Diffusive and convective flow in a hydrogen-atom flow system
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Diffusive and convective flow was studied in a hydrogen-atom flow system using an isothermal calorimetric detector. By varying detector area, total pressure, and linear flow rate, the importance of axial diffusion in the system was investigated. Under conditions of predominantly diffusive flow, signal–distance plots were independent of flow rate. When convective flow predominated, concentration–time plots were independent of flow rate. The efficiency of a detector was clearly dependent on its surface area within wide limits, but diffusion gradients produced by the presence of even large detectors did not appear to be important.
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1982 ◽
Vol 44
(2)
◽
pp. 471-477
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