A BIOSEQUENCE OF SOILS OF THE ROUGH FESCUE PRAIRIE – POPLAR TRANSITION IN SOUTHWESTERN ALBERTA

1966 ◽  
Vol 3 (4) ◽  
pp. 457-471 ◽  
Author(s):  
J. F. Dormaar ◽  
L. E. Lutwick
Keyword(s):  
Organic Matter ◽  
Humic Acids ◽  
Exchange Capacity ◽  
Soil Profiles ◽  
Exchangeable Cation ◽  
Spectral Pattern ◽  
Ph Dependent ◽  
Physical And Chemical ◽  
Rough Fescue ◽  
Populus Spp

A biosequence of soil profiles, ranging from Black through various stages of Dark Gray to Eluviated Dark Gray Chernozems and a Degraded Brown Wooded soil, is found under a sequence of vegetation ranging from rough fescue prairie (Festuca scabrella association) to encroaching poplar (Populus spp.) and fir trees (Pseudotsuga taxifolia (Poir.) Britt.) in the Porcupine Hills of southwestern Alberta. Samples were gathered to establish the differential physical and chemical changes that have occurred in the soils over an 80-year period.Increased eluviation accompanied a reduction in the percentage of exchangeable calcium but it remained the dominant exchangeable cation in all horizons. Most of the exchange capacity arises from the organic matter. The exchange sites are mainly pH-dependent. The changes in the organic matter, because of the encroachment of trees, are more strikingly evident than are the changes in the mineral matter.Infrared absorption spectra of electrodialyzed humic acids display a conspicuous change in spectral pattern between 2 500 and 1 800 cm−1. There are indications of increased acidity and increased aromaticity in the humic acids of the B horizon as eluviation progresses.

scholarly journals Genesis of sandstone-derived soils in the Cerrado of the Piauí State, Brazil

2019 ◽  
Vol 14 (4) ◽  
pp. 1
Author(s):  
Diego Ferreira de Souza ◽  
Ronny Sobreira Barbosa ◽  
Yuri Jacques Agra Bezerra da Silva ◽  
Márcio Cleto Soares de Moura ◽  
Romário Porto de Oliveira ◽  
...  
Keyword(s):  
Organic Matter ◽  
Exchange Capacity ◽  
Low Ph ◽  
Parent Material ◽  
Soil Samples ◽  
Soil Profiles ◽  
Exchangeable Bases ◽  
Low Degree ◽  
Chemical Attributes ◽  
Physical And Chemical

This study characterized the morphological, physical and chemical attributes of sandstone-derived soils at the Cerrado of the Piauí State, Brazil, in order to identify evolutionary standards. The study was carried out with five representative soil profiles identified as P1-RY (Typical Flavic Psychotic Neosol - Aquents), P2-PA (Typical Dystrophic Yellow Argisol - Alfisol), P3-RL (Fragmentary Litholic Distrophic Neosol - Psammenit), P4-RQ (Typical Ortic Quartzenetic Neosol - Orthents) and P5-PV (Typical Dystrophic Red Argisol - Ultisol). Soil samples were submitted laboratory analysis described morphologically. In general, the soils presented high sand content, low pH, low content of exchangeable bases and low cation exchange capacity (CEC). Organic matter governed the CEC in most cases, suggesting dependence of organic matter in the supply of charges. These soils showed a low degree of weathering, but with iron of high crystallinity. Thus, the relief and the parent material are the major important soil-forming factors at the Cerrado of the Piauí State. Moreover, these soils are young, with the soils from the Piauí Formation being more evolved. However, the sandstones from the Canindé Group apparently are providing lithological secondary minerals for the soil.

ESTIMATION OF THE INORGANIC AND ORGANIC pH-DEPENDENT CATION EXCHANGE CAPACITY OF THE B HORIZONS OF PODZOLIC AND BRUNISOLIC SOILS

1968 ◽  
Vol 48 (1) ◽  
pp. 53-63 ◽  
Author(s):  
J. S. Clark ◽  
W. E. Nichol
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Acid Soils ◽  
Exchange Capacity ◽  
Hydrous Oxides ◽  
Before And After ◽  
Ph Dependent ◽  
The Difference ◽  
Wyoming Bentonite

Heating in hydrogen peroxide, dilute oxalic acid, and dilute aluminum oxalate did not change the effective cation exchange capacity (CEC) or the pH-7 CEC of Wyoming bentonite and Alberni clay soil containing excess Al(OH)x. This indicated that treatment of soils with H2O2 to oxidize organic matter and the possible production of oxalates during oxidation did not change the CEC values of the inorganic fraction of soils even if some clay exchange sites were blocked by hydrous oxides of Al.With soils of pH less than approximately 5.4, oxidation of organic matter did not change the effective CECs although the pH-7 CEC values were decreased. Thus, organic matter in acid soils appeared to have little or no effective CEC. Because of this and the negligible effect of H2O2 oxidation on the CEC values of clays, the difference of the pH-7 CEC of soils before and after H2O2 oxidation provided a simple means of estimating the amount of organic pH-dependent CEC in acid soils.The amount of organically derived pH-dependent CEC was determined in a number of soils by means of peroxide oxidation. The technique provided a useful indication of the quantities of sesquioxide–organic matter complexes accumulated in medium- and fine-textured soils.

Mineralogical, physical and chemical investigation of compacted Kunigel V1 bentonite in contact with a steel heater in the ABM test package 1 experiment, Äspö laboratory, Sweden

Clay Minerals ◽  
2017 ◽  
Vol 52 (1) ◽  
pp. 127-141 ◽  
Author(s):  
H. Sasamoto ◽  
T. Isogai ◽  
H. Kikuchi ◽  
H. Satoh ◽  
D. Svensson
Keyword(s):  
Exchange Capacity ◽  
Exchangeable Cations ◽  
Exchangeable Cation ◽  
Exchange Reactions ◽  
Swelling Properties ◽  
X Ray ◽  
Set Up ◽  
The Stability ◽  
High Level ◽  
Physical And Chemical

AbstractIn many countries, compacted bentonite is a candidate engineering barrier material for safe disposal of high-level radioactive waste. The Swedish Nuclear Fuel and Waste Management Company (SKB) set up an in situ experiment (the ABM project) to compare the stability of different bentonites under the conditions of exposure to an iron source and to elevated temperature (up to 130°C) at the Äspö Hard Rock Laboratory, Sweden. Results for the Japanese bentonite (Kunigel V1) are summarized in the present study.Mineralogical investigation using X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX) suggested no transformation of smectite or neoformed clay phases. However, a distinct change in exchangeable cations of smectite was indicated (i.e. from Na type to Fe type and/or Ca type) in the bentonite in the vicinity of the steel heater.Measurements of hydraulic conductivity and swelling properties suggest that no significant changes occurred in the bentonite even in the vicinity of the steel heater. This is attributed to the limited portion of the bentonite affected by the iron–bentonite interactions and the incomplete ion-exchange reactions. The methylene blue cation exchange capacity and the determination of the exchangeable cations showed that the lateral distribution for these parameters was constant. However, the total exchangeable cation population has changed significantly compared to the initial sample.

scholarly journals Impact of Cement Dust on Physical and Chemical Nutrients Properties of Forest Topsoil

2021 ◽  
Vol 25 (5) ◽  
pp. 695-700
Author(s):  
A.P. Adebiyi ◽  
H.O. Adigun ◽  
K.J. Lawal ◽  
K.D. Salami ◽  
V.A.L. Adekunle ◽  
...  
Keyword(s):  
Organic Matter ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Cement Dust ◽  
Sodium Calcium ◽  
Close Proximity ◽  
Calcium Magnesium ◽  
Magnesium Cation ◽  
Physical And Chemical ◽  
Nitrogen Phosphorus

: The study examined the impact of Cement dust on physical and chemical nutrients properties of forest topsoil in close proximity to a major private cement industry in Obajana, Kogi State, Nigeria using standard methods by collecting Topsoil samples for physical and chemical properties analyses which are particle size, moisture content, pH, carbon, nitrogen,phosphorus, potassium, sodium, calcium, magnesium, cation exchange capacity and organic matter.Data revealed a strong influence of the particulate pollutants on the forest topsoil in close proximity to the Cement factory. It was observed that the soil properties; moisture content and soil pH varied at distances away from the factory. The result showed that the Cement dust particles entering the soil increased the pH of the soil, it more alkaline. The highest pH (6.03) was observed from hundred and fifty meters sample indicating the highest particulate pollution. There were also variations in the other soil nutrient properties; carbon, nitrogen, phosphorus, potassium, sodium, calcium, magnesium, cation exchange capacity and organic matter arising from the effect of cement dust. High organic matter content was recorded in the location samples compared with the control sample. This is attributed to the addition of cement dust to the soils, resulting in improved organic-matter cycling and plant growth. The result also showed that the chemical properties; organic carbon (OC), organic matter (OM), phosphorus (P), potassium (K), sodium (Na), calcium (Ca) and magnesium (Mg) are significantly higher in the study areas than the control. The study therefore concludes that the emission of cement dust on the forest stands over the years was found to have significantly affected the topsoil properties.

Pronamide Phytotoxicity in Ten Wisconsin Soils

Weed Science ◽  
1980 ◽  
Vol 28 (4) ◽  
pp. 429-432 ◽  
Author(s):  
T. E. Dutt ◽  
R. G. Harvey
Keyword(s):  
Organic Matter ◽  
Chemical Properties ◽  
Clay Content ◽  
Exchange Capacity ◽  
Fresh Weight ◽  
Relationship Of ◽  
Physical And Chemical ◽  
Mg Content ◽  
The Relationship ◽  
And Chemical Properties

Pronamide [3,5-dichloro-(N-1, 1-dimethyl-2-propynyl) benzamide] phytotoxicity was compared in 10 Wisconsin soils and the relationship of activity to soil physical and chemical properties appraised. Twelve soil properties were measured and correlated with pronamide I50(50% fresh weight inhibition) values using oats (Avena sativaL. ‘Portal’) as the indicator plant in bioassays conducted under greenhouse conditions. Organic matter was the soil variable most inversely correlated with pronamide phytotoxicity. Cation exchange capacity, field moisture capacity, and Mg content were also inversely correlated with pronamide phytotoxicity, but probably reflect changes in soil organic matter levels. Clay content did not significantly affect pronamide phytotoxicity.

scholarly journals Temperature effects on carbon storage are controlled by soil stabilisation capacities

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Iain P. Hartley ◽  
Tim C. Hill ◽  
Sarah E. Chadburn ◽  
Gustaf Hugelius
Keyword(s):  
Critical Role ◽  
Exchange Capacity ◽  
System Model ◽  
Soil Profiles ◽  
Mean Annual Temperature ◽  
Soil C ◽  
C Storage ◽  
Soil Stabilisation ◽  
Mineral Soils ◽  
Physical And Chemical

AbstractPhysical and chemical stabilisation mechanisms are now known to play a critical role in controlling carbon (C) storage in mineral soils, leading to suggestions that climate warming-induced C losses may be lower than previously predicted. By analysing > 9,000 soil profiles, here we show that, overall, C storage declines strongly with mean annual temperature. However, the reduction in C storage with temperature was more than three times greater in coarse-textured soils, with limited capacities for stabilising organic matter, than in fine-textured soils with greater stabilisation capacities. This pattern was observed independently in cool and warm regions, and after accounting for potentially confounding factors (plant productivity, precipitation, aridity, cation exchange capacity, and pH). The results could not, however, be represented by an established Earth system model (ESM). We conclude that warming will promote substantial soil C losses, but ESMs may not be predicting these losses accurately or which stocks are most vulnerable.

The role of active fractions of soil organic matter in physical and chemical fertility of Ferrosols

Soil Research ◽  
1998 ◽  
Vol 36 (5) ◽  
pp. 809 ◽  
Author(s):  
M. J. Bell ◽  
P. W. Moody ◽  
R. D. Connolly ◽  
B. J. Bridge
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Management Practices ◽  
Chemical Properties ◽  
Aggregate Stability ◽  
Infiltration Rate ◽  
Exchange Capacity ◽  
Organic C ◽  
Wide Range ◽  
Physical And Chemical

The relationships between fractions of soil organic carbon (C) oxidised by varying strengths of potassium permanganate (KMnO4) and important soil physical and chemical properties were investigated for Queensland Ferrosols. These soils spanned a wide range of clay contents (31-83%), pH values (4·4-7·9; 1 : 5 water), and total C contents (12· 1-111 g/kg). Carbon fractions were derived by oxidation with 33 mM (C1), 167 mM (C2), and 333 mM (C3) KMnO4, while organic C and total C were determined by Heanes wet oxidation and combustion, respectively. Aggregate stability was determined by wet sieving soil from the surface crust after 30 min of high intensity (100 mm/h), simulated rainfall on disturbed samples in the laboratory. The proportion of aggregates <0·125 mm (P125) was used as the stability indicator because of the high correlation between this size class and the final rainfall infiltration rate (r2 = 0qa86, n = 42). The soil organic C fraction most closely correlated with P125 was C1 (r2 = 0·79, n = 42). This fraction was also highly correlated with final, steady-state infiltration rates in field situations where there were no subsurface constraints to infiltration (r2 = 0·74, n = 30). Multiple linear regression techniques were used to identify the soil properties determining effective cation exchange capacity (ECEC, n = 89). Most variation in ECEC (R2 = 0 ·72) was accounted for by a combination of C1 (P < 0·0001) and pH (P < 0·0001). These results confirm the very important role played by the most labile (easily oxidised) fraction of soil organic matter (C1) in key components of the chemical and physical fertility of Ferrosols. Management practices which maintain adequate C1 concentrations are essential for sustainable cropping on these soils.

Zinc Adsorption in Different Calcareous Soils

2020 ◽  
Vol 23 (2) ◽  
pp. 118-130
Author(s):  
Payizan Ihsan Ramadhan ◽  
Lazkeen Ahmed Merween Mehmedany
Keyword(s):  
Organic Matter ◽  
Calcium Carbonate ◽  
Calcareous Soils ◽  
Clay Content ◽  
Exchange Capacity ◽  
Ion Concentration ◽  
Available Phosphorus ◽  
The Difference ◽  
Physical And Chemical ◽  
Zinc Adsorption

Zinc adsorption was studied for ten selective representative soils according the difference amount of clay content, calcium carbonate and organic matter in Duhok governorate, Iraqi-Kurdistan region included (Kanimasi-1&2, Batofa, Zakho, Assih, Semeel, Khanke, Faydi, Zawita and Bamarny locations). Samples were air dried and sieved through a 2-mm sieve to study the physical and chemical characteristics of the soils, forms of zinc and it’s adsorption. Results showed the soluble, DTPA extractable zinc (available), CaCl2 extractable zinc (exchangeable) and total zinc ranged between (0.29 – 0.94), (0.88 – 1.64), (1.71 – 2.05), and (12.25 – 56.15) mg kg-1 respectively. Negative significant correlation found between soluble zinc with pH, also negative significant correlation found between DTPA extractable zinc with exchangeable potassium, bicarbonate and available phosphorus but positive significant correlation found between CaCl2 extractable zinc with pH, total–Zn negatively affected with pH and positively with HCO3 and sand. Results demonstrated that by increasing added zinc concentration to studied soil zinc will be adsorbed zinc adsorbed greatly at temperature 25°C and 48°C. In general total zinc adsorbed at 25C° in six concentrations was less than zinc adsorbed at 48C°. At temperatures 25°C and 48°C the high total amount of zinc adsorbed found in the soil of Zawita and Zakho respectively, but the lower total zinc adsorbed observed in soil of Batofa and Kani masi-2. The quantity of adsorption affected positively by presence of clay, calcium carbonate, active calcium carbonate and cation exchange capacity and negatively affected by the ion concentration of bicarbonate, calcium, potassium, organic matter and sand content.

scholarly journals Effects of land use changes on the dynamics of selected soil properties in northeast Wellega, Ethiopia

SOIL ◽  
2016 ◽  
Vol 2 (1) ◽  
pp. 63-70 ◽  
Author(s):  
Alemayehu Adugna ◽  
Assefa Abegaz
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Soil Properties ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Cultivated Land ◽  
Grazing Land ◽  
Physical And Chemical

Abstract. Land use change can have negative or positive effects on soil quality. Our objective was to assess the effects of land uses changes on the dynamics of selected soil physical and chemical properties. Soil samples were collected from three adjacent soil plots under different land uses, namely forestland, grazing land, and cultivated land at 0–15 cm depth. Changes in soil properties on cultivated and grazing land were computed and compared to forestland, and ANOVA (analysis of variance) was used to test the significance of the changes. Sand and silt proportions, soil organic content, total nitrogen content, acidity, cation exchange capacity, and exchangeable Ca2+ content were higher in forestlands. Exchangeable Mg2+ was highest in grazing land, while clay, available phosphorous, and exchangeable K+ were highest in cultivated land. The percentage changes in sand, clay, soil organic matter, cation exchange capacity, and exchangeable Ca2+ and Mg2+ were higher in cultivated land than in grazing land and forestland. In terms of the relation between soil properties, soil organic matter, total nitrogen, cation exchange capacity, and exchangeable Ca2+ were strongly positively correlated with most of soil properties, while available phosphorous and silt have no significant relationship with any of the other considered soil properties. Clay has a negative correlation with all soil properties. Generally, cultivated land has the least concentration of soil physical and chemical properties except clay and available phosphorous, which suggests an increasing degradation rate in soils of cultivated land. So as to increase soil organic matter and other nutrients in the soil of cultivated land, the integrated implementation of land management through compost, cover crops, manures, minimum tillage, crop rotation, and liming to decrease soil acidity are suggested.

Loss of soil organic matter following cultivation of long-term pasture: effects on major exchangeable cations and cation exchange capacity

Soil Research ◽  
2015 ◽  
Vol 53 (4) ◽  
pp. 377 ◽  
Author(s):  
D. Curtin ◽  
P. M. Fraser ◽  
M. H. Beare
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Crop Production ◽  
Exchange Capacity ◽  
Exchangeable Cations ◽  
Exchangeable Cation ◽  
C Stocks

Cultivation of grassland is known to lead to the depletion of soil organic matter (SOM), but the effect on the size and composition of the exchangeable cation suite has not been documented. We measured cation exchange capacity (CEC) and exchangeable cations (calcium, Ca; magnesium, Mg; potassium, K; sodium, Na), as well as soil carbon (C) and nitrogen (N) (0–7.5, 7.5–15, and 15–25 cm), 8 years after conversion of long-term ryegrass–white clover pasture (grazed by sheep) to annual crop production. The trial was near Lincoln, Canterbury, New Zealand. The trial included three tillage treatments: crops established using intensive cultivation (mouldboard ploughing), minimum tillage (shallow cultivation, ~10 cm), or no-tillage. The 8-year rotation was barley, wheat, pea, barley, pea, barley, barley, barley. A sheep-grazed pasture was maintained as an experimental control. The experiment also included a permanent fallow treatment (maintained plant-free using herbicides; not cultivated). After 8 years under arable cropping, soil C stocks (0–25 cm) were 10 t ha–1 less, on average, than under pasture. The vertical distribution of soil organic matter (SOM) was affected by tillage type, but the total amount of organic matter in the top 25 cm did not differ (P > 0.05) among the tillage treatments. Under permanent fallow (C loss of 13 t ha–1 relative to pasture), total exchangeable cation (Ca + Mg + K +Na) equivalents declined by 47 kmolc ha–1, a 20% decrease compared with pasture. Loss of exchange capacity resulted in the selective release of cations with lower affinity for SOM (K, Na, Mg). Smaller losses of exchangeable cations were recorded under the arable cropping rotation (average 31 kmolc ha–1), with no differences among tillage treatments. Effective CEC (at field pH) decreased under permanent fallow and cultivated treatments because of: (1) depletion of SOM (direct effect); and (2) soil acidification, which eliminated some of the remaining exchange sites (indirect effect). Acidification in the permanent fallow can be attributed to the N mineralisation process, whereas in the cropped systems, excess cation removal in harvested straw and grain accounted for about half of the measured acidification. There was evidence that the organic matter lost under arable cropping and fallow had lower CEC than SOM as a whole.

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