Photoconductive behavior of binary porphyrin crystalline assemblies

2017 ◽  
Vol 21 (09) ◽  
pp. 569-580 ◽  
Author(s):  
Bryan Borders ◽  
Morteza Adinehnia ◽  
Naomi Rosenkrantz ◽  
Marshall van Zijll ◽  
K. W. Hipps ◽  
...  
Keyword(s):  
Laser Light ◽  
Soret Band ◽  
Charge Carriers ◽  
Water Molecules ◽  
Persistent Photoconductivity ◽  
Temperature Dependent ◽  
Recombination Mechanism ◽  
Laser Illumination ◽  
Proposed Model ◽  
Illumination Wavelength

The mechanism of photoconductivity in a crystalline photoconductor synthesized from 1:1 ratio of meso-tetra(4-pyridyl)porphyrin (TPyP) and meso-tetra(4-sulfonatophenyl)porphyrin (TSPP) ionic tectons was examined. The rod-like crystals of TPyP:TSPP insulate in the dark but become photoconducting on illumination and a portion of the photoinduced current persists after the laser light is turned off. This persistent photoconductivity (PPC) is investigated as a function of laser illumination wavelength, laser power, and sample temperature. The primary charge carriers in the TPyP:TSPP upon photoexcitation are electrons and the charge recombination mechanism follows monomolecular kinetics. The number of electrons contributing to the photocurrent is directly proportional to the number of photons absorbed thus, the mechanisms of the photoconductivity resulting from excitations within the Soret band and the Q-band are the same. The PPC is interpreted to be the result of the formation of photoinduced metastable defects that allow for Miller–Abrahams-like hopping conductivity. The TPyP:TSPP has an incommensurately modulated crystal lattice and its proposed model structure is based on both ionic and neutral porphyrin tectons. The thermogravimetric analysis shows that the porphyrin crystals undergo dehydration on heating (˜50 ∘C) by losing water molecules located in the crystalline channels. Temperature dependent XRD indicates that dehydration causes irreversible changes to the crystal structure. The loss of crystallinity observed with heating the TPyP:TSPP crystals above 90 ∘C causes approximately 25% loss in photoconductivity but has little effect on the lifetime associated with the persistent photoconductivity.

Persistent Photoconductivity And Thermal Recovery Kinetics Of Low Energy Ar + Bombarded GaAs

1991 ◽  
Vol 223 ◽  
Author(s):  
A. Vaseashta ◽  
L. C. Burton
Keyword(s):  
Deep Level Transient Spectroscopy ◽  
Deep Level ◽  
Thermal Recovery ◽  
Low Energy ◽  
Persistent Photoconductivity ◽  
Transport Parameters ◽  
Excellent Correlation ◽  
Proposed Model ◽  
Transient Spectroscopy ◽  
Kinetics Of

ABSTRACTKinetics of persistent photoconductivity, photoquenching, and thermal and optical recovery observed in low energy Ar+ bombarded on (100) GaAs surfaces have been investigated. Rate and transport equations for these processes were derived and simulated employing transport parameters, trap locations and densities determined by deep level transient spectroscopy. Excellent correlation was obtained between the results of preliminary simulation and the experimentally observed values. The exponential decay of persistent photoconductivity response curve was determined to be due to metastable electron traps with longer lifetime and is consistent with an earlier proposed model.

scholarly journals Hyaluronan orders water molecules in its nanoscale extended hydration shells

2021 ◽  
Vol 7 (10) ◽  
pp. eabf2558
Author(s):  
J. Dedic ◽  
H. I. Okur ◽  
S. Roke
Keyword(s):  
Second Harmonic ◽  
Hydration Shell ◽  
Water Molecules ◽  
Temperature Dependent ◽  
Flexible Chain ◽  
Optical Modeling ◽  
Hydration Shells ◽  
Second Harmonic Scattering ◽  
Nuclear Quantum Effects ◽  
Extracellular Environment

Hyaluronan (HA) is an anionic, highly hydrated bio-polyelectrolyte found in the extracellular environment, like the synovial fluid between joints. We explore the extended hydration shell structure of HA in water using femtosecond elastic second-harmonic scattering (fs-ESHS). HA enhances orientational water-water correlations. Angle-resolved fs-ESHS measurements and nonlinear optical modeling show that HA behaves like a flexible chain surrounded by extended shells of orientationally correlated water. We describe several ways to determine the concentration-dependent size and shape of a polyelectrolyte in water, using the amount of water oriented by the polyelectrolyte charges as a contrast agent. The spatial extent of the hydration shell is determined via temperature-dependent measurements and can reach up to 475 nm, corresponding to a length of 1600 water molecules. A strong isotope effect, stemming from nuclear quantum effects, is observed when light water (H2O) is replaced by heavy water (D2O), amounting to a factor of 4.3 in the scattered SH intensity.

scholarly journals Solid-Phase “Self-Hydrolysis” of [Zn(NH3)4MoO4@2H2O] Involving Enclathrated Water—An Easy Route to a Layered Basic Ammonium Zinc Molybdate Coordination Polymer

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 4022
Author(s):  
Kende Attila Béres ◽  
István E. Sajó ◽  
György Lendvay ◽  
László Trif ◽  
Vladimir M. Petruševski ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Solid Phase ◽  
Water Molecules ◽  
Temperature Dependent ◽  
Dynamic Interactions ◽  
Ammonia Release ◽  
Successive Substitution ◽  
Red Dye ◽  
Hydrolysis Of ◽  
Zinc Molybdate

An aerial humidity-induced solid-phase hydrolytic transformation of the [Zn(NH3)4]MoO4@2H2O (compound 1@2H2O) with the formation of [(NH4)xH(1−x)Zn(OH)(MoO4)]n (x = 0.92–0.94) coordination polymer (formally NH4Zn(OH)MoO4, compound 2) is described. Based on the isostructural relationship, the powder XRD indicates that the crystal lattice of compound 1@2H2O contains a hydrogen-bonded network of tetraamminezinc (2+) and molybdate (2−) ions, and there are cavities (O4N4(μ-H12) cube) occupied by the two water molecules, which stabilize the crystal structure. Several observations indicate that the water molecules have no fixed positions in the lattice voids; instead, the cavity provides a neighborhood similar to those in clathrates. The @ symbol in the notation is intended to emphasize that the H2O in this compound is enclathrated rather than being water of crystallization. Yet, signs of temperature-dependent dynamic interactions with the wall of the cages can be detected, and 1@2H2O easily releases its water content even on standing and yields compound 2. Surprisingly, hydrolysis products of 1 were observed even in the absence of aerial humidity, which suggests a unique solid-phase quasi-intramolecular hydrolysis. A mechanism involving successive substitution of the ammonia ligands by water molecules and ammonia release is proposed. An ESR study of the Cu-doped compound 2 (2#dotCu) showed that this complex consists of two different Cu2+(Zn2+) environments in the polymeric structure. Thermal decomposition of compounds 1 and 2 results in ZnMoO4 with similar specific surface area and morphology. The ZnMoO4 samples prepared from compounds 1 and 2 and compound 2 in itself are active photocatalysts in the degradation of Congo Red dye. IR, Raman, and UV studies on compounds 1@2H2O and 2 are discussed in detail.

scholarly journals A General Temperature-Dependent Stress–Strain Constitutive Model for Polymer-Bonded Composite Materials

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1393
Author(s):  
Xiaochang Duan ◽  
Hongwei Yuan ◽  
Wei Tang ◽  
Jingjing He ◽  
Xuefei Guan
Keyword(s):  
Composite Materials ◽  
Constitutive Model ◽  
Model Parameters ◽  
Temperature Dependent ◽  
Stress Strain ◽  
Proposed Model ◽  
Single Temperature ◽  
Testing Data ◽  
Bonded Composite ◽  
Tension And Compression

This study develops a general temperature-dependent stress–strain constitutive model for polymer-bonded composite materials, allowing for the prediction of deformation behaviors under tension and compression in the testing temperature range. Laboratory testing of the material specimens in uniaxial tension and compression at multiple temperatures ranging from −40 ∘C to 75 ∘C is performed. The testing data reveal that the stress–strain response can be divided into two general regimes, namely, a short elastic part followed by the plastic part; therefore, the Ramberg–Osgood relationship is proposed to build the stress–strain constitutive model at a single temperature. By correlating the model parameters with the corresponding temperature using a response surface, a general temperature-dependent stress–strain constitutive model is established. The effectiveness and accuracy of the proposed model are validated using several independent sets of testing data and third-party data. The performance of the proposed model is compared with an existing reference model. The validation and comparison results show that the proposed model has a lower number of parameters and yields smaller relative errors. The proposed constitutive model is further implemented as a user material routine in a finite element package. A simple structural example using the developed user material is presented and its accuracy is verified.

Thermomechanical Model of Spot Welding for Calculating Residual Stresses

2003 ◽  
Author(s):  
Lijun Xu ◽  
Jamil A. Khan
Keyword(s):  
Residual Stresses ◽  
Heat Generation ◽  
Spot Welding ◽  
Welding Process ◽  
Mechanical Analysis ◽  
Temperature Dependent ◽  
Thermomechanical Model ◽  
Faying Surface ◽  
Proposed Model ◽  
Electrode Interface

A comprehensive axisymmetric model of the coupled thermal-electrical-mechanical analysis predicting weld nugget development and residual stresses for the resistance spot welding process of Al-alloys is developed. The model estimates the heat generation at the faying surface, the workpiece-electrode interface, and the Joule heating of the workpiece and electrode. The phase change due to melting in the weld pool is considered. The contact area and its pressure distribution at both the faying surface and the electrode-workpiece interface are determined from a coupled thermal-mechanical model using a finite element method. The knowledge of the interface pressure provides accurate prediction of the interfacial heat generation. For the numerical model, temperature dependent thermal, electrical and mechanical properties are used. The proposed model can successfidly calculate the nugget diameter and thickness, and predict the residual stresses and the elastic-plastic deformation history. The calculated nugget shape and the deformation of sheets based on the model are compared with the experimental data. The computed residual stresses approach the distribution of experimental measurement of the residual stress.

scholarly journals Charge Carriers Relaxation Behavior of Cellulose Polymer Insulation Used in Oil Immersed Bushing

Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 336
Author(s):  
Yu Shang ◽  
Qiang Liu ◽  
Chen Mao ◽  
Sen Wang ◽  
Fan Wang ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Moisture Content ◽  
Charge Carriers ◽  
Dynamics Simulation ◽  
Water Molecules ◽  
Stable Operation ◽  
Polarization Current ◽  
Depolarization Current ◽  
Moisture Condition ◽  
Dc Voltage

Cellulose insulation polymer material is widely used in oil immersed bushing. Moisture is one of the important reasons for the deterioration of cellulose polymer insulation, which seriously threatens the safe and stable operation of bushing. It is significant to study the polarization and depolarization behavior of oil-immersed cellulose polymer insulation with different moisture condition under higher voltage. Based on polarization/depolarization current method and charge difference method, the polarization/depolarization current, interfacial polarization current and electrical conductivity of cellulose polymer under different DC voltages and humidity were obtained. Based on molecular-dynamics simulation, the effect of moisture on cellulose polymer insulation was analyzed. The results show that the polarization and depolarization currents become larger with the increase in DC voltage and moisture. The higher applied voltage will accelerate the charge carrier motion. The ionization of water molecules will produce more charge carriers. Thus, high DC voltage and moisture content will increase the interface polarization current. Increased moisture content results in more charge carriers ionized by water molecules. In addition, the invasion of moisture will reduce the band width of cellulose polymer and enhance its electrostatic potential, so as to improve its overall electrical conductivity. This paper provides a reference for analyzing the polarization characteristics of charge carriers in cellulose polymer insulation.

On the time delay of the photoplastic effect

1986 ◽  
Vol 1 (1) ◽  
pp. 3-6 ◽  
Author(s):  
Joseph Pellegrino ◽  
J. M. Galligan
Keyword(s):  
Time Delay ◽  
Temperature Dependence ◽  
Cadmium Telluride ◽  
Deformation Temperature ◽  
Mercury Cadmium Telluride ◽  
Charge Carriers ◽  
Temperature Dependent ◽  
Simple Analysis ◽  
Photoplastic Effect

Photoplasticity in mercury cadmium telluride, Hg1-x Cdx Te with x = 0.3, has been studied as a function of light frequency and deformation temperature. We show that there is an easily measurable time delay accompanying irradiation of the crystal and the change in stress. This time delay is temperature dependent, suggesting a diffusion of charge carriers, introduced by the light, to the interior of the crystal. A simple analysis is given of the observed temperature dependence that is consistent with the experiments.

Electrical Resistivity and Magnetoresistance of the δ-FeZn10 Complex Intermetallic Phase

2013 ◽  
Vol 1517 ◽  
Author(s):  
P. Koželj ◽  
S. Jazbec ◽  
J. Dolinšek
Keyword(s):  
Electrical Resistivity ◽  
Intermetallic Phase ◽  
Structural Complexity ◽  
Weak Localization ◽  
Intrinsic Disorder ◽  
Atomic Clusters ◽  
Charge Carriers ◽  
Temperature Dependent ◽  
Temperature Dependent Resistivity ◽  
Complex Metallic Alloys

ABSTRACTThe δ-FeZn10 phase possesses high structural complexity typical of complex metallic alloys: a giant unit cell comprising 556 atoms, polyhedral atomic order with icosahedrally-coordinated environments, fractionally occupied lattice sites and statistically disordered atomic clusters that introduce intrinsic disorder into the structure. The electrical resistivity is large and exhibits a maximum at about 220 K. The magnetoresistance is sizeable, amounting to 1.5 % at 2 K in 9 T field. The temperature–dependent resistivity is discussed within the frame of the theory of slow charge carriers, applicable to metallic systems with weak dispersion of the electronic bands, where the electron motion changes from ballistic to diffusive upon heating. A comparison to the theory of weak localization is also made.

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