – mass spectrometryzircon U–Pb age data indicate that the syenogranite, monzogranite, and alkali feldspar granite units, as well as their associated diorite microgranular enclaves, were emplaced between 150–142 Ma, providing evidence of Late Jurassic to Early Cretaceous magmatic events within the Xing’an Block. The granites contain high concentrations of SiO2 (65.24%–75.73 wt.%) and K2O (3.94%–5.30 wt.%), low concentrations of MgO (0.10%–1.30 wt.%), and A/CNK values of 0.92–1.06. In addition, Hf isotopic analysis of zircons from the 150–142 Ma granites yields εHf(t) values of +4.54 to +12.16 and two-stage Hf model aged from 906 to 423 Ma, indicating that they formed from magmas generated by partial melting of a juvenile Neoproterozoic–Phanerozoic accreted crustal source. The basic magma source for the diorite microgranular enclaves most likely formed from partial melting of a depleted mantle that had been metasomatized by subduction-related fluids. Combining these new geochemical data with the geology of this region, Late Jurassic to Early Cretaceous magmatism in the Xing’an Block most likely occurred in an extensional environment associated with closure of the Mongol–Okhotsk Ocean.

scholarly journals Geochemistry and petrogenesis of post-collisional ultrapotassic syenites and granites from southernmost Brazil: the Piquiri Syenite Massif

2008 ◽  
Vol 80 (2) ◽  
pp. 353-371 ◽  
Author(s):  
Lauro V.S. Nardi ◽  
Jorge Plá-Cid ◽  
Maria de Fátima Bitencourt ◽  
Larissa Z. Stabel
Keyword(s):  
Granitic Rocks ◽  
Geochemical Data ◽  
Fine Grained ◽  
Enriched Mantle ◽  
Calcic Amphibole ◽  
Pan African ◽  
High K ◽  
Mantle Sources ◽  
Orogenic Cycle ◽  
Tholeiitic Magmatism

The Piquiri Syenite Massif, southernmost Brazil, is part of the post-collisional magmatism related to the Neoproterozoic Brasiliano-Pan-African Orogenic Cycle. The massif is about 12 km in diameter and is composed of syenites, granites, monzonitic rocks and lamprophyres. Diopside-phlogopite, diopside-biotite-augite-calcic-amphibole, are the main ferro-magnesian paragenesis in the syenitic rocks. Syenitic and granitic rocks are co-magmatic and related to an ultrapotassic, silica-saturated magmatism. Their trace element patterns indicate a probable mantle source modified by previous, subduction-related metasomatism. The ultrapotassic granites of this massif were produced by fractional crystallization of syenitic magmas, and may be considered as a particular group of hypersolvus and subsolvus A-type granites. Based upon textural, structural and geochemical data most of the syenitic rocks, particularly the fine-grained types, are considered as crystallized liquids, in spite of the abundance of cumulatic layers, schlieren, and compositional banding. Most of the studied samples are metaluminous, with K2O/Na2O ratios higher than 2. The ultrapotassic syenitic and lamprophyric rocks in the Piquiri massif are interpreted to have been produced from enriched mantle sources, OIB-type, like most of the post-collisional shoshonitic, sodic alkaline and high-K tholeiitic magmatism in southernmost Brazil. The source of the ultrapotassic and lamprophyric magmas is probably the same veined mantle, with abundant phlogopite + apatite + amphibole that reflects a previous subduction-related metasomatism.

scholarly journals Magma Mixing Genesis of the Mafic Enclaves in the Qingshanbao Complex of Longshou Mountain, China: Evidence from Petrology, Geochemistry, and Zircon Chronology

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 195 ◽  
Author(s):  
Wenheng Liu ◽  
Xiaodong Liu ◽  
Jiayong Pan ◽  
Kaixing Wang ◽  
Gang Wang ◽  
...  
Keyword(s):  
Host Rock ◽  
Inductively Coupled Plasma ◽  
Magma Mixing ◽  
Coarse Grained ◽  
Calc Alkaline ◽  
Quartz Crystals ◽  
Alkaline Rocks ◽  
Mafic Enclaves ◽  
Normal Zoning ◽  
Host Rocks

The Qingshanbao complex, part of the uranium metallogenic belt of the Longshou-Qilian mountains, is located in the center of the Longshou Mountain next to the Jiling complex that hosts a number of U deposits. However, little research has been conducted in this area. In order to investigate the origin and formation of mafic enclaves observed in the Qingshanbao body and the implications for magmatic-tectonic dynamics, we systematically studied the mineralogy, petrography, and geochemistry of these enclaves. Our results showed that the enclaves contain plagioclase enwrapped by early dark minerals. These enclaves also showed round quartz crystals and acicular apatite in association with the plagioclase. Electron probe analyses showed that the plagioclase in the host rocks (such as K-feldspar granite, adamellite, granodiorite, etc.) show normal zoning, while the plagioclase in the mafic enclaves has a discontinuous rim composition and shows instances of reverse zoning. Major elemental geochemistry revealed that the mafic enclaves belong to the calc-alkaline rocks that are rich in titanium, iron, aluminum, and depleted in silica, while the host rocks are calc-alkaline to alkaline rocks with enrichment in silica. On Harker diagrams, SiO2 contents are negatively correlated with all major oxides but K2O. Both the mafic enclaves and host rock are rich in large ion lithophile elements such as Rb and K, as well as elements such as La, Nd, and Sm, and relatively poor in high field strength elements such as Nb, Ta, P, Ti, and U. Element ratios of Nb/La, Rb/Sr, and Nb/Ta indicate that the mafic enclaves were formed by the mixing of mafic and felsic magma. In terms of rare earth elements, both the mafic enclaves and the host rock show right-inclined trends with similar weak to medium degrees of negative Eu anomaly and with no obvious Ce anomaly. Zircon LA-ICP-MS (Laser ablation inductively coupled plasma mass spectrometry) U-Pb concordant ages of the mafic enclaves and host rock were determined to be 431.8 5.2 Ma (MSWD (mean standard weighted deviation)= 1.5, n = 14) and 432.8 4.2 Ma (MSWD = 1.7, n = 16), respectively, consistent with that for the zircon U-Pb ages of the granite and medium-coarse grained K-feldspar granites of the Qingshanbao complex. The estimated ages coincide with the timing of the late Caledonian collision of the Alashan Block. This comprehensive analysis allowed us to conclude that the mafic enclaves in the Qingshanbao complex were formed by the mixing of crust-mantle magma with mantle-derived magma due to underplating, which caused partial melting of the ancient basement crust during the collisional orogenesis between the Alashan Block and Qilian rock mass in the early Silurian Period.

Early Cretaceous crust–mantle interaction linked to rollback of the Palaeo-Pacific flat-subducting slab: constraints from the intermediate–felsic volcanic rocks of the northern Great Xing’an Range, NE China

2021 ◽  
pp. 1-22
Author(s):  
Jia-Hao Jing ◽  
Hao Yang ◽  
Wen-Chun Ge ◽  
Yu Dong ◽  
Zheng Ji ◽  
...  
Keyword(s):  
Early Cretaceous ◽  
Volcanic Rocks ◽  
Geochemical Data ◽  
Calc Alkaline ◽  
Ne China ◽  
Asthenospheric Mantle ◽  
High K ◽  
Wide Range ◽  
Great Xing’An Range ◽  
Subducting Slab

Abstract Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.

New approaches to crustal evolution studies and the origin of granitic rocks: what can the Lu-Hf and Re-Os isotope systems tell us?

1996 ◽  
Vol 87 (1-2) ◽  
pp. 339-352 ◽  
Author(s):  
Clark M. Johnson ◽  
Steven B. Shirey ◽  
Karin M. Barovich
Keyword(s):  
Continental Crust ◽  
Isotope Ratios ◽  
Granitic Rocks ◽  
Nd Isotope ◽  
Volcanic Arcs ◽  
Depleted Mantle ◽  
Os Isotopes ◽  
Isotope System ◽  
Os Isotope

ABSTRACT:The Lu-Hf and Re-Os isotope systems have been applied sparsely to elucidate the origin of granites, intracrustal processes and the evolution of the continental crust. The presence or absence of garnet as a residual phase during partial melting will strongly influence Lu/Hf partitioning, making the Lu–Hf isotope system exceptionally sensitive to evaluating the role of garnet during intracrustal differentiation processes. Mid-Proterozoic (1·1–1·5Ga ) ‘anorogenic’ granites from the western U.S.A. appear to have anomalously high εHf values, relative to their εNd values, compared with Precambrian orogenic granites from several continents. The Hf-Nd isotope variations for Precambrian orogenic granites are well explained by melting processes that are ultimately tied to garnet-bearing sources in the mantle or crust. Residual, garnet-bearing lower and middle crust will evolve to anomalously high εHf values over time and may be the most likely source for later ‘anorogenic’ magmas. When crustal and mantle rocks are viewed together in terms of Hf and Nd isotope compositions, a remarkable mass balance is apparent for at least the outer silicate earth where Precambrian orogenic continental crust is the balance to the high-εHf depleted mantle, and enriched lithospheric mantle is the balance to the low-εHf depleted mantle.Although the continental crust has been envisioned to have exceptionally high Re/Os ratios and very radiogenic Os isotope compositions, new data obtained on magnetite mineral separates suggest that some parts of the Precambrian continental crust are relatively Os-rich and non-radiogenic. It remains unclear how continental crust may obtain non-radiogenic Os isotope ratios, and these results have important implications for Re-Os isotope evolution models. In contrast, Phanerozoic batholiths and volcanic arcs that are built on young mafic lower crust may have exceptionally radiogenic Os isotope ratios. These results highlight the unique ability of Os isotopes to identify young mafic crustal components in orogenic magmas that are essentially undetectable using other isotope systems such as O, Sr, Nd and Pb.

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