Antiferromagnetic exchange in manganese(II) monophenylphosphinate and the effects of cadmium doping

1989 ◽  
Vol 67 (7) ◽  
pp. 1239-1243 ◽  
Author(s):  
Jlng-Long Du ◽  
Robert C. Thompson
Keyword(s):  
Magnetic Susceptibility ◽  
Theoretical Models ◽  
Magnetic Data ◽  
Coupling Constant ◽  
Scanning Calorimetry ◽  
Manganese Compound ◽  
Linear Chains ◽  
Magnetic Chain ◽  
Metal Materials ◽  
Polymeric Structures

Mn[H(C6H5)PO2]2, its cadmium analogue, and mixed metal materials of composition Mn1−xCdx[H(C6H5)PO2]2 (x = 0.005, 0.01, 0.09, 0.27, and 0.47) have been synthesized and characterized by X-ray powder diffraction, infrared spectroscopy, differential scanning calorimetry and low-temperature (4.2 to 80 K) magnetic susceptibility studies. The materials are shown to be isomorphous and are considered to have polymeric structures in which chains of metal atoms are linked by bridging phosphinate groups. The pure manganese compound is antiferromagnetic (maximum in xm at ~35 K) and the magnetic data for the compound have been analyzed according to two theoretical models for linear chains of antiferromagnetically coupled manganese(II) (d5, spin-free) ions. The Wagner and Friedberg model gives J = −3.00 cm−1 and the Weng model gives J = −2.78 cm−1. The effects of replacing Mn2+ by Cd2+ ions in the polymer is to increase the magnetic susceptibility (per mol of Mn) at all temperatures. Analysis of the data as a function of Cd doping indicates the incorporation of a paramagnetic component to the susceptibility which increases with increasing Cd content. In addition, the absolute value of the exchange coupling constant appears to decrease as the Cd content increases. These effects are considered in terms of a random defect model in which the replacement of Mn ions in the polymer by Cd ions results in the formation of Cd ion separated finite magnetic chain fragments. Keywords: manganese(II) monophenylphosphinate, magnetic properties, coordination polymer, cadmium doped antiferromagnet.

Magnetic concentration and polymorphism in di-n-octyl-, di-n-decyl-, and di-n-dodecylphosphinates of copper(II)

1985 ◽  
Vol 63 (5) ◽  
pp. 1111-1117 ◽  
Author(s):  
John S. Haynes ◽  
Katherine W. Oliver ◽  
Robert C. Thompson
Keyword(s):  
Differential Scanning Calorimetry ◽  
Magnetic Susceptibility ◽  
Heisenberg Model ◽  
Variable Temperature ◽  
Electronic Spectroscopy ◽  
Chain Structure ◽  
Magnetic Data ◽  
Scanning Calorimetry ◽  
Extended Chain ◽  
Linear Chains

Phosphinates of copper(II) of the type Cu(R2PO2)2 where R is n-octyl, n-decyl, and n-dodecyl have been synthesized and characterized by differential scanning calorimetry, vibrational and electronic spectroscopy, and variable temperature (300 to 4.2 K) magnetic susceptibility studies. Each of these compounds was obtained in distinct α and β structural forms. All materials appear to have the double phosphinate bridged extended chain structure and the magnetic data have been successfully analyzed according to the isotropic Heisenberg model for linear chains. The α forms exhibit antiferromagnetic behaviour with J values of −25, −29, and −29 cm−1 for the octyl, decyl, and dodecyl derivatives respectively. The β forms are ferromagnetic and have corresponding J values of 1.8, 2.1, and 2.3 cm−1 respectively. Magneto-structural correlations in these extended chain coordination polymers are discussed.

Magnetic chains formed from tetra-coordinate Co(II) complexes

2013 ◽  
Vol 67 (3) ◽  
Author(s):  
Monika Idešicová ◽  
Alžbeta Krutošíková ◽  
Viera Mrázová ◽  
Roman Boča
Keyword(s):  
Magnetic Susceptibility ◽  
Low Temperature ◽  
Exchange Interaction ◽  
Exchange Coupling ◽  
Magnetic Interaction ◽  
Donor Ligands ◽  
Coupling Constant ◽  
Exchange Coupling Constant ◽  
Π Stacking ◽  
Magnetic Chain

AbstractTwo tetra-coordinate Co(II) complexes, [CoCl2(bzfupy)2] and [CoCl2(p-tol)2] with N-donor ligands, are apparently mononuclear systems. The magnetic susceptibility at low temperature attains a maximum which is a fingerprint of the exchange interaction. The exchange coupling constant fitted to a model of 1D-magnetic chain yields J/hc = −0.50 cm−1 and −0.57 cm−1, respectively. The magnetic interaction is mediated by the π-π stacking in the first complex, and the short Cl…Cl contacts in the second.

Metal pyrazolate polymers. Part 2. Synthesis, structure, and magnetic properties of [Cu(4-Xpz)2]x polymers (where X = Cl, Br, Me, H; pz = pyrazolate)

1991 ◽  
Vol 69 (3) ◽  
pp. 432-439 ◽  
Author(s):  
Martin K. Ehlert ◽  
Steven J. Rettig ◽  
Alan Storr ◽  
Robert C. Thompson ◽  
James Trotter
Keyword(s):  
Exchange Coupling ◽  
Structural Parameters ◽  
Magnetic Data ◽  
Antiferromagnetic Exchange ◽  
Coupling Constant ◽  
Orthorhombic Space Group ◽  
Magnetic Exchange ◽  
Linear Chains ◽  
Green Form ◽  
Reliable Methods

Novel and reliable methods for the synthesis of the polymers [Cu(4-Xpz)2]x (where X = H, Cl, Br, and Me; pz = pyrazolate) are presented. The X = Cl compound was obtained as green and brown forms. Single crystals of the polymers with X = Me and X = Cl (green form) suitable for X-ray analysis have been obtained. [Cu(4-Mepz)2]x and [Cu(4-Clpz)2]x are isomorphous, crystallizing with four formula units per unit-cell in the orthorhombic space group Ibam, a = 9.7436(6), 9.155(4), b = 12.6106(8), 12.968(6), and c = 7.7482(6), 7.717(5) Å, respectively, for the 4-Me and 4-Cl derivatives. The structures were refined by full-matrix least-squares procedures to R = 0.027 and 0.041 for 430 and 246 reflections with I ≥ 3σ(I), respectively. Magnetic susceptibility studies over the temperature range 2 to 300 K have revealed that all the polymers exhibit very strong antiferromagnetic exchange between copper(II) centres in the extended linear chains. Discontinuities displayed in the susceptibility versus temperature plots suggest the presence of phase transitions at ~133 and ~108 K in the X = Cl (green form) and X = Br materials, respectively. The four compounds, X = H, Br, Me, and Cl (green form) also exhibit thermochromism over the 77 to 176 K region. The magnetic data have been analyzed employing an isotropic Heisenberg model for antiferromagnetic exchange in extended chain polymers. Values of the exchange coupling constant, J, for the room temperature forms of these materials are determined as −81, −105, −96, −104, and −88 cm−1 for 4-X = H, Br, Me, Cl (green form), and Cl (brown form), respectively. The magnitude of the exchange coupling is discussed in relation to structural parameters for the X = H, Me, and Cl (green form) compounds. Key words: copper(II) 4-substituted pyrazolate polymers, crystal structures, magnetic exchange.

Metal pyrazolate polymers. Part 3. Synthesis and study of Cu(I) and Cu(II) complexes of 4-Xdmpz (where X = H, Cl, Br, I, and CH3 for Cu(I) and X = H, Cl, Br, and CH3 for Cu(II); dmpz = 3,5-dimethylpyrazolate)

1992 ◽  
Vol 70 (4) ◽  
pp. 1121-1128 ◽  
Author(s):  
Martin K. Ehlert ◽  
Alan Storr ◽  
Robert C. Thompson
Keyword(s):  
Magnetic Susceptibility ◽  
Spectroscopic Studies ◽  
Magnetic Data ◽  
Antiferromagnetic Coupling ◽  
Polymeric Chain ◽  
Differential Scanning Calorimetric ◽  
Scanning Electron Micrographs ◽  
Coupling Constant ◽  
Abrupt Decrease ◽  
Calorimetric Studies

The copper(I) complexes [Cu(4-Xdmpz)]3 (where X = H, Cl, Br, I and CH3; dmpz = 3,5-dimethylpyrazolate) and the copper(II) complexes [Cu(4-Xdmpz)2]x have been synthesized and characterized. Qualitative solubility, infrared spectroscopic, and differential scanning calorimetric studies are reported for all complexes. Mass spectra support trimeric formulations for the copper(I) complexes. Scanning electron micrographs and powder X-ray diffractograms have been recorded for the copper(II) compounds. Electronic and EPR spectroscopic studies as well as magnetic susceptibility studies from 2 to 300 K are also reported for the copper(II) compounds, which are proposed to have polymeric chain structures. The magnetic data reveal strong antiferromagnetic interactions in all four of the copper(II) compounds. The data have been analysed employing an isotropic Heisenberg model for antiferromagnetic coupling in extended chain polymers. Values of the exchange coupling constant, J, are determined as −58, −61, −66, and −66 cm−1 for the X = H, CH3, Cl, and Br complexes respectively. The X = Cl compound exhibits an abrupt decrease in magnetic susceptibility below 40 K and possible causes of this anomalous behaviour are discussed.

An Augmented Iteratively Re-weighted and Refined Least Squares Method for lp Minimization Problem in Inverse Modeling of Potential Field Magnetic Data

2020 ◽  
Vol 1 (3) ◽  
Author(s):  
Maysam Abedi
Keyword(s):  
Magnetic Field ◽  
Magnetic Susceptibility ◽  
Least Squares ◽  
Minimization Problem ◽  
Potential Field ◽  
Field Data ◽  
Least Squares Method ◽  
Porphyry Copper ◽  
Magnetic Data ◽  
Magnetic Field Data

The presented work examines application of an Augmented Iteratively Re-weighted and Refined Least Squares method (AIRRLS) to construct a 3D magnetic susceptibility property from potential field magnetic anomalies. This algorithm replaces an lp minimization problem by a sequence of weighted linear systems in which the retrieved magnetic susceptibility model is successively converged to an optimum solution, while the regularization parameter is the stopping iteration numbers. To avoid the natural tendency of causative magnetic sources to concentrate at shallow depth, a prior depth weighting function is incorporated in the original formulation of the objective function. The speed of lp minimization problem is increased by inserting a pre-conditioner conjugate gradient method (PCCG) to solve the central system of equation in cases of large scale magnetic field data. It is assumed that there is no remanent magnetization since this study focuses on inversion of a geological structure with low magnetic susceptibility property. The method is applied on a multi-source noise-corrupted synthetic magnetic field data to demonstrate its suitability for 3D inversion, and then is applied to a real data pertaining to a geologically plausible porphyry copper unit.  The real case study located in  Semnan province of  Iran  consists  of  an arc-shaped  porphyry  andesite  covered  by  sedimentary  units  which  may  have  potential  of  mineral  occurrences, especially  porphyry copper. It is demonstrated that such structure extends down at depth, and consequently exploratory drilling is highly recommended for acquiring more pieces of information about its potential for ore-bearing mineralization.

Magnetic Susceptibilities of 2T2 Ions. Part 1

1972 ◽  
Vol 50 (10) ◽  
pp. 1468-1471 ◽  
Author(s):  
Alan D. Westland
Keyword(s):  
Magnetic Susceptibility ◽  
Excited State ◽  
Reduction Factor ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Coupling Constant ◽  
Magnetic Susceptibilities

An expression for the magnetic susceptibility of octahedral d1 complexes is derived exactly in terms of an orbital reduction factor k taking into account the presence of the formal 2E excited state. Sample calculations show that the improved expression gives results for susceptibility which are lower at times by several percent from those given by previous expressions. The results given by Figgis using Kotani's method are adequately precise when the spin–orbit coupling constant is no larger than ~0.1 Dq.

ESTIMATION OF SOURCE PARAMETERS IN IBADAN, SOUTH – WESTERN NIGERIA USING DIGITIZED AEROMAGNETIC DATA

2018 ◽  
Vol 14 (2) ◽  
pp. 15-28
Author(s):  
A A ALABI ◽  
O OLOWOFELA
Keyword(s):  
Magnetic Susceptibility ◽  
Source Parameters ◽  
Granite Gneiss ◽  
Geological Structure ◽  
Magnetic Data ◽  
Susceptibility Map ◽  
Rock Types ◽  
Upward Continuation ◽  
Magnetic Basement ◽  
Local Wavenumber

Airborne magnetic data covering geographical latitudes of 7000‟N to 7030‟N and longitudes of 3 30′E to 4 00′E within Ibadan area were obtained from Nigeria Geology Survey Agency. The data were ana-lyzed to map the sub surface structure and the source parameters were deduced from the quantitative and qualitative interpretation of magnetic data. The upward continuation technique was used to de-emphasize short – wavelength anomaly while the depth to magnetic sources in the area was deter-mined using local wavenumber technique, the analytic signal was also employed to obtain the depths of the magnetic basement. Analysis involving the local wavenumber, upward continuation and appar-ent magnetic susceptibility techniques significantly improves the interpretation of magnetic data in terms of delineating the geological structure, source parameter and magnetic susceptibility within Iba-dan area.. These depth ranges from 0.607km to 2.48km. The apparent susceptibility map at the cut-off wavelength of 50 m ranges from -0.00012 to 0.00079 which agree with the susceptibility value of some rock types; granite gneiss, migmatite biotite gneiss, biotite muscovite granite, hornblende granite, quartz and schists. The result of the local wavenumber suggests variation along the profiles in the surface of magnetic basement across the study area.

Classifying Copper-Molybdenum-Gold Porphyry Deposit Alteration using Magnetic and Spectral data

2021 ◽  
Author(s):  
Oliver Dixon ◽  
William McCarthy ◽  
Nasser Madani ◽  
Michael Petronis ◽  
Steve McRobbie ◽  
...  
Keyword(s):  
Machine Learning ◽  
Magnetic Susceptibility ◽  
Spectral Data ◽  
Learning Algorithm ◽  
Copper Production ◽  
Magnetic Data ◽  
Machine Learning Algorithm ◽  
Porphyry Deposit ◽  
Remanent Magnetisation ◽  
Magnetic Remanence

<p>Copper is one of the most important critical metal resources needed to achieve carbon neutrality with a projected increase in demand of >300% over the next half century from electronics and renewables.  Porphyry deposits account for most of the global copper production, but the discovery of new reserves is ever more challenging. Machine learning presents an opportunity to cross reference new and traditionally under-utilised data sets with a view to developing quantitative predictive models of hydrothermal alteration zones to guide new, ambitious exploration programs.</p><p>The aim of this study is to demonstrate a new alteration classification scheme driven by quantitative magnetic and spectral data to feed a machine learning algorithm. The benefits of an alteration model based on quantitative data rather than subjective observations by geologists, are that there is no bias in the data collected, the arising model is quantifiable and therefore easy to model and the process be fully automated. Ultimately, this approach aids more detailed exploration and mine modelling, in turn, reducing the extraction process carbon footprint and more effectively identifying new deposits.</p><p>Presented here are magnetic susceptibility and shortwave infrared (SWIR) data collected from the KazMinerals plc. owned Aktogay Cu-Mo giant porphyry deposit, eastern Kazakhstan, which has a throughput of 30Mtpa of ore. These data are cross referenced using a newly developed machine learning algorithm. Generated autonomously, our results reveal twelve statistically and geologically significant clusters that define a new alteration classification for porphyry style mineralisation. Results are entirely non-subjective, reproducible, quantitative and modellable.</p><p>Importantly, magnetic susceptibility measurements improve the algorithm’s ability to identify clusters by between 29-36%; enhancing the sophistication of the included magnetic data promises to yield substantially better statistical results. Magnetic remanence data are therefore being complied on representative samples from each of the twelve identified clusters, including hysteresis, isothermal remanent magnetisation (IRM) acquisition, FORC measurements, natural remanent magnetisation (NRM) and anhysteretic remanent magnetisation (ARM). Through collaboration with industry partners, we aim to develop an automated means of collecting these magnetic remanence data to accompany the machine learning algorithm.</p>

Linking cave sediments and soil magnetism in the Urșilor cave (Romania)

2021 ◽  
Author(s):  
Cristian George Panaiotu ◽  
Cristian Necula ◽  
Relu D. Roban ◽  
Alexandru Petculescu ◽  
Ionut-Cornel Mirea ◽  
...  
Keyword(s):  
Magnetic Susceptibility ◽  
Frequency Dependence ◽  
Remanent Magnetization ◽  
Rock Magnetism ◽  
Magnetic Mineral ◽  
Magnetic Data ◽  
Sediment Samples ◽  
Superparamagnetic Particles ◽  
Susceptibility Data ◽  
Cave Sediments

<p>Cyclical changes in the magnetic mineral assemblages have been observed in numerous sedimentary records confirming the relationship between rock magnetism and past global change. Several studies have shown that the magnetic susceptibility data of cave sediments reflect both long- and short-term climatic oscillations. These magnetic susceptibility variations are attributed to changes in climate-controlled pedogenesis which influence the production of low coercivity magnetic mineral phases, magnetite, and maghemite outside the cave. These soils with climate-dependent magnetic properties are then washed, blown, or tracked into the cave where they accumulate, creating the changes observed in rock magnetic data. We present a rockmagnetism study of the sediments from the Urșilor cave and the soils above the cave. Our focus is the detailed characterization of the ferromagnetic mineralogy preserved in the cave sediments and its links with potential soil sources. In the cave, we sampled four sections (2-3 m high) consisting mainly of silts and clays, with some sand layers. The age of the sediments is older than 40 ka. At the surface, we sampled various types of soils from 9 sites. For all samples, we measured: variation of magnetic susceptibility with frequency (976 and 15616 Hz), the anisotropy of magnetic susceptibility, isothermal remanent magnetization, and anhysteretic remanent magnetization. Because soils are characterized by the presence of superparamagnetic magnetite produced by pedogenesis which can be detected by the frequency dependence of magnetic susceptibility, we also measured the frequency dependence of soils and selected cave sediment samples at 13 frequencies (between 128 and 512000 Hz). Multi-frequencies measurements of the magnetic susceptibility of recent soils show that all the sampled soils have a strong frequency dependence indicating the presence of superparamagnetic particles produced by pedogenesis. Most of the sediment samples have an important frequency dependence similar to the one observed in the recent soils. As a preliminary conclusion, we can state that most of the fine cave sediments contain superparamagnetic particles, which can be probably attributed to soils transported into the cave by erosion. These results suggest that during the deposition of high magnetic susceptibility sediments it was a climate favorable for intense pedogenesis. The interpretation of the intervals with lower values of magnetic susceptibility is still under investigation to decide if represents a climatic signal or a change in the dynamics of sediment transport. <strong>Acknowledgment:</strong> The research leading to these results has received funding from the EEA Grants 2014-2021, under Project contract no. EEA-RO-NO-2018-0126.</p>

scholarly journals Extended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benzene (DITFB) Halogen Bond Donors

Crystals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 319 ◽  
Author(s):  
Xin Ding ◽  
Matti Tuikka ◽  
Kari Rissanen ◽  
Matti Haukka
Keyword(s):  
Carbonyl Compounds ◽  
Halogen Bond ◽  
Halogen Bonding ◽  
Single Chain ◽  
Linear Arrangement ◽  
Linear Chains ◽  
Ruthenium Carbonyl ◽  
Polymeric Assemblies ◽  
Polymeric Structures ◽  
Iodine Complexes

The ruthenium carbonyl compounds, Ru(bpy)(CO)2X2 (X = Cl, Br or I) act as neutral halogen bond (XB) acceptors when co-crystallized with 1,4-diiodotetrafluoro-benzene (DITFB). The halogen bonding strength of the Ru-X⋅⋅⋅I halogen bonds follow the nucleophilic character of the halido ligand. The strongest halogen bond occurs between the chlorido ligand and the iodide atoms of the DITFB. All three halogen bonded complexes form polymeric assemblies in the solid state. In Ru(bpy)(CO)2Cl2⋅DITFB (1) and in Ru(bpy)(CO)2Br2⋅DITFB (2) both halido ligands are halogen bonded to only one DITFB donor. In Ru(bpy)(CO)2I2⋅DITFB (3) only one of the halido ligands is involved in halogen bonding acting as ditopic center for two DITFB donors. The polymeric structures of 1 and 2 are isomorphic wave-like single chain systems, while the iodine complexes form pairs of linear chains attached together with weak F⋅⋅⋅O≡C interactions between the closest neighbors. The stronger polarization of the iodide ligand compared to the Cl or Br ligands favors nearly linear C-I⋅⋅⋅I angles between the XB donor and the metal complex supporting the linear arrangement of the halogen bonded chain.

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